煤变质作用对煤层气赋存和富集的控制--以沁水盆地为例

通过对国内外有关煤变质作用与煤层气形成、赋存和富集关系研究成果的系统总结，阐述了煤变质作用类型及煤变质作用程度与煤层气的生成、吸附量、煤储层孔隙—裂隙系统形成发育及煤层特性的相互关系，认为煤变质作用对煤层气赋存富集的影响集中体现在它对煤储层孔隙一裂隙系统形成发育过程的控制上。并以沁水盆地为例，探讨了高阶煤煤变质作用对煤层气赋存富集的控制作用，提出了对沁水盆地高阶煤煤层气勘探开发研究的几点思考和建议。     

喜马拉雅造山带中段亚东地区石榴角闪岩的成因：岩石学和锆石U- Pb年代学

喜马拉雅造山带中段出露的基性麻粒岩是理解印度大陆前喜马拉雅期演化历史和新生代碰撞造山作用的理想研究对象。本文对亚东多庆湖地区的石榴角闪岩进行了岩石学、全岩主微量元素地球化学和锆石U- Pb年代学研究,揭示了其原岩类型和新生代的变质作用过程。石榴角闪岩的原岩很可能为新元古代(~890 Ma)的玄武岩,具有E- MORB型岩石的地球化学特征。石榴角闪岩具有三期矿物组合：① 进变质矿物组合可能为石榴子石+角闪石+斜长石+钛铁矿+石英,即石榴子石核部及其中包裹体;② 峰期矿物组合为石榴子石+角闪石+斜长石+黑云母+石英,即石榴子石边部和基质矿物;③ 退变质矿物组合为角闪石+斜方辉石+斜长石+黑云母+石英,包括退变质域和石榴子石边部的后成合晶矿物。矿物温压计和相平衡模拟表明,石榴角闪岩进变质、峰期和退变质条件分别为609~621℃和0. 59~0. 65 GPa、805~845℃和0. 91~1. 04 GPa、825~840℃和0. 61~0. 68 GPa,经历了峰期高压麻粒岩相的变质作用。锆石U- Pb年代学研究表明,石榴角闪岩的峰期变质时间为34. 8~20. 3 Ma,退变质时间为18. 1~17. 7 Ma,可能经历了一个较长期的部分熔融过程。本文研究认为,亚东石榴角闪岩是印度板块向欧亚板块长期俯冲、地壳增厚成因的基性麻粒岩,原岩可能与Rodinia超大陆拼合相关;其以加热埋藏、近等温降压为特征的顺时针P- T轨迹指示了喜马拉雅造山带中段的大喜马拉雅岩系上部构造层位经历了长期持续的地壳增厚和高温麻粒岩相变质作用,以及早中新世(21~17 Ma)相对快速的减压抬升和随后(17 Ma之后)相对缓慢的折返至地表的演化过程。     

Early Cambrian high pressure/low temperature metamorphism in the southeastern Tarim craton in response to circum-Gondwana cold subduction

The circum-Gondwana subduction initiated by the early Cambrian has been suggested to reflect the establishment of the modern plate tectonics. The metamorphic rocks with low thermobaric (T/P) ratios indicative of cold subduction in the present tectonic regime have not been well investigated. To better understand the circum-Gondwana subduction and to test its possible link with the emergence of the modern plate tectonics, this study focused on blueschist-facies metamorphic rocks in the Altyn Tagh of the southeastern Tarim craton. Mineral assemblage and chemistry, phase equilibrium modelling, and quartz-in-garnet Raman elastic geobarometry reveal that the zoisite blueschist and glaucophane (Gln)-bearing quartz schist in northern Altyn Tagh were metamorphosed to lawsonite to epidote blueschist-facies at 520–545 °C and 16–19 kbar. It reflects high-pressure (HP)/low temperature (LT) metamorphism with low T/P ratios of <300 °C/GPa and thermal gradients of <10 °C/km. These blueschist-facies metamorphic rocks underwent rapid decompression starting at P-T conditions of <495 °C and <9.6 kbar during exhumation. Ar-Ar geochronology records paragonite Ar-Ar plateau ages of 520–506 Ma for the zoisite blueschist samples and phengite Ar-Ar plateau ages of 522–516 Ma for the Gln-bearing quartz schist samples, suggesting that the peak HP/LT metamorphism occurred prior to ca. 522 Ma. Based on new results and available data from the major Gondwana blocks, cold subduction was suggested to profoundly operate along circum-Gondwana in the early Cambrian after the amalgamation of Gondwana. The extensive circum-Gondwana subduction represents the earliest global cold subduction in Earth’s history associated with the establishment of the modern plate tectonics, as directly recorded by the studied early Cambrian blueschist-facies metamorphic rocks and a dramatic drop in the mean T/P of metamorphism since the early Paleozoic.     

Quantitative Constraints on Metamorphism in the Variscides of Southern Brittany--a Complementary Pseudosection Approach

Previous studies of metapelitic rocks from the core of the southernBrittany metamorphic belt suggest a complex clockwise P–Tevolution. We use pseudosections calculated for an average subaluminousmetapelite composition in the MnNCKFMASH system and averageP–T calculations to investigate in more detail the metamorphicevolution of these rocks. For migmatites, sequential occurrenceof kyanite, kyanite + staurolite and sillimanite suggests thata prograde evolution to P > 8 kbar at T     

Paleozoic serpentinite-enclosed chromitites from Tehuitzingo (Acatlán Complex, southern Mexico): a petrological and mineralogical study

The serpentinites and associated chromitite bodies in Tehuitzingo (Acatlán Complex, southern Mexico) are in close relationship with eclogitic rocks enclosed within a metasedimentary sequence, suggesting that the serpentinites, chromitites and eclogitic rocks underwent a common metamorphic history.Primary chromites from the chromitite bodies at Tehuitzingo are of refractory-grade (Al-rich) and have a chemical composition similar to that expected to be found in an ophiolitic environment. The chromite grains in chromitites and serpentinites are systematically altered to ‘ferritchromite’. The alteration trend is usually characterized by a decrease in the Al, Mg and Cr contents coupled by an increase in Fe³⁺ and Fe²⁺.The Tehutizingo chromitites have low Platinum Group Elements (PGE) contents, ranging from 102 to 303 ppb. The chondrite-normalized PGE patterns are characterized by an enrichment in the Ir-subgroup elements (IPGE=Os, Ir, Ru) relative to the Pd-subgroup elements (PPGE=Rh, Pt, Pd). In addition, all chromitite samples display a negative slope from Ru to Pd [(Os+Ir+Ru)/(Pt+Pd)=4.78−14.13]. These patterns, coupled with absolute PGE abundances, are typical of ophiolitic chromitites elsewhere. Moreover, all the analyzed samples exhibit chondrite-normalized PGE patterns similar to those found for non-metamorphosed ophiolitic chromitites. Thus, the PGE distribution patterns found in the Tehuitzingo chromitites have not been significantly affected by any subsequent Paleozoic high-pressure (eclogite facies) metamorphic event.The chondrite-normalized PGE patterns of the enclosing serpentinites also indicate that the PGE distribution in the residual mantle peridotites exposed in Tehuitzingo was unaffected by high-pressure metamorphism, or subsequent hydrothermal alteration since the serpentinites show a similar pattern to that of partially serpentinized peridotites present in mantle sequences of non-metamorphosed ophiolites.Our main conclusion is that the chromitites and serpentinites from Tehuizingo experienced no significant redistribution (or concentration) of PGE during the serpentinization process or the high-pressure metamorphic path, or during subsequent alteration processes. If any PGE mobilization occurred, it was restricted to individual chromitite bodies without changing the bulk-rock PGE composition.Our data suggest that the Tehuitzingo serpentinites and associated chromitites are a fragment of oceanic lithosphere formed in an arc/back-arc environment, and represent an ophiolitic mantle sequence from a supra-subduction zone, the chemical composition of which remained essentially unchanged during the alteration and metamorphic events that affected the Acatlán Complex.     

北秦岭二郎坪群低压变质作用研究

在对二郎坪群低压变质带进行相图分析后发现，二郎坪群低压变质带是叠加变质带，低压变质作用是在早期中压变质的抬升过程中发生的，中压变质的温压条件为0．5-0．6GPa、560～580℃，低压变质的压力为0．3-0．45GPa，红柱石-十字石带的温度为510～580℃，堇青石带为590-620℃。pT视剖面图在区分岩石中不同条件和期次的矿物组合及分析岩石温压演化历史和温压条件时显得更行之有效。     

Three mechanisms of ore re-mobilisation during amphibolite facies metamorphism at the Montauban Zn–Pb–Au–Ag deposit

The relative importance of mechanical re-mobilisation, hydrothermal dissolution and re-precipitation, and sulphide melting in controlling redistribution of metals during concurrent metamorphism and deformation is evaluated at the middle amphibolite facies Montauban deposit in Canada. As at many other deposits, ductile deformation was important in driving mechanical re-mobilisation of massive sulphides from limb regions into hinge regions of large-scale folds and is thus the most important for controlling the economics of Pb and Zn distribution. Two possible stages of hydrothermally driven re-mobilisation are discussed, each of which produces characteristically different alteration assemblages. Prograde hydrothermal re-mobilisation is driven by pyrite de-sulphidation and concurrent chlorite dehydration and is thus an internally driven process. At Montauban, the H₂S-rich fluid generated through this process allowed re-mobilisation of gold into the wall rock, where it was deposited in response to sulphidation of Fe Mg silicates. Retrograde hydrothermal re-mobilisation is an externally driven process, whereby large volumes of fluids from outside the deposit may dissolve and re-precipitate metals, and cause hydration of silicate minerals. This second hydrothermally driven process is not recognised at Montauban. Sulphide melting occurred as temperatures neared the peak metamorphic conditions. Melting initiated in the massive sulphides through arsenopyrite breakdown, and a small volume of melt was subsequently re-mobilised into the wall rock. Trace element partitioning and fractional crystallisation of this melt generated a precious metal-rich fractionate, which remained mobile until well after peak metamorphism. Thus, prograde hydrothermal re-mobilisation and sulphide melting were the most important mechanisms for controlling the distribution of Au and Ag.     

点苍山-哀牢山变质杂岩带变沉积岩的变质演化

点苍山-哀牢山变质杂岩带位于青藏高原东南缘大理-元江-元阳-河口一带,出露规模达数百千米,是扬子板块和印支陆块之间的一条重要构造带.该变质杂岩带主要由各类正片麻岩、副片麻岩、大理岩所组成,夹有斜长角闪岩、石榴辉石岩和超镁铁质岩石的透镜体或团块.其中,变沉积岩如含夕线石和蓝晶石的片麻岩类岩石保存了多阶段的矿物组合及异常复杂的矿物相转变关系.详细的岩相学、成因矿物学以及矿物相转变关系分析表明,变沉积岩系经历了早期进变质阶段(M1)、峰期角闪-麻粒岩相变质阶段(M2)、峰后近等温减压(脱水熔融)阶段(M3)以及晚期退变质阶段(M4)的变质演化.其中,M1阶段的稳定矿物组合为石榴石+斜长石+白云母+石英+十字石±蓝晶石±黑云母±钾长石,M2阶段的稳定矿物组合为石榴石+黑云母+蓝晶石/夕线石+斜长石+石英、石榴石+黑云母+斜长石+石英±钾长石±夕线石,M3阶段的共生矿物组合为石榴石+黑云母+夕线石+斜长石+石英,M4阶段的矿物组合为黑云母+白云母+斜长石+石英±钾长石±石榴石等.通过传统GB-GASP温压计和二云母温度计的估算结果,配合P-T视剖面定量计算,确定早期进变质阶段(M1)的温压条件为T=560 ～ 590℃,P=5.5 ～6.3kb,峰期角闪-麻粒岩相阶段(M2)的温压条件为T=720～ 760℃、P=8.0～9.3kb,峰后近等温减压阶段(M3)的温度压力条件为T=640～760℃,P=5.0～7.3kb,晚期退变阶段(M4)的温压条件为T=521～648℃,P=4.0～5.0kb.上述研究结果表明,点苍山-哀牢山变沉积岩记录了典型碰撞造山带型式的顺时针P-T演化轨迹,表明点苍山-哀牢山变质杂岩带的形成与印度板块和欧亚板块之间的俯冲-碰撞存在密切的成因关系.     

New constraints on UHT metamorphism in the Eastern Ghats Province through the application of phase equilibria modelling and in situ geochronology

High Mg–Al granulites from the Sunki locality in the central portion of the Eastern Ghats Province record evidence for the high-temperature peak and retrograde evolution. Peak metamorphic phase assemblages from two samples are garnet + orthopyroxene + quartz + ilmenite + melt and orthopyroxene + spinel + sillimanite + melt, respectively. Isochemical phase diagrams (pseudosections) based on bulk rock compositions calculated in the chemical system Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–Fe₂O₃ (NCKFMASHTO) and Al contents in orthopyroxene indicate peak UHT metamorphic conditions in excess of 960 °C and 9.7 kbar. Microstructures and the presence of cordierite interpreted to record the post-peak evolution show that the rocks underwent decompression and minor cooling from conditions of peak UHT metamorphism to conditions of ~ 900 °C at ~ 7.5 kbar. In situ U–Pb isotope analyses of monazite associated with garnet and cordierite using the Sensitive High Resolution Ion Microprobe (SHRIMP) yield a weighted mean ²⁰⁷Pb/²³⁵U age of ca. 980 Ma, which is interpreted to broadly constrain the timing of high-temperature monazite growth during decompression and melt crystallization at ~ 900–890 °C and 7.5 kbar. However, the range of ²⁰⁷Pb/²³⁵U monazite ages (from ca. 1014 Ma to 959 Ma for one sample and ca. 1043 Ma to 922 Ma for the second sample) suggest protracted monazite growth during the high-temperature retrograde evolution, and possibly diffusive lead loss during slow cooling after decompression. The results of the integrated petrologic and geochronologic approach presented here are inconsistent with a long time gap between peak conditions and the formation of cordierite-bearing assemblages at lower pressure, as proposed in previous studies, but are consistent with a simple evolution of a UHT peak followed by decompression and cooling.     

华南晚古生代末超高温变质作用:以十万大山花岗岩中麻粒岩包体为例

广西东南部大容山-十万大山地区过铝质(S型)花岗岩中包含丰富的副变质麻粒岩包体.部分麻粒岩包体保留了尖晶石+石英、斜方辉石+夕线石±石英等超高温变质矿物组合,指示这些麻粒岩包体曾经历了超高温变质作用.矿物温压估算结果显示:峰期温压条件为7.5～8.0kbar,950～1000℃,峰后退变质温压条件为3.2～3.7kba...