四川盆地东北部三叠系飞仙关组碳酸盐岩成岩作用和白云岩成因的研究现状和存在问题

四川盆地东北部三叠系飞仙关组是我国重要的天然气储集层，优质储层形成机制直接与碳酸盐岩成岩作用、尤其是白云岩化作用相关，但飞仙关组碳酸盐岩在锰含量、锶含量、阴极发光性等特征上反映其成岩过程与经典成岩理论相悖；碳酸盐岩的锶同位素组成和锰、锶含量的关系也表明与大气水有关的成岩过程和作为重要储集岩的结晶白云岩的形成机制无关，传统的白云岩化机制难以解释结晶白云岩的成因。具有海源色彩的高锶、低锰成岩流体在很大程度上控制了飞仙关组碳酸盐的成岩作用，其来源与成因值得进一步关注，控制其运移、封存和发生水—岩反应的时空机制有待回答。整个海相三叠纪时间段盆地尺度碳酸盐岩和蒸发岩的沉积地球化学研究、尤其是不同结构组分碳酸盐的锶同位素组成、锶和锰含量研究（包括碳酸盐岩中不同结构组分的阴极发光性研究），可为四川盆地东北部飞仙关组碳酸盐岩成岩作用（尤其是白云岩化作用和作为重要储集岩的结晶白云岩的成因研究），天青石矿床成因研究和四川盆地三叠系深层富钾、锶、硼、溴卤水的成因研究提供重要的线索。     

Methane-induced dolomite “chimneys” on the Kuroshima Knoll, Ryukyu islands, Japan

The Kuroshima Knoll is about 26 km south of Ishigaki Island in the southern part of the Ryukyu Arc. The area is considered to be the source area of “The 1771 Yaeyama Earthquake Tsunami”, which was due to the submarine landslide caused by an earthquake. It has been cleared from some investigations using “Dolphin 3K” and “Shinkai 2000” that there are large-scale dead Calyptogena colonies, many gravels of fallen dolomite chimneys and carbonates on the top of the Knoll [Matsumoto, T., Uechi, C., Kimura, M., 1997; Machiyama, H., Matsumoto, T., Matsumoto, R., Hattori, M., Okano, M., Iwase, R., Tomaru, H., 2001b.]. Carbonates of Kuroshima Knoll have various shapes and macroscopic textures. These have been classified into 4 types; shell crust (pavement), chimney, burrow, and nodule. It is clear that all chimney and burrow carbonates are composed of dolomite, while shell curst and nodule are composed of calcite, sometimes both calcite and dolomite. These carbonates are considered to have been formed by cold seep, because they are characterized by the light carbon isotopic ratio (semi-biogenic) and the heavy oxygen isotopic ratio. This suggests that methane hydrate layers develop under this survey area and the water that has the heavy oxygen and the light carbon isotopic ratio is derived from the dissociation of methane hydrate.     

Carbon isotopic change at the base of the upper permian zechstein sequence

Fluctuation of the carbon isotope composition of marine carbonates has recently been developed as a powerful tool for the identification of ocean-wide anoxic conditions and changes in the world budget of carbon and oxygen. A change in δ¹³ from the normal marine values (0 to + 2%) to values highly enriched in ¹³C (+3·5 to 4·5%) is recorded at the base of the Zechstein sequence both in central Germany and northeastern England. The change occurred over a relatively short period of time indicating a rapid and pronounced change in the organic carbon/carbonate budget. Evidence from other Permian basins show similar highly enriched δ¹³C values. This change may correspond to that in carbon balance distinguished by the Garrels and Perry (1975) model and based on the change in sulphur isotopic composition during the Permian.     

塔里木盆地下奥陶统蓬莱坝组白云岩成因及储层主控因素分析——以巴楚大班塔格剖面为例

寒武系-下奥陶统白云岩是塔里木盆地非常重要的勘探接替领域,但由于白云岩埋藏深度大,勘探和研究程度低,目前的认识程度无法满足勘探的需求,尤其是白云岩储层成因和分布的认识。本文以巴楚地区大班塔格剖面蓬莱组白云岩的精细解剖为例,测制解剖剖面9条,采集样品195块,系统的开展了岩石薄片、物性及地球化学特征分析,取得了两个方面的新的认识。1)是塔里木盆地蓬莱坝组发育粉晶、细晶、中晶和粗晶四种白云岩,主要形成于早-中埋藏期与海源流体有关的白云石化作用中,局部受到热液改造,其晶粒大小与原岩结构的粗细及孔隙空间的大小有关,原岩结构粗,形成的白云石晶粒就粗,原岩孔隙空间大,白云石晶粒就大。2)是白云岩储层的分布具成层性和旋回性,孔隙发育段总体位于向上变浅旋回的顶部,与高频旋回的暴露面有关,其载体以细-粗晶白云岩为主,孔隙主体来自原岩孔隙的继承和再调整,少量来自埋藏(热液)溶蚀作用,而并不是传统观点所认为的白云石化作用建造孔隙,这一认识对塔里木盆地深层白云岩有效储层预测具重要的指导意义。     

白云鄂博矿床白云岩的Sm—Nd、Rb—Sr同位素体系

白云鄂博矿床的年龄和成因长期争论.本文报道了白云鄂博矿床白云岩及其组成矿物的Sm-Nd、Rb-Sr同位素分析结果.采自该矿床主、东矿等地的15个白云岩样品的Sm-Nd同位素分析结果呈现一条等时线,等时年龄1273±100(2σ)Ma,INd=0.510919士36(2d),MSWD1.01.全岩Rb-Sr同位素分析结果分散,不构成等时线.87Rb/86Sr0～2.092×100-2,87Sr/86Sr0.70341～0.70541.白云岩矿物的Sm-Nd同位素分析结果给予了与全岩类似的Sm-Nd等时年龄,t=1250士210(2σ)Ma,1Nd=0.510914±77(2σ),MSWD 0.56.白云鄂博矿床可能是中元古代末期大离子亲石微量元素略为富集地幔源区部分熔融岩浆活动产物.     

川西中三叠统雷口坡组三段-四段白云岩特征与成因——来自于岩相学及地球化学的约束

白云岩化是影响储层发育是否的重要沉积-成岩过程。作者通过在对川西地区的中三叠统雷口坡组的雷三至雷四段的岩相学,碳、氧、锶、镁同位素以及元素地球化学等综合研究,划分出含膏的泥晶云岩AD0、泥晶云岩D0、泥粉晶云岩D1、粉细晶云岩D2、微生物云岩MD、含灰质藻云岩CD(交代结构)以及去云化的泥粉晶云岩(CD0CD1)等七类白云岩。白云石有序度及铁、锰含量较低。阴极发光以暗紫、暗紫红、蓝紫为主;次为玫瑰红、橙红及橙黄红色。δ~(13)CPDB=1. 95‰～2. 46‰,δ~(18)OPDB=-4. 05‰～2. 70‰;~(87)Sr/~(86)Sr=0. 70778～0. 70807,δ~(26)Mg=-1. 872‰～-2. 124‰,其中δ~(13)C_(PDB)、~(87)Sr/~(86)Sr的平均值与中三叠世全球海水相似;δ~(18)O_(PDB)为弱负漂及正偏移。从D2、D1至D0、AD0,Sr、Na和大部分微量元素含量及比值和δ~(18)O_(PDB)逐渐增加; AD0、少量D0或MD相对富含硅、铝,并与高(低镁)方解石、黏土、有机质等共生。离子组成反映出白云石的前驱物以方解石型为主,少量为文石、原白云石结构。存在广盐、稍咸和超盐度的碱性等沉积环境。白云岩形成主要受向上变浅米级旋回序列,干燥、炎热为主、偶夹潮湿古气候以及古地貌-古水文条件等因素影响。存在浅潟湖的萨勃哈(AD0或D0)、环潮缘至局限台地(D0-D1、微生物诱导MD)、潮间-潮下的微生物礁(席)构成的障壁的台缘带(MD-CD1-CD)、潮坪-开阔台地(D0-D2-CD1、MD)等环境,以萨勃哈和受蒸发泵-密度差驱动的"渗透-回流白云石化"模式为主。     

Evaluating new fault-controlled hydrothermal dolomitization models: Insights from the Cambrian Dolomite,Western Canadian Sedimentary Basin

Fault-controlled hydrothermal dolomitization in tectonically complex basins can occur at any depth and from different fluid compositions, including ‘deep-seated’, ‘crustal’ or ‘basinal’ brines. Nevertheless, many studies have failed to identify the actual source of these fluids, resulting in a gap in our knowledge on the likely source of magnesium of hydrothermal dolomitization. With development of new concepts in hydrothermal dolomitization, the study aims in particular to test the hypothesis that dolomitizing fluids were sourced from either seawater, ultramafic carbonation or a mixture between the two by utilizing the Cambrian Mount Whyte Formation as an example. Here, the large-scale dolostone bodies are fabric-destructive with a range of crystal fabrics, including euhedral replacement (RD1) and anhedral replacement (RD2). Since dolomite is cross-cut by low amplitude stylolites, dolomitization is interpreted to have occurred shortly after deposition, at a very shallow depth (<1 km). At this time, there would have been sufficient porosity in the mudstones for extensive dolomitization to occur, and the necessary high heat flows and faulting associated with Cambrian rifting to transfer hot brines into the near surface. While the δ¹⁸O_water and ⁸⁷Sr/⁸⁶Sr ratios values of RD1 are comparable with Cambrian seawater, RD2 shows higher values in both parameters. Therefore, although aspects of the fluid geochemistry are consistent with dolomitization from seawater, very high fluid temperature and salinity could be suggestive of mixing with another, hydrothermal fluid. The very hot temperature, positive Eu anomaly, enriched metal concentrations, and cogenetic relation with quartz could indicate that hot brines were at least partially sourced from ultramafic rocks, potentially as a result of interaction between the underlying Proterozoic serpentinites and CO₂-rich fluids. This study highlights that large-scale hydrothermal dolostone bodies can form at shallow burial depths via mixing during fluid pulses, providing a potential explanation for the mass balance problem often associated with their genesis.     

Microbial signatures in sabkha evaporite deposits of Chott el Gharsa (Tunisia) and their astrobiological implications

This study investigates the geomicrobiological potential of Upper Pleistocene evaporite deposits of the Chott el Gharsa, a wide continental sabkha in southern Tunisia. Organic and inorganic-derived biosignatures are mostly contained in microcrystalline, laminated gypsum lithofacies consisting of light/dark alternations of concordant laminae, which have precipitated from high salt concentrated waters. These biosignatures include mineralized microbial-interpreted morphologies, such as mucilage, rods, and microfibers, and dumbbell morphologies in the hollow cores of dolomite crystals that are associated with sulfates. Mineral products that are induced by microbial activity and their organic compounds lead to the formation of lenticular-shaped gypsum crystals, with a high length/width ratio, dolomite precipitation and formation of pyrite framboids. Morphological and structural aspects of these biosignatures, and their composition, in laminated, dolomite-rich sulfate deposits could be detected through microscopic investigations and micro-analyses performed by the instrumentation that is planned for ongoing Mars sample return missions.     

辽东半岛南部早古生代馒头组—冶里组沉积盆地演化

辽东半岛南部早古生代地层发育,其中馒头组—冶里组的沉积过程,具有完整的陆源碎屑岩—碳酸盐岩堆积特点。从层序划分、沉积环境演化、古气候变迁等方面分析,馒头组—冶里组反映了一个完整的碳酸盐岩台地的发展过程,可划分出准备阶段（形成碎屑岩垫板）、生长—发育阶段（形成碳酸盐岩缓坡）及衰亡阶段（发育白云岩盖层）。     

Neoproterozoic (Cryogenian) stromatolites from the Wolfe Basin,east Kimberley,Western Australia: Correlation with the Centralian Superbasin

Linella avis, an early to middle Neoproterozoic (Tonian to Cryogenian) stromatolite, occurs in the Eliot Range Dolomite, part of the Ruby Plains Group in the Wolfe Basin, east Kimberley. Previously, this dolomite was assigned to the Mesoproterozoic Bungle Bungle Dolomite in the Osmond Basin, which contains a different suite of stromatolites. Linella avis, which also occurs in the Neoproterozoic Bitter Springs Formation of the Amadeus Basin, central Australia, appears to be restricted to rocks aged around 850 to 800 Ma. The presence of L. avis indicates that the Ruby Plains Group is a probable correlative of the Heavitree Quartzite and Bitter Springs Formation, and is probably much younger than the Bungle Bungle Dolomite. If the correlation suggested here is correct, the Wolfe Basin, together with the Amadeus and Ngalia Basins, formed part of the Centralian Superbasin.