丽江7.0级地震前地震活动特征

本论述了丽江７．０级地震前地震活动条带、能量释放加速、复发周期时间扫描、剪切应力值异常等地震活动性的中长期背景异常和ｂ值、缺震、振幅比、剪切应力场地动态分布、地震窗等短期异常。     

Ballon-borne and aircraft infrared measurements of ethane (C2H6) in the upper troposphere and lower stratosphere

Quantitative infrared measurements of ethane (C₂H₆) in the upper troposphere and lower stratosphere are reported. The results have been obtained from the analysis of absorption features of the ₉ band at 12.2 m, which have been identified in high-resolution ballon-borne and aircraft solar absorption spectra. The ballon-borne spectral data were recorded at sunset with the 0.02 cm^-1 resolution University of Denver interferometer system from a float altitude of 33.5 km near Alamogordo, New Mexico, on 23 March 1981. The aircraft spectra were recorded at sunset in July 1978 with a 0.06 cm^-1 resolution interferometer aboard a jet aircraft at 12 km altitude, near 35°N, 96°W. The balloon analysis indicates the C₂H₆ mixing ratio decreased from 3.5 ppbv near 8.8 km to 0.91 ppbv near 12.1 km. The results are consistent with the colum value obtained from the aircraft data.     

Alkaline Degradation of Dissolved Organic Matter

The degradation of dissolved organic matter (DOM) was studied in alkaline solution. The products were characterised using UV/vis spectroscopy, size‐exclusion chromatography (SEC), and by the analysis of low‐molecular‐weight organic acids (LMWOA). The degradation experiments were performed with water from a brown water lake or its isolated fulvic acid fraction and sodium hydroxide at different reaction times and temperatures. Depending on the wavelength and the reaction time, the UV/vis absorbance between 230 nm and 600 nm increased or decreased. The behaviour of model compounds during reactions in alkaline media was compared to the UV/vis spectroscopic behaviour of DOM. The release of LMWOA was described by kinetic data and compared to the data of model reactions. Evidence was given for the carboxylic esters playing a significant role in the release of LMWOA only during the beginning of the alkaline degradation. The results gained by SEC with on‐line UV and DOC detection showed that the average size of DOM was decreasing, and that a major part of the degradation products consisted of low‐molecular‐weight mono‐ and dicarboxylic acids.     

Filtrate Quality from Different Filter Operations

A brief review of the literature on filtrate quality obtained in constant and variable declining rate operation systems is presented, with the general conclusion that both systems usually produce filtrate of similar quality, assuming the flow‐rate controllers in the constant flow rate system operate properly. A mathematical model of CR (constant rate) filters and VDR (variable declining rate) filters based on the model by Mackie and Zhao (1999) has been described and used to investigate filtrate quality under different operating conditions. A similar quality of filtrate was achieved in computations carried out for both modes of operation, while the total head loss was much lower in the VDR mode. For the same time of filter runs slightly better filtration quality resulted from CR operation, but for different filter runs resulting from the same head loss of flow just before a backwash, the VDR control system produced lower turbidity filtrate.     

Determination of Antibiotic Residues in Manure,Soil, and Surface Waters

In the last years more and more often detections of antimicrobially active compounds (“antibiotics”) in surface waters have been reported. As a possible input pathway in most cases municipal sewage has been discussed. But as an input from the realm of agriculture is conceivable as well, in this study it should be investigated if an input can occur via the pathway application of liquid manure on fields with the subsequent mechanisms surface run‐off/interflow, leaching, and drift. For this purpose a series of surface waters, soils, and liquid manures from North Rhine‐Westphalia (Northwestern Germany) were sampled and analyzed for up to 29 compounds by HPLC‐MS/MS. In each of the surface waters antibiotics could be detected. The highest concentrations were found in samples from spring (300 ng/L of erythromycin). Some of the substances detected (e.g., tylosin), as well as characteristics in the landscape suggest an input from agriculture in some particular cases. In the investigation of different liquid manure samples by a fast immunoassay method sulfadimidine could be detected in the range of 1…2 mg/kg. Soil that had been fertilized with this liquid manure showed a content of sulfadimidine extractable by accelerated solvent extraction (ASE) of 15 μg/kg dry weight even 7 months after the application. This indicates the high stability of some antibiotics in manure and soil.     

A crystal-chemical investigation of Cr substitution in muscovite by XANES spectroscopy

 This work introduces a novel procedure to fit the scattering features of XANES spectra. The procedure was applied and validated on a chromium-containing muscovite for which structural and crystal-chemical characterization is available from literature. The simulation, which involved clusters formed by up to 90 atoms, proved to be effective in representing the Cr local environment, even if the system is characterized by a very low metal content, as demonstrated by the extremely good correspondence with experimental data. Received: 23 May 2002 / Accepted: 6 November 2002     

Numerical modeling of the transient hydrogeological response produced by tunnel construction in fractured bedrocks

Groundwater inflows into tunnels constructed in fractured bedrocks not only constitute an important factor controlling the rate of advancement in driving the tunnel but may pose potential hazards. Drawdowns caused by tunnel construction may also induce geotechnical and environmental impacts. Here we present a numerical methodology for the dynamic simulation of the hydrogeological transient conditions induced by the tunnel front advance. The methodology is based on the use of a Cauchy boundary condition at the points lying along the tunnel according to which water discharge, Q, is computed as the product of a leakage coefficient, , and the head difference, (H−h), where H is the prescribed head at the tunnel wall and h is the hydraulic head in the fractured rock in the close vicinity of the tunnel. At a given position of the tunnel, is zero until the tunnel reaches such position when it is assigned a positive value. The use of step-wise time functions for allows an efficient and accurate simulation of the transient hydrogeological conditions at and around the tunnel during the excavation process. The methodology has been implemented in TRANMEF-3, a finite element computer code for groundwater flow in 3D fractured media developed at the University of A Coruña, Spain, and has been used to simulate the impact of a tunnel on the groundwater system at the Äspö island (Sweden). This tunnel was constructed to access an underground laboratory for research on radioactive waste disposal. The large amount of available data at this site provides a unique opportunity to test the performance of the numerical model and the proposed methodology for tunnel advance. With just minor calibration, the numerical model is able to reproduce accurately the measurements of inflows into the tunnel at several reaches and hydraulic heads at surface-drilled boreholes. These results obtained at the Äspö site lead us to conclude that accurate predictions of the transient hydrogeological responses induced by tunneling works in fractured bedrocks, can be achieved provided that a sound hydrogeological characterization of large-scale fracture zones is available.     

Determination of Chromium, Nickel, Copper and Zinc in Milligram Samples of Geological Materials Using Isotope Dilution High Resolution Inductively Coupled Plasma-Mass Spectrometry

A simple and accurate method for the determination of Cr, Ni, Cu and Zn at μg g^?1 levels in milligram‐sized bulk silicate materials is reported using isotope dilution high‐resolution inductively coupled plasma‐mass spectrometry (HR‐ICP‐MS) with a flow injection system. Silicate samples with Cr, Ni, Cu and Zn spikes were digested with HF‐HBr and Br₂, and subsequently decomposed at 518 K in a Teflon bomb. In this procedure, all sulfides and chromite, major hosts of these elements, were completely decomposed, thus allowing for isotope equilibration between the sample and spike. Magnesium and Al fluorides formed after the digestion of the sample were removed by centrifugation, and the supernatant was directly aspirated into a HR‐ICP‐MS at a mass resolution of 7500, where interfering oxide ions, ArO⁺, CaO⁺, TiO⁺, CrO⁺ and VO⁺, were separated from Cr⁺, Ni⁺, Cu⁺ and Zn⁺. No matrix effects were observed down to a dilution factor of 50. Detection limits for these elements in silicate samples were < 0.04 μg g^?1. The effectiveness of the technique was demonstrated by the analysis of 13 to 40 mg test portions of USGS and GSJ silicate reference materials with a major element composition ranging from andesite to peridotite, in addition to 8‐23 mg of the Smithsonian reference Allende. Both the reproducibility and the deviation from the reference value for most reference materials of various rock types were < 9%, and thus confirm that the method gives accurate analytical results for small sample sizes over a wide range of Cr, Ni, Cu and Zn contents. This method is, therefore, suitable for analysing small and/or precious bulk samples, such as meteorites, mantle peridotites and mineral separates, and for the characterisation of silicate and sulfide minerals for use as calibration samples in secondary ion mass spectrometry or laser ablation ICP‐MS.     

集成地图环境下GPS卫星跟踪定位系统设计一例

介绍了MapInf04．5集成地图环境下利用VB6．o的Activex控件实现GPS卫星定位信号接收，实时显示测量车位置及测量点状态的系统设计实例。     

V6多功能系统及其在CSAMT勘查应用中的效果

地球物理多功能探测系统V6是中国科学院地质与地球物理所2000年底从加拿大凤凰公司引进的新仪器，它具有频点多（62频点系列），抗干扰能力强，发射功率大，A/D转换16位置及发射与接收信号GPS（Globe Position System)时钟同步等特点，能有效地提高纵向分辩率和测量信号的信噪比，为浅层精细勘探提供了保障。V6系统在牛栏山水源八厂标准剖面的试验，山东莱芜业庄矿突水勘查工作等充分证明，V6系统能较准确地确定目标的层深度，结合地质资料，可以提供含水性的判断。