大别山中生代岩浆岩矿物—水氧同位素交换的地球化学动力学

大别山中生代侵入岩氧同位素结果表明它们受到了岩浆期后亚固相水—岩相互作用的扰动。为了确定水—岩交换过程中的有关参数,本文利用交换反应动力学模型分别对大别山中生代主簿源、天柱山和团岭花岗岩以及沙村和椒子岩辉长岩矿物—水氧同位素交换反应动力学进行了定量计算,并估计了水—岩反应有效时限、流体流动速率和水/岩值。多维矿物相—水氧同位素交换反应动力学定量模拟结果表明,大别山主簿源、天柱山和团岭花岗岩岩浆期后亚固相水-岩反应的有效时限约为0.3~3 Ma,流体流动速率约为1×10-15~3×10-14mol/s,水/岩值为0.27~0.78;沙村和椒子岩辉长岩岩浆期后亚固相水-岩反应的有效时限约为0.02~0.4 Ma,流体流动速率约为1.6×10-14~4.8×10-13mol/s,水/岩值为0.11~0.33。     

Sources of ore-forming fluids and metallic materials in the Jinwozi lode gold deposit, eastern Tianshan Mountains of China

This paper presents gas compositions and H-, O-isotope compositions of sulfide- and quartz-hosted fluid inclusions, and S-, Pb-isotope compositions of sulfide separates collected from the principal Stage 2 ores in Veins 3 and 210 of the Jinwozi lode gold deposit, eastern Tianshan Mountains of China. Fluid inclusions trapped in quartz and sphalerite are dominantly primary. H- and O-isotopic compositions of pyrite-hosted fluid inclusions indicate two major contributions to the ore-forming fluid that include the degassed magma and the meteoric-derived but rock 18O-buffered groundwater. However, H- and O-isotopic compositions of quartz-hosted fluid inclusions essentially suggest the presence of groundwater. Sulfide-hosted fluid inclusions show considerably higher abundances of gaseous species CO2, N2, H2S, etc. Than quartz-hosted ones. The linear trends among inclusion gaseous species reflect the mixing tendency between the gas-rich magmatic fluid and the groundwater. The relative enrichment of gaseous species in sulfide-hosted fluid inclusions, coupled with the banded ore structure indicating alternate precipitation of quartz with sulfide minerals, suggests that the magmatic fluid has been inputted to the ore-forming fluid in pulsation. Sulfur and lead isotope compositions of pyrite and galena separates indicate an essential magma derivation for sulfur but the multiple sources for metallic materials from the mantle to the bulk crust.     

Paleozoic ophiolites and blueschists in Japan and Russian Primorye in the tectonic framework of East Asia: A synthesis

Abstract   Ophiolites and high-pressure (HP) metamorphic rocks are studied to test continuation of Paleozoic and early Mesozoic geological units from Japan to Primorye over the Japan Sea. The early Paleozoic ophiolites are present on both sides, and the late Paleozoic ophiolite of south-western Japan may also have its counterpart in Primorye. The Shaiginskiy HP schist and the associated Avdakimov gneiss in Primorye, both tectonically underlying the early Paleozoic ophiolitic complex, yield a 250-Ma phengite and hornblende K–Ar age, which is intermediate between those of the Renge (280–330 Ma) and Suo (170–220 Ma) blueschists in south-western Japan. This age also coincides with that of the coesite-bearing eclogites in the Sulu–Dabie suture in China and several medium-pressure metamorphic rocks in East Asia. On the basis of these results and other geological data, the authors propose the 'Yaeyama promontory' model for an eastward extension of the Sulu–Dabie suture. The collision suture warps southward into the Yellow Sea and detours around Korea, turns to the north at Ishigaki Island in the Yaeyama Archipelago of Ryukyu, where it changes into a subduction zone and further continues toward south-western Japan and Primorye. Most ophiolites from this area represent crust–mantle fragments of an island arc–back-arc basin system, and the repeated formation of ophiolite–blueschist associations may be due to the repetition of the Mariana-type non-accreting subduction and Nankai-type accreting subduction.     

低温榴辉岩中石榴子石的成分分带:快速抬升的证据

对南大别黄镇冷榴辉岩中——颗石榴子石进行了详细的电子探针工作，对其特殊的成分分带，建立了扩散模型并进行数值模拟，结果得到4．5mm／a的快速抬升速率。该结果表明黄镇榴辉岩曾经历了一个快速的抬升过程。     

北大别晚中生代火山岩的地球化学特征及对北大别构造属性的启示

北大别沙村地区发育一套由石英安山岩、粗面岩、粗面斑岩、晶屑凝灰熔岩和凝灰岩组成的晚中生代火山岩系,其K/Ar年龄变化于144～136 Ma。该火山岩系属偏铝质—弱过铝质高钾钙碱性岩石,LILE和LREE富集,Nb-Ta亏损明显,ε(Nd,t)=-18.73～-24.15,Ni(~(87)Sr)/Ni(~(86)Sr)=0.707 0～0.708 5。具有与北淮阳毛坦厂组火山岩(150～135 Ma)一致的元素-同位素地球化学特征。其元素-同位素变化主要受控于源区差异,岩浆源自10％～20％扬子陆块下地壳物质加入的富集岩石圈地幔。北大别与北淮阳构造带晚中生代火山岩有着相似的岩浆源区,暗示华北—扬子陆块俯冲碰撞的岩石圈边界可能并不与晓天—磨子潭断裂壳内缝合线叠合,而可能在水吼—五河断裂或其以南。     

安徽中部燕山期富钾岩浆岩系的成因及其对成矿作用的制约

安徽中部大别山地区和下扬子地区燕山期岩浆岩富K、大离子亲石元素，亏损高场强元素Nb、Ta，岩浆从早到晚的演化趋势为：高钾钙碱性一钾玄岩系列→钾玄岩系列→双峰式岩浆岩或者A型花岗岩，表明大别造山带和下扬子地区在燕山期处于同一个构造一岩浆活动区。大别地区富K岩系的源区与富集地幔密切相关，下扬子地区的则与下地壳有更多亲缘关系。岩浆源区的不同是造成大别地区和下扬子地区成矿作用重大差别的根本原因。     

Geochemical Characteristics and Implications of Eclogite Gravels from Mesozoic Strata at the Northern Margin of Dabie Orogenic Belt

The eclogite gravels, which were found in the Mesozoic Fenghuangtai and Maotanchang formations on the northern margin of the Dabie orogenic belt, are rich in K2O(1.21%),∑REE (278μg/g) ,and LILE(such as Rb, Ba, K, Th, etc.) , with high (La/Yb)N ratios(14.4),on the basis of the analyses of major elements, rare-earth elements (REE) and trace elements. Their enrichment in LILE, notable Nb-Ta depletion through, and depletion in HFSE relative to REE in comparison with the primitive mantle and N-MORB indicate that the protoliths of the eclogite gravels were formed in an island-arc setting. According to the Th-Hf-Ta discrimination diagram, the protoliths of the eclogite gravels are characterized by volcanic arc basalts.Trace element data indicate that the subducted marine sediments were assimilated in the magma chamber, resulting in the enrichment of LILE in the protoliths. Therefore, the protoliths of the eclogite gravels are considered to have been formed in an inland-arc setting, indicating that there had developed a paleo-inland arc before Triassic collision between the North and South China blocks in the Dabie orogenic belt. There is a marked difference between the eclogite gravels and the eclogites developed along the Dabie orngenic belt, solely based on their geochemical data,especially REE. Therefore, the eclogite gravels may not be derived from eclogite terrains preserved in the Dabie orogenic belt.     

Early Cooling History of Eciogites from the Dabie-Sulu Orogen： Constraints from Diffusion Kinetics of Garnet

Abstract For the first time, we apply different geospeedometric models to garnet zoning patterns that were obtained in this study from detailed EMP analyses for garnets from eclogites and granulite in the Dabie‐Sulu orogen. Various zonings of cation diffusion were preserved in the garnets, enabling the acquirement of average cooling rates for the high‐to ultrahigh‐pressure rocks without using geochronological approaches. The coesite‐bearing hot eclogites yield fast cooling rates of about 20 to 30°C/Ma subsequent to peak metamorphic temperatures, whereas the cold eclogite gives a relatively slow cooling rate of 8°C/Ma at its initial exhumation. A very slow cooling rate of <0.3°C/Ma is obtained for the granulite at Huangtuling, suggesting that the granulite may not be involved in the continental deep subduction.     

Basement-Cover Sequences within the UHP unit of the Dabie Shan

Field data define two lithologically distinct basement‐cover sequences within the ultrahigh‐pressure metamorphic (UHPM) unit of the Dabie Shan, eastern China. One of the cover units, the Changpu unit, comprises calc‐arenitic metasediments in stratigraphic contact with a basement consisting of gneisses of the Yangtze craton. The second cover unit, the Ganghe unit, consists of felsic‐intermediate metavolcanics and clastic metasediments. Basement exposure of the Ganghe unit is not known. Fold axes in the Ganghe unit are oblique to those of the Changpu unit, which are parallel to those of the Yangtze gneisses. Preservation of primary textures in some volcanic rocks, and tectonic separation from the Yangtze gneisses by a greenschist facies mylonite, support an interpretation of the Ganghe unit as a low‐strain domain. Protolith associations in the Ganghe and Changpu units are compatible with deposition in a rift setting and along a passive continental margin, respectively. A U–Pb single zircon age of 761 ± 33 Ma for volcanoclastic rocks of the Ganghe unit demonstrates a Neoproterozoic deposition age, concordant with inferred rifting at that time. Eclogite facies parageneses in the gneisses and both cover units, along with P–T data demonstrate regional UHPM in the Dabie Shan.     

Zircon U／Pb Dating of Cretaceous Adakitic Volcanic Rocks in the Eastern Part of North Dabie Mountains

1IntroductionMostgeologistshaveacceptedthattheQinling Dabieorogenicbeltistheproductofcontinentaldeepsubduction (Okayetal.,1993;Cong ,B .etal.,1995 ;Hackeretal.,1995 ;DongShuwenetal.,1993) .Butasthebiggest scaleUHPmetamorphicbeltintheworld ,thereactionbetweenthecrustandthemantleatthepost orogenicstageandtheexhumation ,upliftinganddenudationoftheorogenicbeltarethecomplexdynamicprocesses .ItwasreportedpreviouslythatsomeCretaceousvolcanicrocksexistinthemiddleoftheDabieMountains (GuanYuncaiet…