高压下天然菱铁矿的压缩性和电子结构研究

采用同步辐射光源和金刚石对顶砧(DAC)技术,对天然菱铁矿的压缩性和电子结构进行了原位X射线衍射(XRD)和X射线吸收近边结构谱(XANES)测试研究。在室温下随着压力逐渐升高至50.2 GPa,菱铁矿保持方解石型结构不变,但是逐渐向Na Cl型结构转变;刚性[CO3]2-基团平行于ab-平面定向排列使c轴的压缩性大于a轴。菱铁矿在44.6~47.1 GPa之间发生电子由高自旋态(HS)向低自旋态(LS)的转变,表现为体积塌陷8%。HS菱铁矿的等温状态方程参数为K0=112(5)GPa和K'0=4.6(3)。首次采用XANES技术对菱铁矿中Fe2+的电子结构进行了研究,结果表明:随着压力升高至37.3 GPa,Fe2+的配位和局域对称并未发生明显变化;此后电子结构开始转变,Fe2+的3d轨道分裂能降低,电子跃迁概率增大,呈现LS特性。     

Determination of Ge, As, Se and Te in Silicate Samples Using Isotope Dilution-Internal Standardisation Octopole Reaction Cell ICP-QMS by Normal Sample Nebulisation

A method for the determination of Ge, As, Se and Te in silicate samples using isotope dilution-internal standardisation (ID-IS) octopole reaction cell (ORC) ICP-QMS by normal sample nebulisation was developed. The method does not involve either hydride generation or ion exchange. Germanium, Se and Te were determined by isotope dilution (ID), and As was determined by ID-IS. A silicate sample with an added Ge-Se-Te spike was digested with an HF-HNO₃-HBr mixture, dried, re-dissolved with HF and the supernatant liquid was directly aspirated into an ORC-ICP-QMS instrument with He or H₂ gas. No matrix effects were observed down to a dilution factor (DF) of ∼ 70 for Ge, Se and Te and DF of ∼ 1000 for As, which resulted in 3s detection limits in silicates of 2, 1, 0.1 and 4 ng g⁻¹, respectively. Advantages of the method are the simple sample introduction as well as a capability of determining S, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by ID-IS-ICP-QMS/SFMS from the same solution. Furthermore, the total sample solution consumption was only 0.253 ml with DF = 2000. Therefore, only a 0.13 mg test portion was required. To demonstrate the applicability of this technique, Ge, As, Se and Te in eight silicate reference materials were determined, as well as S, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta in four carbonaceous chondrites.     

Impulsive force of debris flow on a curved dam

Although Sabo dams are an efficient method for river and basin management, traditional Sabo dams have a great impact on ecology and landscape. Moreover, such dams are hit and often damaged by great impulsive force when they block the debris flow. Therefore, alternative shapes for Sabo dam deserve thorough investigation. In this investigation, a curved dam was designed by changing the upstream-dam-surface geometric shape to reduce the impulsive force of the debris flow, with enhanced stability and reduced concrete mass being the anticipated outcomes. In this study, the flume and laboratory facilities simulated the impulsive force of the debris flow to the Sabo dams. Three geometric forms, including vertical, slanted and curved Sabo dams, were used to determine the impulsive force. Impulsive force theories of the debris flow were derived from the momentum equation and the Bernoulli equation. In these, the impulsive force was balanced by the friction force of the Sabo dam and the opposite force of the load cell behind the dam as it was hit by the debris flow. Positive correlations were found when comparing the experimental data with the theoretical results. These findings suggest that our impulsive force theory has predictive validity with regard to the experimental data. The results from both theory and experimental data clearly show that curved darns were sustained less force than the other darns under the same debris flow. This comparison demonstrates the importance of curved geometry for a well-designed Sabo dam.     

青海省河南县三叠系伊利石结晶度与极低级变质作用

在开展“青海省河南县托叶玛地区I47E007023、I47E008023、I47E009023、1I47E009024四幅1:5万区域地质矿产调查”时,为验证该地区三叠系变质情况,针对三叠系中泥岩(页岩)的伊利石结晶度做了分析测试。30件样品的实验结果表明: 北部宗务隆—泽库地层分区三叠系泥岩(页岩)伊利石Kübler结晶度指数为0.312~0.537,晶胞参数b₀为0.898 0~0.903 2 nm,判断其变质温度小于350 ℃,具葡萄石-绿纤石和沸石相; 南部西倾山地层分区三叠系泥岩(页岩)的伊利石Kübler结晶度指数为0.21~0.318,b₀为0.898 1~0.901 4 nm,变质温度主要分布在200~350 ℃,局部>350 ℃,具葡萄石-绿纤石和绿片岩相。研究认为青海省河南县地区区域变质程度较低,为极低级变质作用或者未发生区域变质作用,且南部西倾山地层分区的变质程度略高于北部宗务隆—泽库地层分区变质程度。这一变质相带研究结论与前人认为的“区域低温动力变质作用及低绿片岩相变质带”不一致,变质程度相对更低。该研究证实了在青海省河南县地区三叠系地层中不存在大面积区域变质作用,仅存在极低级区域变质作用。     

肺小细胞神经内分泌癌MDCT征象分析

目的：探讨肺小细胞神经分泌癌的MDCT表现特征。方法：对具有完整胸部MDCT资料并经病理证实的28例肺小细胞神经内分泌癌CT表现进行回顾性分析。结果：中央型肺小细胞神经内分泌癌18例（64％）,支气管管壁增厚伴肺内肿块或结节17例（94％）,纵隔或肺门淋巴结肿大15例（83％）,增强扫描可见肿块与肿大淋巴结明显不均匀强化,周围型肺小细胞神经内分泌癌10例（36％）,密度均匀,呈分叶状,强化明显,CT无特征性表现。结论：肺小细胞神经内分泌癌主要征象以支气管管壁增厚伴肺门区肿块为主,多伴有肺门、纵膈淋巴结转移。     

CT强化幅度与食管癌病理形态学和血管内皮生长因子表达间的关系

目的:对56例食管癌患者血管内皮生长因子(VEGF)表达结果与CT强化峰值参数间进行对照,研究其相关性,为食管癌的影像学诊断及早期发现提供参考依据。方法:56例患者均于术前行CT平扫+动态增强扫描,记录不同扫描时期病灶的CT平扫值、增强峰值;VEGF在正常食管粘膜和食管癌组织中的表达用免疫组织化学法(SP法)测定。所有数据均通过SPSS 21.0统计软件处理。结果:VEGF的表达增强可能是鳞状细胞癌恶性度增高及发生淋巴结转移的标志,CT扫描增强幅度与食管癌中VEGF表达强弱无关。结论:VEGF的表达增强可能是鳞状细胞癌的发生及淋巴结发生转移的标志,CT扫描中病灶增强幅度不能反应肿瘤淋巴结的转移。     

多房囊性肾细胞癌的256层iCT诊断与病理对照

目的:探讨多房囊性肾细胞癌(MCRCC)的256层iCT增强扫描影像特征。方法:搜集6例经外科手术病理证实为多房囊性肾细胞癌患者的临床资料、CT影像资料及病理资料,对比分析多房囊性肾细胞癌的影像特点。结果:6例均发生于肾实质区,增强扫描可见不同程度囊性改变、无明显壁结节、有包膜边界清晰、肾盂肾盏无侵蚀破坏,无肾静脉癌栓形成,均无远处转移征象,3例行患侧肾全切除术,3例行肾肿瘤楔形切除术。结论:多房囊性肾细胞癌的256层iCT增强扫描表现有一定特征性,可作为术前诊断的理想手段,对治疗方案的优选及改善患者生存质量有积极意义。     

阿克苏地区西部冰雹天气雷达回波演变特征分析

利用2009—2020年阿克苏地区西部6县市中国气象局灾情直报、地面观测、阿克苏多普勒雷达资料,分析阿克苏雷达监测覆盖区冰雹天气时空分布及雹云雷达回波演变特征,结果表明：（1）2009—2020年共出现211站次冰雹,2011年最多,28站次;高发期为5—8月,6月冰雹频次最高;日变化峰值在16—19时。（2）雹云单体最强反射率因子均≥52 dBZ,回波顶高高于8 km,垂直累积液态水含量跃增达4.47 kg/m2及以上且垂直累积液态水含量最大值大于10.0 kg/m 2时雷暴单体发展为雹暴的可能性极大。超级单体雹暴反射率因子、回波顶高、VILmax统计指标均高于多单体和普通单体雹暴。（3）普通单体风暴多初生于乌什县、温宿县北部沿山一带;多单体雹云多初生于乌什县西部南部、温宿县北部沿山一带,乌什县境内最多;超级单体雹云多初生于温宿县。回波单体移动大多以西北-东南路径为主。（4）雹云回波发展初期往往伴随着第一次爆发式增长：反射率因子增大、回波顶升高、VIL跃增,超级单体雹暴表现更为明显,降雹时刻伴随着再一次爆发式增长。VIL急剧增大或急剧减少与降雹开始和结束关系最为密切。（5）超级单体雹暴维持时间和整体生命史均较多单体雹暴和普通单体雹暴时间长;多单体风暴需要较长的酝酿时间且影响区域较大。     

绿柱石与硅铍石原位结晶实验研究

绿柱石与硅铍石均为铍矿物家族中的主要成员,是重要的工业铍矿物,利用背散射和电子探针研究矿物特性时,常可见两者共生或发生交代的现象（饶灿,2009;Reyf, 2008; Evensen, 1999）,其结晶条件对于成矿环境与成矿机制均具有重要的指示意义。前人已进行了关于绿柱石,硅铍石等铍矿物稳定性的实验研究,但研究多采用高温淬火的高温高压实验装置,误差大,且无法原位观测矿物结晶习性（王振杰, 1992;Sirbescu et al., 2009）,本文利用热液金刚石压腔,原位观测了绿柱石与硅铍石的结晶过程,得到了它们结晶的温压条件及结晶习性。     

风暴分类识别技术在人工防雹中的应用

利用新一代多普勒天气雷达资料,在风暴跟踪识别算法的基础上,发展了风暴分类技术,以提高人工防雹作业指挥的效率。首先以SCIT算法为基础,结合风暴的结构特征,综合利用雷达、探空资料,自动提取风暴结构特征指数;其次采用基于决策树模型的风暴自动分类技术,将风暴按强度分为雷雨云、单体风暴、多单体风暴和强风暴;最后根据风暴强度、高度和位置等属性,对有可能产生冰雹的单体,结合GIS,自动对下游方向或附近作业点进行预警或输出作业参数。通过对2006—2014年期间重庆、辽宁大连和河南三门峡三地发生的较为典型的31次冰雹天气过程、182站次冰雹样本的检验来看:该方法通过对风暴按强度、垂直结构等综合属性进行分类,能有效提高冰雹识别的命中率、降低空报率,其中强风暴的命中率能达到100%,空报率仅为11.4%。能有效提高人工防雹作业的自动化程度,对防雹作业的科学决策有着重要参考作用。