酸溶——催化极谱法测定地质样品中的钨、钼

本文采用混合酸溶解样品,对影响催化体系稳定的酸度、温度和不同反应时间的因素分别进行了对比试验,确定催化体系相对稳定的最佳条件,经过大量样品的分析验证,分析方法可靠。     

GIS支持下的煤层气目标区模糊综合评价模型

地理信息系统(GIS)以空间数据库技术为核心,将空间要素与统计数据有机地结合在一起,具有直观灵活、分析功能强大、制表制图方便等优点。根据中国煤层气(CBM)目标区的特点,建立了4种原则下用于不同情形的煤层气目标区评价模型:第1种模型为全面考虑各个因素原则,第2种模型为只考虑重点因素原则,第3种模型为着重考虑重点因素原则,第4种模型为既全面考虑又兼顾重点因素原则。根据这4种模型,在常用GIS软件MapGIS基础上进行了二次开发并实现模型,以华北聚气区煤层气为例进行综合评价,目标区评价结果与实际情况基本相符。     

华北地台中元古代碳酸盐岩中的微生物成因构造及其生烃潜力

华北地台中元古界主要由环潮坪石英砂岩、浅海碳酸盐岩和浅海—泻湖相暗色页岩3种沉积相组合构成,以陆表海浅水碳酸盐岩占主导。碳酸盐岩中除含有丰富的微古植物、宏观藻类和微生物建隆外,还发育大量的微生物成因构造(MISS)和微生物诱发的碳酸盐沉淀(MMCP)。微生物席和MISS构造在高于庄组上部(约1.6 Ga)和雾迷山组下部(约1.45 Ga)碳酸盐岩中尤为发育,表明活跃的微生物活动和高有机质产量。在石化微生物席中,发现有丝状、球状细菌化石和草莓状黄铁矿;围岩中发现有针状文石、花瓣状重晶石、放射状菱铁矿、铁白云石和葡萄状碳酸盐胶结物等多种自生碳酸盐矿物,指示甲烷厌氧氧化(AOM)导致的自生碳酸盐沉淀。中元古代的温暖气候和海洋分层、缺氧、硫化条件有利于微生物的高生产量和高有机质埋藏率。气隆构造和核形石状碳酸盐结核反映浅埋藏条件下活跃的成烷作用和甲烷排放,围岩和MMCP中富沥青质。华北地台中元古界富微生物席碳酸盐岩有良好的生烃潜力,有可能形成重要的烃源岩。据微生物席、MISS构造及MMCP的研究,初步估算华北地台中元古代碳酸盐岩的概略生烃潜力约为10×108t石油当量。     

华北安鹤煤田煤储层特征与煤层气有利区分布

通过对安鹤煤田采集煤样的煤质、显微组分、煤相、显微裂隙分析,等温吸附、低温氮比表面及孔隙结构和压汞孔隙结构测试,研究了该区煤层气赋存的地质条件、煤层气生气地质特征和煤储层物性特征。并采用基于G IS的多层次模糊数学评价方法计算了该区的煤层气资源量,预测了煤层气有利区分布。研究结果表明,该区煤层气总资源量为1 115.73×108m3,煤层气资源丰度平均为1.18×108m3/km2,具有很好的煤层气资源开发潜力。在煤田中部的四矿到八矿之间的地区以及北部的水冶镇附近地区,煤层累计有效厚度大、煤层气资源丰度高、煤层埋深适中、煤储层孔裂隙系统发育、渗透性高,是该区煤层气勘探开发的最有利目标区。     

湿地生态系统碳循环过程及碳动态模型

从地上、地下有机物质生产对湿地碳输入的贡献,湿地土壤碳库以及土地利用变化对湿地土壤碳库和碳排放的影响,甲烷排放和可溶性有机碳输出以及影响因子,湿地生态系统碳循环动态模型4个方面对湿地生态系统碳循环国内外研究进展和研究成果进行综述、分析,提出了我国亚热带区域天然湿地碳循环研究的主要热点和方向:⑴沿海湿地碳库估算及土地利用转化对土壤碳库和温室气体排放的影响;⑵酸沉降对于我国东南沿海低纬度地区湿地甲烷排放的影响;⑶沿海湿地生态系统碳循环动态模型的应用与开发;⑷湿地系统可溶性有机碳的输出机理探讨.     

Dissolved silica budget in the North basin of Lake Lugano

We studied the dissolved silica cycle in the water column of the North basin of Lake Lugano, Switzerland/Italy. Lake Lugano is a meromictic, eutrophic lake, permanently stratified below 100-m depth. A one-box model was used to calculate a silica mass-balance over 1993, based on various lake measurements, such as sediment traps, sediment cores, water analysis and biota countings. We found that the North basin of Lake Lugano is at steady state as far as dissolved silica is concerned. The primary source of dissolved silica in the lake is river input (about 80%), with diffusion from bottom sediments and groundwater input also playing a role. Atmospheric input is negligible. The main export of dissolved silica occurs via biogenic uptake by diatoms and final burial of their frustules in the bottom sediment. Loss of dissolved silica through the lake outflow only represents 15% of the total output. Of the total amount of Si exported to the lake bottom through diatom sinking, less than 20% is re-supplied to the surface water by diffusion. Thus, the lake acts as an important permanent sink for silica. The long residence time of dissolved silica in the lake (7 years) is related to the strong physical stratification of the lake. Only about 10% of the standing stock are available to phytoplankton uptake.     

Floodplain–river ecosystems: lateral connections and the implications of human interference

Floodplains are ecotones that form a transition between aquatic and terrestrial environments. These important ecosystems can be described as dynamic spatial mosaics in which water plays an important role in connecting various patches on the floodplain surface. Hydrological connections facilitate the exchange of carbon and nutrients between the river channel and the floodplain and therefore influence the productivity of the entire river system. This paper examines the influence of hydrological connections on the potential exchange of dissolved organic carbon between a large Australian floodplain to a river channel, and the effects of land and water developments on these exchanges. The paper proposes that an understanding of floodplain ecosystems requires an interdisciplinary approach—a recognition of the importance of the three disciplines hydrology, geomorphology and ecology. Large-scale water-resources and floodplain development has significantly altered the spatial and temporal patterns of hydrological characteristics in the Lower Balonne floodplain, Australia. The magnitude, frequency and duration of flooding events have all been reduced. The construction of levees and water storages has also reduced the reactive floodplain surface area. The presented data show the impacts of these changes on the potential supply of dissolved organic carbon from the floodplain surface during periods of inundation. Annual reductions of up to 1293 tonnes of dissolved organic carbon supply were noted and reductions were especially significant for floods with an average recurrence interval of 2 years or less. Some small flood events no longer facilitate the potential supply of dissolved organic carbon from the floodplain to the river channel because of water-resources and floodplain developments.     

油气化探中甲烷碳同位素应用、存在问题与对策研究

阐述了在地表油气化探实践当中甲烷碳同位素对地表土壤烃气成因判别的有效性，但有时也会遇到判断错误的情况。通过对应用实例的分析，指出因忽略了土壤中异常甲烷是一种混合成因甲烷，从而导致判断失误。为全面解决这一问题，提出了同时选送数量相当的背景土壤样品和异常样品进行甲烷同位素测定，然后通过教学方法计算出真实反映来源于油气藏中的甲烷的碳同位素值的对策方案。     

陕西彬县大佛寺D4钻孔勘察地球化学研究

运用烃类勘察地球化学方法，对鄂尔多斯盆地南部彬县大佛寺井田钻遇中休罗统煤层的耽钻孔，进行了垂向剖面多指标的综合地球化学研究。结果表明：剖面中所有岩样中的烃类物质均为热解烃生成初期演化阶段的煤成烃产物，具明显的同一性；由煤层至地表黄土，所有岩样中的烃类呈明显的、规律性垂直向上运移。这证实地下煤层烃类在近地表具有很好的地球化学信息显示，利用勘察地球化学方法找煤／煤层气是可行的。     

淮南谢—矿煤的组成对甲烷吸附性的影响

从淮南谢—矿五层煤（Ｃ＿（１３）、Ｂ＿（１１ｂ）、Ｂ＿（１０）、Ｂ＿（４ｂ）和Ａ＿３）中精选出镜煤、壳质暗煤、惰性暗煤及构造煤，采用重量法，分别测定它们的甲烷吸附量，从而研究不同成分组成的煤其甲烷吸附性能。