我国典型季风海洋性冰川区雪坑中主要阴、阳离子的来源

运用海盐示踪法、相关分析、趋势分析等方法,对我国两处典型季风海洋性冰川(海 螺沟1 号冰川和白水1 号冰川) 积累区雪坑主要化学离子来源进行了综合分析,结果表明： 两冰川区除Na⁺ 是海洋源外,其他离子主要是非海洋源;Cl^-、NO₃ ^-、SO₄ ^2- 、K⁺、Ca²⁺、Mg²⁺ 非 海洋源所占的比重,在海螺沟1 号冰川依次为52%、99%、100%、98%、99.9%、83%,白水 1 号冰川依次为68%、99%、100%、98%、99%、59%;分析认为,海螺沟1 号冰川离子的非 海洋源主要是大气环流远源物质和高原面物质输入,而白水1 号冰川除上述来源外,冰川区 近源物质输入对离子浓度贡献很大。两冰川区各离子具体来源存在较大的差异性并且阴、阳 离子来源的共源性较低,其主要原因是：(1) 冰川区内局地环境的差异,比如岩性、山谷风系 统、地形地貌等;(2) 两冰川区离子淋溶作用强度的差异,分析认为,海螺沟1 号冰川离子淋 溶作用较强;(3) 不同离子的来源方式、沉降方式、自身化学特征以及沉积后过程不同所致。     

太平洋深海沉积物来源的菌株Tenacibaculum sp.HMG1对孔雀石绿降解特性的研究

本文在太平洋深海沉积物中分离得到一株孔雀石绿降解菌株,鉴定命名为Tenacibaculum sp.HMG1。通过菌株生长实验和高效液相色谱的研究表明, HMG1菌株可以在20 mg/L的孔雀石绿中维持较快的生长速率,并且在12 h内可降解98.8%的孔雀石绿,这证明该菌株具有很高的孔雀石绿耐受能力和降解活性。通过基因组测序在HMG1菌株发现一条过氧化物酶基因可能参与了孔雀石绿的降解,随后利用原核表达获得了相应的重组蛋白。实验表明,该重组过氧化物酶具有极强的活性,可在1000 mg/L的孔雀石绿中发挥降解功能。本文利用液相色谱-质谱联用（LC-MS）技术对孔雀石绿的菌株降解产物和重组酶降解产物进行鉴定,并基于鉴定结果推测了两种降解途径。结果发现两种降解方式存在共同的降解途径。此外,孔雀石绿降解条件的实验结果证明重组过氧化物酶可以在低温（20℃）、复杂的pH值（6.0–9.0）、高盐度（100 mmol/L）、金属离子和EDTA等反应条件下依旧维持很高的孔雀石绿降解活性。以上实验结果表明,HMG1菌株和重组过氧化物酶均在孔雀石绿污染生物修复方面具有很大潜力。     

基于多源数据的山东省围填海造地特点及发展趋势研究

文章基于文献资料分析、官方数据汇总、国产高分辨率资源卫星遥感影像信息提取以及发展趋势研判等方法,对改革开放以来山东省全海域范围内围填海造地的历史发展、现状特征、发展趋势及其对生态环境的影响进行了分析和总结,并提出相关的政策建议。研究表明:改革开放以来,山东省围填海造地累计已超过4.58万hm~2。21世纪以来围填海造地进入快速增长时期,尤其是2010年以来,全省围填海造地又掀起了一次新的热潮,其面积和速度都远远超过了历史水平。鉴于围填海造地对环境和生态的巨大影响,文章提出了加强管理、严格环境影响评价、引入生态环境补偿机制以及建立分级填海评估制度和年度监测机制等建议。     

Improvement in the calculation of anti-Stokes energy transfer and experimental justification based on Er0.01YbxY1 - 0.01 - xVO4 crystal

The improvement on the calculation of anti-Stokes energy transfer rate is studied in the present work. The additional proportion coefficient between Stokes and anti-Stokes light intensities of quantum Raman scattering theory as compared with the classical Raman theory is introduced to successfully describe the anti-Stokes energy transfer. The theoretical formula for the improvement on the calculation of anti-Stokes energy transfer rate is derived for the first time in this study. The correctness of introducing coefficient exp{ΔE / kT} from well-known Raman scatter theory is demonstrated also. Moreover, the experimental lifetime measurement in Er_0.01Yb_xY_{1 - 0.01 - x}VO₄ crystal is performed to justify the validity of our important improvement in the original phonon-assisted energy transfer theory for the first time.     

Determination of the REE in Geological Reference Materials DTS-1 (Dunite) and PCC-1 (Peridotite) by Ultrasonic and Microconcentric Desolvating Nebulisation ICP-MS

Inductively coupled plasma-mass spectrometry is well suited for the precise, accurate and rapid determination of rare earth elements in most geological samples. However, determination of rare earth elements in certain mantle-derived materials, without applying preconcentration techniques, remains problematical due to low natural concentrations (generally < 1 ng g⁻¹). Consequently, USGS reference materials DTS-1 (a dunite) and PCC-1 (a partially serpentinized harzburgite) have only suggested rather than recommended values for the rare earth elements in reference material compilations. We compared results obtained using two ICP-MS instruments: a U-5000AT ultrasonic nebuliser coupled to a PQ2+ quadrupole ICP-MS and an ELEMENT sector field ICP-MS equipped with a MCN-6000 microconcentric desolvating nebuliser, with the suggested literature values for these two reference materials. Precision and accuracy of analytical methods employed by both instruments were demonstrated by excellent relative standard deviations (< 2%) and inter-laboratory agreement (< 5%) for numerous analyses of BHVO-1 and BIR-1, which are well established with rare earth elements contents at the μg g⁻¹ level. Repeat analyses of DTS-1 and PCC-1 at each laboratory indicate that each method is generally precise to better than 5% at sub-g g⁻¹ levels. Furthermore, values from both instruments generally agree to within 10%. Our DTS-1 and PCC-1 values agree reasonably well with selected data reported in the literature (except for Ce and Sm in DTS-1) but exhibit poorer agreement with reported compilation values. With the demonstrated level of precision and accuracy, we contend that these new values for DTS-1 and PCC-1, generated by two different instruments, are the best estimates of the true whole-rock composition of these samples reported to date.     

The Distribution of Chadian and earliest Arundian strata in North Wales: Implications for Dinantian (Carboniferous) lithostratigraphy and palaeogeography

The late Chadian Foel Formation, previously thought to be confined to the Dyserth area of North Wales, forms a poorly exposed but persistent basal unit to much of the Dinantian crop east of the Clwydian Range, necessitating a revision of the local lithostratigraphy. The formation comprises a peritidal heterolith which, together with the lowest few metres of the overlying Llanarmon Limestone, yields microfossil assemblages diagnostic of the Eoparastaffella Cf4α Subzone. Succeeding strata, containing the lowest archaediscid foraminifera, provide the first record of Cf4β assemblages from North Wales and establish an early Arundian age for these beds. The Foel Formation was deposited as an aggradational sequence on the northern flank of St. George's Land during a pulsed transgression which began in late Chadian times. The widely recognized basal Arundian transgression is represented by the contact between the Foel Formation and overlying platform carbonates. The latter overlap the Foel Formation in the southernmost part of the Clwydian crop demonstrating, for the first time, southwards onlap on the northern side of the Bala–Bryneglwys Fault System.     

试论陆壳增生的两种基本模式及其对比

大陆地壳是地球形成演化的必然产物。大陆地壳由不同时代、不同类型、不同规模地体的拼贴而增生；同时已形成的大陆地壳沿着新的断裂分裂、离散而碱小。因此大陆地壳是地体拼贴增生与分裂离散的综合结果。太古代早期，原始陆壳形成后，主要通过环太平洋型与天山型两种基本模式达到陆壳的增生。环太平洋型陆壳增生模式出现于陆块的边缘，由古大陆向大洋方向单向增生，增生年代由老到新，增生地体一般都有较大距离的移置，其增生与板块的俯冲作用密切有关。天山型陆壳增生模式出现在陆块的内部，其形成与陆块的开台作用密切有关，可以但不一定伴随有俯冲作用。当古大陆沿一定方向断裂带分裂、离散。其间形成新的海槽接受碳酸盐岩和正常陆源碎屑沉积物与来自地壳深部或地幔的火山物质。由于壳下应力条件改变，两侧古陆相向运动，海槽中物质受两侧古陆碰撞挤压，形成褶皱造山带，并把两侧的古大陆“焊接”成新的、范围更大的大陆地壳。     

地质异常理论在兰坪盆地演化中的应用

基于地质异常理论的分析，并结合兰坪盆地的地质、构造特点，充分发挥地壳升降系数法的定量化及其空间优势，对兰坪盆地地质、构造演化进行了形象、直观的表述，对进一步反演兰坪盆地独特构造格架形成的古应力场，具有十分重要的作用。     

张广才岭燕山早期白石山岩体成因与壳幔相互作用

出露于东北地区张广才岭的白石山岩体,其全岩-矿物Rb-Sr等时线年龄为196士4 Ma,表明形成于中生代的燕山早期,而非传统认识上的印支期.岩体主岩和闪长质包体均具有低ISr(≈0.705)和正εNd(t)(+1.7～+2.2)值的特点,反映岩体成因与地幔具有密切的联系.地质学、岩石学和地球化学的详细研究表明该岩体具有壳幔混合成因,闪长质包体是较基性的地幔岩浆进入主岩浆中淬火结晶而成,花岗质岩浆的源区主要为新生的地壳物质.动力学分析表明,本区在华北板块和西伯利亚板块碰撞拼合后,由于东侧大洋板块的俯冲及后续的岩石圈拆沉效应,导致软流圈地幔上隆及幔源岩浆的板底垫托,并进而造成先存和新生地壳的部分熔融和不同源区岩浆的混合作用.底垫的新生地壳是兴蒙造山带造山后晚期形成的.因此,古生代-中生代是本区地壳生长的重要时期,且这种地壳生长是在垂向构造机制下进行的.     

基于多源遥感影像的长春市城市建成区提取

夜光遥感影像记录的城市灯光与人类活动密切相关,已广泛应用于城市信息提取。珞珈一号作为新一代夜光遥感数据源,比以往的夜光数据具有更高的空间分辨率和光谱分辨率,可以更清晰地表达城市建成区范围和内部结构。本文利用珞珈一号夜光遥感影像,通过人类居住指数（human settlement index, HSI）、植被覆盖和建筑共同校正的城市夜光指数（vegetation and build adjusted nighttime light urban index, VBANUI）及支持向量机（support vector machine, SVM）监督分类3种方法对长春市城市建成区进行提取,并与利用NPP/VIIRS（suomi national polar-orbiting partnership/visible infrared imaging radiometer suite）夜光遥感影像、采用同样方法得到的结果对比。结果显示：本文提出的VBANUI提高了传统植被覆盖校正的城市夜光指数（vegetation adjusted nighttime light urban index, VANUI）的提取精度,使用珞珈一号夜光遥感影像通过VBANUI提取的城市建成区结果最优,其Kappa系数为0.80,总体分类精度为90.74%;使用珞珈一号和NPP/VIIRS夜光遥感影像通过HSI按最佳阈值提取城市建成区的Kappa系数分别为0.75和0.72,总体分类精度分别为88.27%和86.54%;复合数据的SVM监督分类法中Landsat-NDBI、Landsat-NDBI-VIIRS、Landsat-NDBI-LJ和Landsat-NDBI-LJlog的Kappa系数分别为0.602、0.627、0.643和0.681,总体分类精度分别为81.11%、81.52%、82.25%和84.48%。研究结果表明：3种提取方法下,均为使用珞珈一号夜光遥感影像的结果优于使用NPP/VIIRS夜光遥感影像的结果,证明相比于NPP/VIIRS夜光遥感影像,珞珈一号夜光遥感影像更适用于城市尺度的建成区范围提取。