Formation and stability of mixed Mg/Ca/phytate species in synthetic seawater media: Consequences on ligand speciation

The results of a potentiometric investigation (by ISE-H⁺, glass electrode) on the speciation of phytate ion (Phy¹²⁻) in an ionic medium simulating the major components (Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl⁻ and SO₄²⁻) of natural seawater, at different salinities and t = 25 °C, are reported. The work was particularly aimed at determining the possible formation of mixed Ca²⁺–Mg²⁺–phytate ion pairs, and to establish how including the formation of these mixed species would affect the speciation modeling in seawater media. After testing various speciation models, that considering the formation of the MgCaH₃Phy⁵⁻, MgCaH₄Phy⁴⁻, Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ species was accepted, and corresponding stability constants were determined at two salinities (S = 5, 10). A discussion is reported both on the choice of the experimental conditions and on the possibility to extend these results to those typical of real seawater. A detailed procedure is also described to demonstrate that the stability of these species is higher than that statistically predicted. As reported in literature, a parameter, namely log X, has been determined in order to quantify this extra stability for the formation of each mixed species at various salinities. For example, at S = 10, log X₁₁₃ = 2.67 and log X₁₁₄ = 1.37 for MgCaH₃Phy⁵⁻ and MgCaH₄Phy⁴⁻ (statistical value is log X_stat = 0.60), and log X₂₁₃ = 6.11 and log X₂₁₄ = 2.15 for Mg₂CaH₃Phy³⁻ and Mg₂CaH₄Phy²⁻ (log X_stat = 1.43), respectively. Results obtained also showed that the formation of these species may occur even in conditions of low salinity (i.e. low concentration of alkaline earth cations) and low pH (i.e., more protonated ligand).     

济南张夏组灰岩岩溶地下水供水潜力探讨

济南南部广布巨厚张夏组灰岩,其中赋存优质丰富的岩溶地下水。出露众多泉水,其流量为800～8000m3/d。该文通过简述济南地区张夏组灰岩岩溶地下水的赋存条件与水文地质特征,概略计算与评价其资源量,论证开发利用这一新水源的可行性,以期为济南供水与保泉开辟新途径。     

Research on formation density MWD instrument in engineering geological exploration

A high efficiency method is very important in geological survey for a new city in China. Geophysical parameters are Measured While Drilling(MWD), and these parameters are processed and explained on the ground, so the method can replace conventional engineering geological exploration for drilling rock sample. According petroleum engineering MWD, using the different characters of different rock absorbs γ radial, with the method of storing data in hole and explaining data on the ground, engineering geological exploration formation density MWD is researched. The MWD works stabilized, and the performance is good with precise data.     

井下双向流动阀防漏失技术在埕岛油田的应用

埕岛油田位于渤海西南部极浅一浅海地区,是一个大型潜山披覆构造油田。随着埕岛油田开采力度加强,地层亏空十分严重,作业过程中的地层漏失是困绕埕岛油田油层保护的一大难题。据此介绍了胜利油田海上埕岛油田油层保护的一项新技术——井下双向流动阀防漏失技术的应用情况,阐述了井下双向流动阀的结构、原理以及应用后对油层保护所起到的作用。     

Monte Carlo simulation of scintillation crystal detector for formation element logging

Formation elements logging is a neutron gamma spectroscopy logging technique used to acquire the content of elements and minerals by recording the gamma ray produced by the reaction of neutron and elemental nucleus in the formation. It has a wide usage in discriminating complex lithology and evaluating unconventional reservoir. The Monte Carlo simulation model of formation elements logging tool is established in this paper, with which the effects of tool parameters including the material and length of the scintillation crystal and source spacing on logging responses are modeled. The results show that the energy response of LaBr_3: Ce crystal is better than others, and the detection efficiency increases with the crystal length but decrease with source spacing. The above results may be used as a reference for optimizing the tool structure design.     

鲁西大汶口地区全新世临沂组沉积物粒度分布特征及地质意义

出露于大汶口盆地的临沂组为一套第四系松散堆积物,上部以土黄色、灰黄色含砂质粉砂、粉砂质粘土为主,下部为砂砾石层,是大汶口盆地内河流演化过程中的沉积响应和物质记录。通过对临沂组进行研究,可以反演大汶口盆地第四纪以来的沉积区水动力环境、物质运移方式和沉积环境。该文在区域地质调查工作的基础上,结合粒度分析频率曲线、概率累积曲线、粒度参数和沉积物宏观特征,对临沂组的沉积相、沉积环境和沉积韵律进行了研究。研究表明,大汶口地区临沂组下部为河床亚相边滩沉积微相,上部为河漫亚相河漫滩沉积微相,经历了由简单高能→复杂中能-中低能→简单中低能→复杂中低能的水动力沉积环境变化。另外依据岩石组合特征,将其划分为4个明显的沉积韵律和1个不明显的沉积韵律组。     

国内外岩溶塌陷监测方法综述

岩溶塌陷是全球广泛分布的地质灾害问题,严重影响和制约了岩溶地区社会、经济发展,因此,开展岩溶塌陷监测工作,对塌陷预测预报具有及其重要的作用。岩溶塌陷的监测技术与塌陷形成的机理关系密切。该文分析了岩溶塌陷的分布规律和形成的条件,系统总结了国内外岩溶塌陷的监测内容、技术方法、各自优缺点,如BOTDR监测、TDR监测、地质雷达监测、水动力条件监测及地-沉降等方法,为系统性地开展岩溶塌陷监测工作提供技术和方法参考,展望了未来的岩溶塌陷监测工作,认为岩溶塌陷监测需结合塌陷的形成机理、塌陷地区覆盖层特征及水动力条件,综合利用多种监测手段联合进行,并形成完善的监测网络。     

造山型金矿容矿建造分类、成矿模式及找矿勘查

造山型金矿床指造山过程中形成的后生脉状金矿床,受构造、建造双重控制,是全球最重要的金矿勘查类型。按容矿岩石建造的不同,造山型金矿可分为绿岩带型（包括绿片岩型、BIF型和花岗- 片麻岩型3个亚类型）、浊积岩型、碳酸盐岩型和浅成侵入岩型,构成了造山型金矿床完整的成矿谱系。不同类型之间具有紧密的时空和成因联系,可互为找矿标志。绿岩组合和浊积岩系具有高的金丰度,既是容矿岩系,也是重要的矿源层,多类型造山作用驱动大规模区域性流体活动,造就了造山型金矿省/巨型成矿带,岩浆流体叠加和“热机效应”是形成超大型金矿床的重要因素。构建了多源区域性流体+岩浆流体叠加的地壳连续成矿模型和造山型金矿区域成矿模式,强调了多旋回造山作用对造山型金矿的成矿意义。“富金矿源层+剪切变形带+浅成侵入岩”组合是大型金矿系统的勘查选区标志,靶区优选的目标是获取找矿潜力大的优质矿权;矿权区勘查的优先目标是发现可规模化露天开采的矿床（体）,通过化探异常评价和浅钻追索次生富集带,可快速发现主矿体;矿区深部找矿（深度>300 m）潜力巨大,主攻目标是资源量大、品位高的热液通道相的厚板状或筒状矿体。     

盆地形成及成矿与地幔流体间的成因联系

文中共讨论以下5个问题:(1)盆地起源于幔壳溃变和膨隆,后者是地幔流体(超临界态(>375℃)HACONS流体,简称幔汁)上涌、渗入、交代、富化、致熔的产物。地幔流体造成油气盆地深部的高热流、异常超高压、伊利水云母化、硅化和地层有机碳的加氢成油作用。(2)盆地成矿可分两大阶段,先是沉积时的同生成矿;地层沉积后还有众多的后生成矿。两者组成“盆地矿套”(杜乐天,2002)。成矿无论同生还是后生,其分布均受断裂控制,都和地幔流体活动有关。(3)黑色页岩的实质是碳-硅-泥三元岩系,和热液成矿中的碳酸盐-硅质-泥质蚀变三元完全相当。此类岩系中总是有几十种亲壳亲幔亲气元素的特殊富集。奇异的是,石油、油页岩、沥青及砂岩型铀矿彼此有完全类似的继承性元素特殊富集。此等元素群不可能都是来自盆地之外蚀源区岩体的风化。研究证明,相当多的元素是地幔流体携带上来的。(4)盆地地层中广泛发育由地幔流体衍生的热液作用。(5)盆地实质上是气盆,全盆地排气。许多气田是地幔流体排气形成的。沙漠(原地型)和天然气田的共生很值得注意,两者皆源于地球强烈排气,导致地下和大气增温,过度蒸发,不易降雨,长期干旱而形成沙漠。     

泥质砂岩复电阻率的频散特性实验

不同孔隙流体特性的岩石复电阻率频散实验,是复电阻率测井资料评价水淹层和低阻油层的岩石物理基础。通过水驱水、水驱油、油驱水的岩石复电阻率频散特性的实验研究,发现泥质砂岩的复电阻率频散特性受含油饱和度的影响较大,受地层水矿化度的影响较小,尤其是异相电阻率,受地层水矿化度的影响更小;与含水泥质砂岩相比,含油泥质砂岩的相角相对较大,且随着含油饱和度的增加而增大;含水岩石和含油岩行在频散特性上存在着较大差异。实验研究结果表明,利用基于岩石频散特性发展起来的复电阻率测井技术,可以有效地识别油水层。