黑水─泉州地学断面的重磁解释

讨论华南黑水─泉州地学断面的重磁解释。在解释中除应用常规的２．５维重磁异常反演外，还采用等密度线算法构制梯度层密度模型，用于分辨地壳密度细结构，以及计算自由地幔而深度用于分析上地幔密度的横向不均匀性。重磁模拟结果揭示了１０ｋｍ深度内的上地壳构造以及地壳与上地幔密度的分布。提出华南造山带以低密度上地幔为特征，它可能与上地幔的改造有关；四川盆地具有较高的上地幔密度，为未经改造的原始地幔。扬子克拉通与华南造山带的分界线与上地幔密度的分界线一致。根据布格异常、地表岩石密度和地形资料的综合分析，圈定出反映内生成矿作用深部标志的密度倒转区，可作为进一步找矿的远景区。     

黄河大柳树坝基岩体地震破坏后的密度特征

本文通过对岩体地震破坏后的弹性波测试，分析其波速的制约因素，采取相应的计算公式讨论了岩体密度的计算方法，并将其与平硐内壁裂隙统计计算出的岩体密度值做了比较，说明应用弹性波速计算岩体密度的精度与科学性。     

Evaluation of density in layer compaction using SASW method

SASW test, which is non-intrusive and rapid in the field application, was used to evaluate the layer density in the roller compaction without performing the complicated inversion process. The concept of normalized shear wave velocity was introduced to minimize the effect of confinement in the density evaluation. SASW test was performed to determine the shear wave velocity of the layer, and the free–free resonant column (FF–RC) test was adopted to determine the correlation between the normalized shear wave velocity and density of the site, which is almost unique independent of confinement. Testing and data reduction procedures of both tests were briefly discussed and an evaluation procedure of the field density was proposed by effectively combining in-situ shear wave velocity determined by the SASW test with the correlation between the normalized shear wave velocity and the density determined by the FF–RC test. Finally, the feasibility of the proposed method was verified by performing a field case study at Hoengsung road construction site. Field densities determined by the proposed method matched well with those determined by sand cone tests, showing the potential of applying the proposed method in the field density evaluation.     

上行离子密度分布特性的理论研究

采用动力学方程，求解了定态情况下磁层中上行离子沿磁力线的分布函数，针对不同的Ｋ_ｐ指数，分别对北半球极光带区起源的上行离子Ｏ_＋、Ｈ_＋和Ｈｅ_＋在子午面内沿磁力线的密度分布及其特性进行了研究．结果表明：１．沿磁力线向外，上行离子密度在近地空间呈急剧下降趋势，在远地空间呈缓慢下降趋势；２．重离子或初始能量较小的离子，其密度沿磁力线向外下降较快；３．Ｋ_ｐ指数越大，离子进入磁层的空间范围越大；４．离子的投掷角分布对密度分布的影响甚小；５．离子密度沿磁力线的下降程度随到Ｘ轴距离的增大而呈增大趋势；６．在典型参数条件下，求得上行离子Ｏ_＋在等离子体片边界附近的密度为１０^－３－１０^－２个ｃｍ^－３，这与观测结果相一致．     

重力学反问题中零外部位密度的研究

对重力学反问题研究中零外部位密度的数学性质及物理意义进行了系统研究和分析．首先从基本定义及条件的描述入手，推演出其数学表示和限制，由此揭示重力学反问题的非适定性形态，进而论及其与非零外部位密度之间的数学关系．由此证明对应于给定外部位的场源函数可以分解成零外部位密度与调和密度的直和．通过对其物理意义的讨论，为地球物理反演非零外部位场源及物理大地测量学构制等效场源提供理论依据．     

热液体系氢、氧同位素分馏机制及其地质意义

探讨了热液体系氢、氧同位素地球化学行为及其与水/岩交换同位素分馏的内在关系。有效W/R值是除温度条件外,另一控制蚀变岩石和热液水氢、氧同位素组成变化的因素。此外还根据数个矿区成矿热液水和蚀变岩石氢、氧同位素组成及变化特征对水/岩交换和W/R值的应用及地质意义展开讨论。最后提出热液体系中大气降水和岩浆热液水氢、氧同位素组成演化模式简图。     

Studies on Separation of Heavy Metals from Acidic Solutions by Foam Fractionation with Respect to an Application on Acidic Soil Extracts

An experimental investigation is presented on the batch foam fractionation of the heavy metal cations Pb²⁺, Cd²⁺, Cu²⁺, Sb³⁺ and As⁵⁺ from diluted aqueous solutions with hexamethylenedithiocarbamate (HMDC) as complexing agent and sodiumdodecylsulfate (SDS) as surfactant. Among the considered pH-values of 2,4 and 7 the pH 2 experiments allow a direct application of foam fractionation on acidic extracts from heavy metal contaminated soil. The experiments at pH 2 and pH 4 show better results than those at neutral pH. Although a simple device was used, a maximum enrichment factor of 13.8 and a minimum removal factor of 0.01 have been measured. The flotation with weak organic acids like citric acid (CA) and acetic acid (AA) show about 50–70% smaller enrichment factors than those acidified with hydrochloric acid. The dissolution and mixing of the reacting components as well as the concentration of the detergent and the gaseous volume flow can be regarded as basic parameters of foam fractionation.     

稳定氯同位素分馏机理及其应用的研究

过去一直认为稳定氯同位素比值(~(37)Cl/~(35)Cl)几乎不变。80年代以来利用高精度质谱法成功地发现了自然界氯同位素分馏作用。单纯的溶解和对流迁移作用不能引起同位素组分变化,而扩散作用、离子渗透作用和对流混合作用却可导致同位素分馏。各地不同深度海水的氯同位素成分极为一致,故以标准平均海水氯(SMOC)作为对比标准。得克萨斯—路易斯安那海湾油田水的δ~(37)Cl大致为+0.5‰~-1.25‰,且与氯浓度大致呈正相关。热液成矿系统中,氯同位素可作为研究矿床成因的示踪剂,如美国田纳西州密西西比河谷型矿床(MVD)的δ~(37)Cl在+0.2‰~-1.1‰之间,几个斑岩铜矿床(PVD)的早期脉岩与晚期脉岩中不同δ~(37)Cl的存在,都表明在成矿过程中有不同氯源的参与。     

Intracrystalline fractionation of Fe in synthetic (Fe, Mg, Zn) - bearing staurolite: a Mössbauer spectroscopic study

⁵⁷Fe-Mössbauer spectra of eleven Fe-Mg-bearing staurolite samples, synthesized at 5, 20 and 25 kbar and 680°C, ranging in composition from x_Fe?=1.00 to x_Fe?=0.15, and of two Zn-Fe-bearing staurolite samples, synthesized at 20 kbar and 700°C with x_Fe?=0.10 and x_Fe?=0.32 were collected at room temperature. The spectra reveal that about 80% of Fe_tot (in case of Fe-Mg-bearing staurolite) and about 70% of Fe_tot (in case of Fe-Zn-bearing staurolite) are located as Fe²⁺ at the three subsites Fe1, Fe2 and Fe3 of the tetrahedral T2-site. The refinement of the spectra results in almost identical values for the isomer shift (IS) (±1.0 mm/s) but significantly different values for the quadropole splitting (QS) for the three subsites which is in accordance with the different distortions of these sites. About 8% of Fe_tot (in case of Fe-Mg-bearing staurolite) and 13% of Fe_tot (in case of Fe-Zn-bearing staurolite) are located as Fe²⁺ at the octahedral M4 site, while the remainder percents of Fe_tot indistinguishably occur as Fe²⁺ at the octahedral M1 and M2 sites of the kyanite-like part of the structure. Within the whole Fe-Mg-staurolite solid solution series the Mössbauer parameters QS of the sites M4 and (M1, M2) vary systematically with composition whereas IS remains constant. There is a high negative correlation of the total Mg-content with Fe-occupation of all the Fe-bearing sites indicating a continuous substitution of Fe²⁺ by Mg on all these sites. Synthetic Fe-staurolites show no increasing occupation of the octahedral sites by two-valent cations with pressure, as was assumed by several authors.