深孔纳米复合水泥基护壁堵漏材料研究

本文围绕深部钻探技术中护壁堵漏材料性能的实际需要,研制了一种深孔纳米复合水泥基护壁堵漏新材料。首先,通过分析100 ℃条件下2种水泥材料的基本性能,确定了G级油井水泥为胶凝材料;然后,基于深孔钻探护壁堵漏材料的性能缺陷,采用特种纤维、纳米材料针对性改善水泥基浆液的力学性能,并优选早强剂（ZQ）、减水剂（GB）作为外加剂进行正交实验,进而研制出纳米复合水泥基护壁堵漏材料优化配方;最后,对其主要性能进行分析评价。结果表明该材料在深孔钻探中浆液流动性好,力学性能优异,综合性能满足深孔钻探护壁堵漏需求。     

地磁台站建设中磁测异常现象分析

地磁台建设磁性跟踪测试工作很重要,通过对跟踪磁测中发现的一个异常现象的分析,计算了不同重量、距离的铁磁性物质对磁房建筑场地磁场的影响,讨论了排除施工现场磁性干扰的一些办法,并得出各种重量铁磁性物质与磁房建筑物的安全距离,还讨论了地磁台部分建筑材料的选择问题。     

四川甘洛铅锌矿集区闪锌矿Rb-Sr等时线年龄及其地质意义

四川甘洛铅锌矿集区位于扬子地块西南缘的川滇黔铅锌成矿带北段,是四川主要的铅锌产地,具有重要经济价值。为研究该矿集区铅锌成矿时代、成矿大地构造背景和成矿机制,以支撑区域找矿勘查,在区内选择赤普和尔呷地吉两个典型铅锌矿床开展闪锌矿Rb-Sr同位素体系研究,获得Rb-Sr等时线年龄246 ± 17 Ma（MSWD= 2.3）,表明区内铅锌矿化作用发生于早三叠世,与古特提斯洋闭合时限吻合;闪锌矿(87Sr/86Sr)i值变化于0.71061~0.71393,高于幔源87Sr/86Sr值0.70355及峨眉山玄武岩87Sr /86Sr值0.704979~0.706938,低于基底岩石87Sr /86Sr值0.7243~0.7288,暗示成矿物质主要来源于地壳。综合前人研究,认为在古特提斯洋闭合背景下,强烈造山运动诱发盆地卤水深循环并萃取基底地层中的成矿物质,在峨眉山玄武岩岩浆活动的热动力条件下,含矿流体沿马拉哈断裂进一步迁移沉淀形成了赤普和尔呷地吉铅锌矿床。马拉哈深大断裂及造山作用派生的层间或断层破碎带、碳酸盐岩地层是甘洛地区主要的控矿要素。     

石煤钒矿成分分析标准物质的研制

石煤钒矿资源的开发和合理利用需要对其成分进行准确的分析测试和质量控制.目前,国内外尚未有石煤钒矿成分分析的标准物质,现有钒成分分析标准物质无论是其五氧化二钒含量,还是定值成分都无法满足我国对石煤钒矿勘查、开发和研究需要.本文对采自湖北省崇阳县小源冲钒矿、湖南省芷江县牛牯坪钒矿、湖南省古丈县岩头寨钒矿和湖南省凤凰县黑冲钒...     

海山富钴结壳标准物质研制

报道了我国与俄罗斯合作研制的三个海山富钴结壳标准物质GSMC-1,2,3.这三个标准物质的原样分别取自西太平洋麦哲伦海山和中太平洋海山.样品经风干、选配、球磨制备成均匀的粉体样品,其均匀性采用高精度的X-射线荧光光谱法检验.样品的化学组分采用国内外多实验室协同分析方式定值,有八个国内实验室和八个国外实验室参加了合作分析.测试组分均为57个,其中GSMC-1,2有43个组分定为保证值,10个组分作为参考值;GSMC-3有45个组分定为保证值,8个组分作为参考值.经2a多的试用,三个标准物质已于2005年被国家计量部门批准为国家一级标准物质,其编号分别为GBW07337,GBW07338和GBW07339.     

活性污泥和颗粒污泥生物吸附废水中Pb~(2+)的对比研究

采用序批式实验,分别以活性污泥和颗粒污泥为吸附材料,考察接触时间、pH等因素对废水中Pb2+生物吸附效果的影响.结果表明,活性污泥和颗粒污泥对低浓度Pb2+(0～20 mg/L)能在30 min内达到吸附平衡,当Pb2+浓度在20～100 mg/L时,浓度越低,达到平衡时间越快,以被动吸附为主.在Pb2+低浓度条件下(0～20 mg/L),初始pH为4～5时,Pb2+的去除率达99%以上,且初始pH值是影响活性污泥和颗粒污泥生物吸附Pb2+的重要因素.活性污泥和颗粒污泥对Pb2+的生物吸附符合朗缪尔(Langmuir)方程,在pH为4及25 ℃下,活性污泥饱和吸附量为59.88 mg/g,颗粒污泥饱和吸附量为80.65 mg/g.因此,活性污泥和颗粒污泥可作为有效的生物吸附剂处理低浓度(0～20 mg/L)含铅废水,且颗粒污泥比活性污泥的生物吸附效果好.     

稀土催化材料在工业废气、人居环境净化中的研究与应用综述

阐述了稀土催化材料在工业废气、人居环境净化方面的研究与应用现状,并对稀土催化材料的发展进行了展望,认为将稀土催化材料用于工业有机废气污染治理和人居环境净化,是推动稀土催化应用的动力之一。等离子体辅助的催化技术,可以显著改善低温活性。作为长期去除污染物的有效措施,光催化技术应大力开发。开发联合脱硫脱氮的新方法、新理论、新技术及新设备,将成为烟气净化技术发展的总趋势。作为一种新型催化材料应用,掺杂稀土的ABO3钙钛矿复合氧化物以及TiO2为基础的复合氧化物,在环境净化方面的发展方向是努力降低成本,提高光催化剂活性,尽量多利用太阳光,扩大降解范围。     

Explicit stress–strain equations for modeling frictional materials

In this paper, a comprehensive study on simulating the shearing behavior of frictional materials is performed. A set of two explicit equations, describing the relationship among the shear stress ratio and the distortional strain and the volumetric strain, are formulated independently. The equations contain three stress parameters and three strain parameters and another parameter representing the nonuniformity of stress and strain during softening. All the parameters have clear physical significance and can be determined experimentally. It is demonstrated that the proposed equations have the capacity of simulating the complicated shearing behavior of many types of frictional materials including geomaterials. The proposed equations are used to simulate the stress–strain behavior for 27 frictional materials with 98 tests. These materials include soft and stiff clays in both reconstituted and structured states, silicon sands and calcareous sands, silts, compacted fill materials, volcanic soils, decomposed granite soils, cemented soils (both artificially and naturally cemented), partially saturated soils, ballast, rocks, reinforced soils, tire chips, sugar, wheat, and rapeseed. It has been demonstrated that the proposed explicit constitutive equations have the capacity to capture accurately the shearing behavior of frictional materials both qualitatively and quantitatively. A study on model parameters has been performed.     

含部分晶须的钛酸锂的制备及其性能表征

L i4T i5O12是一种循环性能好、有很好的充放电平台、理论比容量较大、不与电解液反应的新型负极材料,研究探索以偏钛酸和碳酸锂为主要原料制备含部分晶须的尖晶石型晶型L i4T i5O12的一种方法。通过此工艺在1 000℃煅烧8 h后在样品中约20%的晶须出现,晶须的直径≤0.5μm,晶须的长度约为7μm。     

Macroscopic criteria for Green type porous materials with spheroidal voids: application to double porous materials

Combined effects of matrix plastic compressibility and void shape are investigated for ductile porous materials. To this end, a spheroidal volume containing a confocal spheroidal (prolate or oblate) void subjected to uniform strain rate boundary conditions has been first studied. A Green type matrix is chosen as a prototype for investigating effects of plastic compressibility. This is carried out by using a kinematics limit analysis theory from which a closed‐form expression of the macroscopic criterion is established for the considered class of materials. These results are then extended to ductile porous materials made up of a green matrix containing randomly oriented spheroidal voids. In the framework of a two‐step homogenization procedure, the obtained results are implemented to describe the macroscopic behavior of double porous materials involving spherical voids at the microscale and randomly oriented and distributed spheroidal voids at the mesoscale. For validation purpose, the new derived criteria are assessed and validated by comparing their predictions to available upper bounds and numerical data from literature. Copyright © 2017 John Wiley & Sons, Ltd.