内蒙古北山造山带时空结构与古亚洲洋演化

内蒙古北山造山带自北向南发育红石山－百合山、月牙山－洗肠井和帐房山－玉石山3条蛇绿构造混杂岩带。其中北部的2条蛇绿岩带揭示了北山造山带两阶段演化的历史：月牙山－洗肠井蛇绿混杂岩带洋壳形成于530~520 Ma,沿该带多处保存较完好的蛇绿岩洋壳残块（洋壳结构具向北变新特征）,与北侧的早古生代公婆泉岩浆弧（由南向北岛弧成熟度变高）共同指示了北山洋向北俯冲消减的过程,即490 Ma初始俯冲,450~440 Ma为俯冲峰期,430~420 Ma为同碰撞阶段,400 Ma的双峰式岩浆岩组合指示了北山洋的消亡和后造山伸展的过程;红石山－百合山蛇绿混杂岩带是发育在雀儿山－圆包山岛弧基础上的SSZ型蛇绿岩,弧后开裂洋壳的形成与南侧最早发育的岛弧岩浆作用年龄接近（340~320 Ma）,310~290 Ma俯冲峰期造成南侧白山岩浆弧大量的岩浆活动,早二叠世末期（275 Ma）的辉长岩和花岗岩侵位及早—中二叠世双堡塘组下部的角度不整合均反映了红石山洋盆的闭合。前人所划"石板井－小黄山蛇绿岩带"实为一条早古生代发育的深大断裂,沿带发育中基性侵入体及少量超基性岩,后期（志留纪末）叠加有较强的韧性剪切变形。中生代以来的走滑作用和逆冲推覆构造改造了古生代的构造格架,使红石山-百合山蛇绿混杂岩带向北左行切错了十余千米,北山南部的中—新元古界推覆至下古生界之上。对内蒙古北山造山带时空结构的厘定,有助于中亚造山带造山作用过程的理解及其对古生代地壳增生的深入研究,也对银额盆地晚古生代新层系油气资源勘查起到基础支撑。     

班公湖-怒江缝合带东段丁青地幔橄榄岩成因: 来自钻孔ZK02地幔橄榄岩矿物学及地球化学特征约束

丁青蛇绿岩位于班公湖-怒江缝合带东段,是该缝合带出露面积最大的蛇绿岩。为查明岩体成因,在丁青东岩体中实施了一口165.19m的钻孔。除最顶部有约0.5m厚的第四系残坡积物外,其余均为地幔橄榄岩。结合显微镜鉴定将岩心划分出17个岩性单元层,岩性主要以方辉橄榄岩为主,夹少量纯橄岩和含铬铁矿纯橄岩。地幔橄榄岩中橄榄石的Fo变化于88.79~93.73,铬尖晶石的Cr^#变化于44.33~81.66,揭示丁青地幔橄榄岩可能经历过约20%~40%的中高度部分熔融作用;全岩地球化学分析表明其具有富镁（MgO=45.98%~49.45%）、贫铝（Al₂O₃=0.19%~1.37%）和贫钙（CaO=0.28%~0.70%）的特点,属于熔融程度较高的地幔残余物质。岩石具有明显不同于阿尔卑斯蛇绿岩的轻稀土元素富集特征,指示区内地幔橄榄岩先经历了较强程度的部分熔融,后经历了俯冲消减过程中的流体交代。利用地幔橄榄岩中的铬尖晶石成分计算母熔体Al₂O₃含量对应的FeO/MgO值,与不同构造环境原始岩浆成分相比较,发现丁青地幔橄榄岩母熔体大多处于玻安岩中。纯橄岩氧逸度估算FMQ=-3.05~-0.71,方辉橄榄岩氧逸度FMQ=-3.89~+1.47,显示丁青地幔橄榄岩有俯冲作用的参与。通过丁青钻孔岩心的研究,提出丁青东岩体可能形成于俯冲带之上的弧前环境这一观点。

     

新疆西准噶尔拉巴西蛇绿混杂岩带地质特征及其意义

新疆西准噶尔地区是古生代经过俯冲-增生形成的复合造山带。该地区分布有多条蛇绿岩带,其中的拉巴西蛇绿岩带是比较重要的一条,通过对该蛇绿混杂岩特征的研究,认为该区蛇绿岩尽管受到强烈的多期构造肢解,但根据岩石类型仍能恢复蛇绿岩的原始层序。本文重点讨论了拉巴西蛇绿混杂岩的地球化学特征,认为其形成时代为晚寒武世-中奥陶世,就位时代为中晚志留世,蛇绿混杂岩产于弧前或弧后小洋盆环境。研究发现,该蛇绿混杂岩具有明显的铬铁矿化,为下一步找矿指明了方向。     

Geology, Geochemistry and Minerogenesis of the Shijuligou Zinc–Copper Deposit in Gansu, China

Abstract: The Shijuligou deposit was separated by an arcuate ductile shear zone cross the center of the deposit region, resulting in the difference between the southern and northern ore bodies. The lead (Pb) isotopic data of ores of the Shijuligou copper deposit have averages of 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb in 17.634, 15.444, and 37.312, respectively. It has been shown that ore-forming metals originated from intrusive and extrusive rocks in the upper part of ophiolites. The sulfur isotopic data of pyrite and chalcopyrite in the northern part change from +7.61‰ to +8.09‰ and +4.95‰ to +8.88‰ in the southern part. Isotopes of δ18O in the Shijuligou copper deposit are between +11.1‰ and +18.6‰, with the calculated δ18OH2O at +0.65‰. It is suggested that the mineralized fluid is a mixture of magma fluid, meteorological water, and seawater through circulating and leaching metals from the volcanic rocks. The zircon uranium-lead (U–Pb) dating of gabbro is 457.9±1.2 Ma, and the lower crossing age of the discordant and concordia curves of pyroxene spilite of zircon is 454±15 Ma. It is indicated that the Shijuligou deposit formed in a new ocean crust (ophiolite) of the back-arc basin in the late Ordovician. Mineralization should occur in the intermittence period after strong volcanic activity, and the age should be the late Ordovician. Moreover, the mineralization of ophiolite-hosted massive sulfide deposits in the ancient orogenic belt of the late Ordovician in the northern Qilian Mountains was controlled by the primary fault/fracture, with the forming of a metallogenic hydrothermal system by a mixture of volcanic magma fluid and seawater, which circularly leached the metallogenic metals from the volcanic rocks, resulting in their accumulation. The ore bodies were transformed with morphology and metallogenic elements. Jasperoid is an important sign for prospecting such deposits. There were many island arcs in the continent of China. This study provides evidence for understanding and exploration of ophiolite-hosted massive sulfide deposits in western China, especially in the area of northern Qilian Mountains.     

Petrogenesis of Volcanic Rocks in the Khabr-Marvast Tectonized Ophiolite:Evidence for Subduction Processes in the South-Western Margin of Central Iranian Microcontinent

Abstract: The Late Cretaceous Khabr–Marvast tectonized ophiolite is located in the middle part of the Nain–Baft ophiolite belt, at the south-western edge of the central Iranian microcontinent. Although all the volcanic rocks in the study area indicate subduction-related magmatism (e.g. high LILE (large ion lithophile elements) / HFSE (high field strenght elements) ratios and negative anomalies in Nb and Ta), geological and geochemical data clearly distinguish two distinct groups of volcanic rocks in the tectonized association: (1) group 1 is comprised of hyaloclastic breccias, basaltic pillow lavas, and andesite sheet flows. These rocks represent the Nain–Baft oceanic crust; and (2) group 2 is alkaline lavas from the top section of the ophiolite suite. These lavas show shoshonite affinity, but do not support the propensity of ophiolite.     

缅甸达贡山蛇绿岩体的地球化学特征及其成矿意义

缅甸达贡山蛇绿岩体是达贡―密支那缝合带的重要组成部分,受控于板块碰撞结合带。该岩体主要由蛇纹石化橄榄岩、斜方辉石橄榄岩等组成。变质橄榄岩具有低的A12O3和CaO含量,以富Mg、贫Ti、HREE为特征,显示一种残留地幔岩的稀土元素地球化学特征,与世界上典型蛇绿岩体中方辉橄榄岩的特征值一致。经估算,达贡山蛇纹岩原岩是原始地幔经过9%~14%部分熔融的地幔残留,初步研究认为,达贡山蛇纹岩原岩是洋内俯冲初始阶段上涌软流圈地幔部分熔融的地幔残留,受类SSZ型熔体交代作用而仍然富集轻稀土元素(LREE)及U、Nb,属类SSZ型地幔橄榄岩;达贡山蛇绿岩体可能形成于俯冲带(SSZ)环境。岩体的m/f平均值8.026.5,利于铬铁矿的成矿。     

西藏雅鲁藏布江缝合带西段普兰纯橄岩中橄榄石的出溶特征及指示意义

西藏雅鲁藏布江缝合带西段普兰纯橄岩中橄榄石存在透辉石和磁铁矿共生出溶现象。这类纯橄岩非常新鲜,主要由橄榄石、尖晶石和透辉石等矿物组成。橄榄石的Fo值是90.1~90.7,铬尖晶石的Cr~#为19.8~20.8,远小于蛇绿岩地幔橄榄岩中常见纯橄岩中铬尖晶石的铬值(Cr~#60)。基于前人研究结果,提出这种现象是由于亏损方辉橄榄岩与含钛、铝、钙熔体发生交代作用,从而形成橄榄石的固溶体存在Ti~(4+)、Al~(3+)、Ca~(2+)、Fe~(3+),而Cr~(3+)进入铬尖晶石结晶。后期由于岩体在抬升过程中降温,橄榄石中出溶形成单斜辉石和磁铁矿,而铬尖晶石结晶被保留。依据铬尖晶石-橄榄石的矿物化学成分,识别出低铬纯橄岩具有最低的部分熔融程度为~8%,Cr~#最高的纯橄岩壳其部分熔融程度达到~50%,表明不同岩相间其形成背景存在明显差异。因此,笔者认为普兰蛇绿岩具有多阶段的过程。首先是在洋中脊环境下经历富Ca、Al和Na等熔体交代和部分熔融作用,后受到俯冲带玻安质熔体改造。     

内蒙古巴林左旗九井子蛇绿岩锆石U-Pb定年:对西拉木伦河缝合带形成演化的约束

本文对位于西拉木伦河蛇绿岩带东段的九井子蛇绿岩中辉长岩脉以及蛇绿岩的围岩开展了锆石U-Pb定年。结果表明辉长岩的形成时代为(274.7±1.7)Ma,MSWD=0.079,属于早二叠世晚期;结合前人地层、古生物、岩浆岩等方面的资料,表明内蒙古东南部早二叠世晚期还可能存在大洋盆地。与九井子蛇绿岩呈断层接触的粉砂岩碎屑锆石年龄大致构成4个峰值:2350~2700 Ma、1700~2100 Ma、370~470 Ma和250~290 Ma,通过与区域构造热事件的对比分析,表明其物源主要来自中朝古板块的北缘。粉砂岩中最小的锆石年龄为晚二叠世末—早三叠世初((249±4.7)Ma),该年龄与内蒙古东南部海相地层消失的时代、安加拉植物群和华夏植物群出现混生的时代、西伯利亚和中朝古板块古纬度曲线收敛的时代以及区域上与碰撞相关的岩浆岩形成时代大致相同,据此本文认为九井子蛇绿岩的构造侵位时代应为晚二叠世末—早三叠世初,同时也可能代表古亚洲洋的最终闭合时代。     

西藏改则县多龙矿集区发现岩墙岭蛇绿岩残片

西藏班公湖-怒江缝合带北缘多龙矿集区是青藏高原新近发现的具有超大型远景的、典型的富金斑岩型铜矿集区,其成岩成矿地质背景是解决班公湖-怒江洋构造演化的关键问题之一。近年来的区域地质调查研究发现,多龙矿集区南侧出露岩墙岭蛇绿岩残片,应该是班公湖-怒江蛇绿岩带的重要组成部分。岩墙岭蛇绿岩主要由席状岩墙群、枕状玄武岩和硅质岩组成,整体呈棱形或透镜体状断续分布于侏罗系复理石沉积内,构成典型的网结状构造。糜棱岩普遍发育在岩墙岭蛇绿岩和围岩的接触部位。综合前人研究成果,初步认为多龙矿集区早白垩世成岩成矿作用应该形成于增生楔之上伸展拉张的构造环境。岩墙岭蛇绿岩的发现和确定进一步约束了多龙矿集区成岩成矿地质背景,同时为班公湖-怒江缝合带的延伸及其构造演化的研究提供了新的线索。     

Petrology and PGE Abundances of High‐Cr and High‐Al Podiform Chromitites and Peridotites from the Bulqiza Ultramafic Massif,Eastern Mirdita Ophiolite,Albania

The Bulqiza ultramafic massif, which is part of the eastern Mirdita ophiolite of northern Albania, is world renowned for its high-Cr chromitite deposits. High-Cr chromitites hosted in the mantle section are the crystallized products of boninitic melts in a supra-subduction zone (SSZ). However, economically important high-Al chromitites are also present in massive dunite of the mantle-crust transition zone (MTZ). Chromian-spinel in the high-Al chromitites and dunites of the MTZ have much lower Cr# values (100Cr/(Cr+Al)) (47.7–55.1 and 46.5–51.7, respectively) than those in the high-Cr chromitites (78.2–80.4), harzburgites (72.6–77.9) and mantle dunites (79.4–84.3). The chemical differences in these two types of chromitites are reflected in the behaviors of their platinum-group elements (PGE). The high-Cr chromitites are rich in IPGE relative to PPGE with 0.10–0.45 PPGE/IPGE ratios, whereas the high-Al chromitites have relatively higher PPGE/IPGE ratios between 1.20 and 7.80. The calculated melts in equilibrium with the high-Cr chromitites are boninitic-like, and those associated with the high-Al chromitites are MORB-like but with hydrous, oxidized and TiO2-poor features. We propose that the coexistence of both types of chromitites in the Bulqiza ultramafic massif may indicates a change in magma composition from MORB-like to boninitic-like in a proto-forearc setting during subduction initiation.