滇西兰坪盆地茅草坪脉状Cu矿床流体包裹体和稳定同位素地球化学研究

兰坪盆地西缘发育一条重要的脉状Cu矿带,矿床的成矿流体来源一直存在较大的争议。本次研究对该矿带南段新发现的茅草坪矿床进行流体包裹体和H-O-C-S同位素研究,结合前人发表的该矿带矿床的同位素数据,探讨矿床成矿流体特征和来源。茅草坪矿床早(A1脉)、晚(A2脉)两期含矿石英脉中的流体包裹体均为含CO2盐水包裹体,可细分为含石盐子晶、富液相(水溶液相)、富气相(CO2相)包裹体等不同类型。根据流体包裹体的共生特点,将其划分为3组包裹体组合:(1)第I组,出现在A1脉石英中,为富液相(I-W型)、富气相(I-C型)和含石盐子晶(I-S型)包裹体共生;(2)第Ⅱ组,同样出现在A1脉石英中,为富液相(Ⅱ-W型)和富气相(Ⅱ-C型)包裹体共生;(3)第Ⅲ组,出现在A2脉石英中,为富液相(Ⅲ-W型)和富气相(Ⅲ-C型)包裹体共生。测温结果显示:I-S型包裹体均一温度在293~370℃之间,流体盐度为30.06%~39.76%Na Cleqv;Ⅱ-W型包裹体均一温度在302~490℃之间,流体盐度为1.23%~18.63%Na Cleqv;Ⅲ-W型包裹体均一温度在263~400℃之间,流体盐度为1.20%~11.34%Na Cleqv。同一组内,包裹体气/液相比高度变化,表明包裹体捕获时的流体呈不均一态,此时包裹体均一温度中低值部分近似代表该组包裹体真实的捕获温度。因此,从I组到Ⅲ组,包裹体分别捕获于280~320℃(I组、Ⅱ组)和260~280℃(Ⅲ组),结合盐度数据,反应初始成矿流体发生沸腾作用,伴随石盐子晶析出,流体盐度下降,随后温度降低。茅草坪矿床成矿流体富CO2的特点与区域内其他脉状Cu矿床一致,但盐度明显偏高。矿床热液石英的δDV-SMOW值变化在-94.6‰~-56.2‰之间,计算的流体的δ18OV-SMOW值集中在+8.1‰~+9.6‰之间,与区域其他脉状Cu矿床相似,数据主要落在原生岩浆水区域的下方,表明流体来源于岩浆水,但经历了开放系统下的脱气作用,没有盆地流体或大气降水的贡献;热液碳酸盐方解石的δ13CV-PDF值为-8.3‰~-2.4‰,δ18OV-SMOW值为14.46‰~16.63‰,与区域其他脉状Cu矿床的C-O同位素组成相似,但C同位素组成明显低于区域脉状Pb-Zn矿床(碳主要来自盆地流体溶解的碳酸盐岩);黄铜矿的δ34SV-CDT值变化于-6.4‰~-3.9‰之间,处于区域其他脉状Cu矿床的S同位素组成范围内,但区别于区域砂岩型Cu矿床(硫来自硫酸盐的细菌还原作用)。因此,推测矿床的CO2和硫可能也来自脱气的岩浆。茅草坪脉状Cu矿床成矿流体的研究表明:兰坪盆地西缘脉状Cu矿床成矿流体可能来自富CO2、经历脱气的岩浆水,没有大气降水和盆地卤水的参与。     

青海祁漫塔格卡尔却卡铜多金属矿区矿床地质特征及控矿因素

卡尔却卡地区是青海省重要的铁、铜、铅、锌、金多金属矿集区,具有特征明显的构造-岩浆岩带。在分析区内地层、构造、岩浆岩及接触带等控矿因素与成矿的关系的基础上,建立了找矿标志;根据区内的成矿特征,初步认为卡尔却卡多金属矿床为斑岩型矿床成矿系列,有斑岩型、夕卡岩型和蚀变岩型3种成因类型,形成斑岩-夕卡岩-热液成矿系统,成矿作用均与中-晚三叠世底侵事件有关。     

赞比亚铜带省桑巴(Samba)铜矿床地质特征及其找矿意义

桑巴铜矿床位于赞比亚铜带省,卡富埃背斜的西翼,接近加丹加地层和不整合接触带的基底中。矿床中主要有价矿物为黄铜矿和斑铜矿,TCu平均品位1.67%,呈脉状,赋矿于基底莫瓦亚群的石英-绢云母/黑云母片岩中,矿化受片理控制明显,具有Cu-Mo矿化组合,其矿化控矿地质因素、矿化蚀变特征、与该区砂页岩型铜钴矿有明显的差异,为该区找矿开拓了新的找矿方向,也为在赞比亚铜矿带寻找新类型矿床提供了有力的依据。     

Deposit modeling of a nickel belt in Finland

Data from 34 Ni−Cu deposits of the 315^c-striking, 420-km long, and 10–40-km wide Kotalahtinickel belt have been recorded in the previously described system of the Ore Data File of Finland. For comparison data from four Ni−Cu deposits outside the belt have been collected. The statistical treatment of the data begins with cluster analysis and four classes are distinguished on the basis of 303 data elements. These classes form eight groups within the linear belt. Two groups containing the largest deposits, Hitura and Kotalahti, are processed by characteristic analysis, and factor analysis is applied to test the interdependence of the characteristics. This paper was presented at the International Geological Correlation Program (IGCP) Project 98: “Standards for Computer Applications in Resource Studies” held at Taita Hills, Kenya, November 8–15, 1977.     

欧亚黄土沉积环境对比研究

本文对采自中国、法国、比利时等国43块黄土样品进行实验室处理后,分析对比了它们在碳酸盐含量、粒度组成、重矿物组成及粘土矿物成分方面的共同特性及差异性。结果表明,中国黄土碳酸盐含量稳定,西欧不同类型的黄土碳酸盐含量差别很大。在粒度组成上,欧亚黄土并没有本质的差别,但西欧不同层位的黄土粒度组成呈有规律变化。对西欧重矿物的分析可以追溯黄土的物质来源,粘土矿物含量在欧亚不同黄土中也有差别。比较结果说明,欧洲的黄土堆积受第四纪冰期、间冰期的气候波动影响较大,中国黄土在堆积期间始终处在干旱、半干旱的气候条件下。     

东川拖布卡金矿矿化层位与找金方向

超大型拖布卡金矿的发现,表明东川地区具备找金前景.“黑层”是金的成矿前提,断裂加蚀变是成矿必备条件,基性与中性岩脉在容矿层中的侵位,是找富金的重要标志.金成矿全过程应是多旋回（晋宁、华力西、燕山、喜马拉雅山）成矿作用,且受剪切破碎带控制的黑层型金矿.     

Study on the relationship between speciation of heavy metals and their ecotoxicity

Heavy metal is a main pollutant in the marine ecosystem, so study on the effect of heavy metal on phytoplankton is important. Algae (Chaetoceros sp.,Dunaliella sp.,Dicrateria zhanjiangenis Hu. var. sp.) were laboratory cultured to observe the effect of heavy metals on their growth. The effect of different metal ion concentration, the detoxication effect of complexation agents and the growth of algae in different media and different nutrition levels were studied to evaluate the effect of metal speciation. It is proved that trace amount of heavy metals can stimulate the growth of algae cells but that high concentration is lethal. The sequence of toxicity is Cd²⁺>Zn²⁺>Pb²⁺. In ordinary nutrition conditions, the detoxication sequence of complexation agents toChaetoceros sp. is EDTA >sodium salicylate>sodium oxalate >sodium citrate>sulfanilic acid>O-phenanthroline. This is in good conformity with the stability constant sequence of these agents with copper and good evidence that toxicity of metal ion is related to its activity and not to its total concentration. Project supported by the Fund of Excellent Young Teachers of State Educational Commission of China.     

Estimation of heavy metals (Cu,Zn, Pb) input into Punat Bay

The fate of heavy metals (Cu, Pb, Zn) from their sources to the final sink was analysed. Investigations included the identification of sources, the input from each source as well as transport towards their temporary (soil, vegetation, and marine water) and final sink (marine sediments). Research was conducted in the catchment area of Punat Bay on the island of Krk (Northern Adriatic, Croatia). Four sources were identified: long-range transport, traffic, antifouling paints and eroded material which annually introduced about 158 kg of Cu, 175 kg of Pb and 666 kg of Zn into the Bay. Antifouling paints were significant but not the main source of pollution in this area as was considered in previous investigations. Due to long-range transport, the input of Zn was almost four times greater, whereas the input of Pb was almost six times greater than the input from antifouling paints. Aerosols emitted from motor vehicles still represent the mayor source of Pb in this area. Cu originates mostly from antifouling paints and long-range transport. It was estimated that only around 30% of analysed elements introduced into the water column would be deposited in their final sink, i.e. marine sediments.     

香格里拉县红牛矽卡岩型铜矿

“三江成矿带”内的红牛铜矿,赋存于大理岩边部矽卡岩化蚀变带及角岩体中。赋矿地层为曲嘎寺组第二段。对矿石结构、构造及矿石矿物成分、共生伴生关系等进行研究,明确找矿标志。     

超大型会泽富锗铅锌矿复合成因

会泽富锗铅锌矿。是近年老矿山深部找矿取得重大突破的典范,而其成因则是当前研究、讨论的热点。笔者认为该矿之形成,既非“MVT型”,亦非“VMS型”,而是与深部隐伏燕山期酸性岩有关的中温岩浆热液叠加、改造、富化的复成因矿床。自加里东期起长期处于张裂环境。深部昭通．弥勒硅镁层隆起,既是幔源玄武岩（热地幔柱）上涌的前奏,又为深部矿源上升创造畅通空间。与多旋回活动的小江深断裂相沟通的NE向矩形断裂网,是导矿、输矿、储矿的有利构造。继火山热液成矿之后,伴随燕山期褶皱、断裂和深部酸性岩浆的上升,发生第二期叠加矿化．矿石中伴生与酸性岩有关的元素组合．并以与酸性岩有关的锗富集为特征。