Microdiamonds — Frontier of ultrahigh-pressure metamorphism: A review

This is a comprehensive review paper devoted to microdiamonds from ultrahigh-pressure metamorphic (UHPM) terranes incorporated in orogenic belts formed at convergent plate boundaries in Paleozoic-Mesozoic-Alpine time. When in 1980 the first small diamonds were discovered within “amphibolite-granulate facies” metamorphic rocks, it came as a great surprise that buoyant continental crust could be subducted to depths of hundreds of kilometers and then subsequently exhumed. Since then, much progress has been made in understanding the mechanism of these diamonds' formation, and the number of new diamond-bearing UHPM terranes was significantly increased, especially within European orogenes. Moreover, new variations in tectonic settings in which UHP rocks can be formed and exhumed came to the attention of geologists simply due to the finding of diamonds in places previously “forbidden” for their formation—e.g., oceanic islands, ophiolites, and forearc environments. Over the past decade, the rapidly moving technological advancement has made it possible to examine microdiamonds in detail and to learn that part of them has a polycrystalline nature; that they contain nanometric, multiphase inclusions of crystalline and fluid phases; and that they keep a “crustal” signature of carbon isotopes. Scanning and transmission electron microscopy, focused-ion-beam techniques, synchrotron infrared spectroscopy, micro X-ray diffraction, and nano-secondary ion mass spectrometry studies of these diamonds provide evidence that they keep traces of fluid originated from both crustal and mantle reservoirs, and that they probably interacted with deep mantle plumes. Hypotheses proposed for diamond formation in subduction zones founded on both analytical and experimental studies are discussed. The paper also emphasizes that the discovery of these microdiamonds (as well as coesite) triggered a major revision in the understanding of deep subduction processes, leading to a clear realization of how continental materials can be recycled into the Earth's mantle and geochemically rejuvenate it.     

A conceptual model for kimberlite emplacement by solitary interfacial mega-waves on the core mantle boundary

If convection in the Earth's liquid outer core is disrupted, degrades to turbulence and begins to behave in a chaotic manner, it will destabilize the Earth's magnetic field and provide the seeds for kimberlite melts via turbulent jets of silicate rich core material which invade the lower mantle. These (proto-) melts may then be captured by extreme amplitude solitary nonlinear waves generated through interaction of the outer core surface with the base of the mantle. A pressure differential behind the wave front then provides a mechanism for the captured melt to ascend to the upper mantle and crust so quickly that emplacement may indirectly promote a type of impact fracture cone within the relatively brittle crust. These waves are very rare but of finite probability. The assumption of turbulence transmission between layers is justified using a simple three-layer liquid model. The core derived melts eventually become frozen in place as localised topographic highs in the Mohorovicic discontinuity (Moho), or as deep rooted intrusive events. The intrusion's final composition is a function of melt contamination by two separate sources: the core contaminated mantle base and subducted Archean crust. The mega-wave hypothesis offers a plausible vehicle for early stage emplacement of kimberlite pipes and explains the age association of diamondiferous kimberlites with magnetic reversals and tectonic plate rearrangements.     

Torngat ultramafic lamprophyres and their relation to the North Atlantic Alkaline Province

Geological mapping and diamond exploration in northern Quebec and Labrador has revealed an undeformed ultramafic dyke swarm in the northern Torngat Mountains. The dyke rocks are dominated by an olivine-phlogopite mineralogy and contain varying amounts of primary carbonate. Their mineralogy, mineral compositional trends and the presence of typomorphic minerals (e.g. kimzeyitic garnet), indicate that these dykes comprise an ultramafic lamprophyre suite grading into carbonatite. Recognized rock varieties are aillikite, mela-aillikite and subordinate carbonatite. Carbonatite and aillikite have in common high carbonate content and a lack of clinopyroxene. In contrast, mela-aillikites are richer in mafic silicate minerals, in particular clinopyroxene and amphibole, and contain only small amounts of primary carbonate. The modal mineralogy and textures of the dyke varieties are gradational, indicating that they represent end-members in a compositional continuum.

The Torngat ultramafic lamprophyres are characterized by high but variable MgO (10–25 wt.%), CaO (5–20 wt.%), TiO₂ (3–10 wt.%) and K₂O (1–4 wt.%), but low SiO₂ (22–37 wt.%) and Al₂O₃ (2–6 wt.%). Higher SiO₂, Al₂O₃, Na₂O and lower CO₂ content distinguish the mela-aillikites from the aillikites. Whereas the bulk rock major and trace element concentrations of the aillikites and mela-aillikites overlap, there is no fractional crystallization relation between them. The major and trace element characteristics imply related parental magmas, with minor olivine and Cr-spinel fractionation accounting for intra-group variation.

The Torngat ultramafic lamprophyres have a Neoproterozoic age and are spatially and compositionally closely related with the Neoproterozoic ultramafic lamprophyres from central West Greenland. Ultramafic potassic-to-carbonatitic magmatism occurred in both eastern Laurentia and western Baltica during the Late Neoproterozoic. It can be inferred from the emplacement ages of the alkaline complexes and timing of Late Proterozoic processes in the North Atlantic region that this volatile-rich, deep-seated igneous activity was a distal effect of the breakup of Rodinia. This occurred during and/or after the rift-to-drift transition that led to the opening of the Iapetus Ocean.     

Geological setting and chemistry of kimberlite clan rocks in the Dharwar Craton, India

Diamond exploration in India over the past decade has led to the discovery of over 80 kimberlite-inferred and lamproite-related intrusions in three of the four major Archean cratons that dominate the subcontinent. These intrusions are Proterozoic (1.1 Ga), and are structurally controlled: locally (at the intersections of faults); regionally (in a 200 km wide, 1000 km long diamond corridor); and globally (in the reconstructed supercontinent of Rodinia). The geochemistry of 57 samples from 13 intrusions in the southern Dharwar Craton of Andhra Pradesh has been determined by XRF spectrometry. The bodies are iron-rich with mg#=50–70 and are neither archetypal kimberlites nor ideal lamproites; this may be the underlying reason that conventional exploration techniques have thus far failed to locate the primary sources of India's historically famous diamonds. The two major fields of kimberlite-clan rocks (KCR) in the Dharwar Craton, Wajrakur and Narayanpet, are separated by a NW–SE trending, transcontinental (Mumbai-Chennai) gravity lineament. About 80% of intrusions in Wajrakur are diamondiferous, but diamonds have not yet been reported in Narayanpet. The gravity anomaly may mark the boundary of an architectural modification in the keel of the sub-continental lithosphere, a suggestion that is supported by differences in kimberlite mineralogy, chemistry, mantle xenoliths, structural setting and crustal host rocks.     

Temporary labour migration and sustainable post-conflict return in Sierra Leone

Economic and social development indicators suggest that the small West African state of Sierra Leone is among the poorest countries in the world. Sierra Leone’s economy and quality of life deteriorated rapidly during a decade of political instability and civil war in the 1990s, when many people fled their homes and abandoned their livelihoods due to the rebel insurgency. This paper examines the post-war reconstruction scenario in Sierra Leone and presents recent evidence from two rural communities in the Eastern Province that were badly affected by the conflict. The paper considers the links between the farming and diamond mining sectors, which, despite severe dislocation during the conflict period, have proved to be remarkably resilient. It is argued that seasonal labour mobility associated with this dual economy has not only continued to be a key ingredient in sustaining livelihood portfolios, but is actually an essential pre-condition for the creation of an enabling environment for sustainable post-conflict return.

A sedimentological study of diamondiferous Quaternary sediments in Southern Shandong,China

A sedimentological study of the lower Quaternary sediments in southern Shandong Province suggests that they were derived from a northern highland area of Archaean gneiss and Palaeozoic sediments. Diamond-bearing kimberlites, intruded during the Ordovician, occur in the highland area and are a possible source of diamonds found in the Quaternary sediments. A warm and humid climate prevailed at the beginning of the Quaternary and braided rivers carried gravel and sand southeast towards the Yellow Sea. Cooler and drier conditions in Q2 times reconcentrated diamonds from the underlying Q1 gravels. Post-Q2 faulting deflected the drainage to the south and subsequent erosion left only small remnants of diamondiferous Q2 gravel. A study of diamond shape characteristics suggests that the diamonds in the Quaternary sediments were derived from the known kimberlites to the north, although the possibility of undiscovered kimberlites occurring beneath the Quaternary sediments cannot be ruled out.     

Crystalline inclusions and C isotope ratios in diamonds from the Snap Lake/King Lake kimberlite dyke system: evidence of ultradeep and enriched lithospheric mantle

U-type paragenesis inclusions predominate (94.7%) among the crystalline inclusion suite of 115 diamonds (−4+2 mm) obtained from the recently discovered Snap Lake/King Lake (SKL) kimberlite dyke system, Southern Slave, Canada. The most common inclusions are olivine (90) and enstatite (22). Sulfide, Cr-pyrope, chromite and Cr-diopside inclusion are less abundant (15, 10, 5 and 1, respectively). Results of the inclusion composition study demonstrate the following. (a) The relatively enriched character of the mantle parent rocks of the U-type diamonds. The average Mg# of olivine inclusions is 92.1, and of enstatite inclusions average 93.3. CaO content in Cr-pyrope inclusions is relatively high (3.73–5.75 wt.%). (b) Four of ten U-type Cr-rich pyrope inclusions contain a majoritic component up to 16.8 mol.% which requires pressures of 110 kbar. Carbon isotopes compositions for 34 diamonds with U-type inclusions have a δ¹³C range from −3.2‰ to −9‰ with a strong peak around −3.5‰. This is much heavier than the ratios of U-type diamonds from Siberia and South Africa (4.5‰). Diamonds with olivine inclusions can be divided into two groups based on their δ¹³C values as well as the Mg# and Ni/Fe ratio in the olivines. Most show a narrow range of δ¹³C values from −3.2‰ to −4.8‰ (average −3.72‰) and have olivine inclusions with Mg# less than 92.3 and relatively high Fe/Ni ratios. A second group is characterized by a much wider variation of C isotope composition (δ¹³C varies from −3.8‰ to −9.0‰, average −5.97‰), and the olivine inclusions having a higher Mg# (up to 93.6) and relatively low Fe/Ni ratios. This difference in the C isotope composition may have several explanations: (a) peculiarities of asthenosphere degassing coupled with an abnormal thickness of lithosphere; (b) the abnormal thickness and enriched character of lithospheric mantle; (c) involvement of subducted C of crustal origin in the processes of the diamond formation. The presence of subcalcic Cr-rich majorite (up to 17 mol.%) pyropes of low-Ca harzburgite paragenesis among the crystalline inclusion suite of SKL diamonds is strong evidence for the existence of diamondiferous depleted peridotite in lithospheric mantle at depth near 300 km beneath Southern Slave area and is postulated to be one of the main reasons for the much heavier C isotope composition of SKL U-type diamonds in comparison with those from Siberian and South African kimberlites.     

Nature of diamonds in Yakutian eclogites: views from eclogite tomography and mineral inclusions in diamonds

We have performed dissections of two diamondiferous eclogites (UX-1 and U33/1) from the Udachnaya kimberlite, Yakutia in order to understand the nature of diamond formation and the relationship between the diamonds, their mineral inclusions, and host eclogite minerals. Diamonds were carefully recovered from each xenolith, based upon high-resolution X-ray tomography images and three-dimensional models. The nature and physical properties of minerals, in direct contact with diamonds, were investigated at the time of diamond extraction. Polished sections of the eclogites were made, containing the mould areas of the diamonds, to further investigate the chemical compositions of the host minerals and the phases that were in contact with diamonds. Major- and minor-element compositions of silicate and sulfide mineral inclusions in diamonds show variations among each other, and from those in the host eclogites. Oxygen isotope compositions of one garnet and five clinopyroxene inclusions in diamonds from another Udachnaya eclogite (U51) span the entire range recorded for eclogite xenoliths from Udachnaya. In addition, the reported compositions of almost all clinopyroxene inclusions in U51 diamonds exhibit positive Eu anomaly. This feature, together with the oxygen isotopic characteristics, is consistent with the well-established hypothesis of subduction origin for Udachnaya eclogite xenoliths. It is intuitive to expect that all eclogite xenoliths in a particular kimberlite should have common heritage, at least with respect to their included diamonds. However, the variation in the composition of multiple inclusions within diamonds, and among diamonds, from the same eclogite indicates the involvement of complex processes in diamond genesis, at least in the eclogite xenoliths from Yakutia that we have studied.     

Seismic reflection imaging of thin, kimberlite dykes and sills: exploration and deposit characterization of the Snap Lake dyke, Canada

Seismic reflection techniques are, for the first time, used to image a thin, diamondiferous, kimberlite dyke from subcrop to depths greater than 1300 m. Exploration for vertical kimberlite pipes generally utilizes potential field techniques that often fail to reveal subhorizontal or shallow-dipping intrusions. In contrast, seismic reflection methods are well suited for imaging targets with this geometry. Therefore, in order to evaluate seismic reflection as a tool for subhorizontal kimberlite dyke/sill exploration and mine planning, a feasibility study and subsequent seismic survey were undertaken on the diamondiferous Snap Lake dyke (Northwest Territories, Canada). A substantial drilling program has mapped the dyke as a gently dipping sheet that averages 2–3 m in thickness. The detailed structural and composition data available at Snap Lake provides a unique opportunity to test reflection techniques on a well-sampled deposit. The feasibility study involved measuring P-velocities and densities of cores drilled from the kimberlite and host rocks. These data were used to model reflection amplitudes, evaluate resolution limitations, and determine the acquisition parameters for the reflection survey. Two 2-D lines were acquired that provide comparative datasets for different sources (explosive and vibroseis) and ground types (land and lake ice). In addition, the exploration-scale survey incorporated high fold (40–260 nominal) and long offsets (3260 m). The explosive-source profile recorded on land yielded a superb image of the dyke from depths of 60 m to more than 1300 m over a lateral distance of 5700 m. The seismic image correlates well with adjacent drill hole data and adds considerable detail to the topography of the kimberlite sheet determined by drilling. The vibroseis source also imaged the dyke, but only when sources and geophones were on land; the dyke was not imaged beneath the ice due to reverberation and attenuation effects. The frequency response and unusually strong reflection amplitudes from the dyke indicate the importance of tuning effects and multiples for this type of target and acquisition environment. Apparent correlations between reflection amplitudes and dyke structure (e.g., thickness, feathering, 3-D geometry) suggest that seismic reflection data may be valuable for guiding drilling programs. The results demonstrate that, in the appropriate situation, seismic methods have great potential for use in kimberlite exploration, subsurface mapping, and detailed imaging for mine development purposes.     

Spatial distribution of kimberlite in the Slave craton, Canada: a geometrical approach

Exploration within the Slave craton has revealed clusters of kimberlite intrusions, commonly with internally consistent geochemical and temporal characteristics. Translation diagrams (“Fry analysis”) allow an unbiased geometrical examination of the distance and direction between each kimberlite occurrence and all others in the database. Recurrent patterns are visually accentuated due to the square function in data density. Circular histograms quantify the azimuthal density of kimberlite at various distances. For this study, the database comprises the geographic position of 212 kimberlite occurrences of which 70% are from the Lac de Gras field (LDG). Analyses are presented separately for the LDG data and for all non-LDG data in order to test for regional variations and to avoid overwhelming the craton-scale studies by the high density of LDG data.

Empirical grouping of kimberlite locations results in delineation of five elliptical clusters that encompass all but four kimberlite occurrences. Clusters within the western part of the craton are elongate to the north–northeast and align within a narrow zone (“Western Corridor”). Elsewhere, the clusters are elongate to the northwest or west–northwest and appear to be arranged en echelon within a poorly defined north–northwest trending zone (“Central Corridor”). Geometrical spatial analyses of kimberlite locations highlight the craton-scale pattern of emplacement within the two main corridors. At regional and local scales, individual intrusions are preferentially located towards the west–northwest (ca. 280°) and north–northeast (ca. 015°) of other intrusions, and these orientations are interpreted to reflect upper mantle trends in magma generation. At local scales (10–25 km), kimberlite of the central and southern craton tends to be located to the northeast (ca. 045°), and possibly weakly to the east–northeast (ca. 070°), of other intrusions, and these orientations correspond to major crustal fractures systems. It is proposed that kimberlite emplacement is controlled primarily by the interaction of elongate 280° and 015° source regions with near-surface deviations influenced by crustal fracture systems.

The 015° trend evident at craton, regional, and local scales is parallel to a swarm of alkaline diabase dykes that are concentrated in a ca. 30-km-wide corridor passing through Lac de Gras. A profound spatial association between significantly diamondiferous kimberlite and the margins of the dyke corridor suggests the corridor is the surface expression of a mantle-depth structure. It remains unclear whether the proposed mantle structure coincides with a diamond-rich zone near the base of the lithosphere, or delineates pathways favorable for diamond preservation during emplacement. The linear array of kimberlite within the western craton forms a parallel corridor that may be an analogous mantle structure, but which to date has failed to yield economic diamond concentrations.