云南兰坪北部铜多金属矿化区成矿流体流动与矿化分带——流体包裹体和稳定同位素依据

滇西兰坪盆地北部发育了一类受逆冲推覆构造控制的浅成热液Cu—Ag—Pb-Zn矿化，形成了白秧坪、富隆厂、吴底厂、麻栗坪及金满、科登涧等大-中型矿床和矿点，并存在矿化分带。文章利用这些矿化脉体的流体包裹体和热液方解石的碳氧同位素组成资料，研究成矿流体与矿化分带的关系。结果表明，成矿流体主要属于NaCl-H2O成分体系，盐度ω(NaCleq)为2％～11％，形成温度为170～300℃，形成于1．8～3．8km深度内，这些相似性说明这类矿化的发生具有相似的流体性质和沉淀机制。热液方解石在δ^13C-δ^18O图解中呈近水平线展布的型式，指示流体源自地壳浅部的地下水系统，与海相灰岩等围岩作用形成了溶解碳以[HCO3^]-为主的成矿流体，流体与岩石的相互作用可能是成矿流体沉淀的主要机理。从西到东，流体包裹体的盐度-温度由高到低变化与矿化分带和逆冲推覆构造的根带→中带→锋带相配套，显示重力驱动流动可能是主要的流体流动机制。成矿流体在不同构造部位流动的通畅及流体．岩石系统的封闭-开放程度等流体流动性质与矿化发生的强度和规模有关，兰坪北部逆冲推覆构造中带的流体通畅地流动及沉淀时处于相对开放状态，有利于该区形成较大规模的浅成热液多金属矿化。     

西藏驱龙斑岩铜钼矿地球化学异常特征

驱龙铜矿发育多元素的岩石地球化学异常.成矿元素Cu、Mo、(Ag)异常强、规模大,异常与矿化区一致;伴生元素Au、Bi、Pb、As、Sb、Hg异常在Cu、Mo异常边部并套合产出的B Co、Ni Mn Zn的异常主要分布铜钼矿化带外侧.Na₂O在矿化区显示负异常,K₂O为正异常.从异常元素组合、水平分带性和贫Na₂O、富K₂O的成矿环境表明,矿床属典型的斑岩型铜矿地球化学特征,并受到了强烈的剥蚀.     

New national seismic zoning map of China

1 Background of the new national seismic zoning map The policy of seismic disaster mitigation in the Chinese mainland is prevention first. According to the law, the earthquake design for ordinary structures must fit the demand of national seismic zoning map. Seismic zoning map is the basis of the earthquake design (TANG, 1998; WU, et al, 1998). The seismic zoning map must be updated with the progress in methodology and accumula-tion of the data. There are three generations of national seis…     

最优化的矿物扩散地质速率计:北大别黄土岭麻粒岩缓慢冷却的证据

对北大别黄土岭麻粒岩中石榴子石进行了详细的电子探针工作，并根据一颗石榴子石的成分环带，建立了扩散模型并进行了数值模拟，结合最优化的方法，得到了极其缓慢的冷却速率0.1℃/a。从扩散动力学数值模拟的角度对大别山造山带的冷却速率进行了探索性研究。该结果表明，黄土岭麻粒岩在受麻粒岩相改造后经历的是一个极其缓慢、持续时间很长的冷却过程。     

TEM study of a special grain boundary in a synthetic K-feldspar bicrystal: Manebach Twin

 A monoclinic KAlSi₃O₈ feldspar Manebach twin boundary was synthesized by diffusion bonding and examined using high-resolution transmission electron microscopy. The sharp (001) twin boundary is straight and free of strain. The boundary width is smaller than d₀₀₁. There is no rigid body shift observed at the twin boundary, and the feldspar structure is arranged symmetrically across (001). The twin boundary structure consists of bridged tetrahedral crankshafts, which are characteristic of the feldspar lattice. The grain boundary structure is in good agreement with the geometrical model of Taylor et al. (1934). The grain boundary composition of K_1/2H_1/2AlSi₃O₈ differs from their model. Received: 13 February 2002 / Accepted: 24 December 2002 Acknowledgements We thank M. Rühle, S. Hutt, J. Mayer, A. Strecker and U. Salzberger at MPI, Stuttgart, for their support and valuable advice in preparing TEM sections of bicrystals.     

Oscillatory zoning in garnet from the Willsboro Wollastonite Skarn, Adirondack Mts, New York: a record of shallow hydrothermal processes preserved in a granulite facies terrane

Oscillatory zoning in low δ¹⁸O skarn garnet from the Willsboro wollastonite deposit, NE Adirondack Mts, NY, USA, preserves a record of the temporal evolution of mixing hydrothermal fluids from different sources. Garnet with oscillatory zoning are large (1–3 cm diameter) euhedral crystals that grew in formerly fluid filled cavities. They contain millimetre‐scale oscillatory zoning of varying grossular–andradite composition (X_Adr = 0.13–0.36). The δ¹⁸O values of the garnet zones vary from 0.80 to 6.26‰ VSMOW and correlate with X_Adr. The shape, pattern and number of garnet zones varies from crystal to crystal, as does the magnitude of the correlated chemistry changes, suggesting fluid system variability, temporal and/or spatial, over the time of garnet growth. The zones of correlated Fe content and δ¹⁸O indicate that a high Fe³⁺/Al, high δ¹⁸O fluid mixed with a lower Fe³⁺/Al and δ¹⁸O fluid. The high δ¹⁸O, Fe enriched fluids were likely magmatic fluids expelled from crystallizing anorthosite. The low δ¹⁸O fluids were meteoric in origin. These are the first skarn garnet with oscillatory zoning reported from granulite facies rocks. Geochronologic, stable isotope, petrologic and field evidence indicates that the Adirondacks are a polymetamorphic terrane, where localized contact metamorphism around shallowly intruded anorthosite was followed by a regional granulite facies overprint. The growth of these garnet in equilibrium with meteoric and magmatic fluids indicates an origin in the shallow contact aureole of the anorthosite prior to regional metamorphism. The zoning was preserved due to the slow diffusion of oxygen and cations in the large garnet and protection from deformation and recrystallization in zones of low strain in thick, rigid, garnetite layers. The garnet provide new information about the hydrothermal system adjacent to the shallowly intruded massif anorthosite that predates regional metamorphism in this geologically complex, polymetamorphic terrane.     

耦合海-气环流模式中双热带辐合带现象及其热收支分析

文中研究了耦合海-气环流模式中的双热带辐合带(Double ITCZ)现象,并对这一现象的成因从海洋热量收支的角度进行了初步分析。Double ITCZ现象是在热带太平洋赤道南北两侧各出现一条ITCZ的现象,这是耦合海-气环流模式中的较为普遍的一种异常现象,与实际气候中出现的Double ITCZ现象并非指同一问题。文中对比观测和模式结果,指出了Double ITCZ现象的主要特征,针对它的出现过程进行细致分析,再利用模式输出的热量收支各项进行统计,得到了从海洋热收支分析得到的海表温度变化原因。与观测到的正常模态相比,Double ITCZ是一个异常的模态,它的特征突出地表现为西太平洋暖池区的降温和东南太平洋10°S附近的升温。海洋热量收支分析表明,暖池区的降温主要是受到扩散的作用,而表层平流的异常增暖在决定异常辐合带区升温过程中占第一位的作用。     

Disequilibrium for Ca during growth of pelitic garnet

Compositional zoning in hundreds of almandine-rich garnets in amphibolite by facies micaceous quartzites from the Picuris Range, north-central New Mexico USA, indicates that although Mn, Mg and Fe achieve chemical equilibrium at hand-sample scale during garnet growth, Ca does not. Instead, Ca concentrations at the surface of growing garnets appear to depend strongly on kinetic factors that govern the local chemical environment, yielding disequilibrium for Ca at scales larger than the region immediately surrounding an individual porphyroblast. Detailed zoning profiles were obtained for 371 garnet crystals in a small volume of a single sample of garnetiferous quartzite, and core analyses were made of 97 additional crystals. Each analysis was made on a section that passed precisely through the morphological centre of the crystal, located by means of 3-D imagery from computed X-ray tomography. The data reveal strong correlations between crystal size and concentrations of Mn, Mg and Fe (but not Ca) in garnet cores; a relationship between crystal size and isolation; rigorous cross-correlations among concentrations of Mn, Mg and Fe (but not Ca); and systematic variations in Ca concentrations as a function of crystal size and core composition that are anomalous in comparison to the behaviour of the other divalent cations. We interpret these observations as the result of thermally accelerated diffusion-controlled garnet growth, in circumstances that promoted rapid intergranular diffusion and thus rock-wide equilibration of Mn, Mg and Fe, but that prevented equilibration at similar scale for Ca because of its more sluggish intergranular diffusion. The anomalous behaviour of Ca is made evident in these garnets by the presence of sharp spikes in Ca concentration, which are demonstrably not a consequence of any simultaneous rock-wide event, such as a change in pressure, temperature, or some other intensive parameter. Instead, Ca concentrations probably reflect the local extent of reaction in the immediate vicinity of each porphyroblast. To the degree that such kinetic factors introduce departures from chemical equilibrium for Ca, thermobarometric estimates that involve grossular contents of pelitic garnet will be in error.     

毛登锡铜矿床成矿分带及其成因讨论

毛登矿主档是产于花岗斑岩内，外接触带的热液脉型锡铜矿床在容矿构造、矿脉类型及矿石类型、金属矿物组合及主要金属矿物标型，热液蚀变及元素地球化学等诸方面，自花岗斑岩向外，显示出明显的顺向（侧向）脉动分带。     

含金硫化物基岩区红土型金矿的成矿作用

实验表明，在含金硫化物基岩区，硫代硫酸金络阴离子团和硫酸金络阴离子团是金在表生条件下的主要迁移形式，它们的沉淀与铁、锰氢氧化物的形成有密切联系。金的表生迁移－沉淀条件除一般的表生地质条件外，还有特殊的物理化学－生物化学条件。络阴离子团的地球化学性质，控制着红土型金矿床的垂向分带与金的次生富集。