液相色谱-原子荧光光谱联用法测定土壤砷铬锑硒元素价态

土壤重金属污染物的环境效应与其无机价态有密切的关系.As、Cr、Sb和Se元素的价态测定意义重大,但由于价态之间易发生转化使测定工作存在较大难度,标准化程度较低.地质行业标准DD2005-3推荐使用离子交换树脂分离,原子荧光光谱差减法测定As、Sb、Se价态及石墨炉原子吸收光谱法(GFAAS)测定Cr价态.这些方法前处...     

卡拉胶及其结构研究进展

本文概述了卡拉胶的类型、命名、卡拉胶结构特征及卡拉胶在藻体中的存在情况，介绍了卡拉胶的一些分析方法。     

饲料中维生素B6对皱纹盘鲍幼鲍蛋白质代谢的影响

以皱纹盘鲍(Haliotis discus hannaiIno)幼鲍为研究对象,探讨维生素B6对其蛋白质代谢的影响。设计了3种维生素B6不同含量(0,40,4 000 mg/kg)的半精制饲料,在循环水养殖系统中养殖幼鲍240 d。结果表明,皱纹盘鲍内脏团和肌肉中磷酸吡哆醛(PLP)的含量随饲料中维生素B6的添加而显著升高(P<0.05)。饲料中不同维生素B6水平对肌肉组织中蛋白含量没有显著影响(P>0.05),而显著升高内脏团中蛋白质的含量(P<0.05)。内脏团和肌肉中的谷丙转氨酶(ALT)和谷草转氨酶(AST)活力随着饲料中维生素B6添加量的升高而显著增强,分别在维生素B6的添加量为4 000 mg/kg时取得最大值(P<0.05)。内脏团中所检测的各种氨基酸的含量与饲料中维生素B6添加量没有显著影响(P>0.05)。然而,肌肉中的天冬氨酸(Asp)、苏氨酸(Thr)、丝氨酸(Ser)、牛磺酸(Tau)的含量随着饲料中维生素B6添加量的升高而显著增加,并且分别在维生素B6添加量为4 000 mg/kg时取得最大值(P<0.05)。肌肉中甘氨酸(Gly)、丙氨酸(Ala)、缬氨酸(Val)、蛋氨酸(Met)的含量在两个维生素B6添加组(40 mg/kg和4 000 mg/kg)之间没有显著差异(P>0.05),但均显著高于维生素B6缺乏组(0 mg/kg)的值(P<0.05)。     

基于随机振动模型的强地面运动数值模拟及其在广西灵山M6(3/4)地震中的应用

1936年4月1日广西灵山县平山镇东南罗阳山附近发生M6(3/4)地震,该地震是华南大陆自有地震记载以来发生的最大地震。本研究收集整理了灵山M6(3/4)地震的地质资料、活动断层探测最新成果等,选取适当的研究区域,利用随机振动有限断层模型计算区域内网格点的峰值加速度(PGA)及峰值速度(PGV)等参数,并且加入浅层横波速度结构V_s³⁰对地震动参数的影响,最终得到此次地震的地震动分布并分析了地震动特征。本研究将模拟结果与野外调查烈度数据和地震动衰减关系进行对比,结果显示模拟结果与调查烈度值和衰减关系在整体衰减特征、极震区的分布等方面均符合较好,模拟结果可为该地区未来地震危害性评估提供依据。本研究所使用的方法流程亦可应用于本地区地震烈度速报,为震后应急救援及决策指挥提供帮助。     

Ecophysiological Studies on Size-fractionated Phytoplankton Populations by Tracer Technique in Wadi el Majanin Dam,Libya

Wadi el Majanin, one of the largest hydraulic structures in Libya was studied for ecophysiological aspects in relation to ambient environment. The waterbody is alkaline (pH=7.2) and characteristic of hydrogen-carbonate (144.8 mg L^–1 CaCO₃) system. Vertical extinction coefficients (> 4.8) indicate very high (biogenic) turbidity. Conspicuous variations of a quantitative kind in algal development (e.g., Pediastrum bloom) together with abundant diatom populations (chlorococcales-diatom assemblage), apart from very common occurrence of cyanobacteria and euglenoids show eutrophic water condition. Winter-summer alternation induced pronounced seasonal variability in the rates of in situ planktonic algal photosynthetic activities (285.7...1305 mg m^–3 d^–1 C). Dark fixation activity, attributed largely to bacterial production, oscillated by order of 2-fold magnitude, characterized by summer maxima (47.6 mg m^–3 d^–1 C). Size-fractional analysis established that smaller forms (< 60 μm), broadly regarded nanno-phytoplankton, frequently dominated (c. 70%) overall algal productivity.     

Interaction of Aquatic Dissolved Organic Matter(DOM) with Amitrole: The Nature of the Bound Residues

In this study the binding behaviour of the herbicide amitrole with humic substances respectively dissolved organic matter (DOM) is presented. The results of the binding and release experiments using radio actively ¹⁴C-labelled amitrole ledto the conclusion that the binding of amitrole is very low. About 70% of amitrole bound to humic substances was not extractable. The releasable amitrole portion of the purified DOM-amitrolecomplexes led to a harmful effect in the cress test. Solid-state cross polarisation (CP) magic angle spinning (MAS) ¹⁵N-NMR spectroscopy is a powerful spectroscopic method to elucidate the structure of bound xenobiotics. In addition extraction experiments were used resulting in a binding scheme of amitrole to DOM, where above all the covalent bonding occurred via acid amide bonds.     

Amplitude of ENSO cycles in the Santa Barbara Basin,off California,during the past 15 000 years

Varve thickness time series from ODP Site 893 in the Santa Barbara Basin (off California) were analysed to determine variation in the strength of El Niño/Southern Oscillation (ENSO) cycles during the past 15 000 yr. Mean varve thickness and variance changed over time, with thicker varves before ～8000 yr BP indicative of wetter than modern climates. A 100‐yr running standardisation was applied to correct for non‐stationarity. The contribution of ENSO‐scale variability was then estimated as the amplitude of 3–8 year bandpassed data. Results show multidecadal‐ to centennial‐scale modulation of the amplitude. On average, however, the amplitude of ENSO scale variability remained constant throughout the past 15 000 yr. We therefore conclude that, although the expression of ENSO cycles may have changed during the Holocene, there is no indication for a significant change in amplitude of interannual variability. Copyright © 2005 John Wiley & Sons, Ltd.     

ISLAND MAGIC AND THE MAKING OF A TRANSNATIONAL REGION*

ABSTRACT. How can an artificial island and a bridge‐building project shape the dreams and plans for a transnational region? In this article I examine the making of the öresund region of Denmark and Sweden by analyzing the intertwining of bridge construction and region building, from the early dreams and plans, to the actual construction phase, to the ceremonial opening in 2000, and to the difficult transition into an everyday transportation system. The ways in which the construction was organized and staged came to mirror some important trends of the so‐called new economy and many of its buzzwords. Engineering and imagineering were combined in new ways.