羌塘盆地中央隆起带南侧隆额尼-昂达尔错古油藏白云岩地球化学特征及成因意义

以系统的岩石学及沉积相分析为基础,深入探讨了隆额尼-昂迭尔错古油藏白云岩及其伴生灰岩的地球化学特征,认为该区白云岩化作用主要集中在古地理相对高点的潮上高能带、潮坪环境及台地边缘藻丘礁三个沉积相带内,白云岩及伴生灰岩在地球化学特征方面表现出近岸及淡水作用的深刻影响,和前人关于混合水白云岩化作用气候和古地理条件的基本论断是一致的.淡水作用依据主要体现在:①白云岩及伴生灰岩中不溶残渣特征表现为潮湿的古气候环境;②与白云岩伴生灰岩中Sr、Na含量与美国密苏里、田纳西等地淡水成因灰岩Sr、Na含量十分相近;③灰岩及白云岩中微量元素B含量及Sr/Ba指数、Sr/Ca指数,常量元素中m、Fe/Mn指数均反映出该区碳酸盐岩形成于近岸的碳酸盐台地环境,灰岩及白云岩均曾受到淡水的深刻作用和影响.该区白云岩过程中除Sr有明显的带出现象,Na、K有明显带入现象,大部分元素仍保存了其原始的组成特点.     

Geology and petrology of the Hormuz dolomite, Infra-Cambrian: Implications for the formation of the salt-cored Halul and Shraouh islands, Offshore, State of Qatar

Geological investigations of the Halul and the Shraouh islands, offshore Qatar, indicate that most of their calcareous rocks, which display abundant stromatolitic bedding, belong to the Infra-Cambrian Hormuz Series. Mineralogical, petrological, and geochemical analyses show that these calcareous rocks consist dominantly of dolomite and have formed in a reducing depositional environment. Faint laminations and small streaks of organic matter furnish evidence for the involvement of algal mats in their genesis and indicate their formation in an intertidal to supratidal setting. The Halul and Shraouh dolomites experienced extensive recrystallization and sulfatization during the emplacement of the Halul and Shraouh salt domes that form the cores of the islands. During mobilization and ascent of the salt, the dolomite recrystallized, and its Sr initial ratios were abnormally enhanced by the incorporation of ⁸⁷Sr from a source, which is more radiogenic than the attendant seawater at the time of the dolomite formation near the Proterozoic–Cambrian boundary. Geochemical analysis show that Si, Al, Ti Zr, and % of insoluble residue are highly correlative, suggesting the presence of detrital minerals such as rutile and zircon. A paleosabkha model may well agree with this chemical signature. However, the Infra-Cambrian age of the Hormuz rocks and the presence of stromatolitic layers containing organic materials in the studied rocks, suggest that organogenic dolomitization could be an alternative dolomitization model.     

Petrological and geochemical constraints on diagenesis and deep burial dissolution of the Ordovician carbonate reservoirs in the Tazhong area,Tarim Basin,NW China

Deeply buried (4500–7000 m) Ordovician carbonate reservoirs in the Tazhong area, Tarim Basin, NW China show obvious heterogeneity with porosity from null in limestones and sweet dolostones to 27.8% in sour dolostones, from which economically important oils, sour gas and condensates are currently being produced. Petrographic features, C, O, Sr isotopes were determined, and fluid inclusions were analyzed on diagenetic calcite, dolomite and barite from Ordovician reservoirs to understand controls on the porosity distribution. Ordovician carbonate reservoirs in the Tazhong area are controlled mainly by initial sedimentary environments and eo-genetic and near-surface diagenetic processes. However, vugs and pores generated from eogenetic and telogenetic meteoric dissolution were observed to have partially been destroyed due to subsequent compaction, filling and cementation. In some locations or wells (especially ZG5-ZG7 Oilfield nearby ZG5 Fault), burial diagenesis (e.g. thermochemical sulfate reduction, TSR) probably played an important role in quality improvement towards high-quality reservoirs. C2 calcite and dolomite cements and barite have fluid inclusions homogenization temperatures (Ths) from 86 to 113 °C, from 96 to 128 °C and from 128 to 151 °C, respectively. We observed petrographically corroded edges of these high-temperature minerals with oil inclusions, indicating the dissolution must have occurred under deep-burial conditions. The occurrence of TSR within Ordovician carbonate reservoirs is supported by C3 calcite replacement of barite, and the association of sulfur species including pyrite, anhydrite or barite and elemental sulfur with hydrocarbon and ¹²C-rich (as low as −7.2‰ V-PDB) C3 calcite with elevated Ths (135–153 °C). The TSR may have induced burial dissolution of dolomite and thus probably improved porosity of the sour dolostones reservoirs at least in some locations. In contrast, no significant burial dissolution occurred in limestone reservoirs and non-TSR dolostone reservoirs. The deeply buried sour dolostone reservoirs may therefore be potential exploration targets in Tarim Basin or elsewhere in the world.     

Dolomite microstructures between 390° and 700 °C: Indications for deformation mechanisms and grain size evolution

Dolomitic marble on the island of Naxos was deformed at variable temperatures ranging from 390 °C to >700 °C. Microstructural investigations indicate two end-member of deformation mechanisms: (1) Diffusion creep processes associated with small grain sizes and weak or no CPO (crystallographic preferred orientation), whereas (2) dislocation creep processes are related with larger grain sizes and strong CPO. The change between these mechanisms depends on grain size and temperature. Therefore, sample with dislocation and diffusion creep microstructures and CPO occur at intermediate temperatures in relative pure dolomite samples. The measured dolomite grain size ranges from 3 to 940 μm. Grain sizes at T_max >450 °C show an Arrhenius type evolution reflecting the stabilized grain size in deformed and relative pure dolomite. The stabilized grain size is five times smaller than that of calcite at the same temperature and shows the same Arrhenius-type evolution. In addition, the effect of second phase particle influences the grain size evolution, comparable with calcite. Calcite/dolomite mixtures are also characterized by the same difference in grain size, but recrystallization mechanism including chemical recrystallization induced by deformation may contribute to apparent non-temperature equilibrated Mg-content in calcite.     

镇沅老王寨金矿地质特征

镇沅老王寨金矿属超基性岩接触带金矿.金矿体受地层、构造、基性火成岩的控制.该矿经历了多期成矿作用（沉积—成岩期、热液期、表生期）、多种物质来源（矿源层中分散元素、热源为构造挤压摩擦产生）、以及复杂的成矿热液（深源的岩浆热液、变质热液和大气降水）经反复活化、迁移、聚集和沉淀,形成了如今的矿床.     

山东省枣庄市侯孟熔剂用白云岩矿地质特征及开发利用前景

侯孟熔剂用白云岩矿位于枣庄市台儿庄区张山子镇东南,区内圈定了1个矿体,呈层状产出,矿体赋存于震旦纪土门群石旺庄组地层中,受地层层位控制,产出稳定。矿物成分主要为白云石,矿石结构以泥微晶结构为主,块状构造,矿石自然类型为灰色细晶白云岩。该矿床为滨海泻湖相沉积的层状石灰岩经白云岩化形成的交代型白云岩矿床,矿石主要有用组分含量分别为MgO 19.73%,CaO 30.33%,达到了熔剂用白云岩的工业标准要求,具有良好的开发前景。     

Upper Permian Main Dolomite microbial carbonates as potential source rocks for hydrocarbons (W Poland)

Various microbialite lithofacies were common in the shallow-water environments which flourished under highly saline and arid climate conditions in the Polish part of the Zechstein (Upper Permian) Main Dolomite (Ca2) carbonates. Data came from detailed analysis of 78 cores from wells located at the southern and northern margins of the Main Dolomite basin in west Poland. Microbialite lithofacies are represented by columnar, planar and domal stromatolites, clotted thrombolites and biolaminites developed in high-to-low energy environments within the upper slope, lower parts of oolitic barrier/shoal, restricted lagoon, and tidal flat and tidal channel zones. In barrier environments ooids were predominant whereas in lagoonal settings microbial oncoids and peloids were common. In basinal settings laminated dolomudstones formed which are regarded as hemipelagic and are partly pelagic microbial in origin. Microbial communities coexisted with algae and developed mainly within shallow marine environments. Microbialites are built of cyanobacterial filaments and organo-mineral coccoidal forms possibly of bacterial origin. Organic geochemistry data confirm that organic matter was transformed by cyanobacteria and bacteria which may have played a main role in hydrocarbon generation. This is confirmed by C₂₉ to C₃₅ hopanes, Pr/Ph ratio below 1.0, and the presence of gammacerane as typical for Ca2 profiles. The role and occurrence of algae, as confirmed by C₂₉-steranes, in hydrocarbon generation was possibly minor. Thus it is concluded that the Main Dolomite microbialites could be the likely source rocks for hydrocarbons, with calculated original TOC values from 0.8 to ca 2.0 wt. %. These units also form the reservoir rocks, with porosities reaching 20%.     

Multi-approach characterization of shallow-water carbonates off Minamitorishima and their depositional settings/history

Sedimentological, geochemical, and chronological analyses were carried out on 18 carbonate rock samples collected at depths of 938, 1085, and 3354 m on the western slope of Minamitorishima (Marcus Island), which is located near the western margin of the Pacific Plate. Four groups of carbonate rocks were distinguished: a mollusk-rich limestone, a coral-rich dolomite, a foraminiferal-nannofossil packstone, and a phosphatized mudstone/wackestone. The mollusk-rich limestone is characterized by the dominance of bivalves (including rudists) and gastropod shells. Strontium isotope ratios (⁸⁷Sr/⁸⁶Sr) and Mesorbitolina ex gr. texana (a large benthic foraminifer) indicate that the shallow-water carbonates were deposited during the late Aptian–early Albian (ca. 123–111 Ma). The coral-rich dolomite is characterized by abundant scleractinian corals and nongeniculate coralline algae associated with encrusting acervulinid foraminifers. The biotic composition is similar to that of the Oligocene–Pleistocene carbonates reported from other seamounts in the northwestern Pacific. Geochemical data show that the coral-rich carbonates were dolomitized at 9.5–6.8 Ma (Tortonian–Messinian) and that normal seawater was the most likely parent fluid. The foraminiferal-nannofossil packstone is a semi-consolidated foraminiferal-nannofossil ooze and was deposited during the Pleistocene (0.99–0.45 Ma). The phosphatized mudstone/wackestone is marked by the absence of macrofossils and the presence of traces of planktic foraminifers. Although its depositional age is not constrained, the Sr isotope ratios indicate that the phosphatization occurred at 33.2–28.9 Ma. After the deposition of the Cretaceous shallow-water carbonates, including the mollusk-rich limestone, Minamitorishima was drowned and its top was covered with a pelagic cap, represented by the mudstone/wackestone. The late Eocene–early Oligocene volcanism (40.2–33.2 Ma) caused episodic uplift and returned the top of Minamitorishima to a shallow-water environment. After the early Oligocene phosphatization of the pelagic cap, coral reefs flourished on the top of this island. The reef limestone was dolomitized during the Tortonian–Messinian.     

油气田典型岩石三轴压缩变形破坏与声发射活动特征——四川盆地震旦系白云岩及页岩的破坏过程

随着二氧化碳地质封存、深部地热开采、地下储气库建设、页岩气开发、二次驱油/驱气等工业应用的快速发展,与地下流体注入有关的诱发地震活动呈现一定的增加趋势.利用声发射实验观测油气田典型岩石在三轴压缩条件下变形破坏过程与声发射活动特征,对研究注水诱发地震过程有着重要意义.本文利用四川盆地现场采集的震旦系白云岩及页岩,采用实验室声发射技术观测研究岩石三轴压缩变形破坏过程中地震波速度等物性参数及声发射事件时空分布特征.实验结果表明:震旦系白云岩及页岩在变形破坏过程中均有一定的声发射活动.根据声发射定位结果,声发射主要集中在破坏前后的较短时间内,页岩的层理面为结构弱面,控制最终破坏面的形态及声发射特征.根据应力-应变结果,白云岩在压缩的后期阶段有一定的扩容现象,但页岩在整个压缩阶段均没有明显扩容现象.研究结果表明四川盆地较古老的白云岩及页岩具有脆性破坏特征,地下流体注入容易诱发微震活动,形成裂缝,有利于页岩气压裂开采.微震活动有利于监测裂缝的发生发展,但同时在页岩气开发及二氧化碳地质封存时应采取相应的预防控制措施进行安全合理的储盖层管理,避免灾害性诱发地震的发生.     

Rare earth elements and yttrium geochemistry of dolomite from post-Variscan vein-type mineralization of the Nízký Jeseník and Upper Silesian Basins, Czech Republic

Rare earth elements and yttrium geochemistry of dolomite from post-Variscan vein-type Zn–Pb–Cu mineralization was studied in the Nízký Jeseník and Upper Silesian Basins. Combined with crush–leach analyses of fluid inclusions, the study provided important information on fluid–rock interaction, physico-chemical and redox conditions during crystallization of the dolomite. The mineralization is hosted by Carboniferous siliciclastic rocks, representing Variscan flysch and molasse sedimentation. Dolomite samples contain highly variable contents of REE (between 18 and 295 ppm) and Y (between 17 and 95 ppm). REY patterns are divided into four different groups which differ in regional provenance, LREE vs. HREE enrichment/depletion and significance of Eu, Gd and Y anomalies. These patterns can be the result of 1) precipitation of dolomite from near neutral fluids with important concentrations of complexing ligands as a main factor for the REY partitioning, 2) interaction of migrating fluids with host or basement rocks, or, most probably, 3) a combination of both.Regarding the importance of complexing ligands, it is proposed that in all samples fluoride and chloride complexes prevailed over sulphate, bicarbonate and hydroxide complexes. Interaction of fluids with rocks was strongly affected by the fluid temperature. Dolomites which precipitated from fluids with homogenization temperature higher than 110 °C are mostly REY-enriched while fluids colder than 110 °C produced REY-depleted dolomite. The REY-enrichment may indicate higher effectiveness of leaching of REE-bearing minerals (probably monazite, allanite and biotite) at higher temperatures. The preferential loss of LREE can be caused by the recrystallization or remobilization of dolomite. Generally, an increase in salinity and contents of Cl and F in the fluids is mostly accompanied by a higher REY content in dolomite. Positive Eu anomalies and small negative Gd and Y anomalies are typical for most of the chondrite-normalized patterns. Positive Eu_CN anomalies in dolomites are most probably the result of an increase of Eh in the parent fluid. Distribution of Y is expected to be predominantly controlled by solution complexation.