Morphology, mineralogy and magnetic susceptibility of epikarst-Terra Rossa developed in late Quaternary aeolianite deposits of southeastern Saurashtra, India

The nature and development of epikarst and soil development in aeolianites under a monsoonal climatic regime has not yet been described. Late Quaternary aeolianites of the southeastern coast of Saurashtra in western India show a wide array of epikarst and red-soil formation, and serve to typify the character of aeolianite weathering under a monsoonal climate. Three varieties of epikarst are identified that represent down-profile increase in groundwater flow. Five types of Terra Rossae represent a transition from the karstified limestone to soil development. Terra Rossae differ in the content of residual aeolianite and show both simple and complex profiles. The latter at places shows ped development. The results show that an ontogenetic (growth) sequence exists from incipient epikarst to complex palaeosols. This ontogenetic sequence represents an incremental increase in the groundwater budget of the region in response to changing intensification of the Indian monsoon rainfall. Magnetic properties of the Terra Rossae formed under a monsoonal climate are described for the first time. The magnetic susceptibility together with its frequency-dependent and anhysteretic remanent magnetization (ARM) represents both the concentration of single domain and ultrafine superparamagnetic (SP) magnetite. The formation of single domain and superparamagnetic magnetite and hematite are linked genetically to weathering of the aeolianite that leads to the formation of Terra Rossa.     

油气充注对成岩作用的影响

油气充注对成岩作用的影响有三个方面 :抑制石英和伊利石的胶结作用、油气中所有机酸对深部孔隙的溶蚀改造作用、油气超压对压实的缓冲作用。英国北海Miller油气藏等的资料显示 ,油气充注较早时 ,油区的石英胶结速率比水区的明显要低 ,石英的胶结丰度比一般预测值低 ,而孔隙度比一般的预测值要高。我国渤海湾盆地东营凹陷油田资料显示 ,无论浅部或深部 ,凡是含油砂岩 ,其长石类及碳酸盐类矿物的溶解都十分强烈 ,次生孔隙很发育 ,而不含油的砂岩 ,其矿物溶解及次生孔隙发育一般较差 ;油层的方解石、白云石含量一般比水层低 ,深层尤为明显。干酪根生成油气时的流体体积增加 ,可大大增加孔隙流体压力 ,产生超压 ,并可传递到储集层 ,因而大大增加对压实作用的抵抗能力。上述三方面实质上都为深部油气成藏改善了储层基础 ,对深部油气勘探具有非常现实的意义。     

Early and pervasive dolomitization by near-normal marine fluids: New lessons from an Eocene evaporative setting in Qatar

The upper Palaeocene–lower Eocene Umm er Radhuma Formation in the subsurface of Qatar is dominated by subtidal carbonate depositional packages overlain by bedded evaporites. In Saudi Arabia and Kuwait, peritidal carbonate depositional sequences with intercalated evaporites and carbonates in Umm er Radhuma have been previously interpreted to have been dolomitized via downward reflux of hypersaline brines. Here, textural, mineralogical and geochemical data from three research cores in Qatar are presented which, in contrast, are more consistent with dolomitization by near-normal marine fluids. Petrographic relationships support a paragenetic sequence whereby dolomitization occurred prior to the formation of all other diagenetic mineral phases, including chert, pyrite, palygorskite, gypsum, calcite and chalcedony, which suggests that dolomitization occurred very early. The dolomites occur as finely crystalline mimetic dolomites, relatively coarse planar-e dolomites, and coarser nonplanar dolomites, all of which are near-stoichiometric (50.3 mol% MgCO₃) and well-ordered (0.73). The dolomite stable isotope values (range −2.5‰ to +1‰; mean δ¹⁸O = −0.52‰) and trace element concentrations (Sr = 40 to 150 ppm and Na = 100 to 600 ppm) are compatible with dolomitization by near-normal seawater or mesohaline fluids. Comparisons between δ¹⁸O values from Umm er Radhuma dolomite and the overlying Rus Formation gypsum further suggest that dolomitization did not occur in fluids related to Rus evaporites. This study provides an example of early dolomitization of evaporite-related carbonates by near-normal seawater rather than by refluxing hypersaline brines from overlying bedded evaporites. Further, it adds to recent work suggesting that dolomitization by near-normal marine fluids in evaporite-associated settings may be more widespread than previously recognized.     

Tracing suspended organic nitrogen from the Yangtze River catchment into the East China Sea

Total suspended matter was collected along the Yangtze River (Changjiang) and in the East China Sea in April to May and in September 2003, respectively, to study origin and fate of particulate organic nitrogen. Concentrations of particulate organic carbon (POC), nitrogen (PN) and hydrolyzable particulate amino acids (PAA; d- and l-enantiomers) were higher in the Yangtze Estuary than in the river and decreased offshore towards the shelf edge. In the coastal area, higher values of PAA were observed in the surface layer than in the bottom water. Stable carbon isotope ratios (δ¹³C) of POC increased from − 24.4‰ in the river to values around − 21‰ on the East China Sea Shelf. Dominant amino acids were aspartic acid + aspartine (Asx), glutamic acid + glutamine (Glx), glycine, alanine and serine. The proportions of Asx, Glx and isoleucine were higher in the marine than in the riverine samples contrary to the distributions of glycine, alanine, threonine and arginine. The proportions of d-amino acids were highest in the riverine suspended organic matter (6% of PAA) decreasing towards the shelf edge (1.5% of PAA). d-arginine, not reported in natural aquatic samples so far, was the most abundant d-amino acid in the river. The amino acid composition of the particulate organic matter (POM) in the Yangtze River indicates an advanced stage of degradation of POM. Highly degraded organic matter from soils is probably a main source of POM in the Yangtze River, but the relatively high δ¹³C values and low C/N ratios (7.7 ± 1.6) also indicate contribution from anthropogenic sources. The degraded riverine material was a dominant organic matter source in the estuary, where aquatic primary production had only a small overall contribution. In the East China Sea, gradual settling of riverine organic matter and the addition of fresher phytoplankton impacted the amino acid composition and δ¹³C values, and on the outer shelf relatively fresh phytoplankton-derived organic matter dominated.     

Sedimentation, depositional environment and diagenesis of Eocene biosiliceous deposits in Gafsa basin (southern Tunisia)

The sedimentary rocks of the Metlaoui Formation in the Gafsa basin (southern Tunisia), which may be grouped in three units: the basal (Thèlja), middle (Chouabine) and upper unit (Kef Eddour), provide a record of preserved sedimentary, authigenic and biological processes. This paper presents the findings of sedimentological investigations of the biosiliceous deposits of the middle unit. This unit contains either well-preserved (Opal-A) or diagenetically altered (Opal-CT, clinoptilolite, quartz and even clays) diatom frustules. Such diagenetic changes are commonly described in marine and lacustrine biosiliceous deposits. The fossil content of theses diatomaceous layers implies shallow-marine conditions.The opal-rich sediments, and the associated facies record the transgressive transitions associated with high organic productivity, probably enhanced by seasonal input of nutrients, and high sea level stands, and a close association with stratified water column conditions. The formation of bedded diatomaceous sediments is known to require either high organic productivity or anoxic conditions in bottom/intermediate water, and eventually both processes. The initial organic content of the biogenic deposits was impoverished in early stages of sedimentation and diagenesis. A large part of the organic matter could have been destroyed during early diagenetic processes and from further oxidation in outcrops.     

鄂尔多斯盆地镇泾区块延长组长81储层成岩作用特征及其对储集物性的影响

鄂尔多斯盆地镇泾区块上三叠统延长组长81储层具有成分成熟度低,结构成熟度中等到好的特点,岩性以岩屑长石砂岩和长石岩屑砂岩为主.长81砂岩属于特低孔特低渗储层,以次生溶蚀粒间孔为主要储集空间.目前储层正处于中成岩阶段A期,主要发育压实、胶结、溶解和交代4种成岩作用类型.机械压实作用是造成长81储层埋深小于2000 m砂岩...     

福州盆地全新世沉积物的磁学性质及其对环境变化的响应

福州盆地位于海陆过渡地带,在海陆变迁过程中,沉积物记录了高分辨率的环境信息,是揭示沉积特征对环境变化响应过程及模式的理想区域.本文选择位于福州盆地的FZ5钻孔进行岩石磁学、环境磁学和古地磁学方面的研究,以期阐明该区域沉积物磁学性质对陆源碎屑输入、海平面变化和成岩作用的响应.岩石磁学结果表明钻孔沉积物以低矫顽力的亚铁磁性矿物为主体,但是在不同的环境变化阶段,磁性矿物的类型有较大变化.在9~3 cal. ka BP的海侵过程中,沉积物中以磁铁矿为主体,存在菱铁矿和铁硫化物等还原性矿物.硫化作用使细粒磁铁矿溶解形成胶黄铁矿和黄铁矿,其峰面随碎屑磁性矿物的浓度变化而迁移.但硫化作用没有完全消除磁铁矿携带的特征剩磁和陆源碎屑输入量以及海平面升降对该阶段沉积物磁性的控制.在~3 cal. ka BP以来随着海平面下降、沉积环境向陆相氧化环境转化,虽然早期还原作用仍然存在,但后期氧化作用使磁性矿物向高矫顽力的赤铁矿等矿物转变,氧化作用基本扰乱了磁铁矿携带的剩磁.沉积及其后期成岩作用过程中,发生在约~8.2、~7.7、~7.5、~2.7、~1.5、~0.5 cal. ka BP六次强烈的古氧化界面反映了福州盆地当时异常干旱或湿热的气候事件.     

元坝气田长兴组储层特征与形成主控因素研究

本文以宏、微观资料相结合的方法,以优质储层发育与形成为主线开展了元坝气田长兴组礁滩储层发育特征研究。研究证明:(1)元坝气田长兴组礁滩储层岩石类型以亮晶生屑灰岩与亮晶生屑白云岩等颗粒岩为主,西部礁滩储层白云岩含量高于东部,长二段礁滩储层白云岩含量高于长一段浅滩储层;(2)储层类型以孔隙型为主,裂缝-孔隙型次之,储集空间包括晶间溶孔、晶间孔、粒间溶孔及裂缝;(3)元坝地区长兴组礁滩储层以Ⅱ、Ⅲ类为主,西部物性好于东部,长二段储层厚度远大于长一段。元坝地区长兴组储层受沉积相、构造活动及成岩作用等控制,受沉积前古地貌和燕山期后构造作用的双重控制,西部储层物性好于东部;3期破裂作用与3期溶蚀作用是形成储层的关键。     

羌塘盆地侏罗系低渗透碎屑岩储集层特征

羌塘盆地侏罗系碎屑岩主要包括三角洲相、滨海相和河流相砂体,岩性以细砂岩和粉砂岩为主。储层经历了较强的压实作用和胶结作用,颗粒间线—凹凸接触,胶结物主要为钙质和硅质,储集空间以次生溶孔为主,包括颗粒溶孔、粒间溶孔等,溶孔以中孔和小孔为主,喉道为细喉和微喉,构造裂缝的发育对改善储层的渗透性有重要作用。物性统计表明:孔隙度大多小于5%,渗透率小于1mD,为低孔、低渗储层。结合低渗储层分类标准,将碎屑岩储集层分为3类进行了评价,认为上侏罗统雪山组储层最好,其次为中侏罗统雀莫错组,而夏里组相对较差;最有利储集层发育区主要位于北羌塘坳陷西部中央隆起带北缘和盆地东部雀莫错地区,较有利储层发育区位于北羌塘坳陷中部和东部地区,南羌塘坳陷储集层较差。压实作用和胶结作用较强,后期溶蚀作用相对较弱,是造成目前低孔低渗储层的主要因素。