Ice fracturing during jökulhlaups: implications for englacial floodwater routing and outlet development

Theoretical studies of glacial outburst floods (jökulhlaups) assume that: (i) intraglacial floodwater is transported efficiently in isolated conduits; (ii) intraglacial conduit enlargement operates proportionally to increasing discharge; (iii) floodwater exits glaciers through pre‐existing ice‐marginal outlets; and (iv) the morphology and positioning of outlets remains fixed during flooding. Direct field observations, together with historical jökulhlaup accounts, confirm that these theoretical assumptions are not always correct. This paper presents new evidence for spatial and temporal changes in intraglacial floodwater routing during jökulhlaups; secondly, it identifies and explains the mechanisms controlling the position and morphology of supraglacial jökulhlaup outlets; and finally, it presents a conceptual model of the controls on supraglacial outbursts. Field observations are presented from two Icelandic glaciers, Skeiðarárjökull and Sólheimajökull. Video footage and aerial photographs, taken before, during and after the Skeiðarárjökull jökulhlaup and immediately after the Sólheimajökull jökulhlaup, reveal changes in floodwater routing and the positioning and morphology of outlets. Field observations confirm that glaciers cannot transmit floodwater as efficiently as previously assumed. Rapid increases in jökulhlaup discharge generate basal hydraulic pressures in excess of ice overburden. Under these circumstances, floodwater can be forced through the surface of glaciers, leading to the development of a range of supraglacial outlets. The rate of increase in hydraulic pressure strongly influences the type of supraglacial outlet that can develop. Steady increases in basal hydraulic pressure can retro‐feed pre‐existing englacial drainage, whereas transient increases in pressure can generate hydraulic fracturing. The position and morphology of supraglacial outlets provide important controls on the spatial and temporal impact of flooding. The development of supraglacial jökulhlaup outlets provides a new mechanism for rapid englacial debris entrainment. Copyright © 2000 John Wiley & Sons, Ltd.     

Effects of the number of stations and time resolution on derivation

For at least 30 years now it has been well known that the Dst index can be modelled using the solar wind as input. Since then, many attempts have been made to improve the predictability of Dst using different approaches. These attempts are useful, for instance, to understand which features of the solar wind–magnetosphere interactions are most important in producing magnetospheric activity and how the Dst index would improve the space weather forecast. The Dst index is by far the most reliable and simple indication that a magnetic storm is in progress. In this work, the effect of using more than four magnetic stations and shorter time intervals than the hourly averages used in Sugiura's procedures is evaluated. The discussion is based on the results presented by Burton in 1975 and Feldstein in 1984 considering 4 or 12 magnetic stations and time averages of 2.5 min for a magnetic disturbed period that occurred from February 7–28, 1967, including two geomagnetic storms. The analysis has shown that the global representation of a magnetic storm by the standard Dst (Sugiura) is well preserved either using 4, 6, 12 magnetic stations or using 1 h, 2.5 min 1 min averages. A brief review of the current understanding of Dst has been included to support the discussions. The analysis performed has shown that a more refined Dst index (time and number of stations>4) would be useful to investigate the intrinsic processes and the different current systems involved in the ring current development during magnetic storms; the standard Dst, as it is conceived, is quite adequate to monitor geomagnetic storms and identify their overall features; concerning the magnetic stations normally considered, the inclusion of higher magnetic latitude stations (>35) may underestimate the observed Dst.     

2007年宁洱6.4级地震序列精定位

Five mobile digital seismic stations were set up by the Earthquake Administration of Yunnan Province near the epicenter of the main shock after the Ning’er M6.4 earthquake on June 3, 2007. In this paper, the aftershock sequence of the Ning’er M6.4 earthquake is relocated by using the double difference earthquake location method. The data is from the 5 mobile digital seismic stations and the permanent Simao seismic station. The results show that the length of the aftershock sequence is 40km and the width is 30km, concentrated obviously at the lateral displacement area between the Pu’er fault and the NNE-trending faults, with the majority occurring on the Pu’er fault around the main shock. The depths of aftershocks are from 2km to 12km, and the predominant distribution is in the depth of 8～10km. The mean depth is 7.9km. The seismic fault dips to the northwest revealed from the profile parallel to this aftershock sequence, which is identical to the dip of the secondary fault of the NE-trending Menglian-Mojiang fault in the earthquake area. There are more earthquakes concentrated in the northwest segment than in the southeast segment, which is perhaps related to the underground medium and faults. The depth profile of the earthquake sequence shows that the relocated earthquakes are mainly located near the Pu’er fault and the seismic faults dip to the southwest, consistent with the dip of the west branch of the Pu’er fault. In all, the fault strike revealed by earthquake relocations matches well with the strike in the focal mechanism solutions. The main shock is in the top of the aftershock sequence and the aftershocks are symmetrically distributed, showing that faulting was complete in both the NE and SW directions.     

Supraglacial melt channel networks in the Jakobshavn Isbræ region during the 2007 melt season

Supraglacial channels are an important mechanism for surface water transport over the ablation zone of western Greenland. The first assessment of the spatio‐temporal distribution of surface melt channels and their relationship to supraglacial lakes over the Jakobshavn Isbræ region of Western Greenland was analysed using Landsat Enhanced Thematic Mapper Plus panchromatic images during the 2007 melt season. A total of 1188 melt channels were delineated and show an increase in the number of melt channels throughout the season, reaching a peak on 9 August. Water‐filled melt channels advanced to a maximum elevation of 1647 m on 9 August and attained a minimum average slope of 0.009 on 8 July. The ablation zone demonstrates two hydrologic modes, where crevasse and moulin terminating channels dominate at elevations <800 m and higher‐order channel networks >800 m. Development of higher‐order networks is interrupted by flow divergence due to partitioning of melt water into vertical infiltration through moulins and crevasse fields prevalent at lower elevations. Tributary and connector networks between 800 and 1200 m in elevation are correlated with fewer lake occurrences, lower surface velocities (~50 m a^?1), and ice flow dominated by internal deformation over basal sliding. High‐order channels are associated with lake basins that exceed melt water storage capacity. Evolution of channel networks is coupled to changes in melt water production, runoff, and ice dynamics with implication for the englacial and subglacial environments. © 2013 The Authors. Hydrological Processes Published by John Wiley & Sons, Ltd.     

6-硝基-2-苯并噻唑重氮氨基偶氮苯与铜的显色反应及其应用

在pH10～12的Na2B4O7-NaOH缓冲溶液中,TritonX-100表面活性剂存在下,6-硝基-2-苯并噻唑重氮氨基偶氮苯与铜发生显色反应,生成2∶1的深红色配合物。配合物的最大吸收峰位于535nm处,表观摩尔吸光系数1.42×105L·mol-1·cm-1。Cu2+的浓度在0～400μg/L符合比尔定律。用拟定方法测定铝合金及铜矿石样品中的微量铜,结果与原子吸收法结果相符,6次测定的RSD<3%。     

Optimization of the Sampling Technique for the Determination of Dissolved Hydrogen in Groundwater

In this study a field‐sampling technique for dissolved hydrogen (H₂) in groundwater will be presented which allows the transport of gaseous samples into the laboratory for further analysis. The method consists of transferring the headspace trapped in a gas‐sampling bulb which is continuously purged by groundwater into previously evacuated vials using a gas‐tight syringe. Three transfer steps with preceding evacuation of the vial led to a H₂‐recovery of 100 % in laboratory experiments. The method has been applied to determine H₂ concentrations in an aquifer contaminated with chlorinated solvents. Tests concerning the effect of different pumping techniques on H₂ concentrations revealed that most reliable values were obtained with a bladder pump, while an electrically driven submersible pump generated considerable amounts of hydrogen due to electrochemical interactions with the sampled water. Concentrations of dissolved hydrogen in field and laboratory samples were about two orders of magnitude higher when sampling was performed with the electrically driven submersible pump compared to sampling with the bladder pump and a peristaltic pump. Lab experiments with a Plexiglas reservoir to produce H₂‐enriched water were used to study the effect of two tubing materials (PVC, polyamide) on H₂ losses. PVC tubing turned out to allow transfer of H₂‐enriched water over 25 m without significant losses, while PA‐tubing was not suitable for sampling of H₂.     

黄原胶改性微米铁修复地下水中Cr(Ⅵ)污染的试验

为了解决微米铁的重力沉降问题,提高微米铁修复地下水Cr（Ⅵ）污染的原位修复效果,本文利用黄原胶对微米铁进行改性,并通过沉降实验探究改性微米铁浆液的稳定性,同时选择Cr（Ⅵ）作为目标污染物,探究黄原胶改性微米铁去除地下水Cr（Ⅵ）污染的降解能力。实验结果显示：当黄原胶的投加质量浓度分别为0.0、1.0、1.5、2.0、2.5、3.0、6.0 g/L时,改性微米铁浆液的悬浮稳定性逐渐得到加强,在5 h沉降实验结束时,对应的相对分光光度值分别为0.05、0.25、0.46、0.57、0.65、0.73和0.87;黄原胶具有抑制微米铁吸附Cr（Ⅵ）的能力,其可促进Cr（Ⅵ）的还原,提高Cr（Ⅵ）的去除率;随着黄原胶投加质量浓度的增加,对应的Cr（Ⅵ）去除率分别为33.4%、41.2%、47.4%、51.1%、53.0%、63.9%和64.1%;6.0 g/L黄原胶改性的微米铁浆液具有最佳的悬浮稳定性,黄原胶的投加提高了微米铁的反应活性,但当黄原胶投加质量浓度超过3.0 g/L时,其对Cr（Ⅵ）的去除率没有显著提高;黄原胶投加质量浓度越大,黄原胶的缓冲作用就越明显。     

Surface air temperature changes over the Tibetan Plateau: Historical evaluation and future projection based on CMIP6 models

With its amplification simultaneously emerging in cryospheric regions, especially in the Tibetan Plateau, global warming is undoubtedly occurring. In this study, we utilized 28 global climate models to assess model performance regarding surface air temperature over the Tibetan Plateau from 1961 to 2014, reported spatiotemporal variability in surface air temperature in the future under four scenarios (SSP1-2.6, SSP2-4.5, SSP3-7.0, and SSP5-8.5), and further quantified the timing of warming levels (1.5, 2, and 3 °C) in the region. The results show that the multimodel ensemble means depicted the spatiotemporal patterns of surface air temperature for the past decades well, although with differences across individual models. The projected surface air temperature, by 2099, would warm by 1.9, 3.2, 5.2, and 6.3 °C relative to the reference period (1981–2010), with increasing rates of 0.11, 0.31, 0.53, and 0.70 °C/decade under the SSP1-2.6, SSP2-4.5, SSP3-7.0, and SSP5-8.5 scenarios for the period 2015–2099, respectively. Compared with the preindustrial periods (1850–1900), the mean annual surface air temperature over the Tibetan Plateau has hit the 1.5 °C threshold and will break 2 °C in the next decade, but there is still a chance to limit the temperature below 3 °C in this century. Our study provides a new understanding of climate warming in high mountain areas and implies the urgent need to achieve carbon neutrality.     

Transformation of ammonium nitrogen and response characteristics of nitrifying functional genes in tannery sludge contaminated soil

High concentrations of ammonium nitrogen released from tannery sludge during storage in open air may cause nitrogen pollution to soil and groundwater. To study the transformation mechanism of NH₄⁺-N by nitrifying functional bacteria in tannery sludge contaminated soils, a series of contaminated soil culture experiments were conducted in this study. The contents of ammonium nitrogen (as NH₄⁺-N), nitrite nitrogen (as NO₂^?-N) and nitrate nitrogen (as NO₃^?-N) were analyzed during the culture period under different conditions of pollution load, soil particle and redox environment. Sigmodial equation was used to interpret the change of NO₃^?-N with time in contaminated soils. The abundance variations of nitrifying functional genes (amoA and nxrA) were also detected using the real-time quantitative fluorescence PCR method. The results show that the nitrification of NH₄⁺-N was aggravated in the contaminated silt soil and fine sand under the condition of lower pollution load, finer particle size and more oxidizing environment. The sigmodial equation well fitted the dynamic accumulation curve of the NO₃^?-N content in the tannery sludge contaminated soils. The Cr(III) content increased with increasing pollution load, which inhibited the reproduction and activity of nitrifying bacteria in the soils, especially in coarse-grained soil. The accumulation of NO₂^?-N contents became more obvious with the increase of pollution load in the fine sand, and only 41.5% of the NH₄⁺-N was transformed to NO₃^?-N. The redox environment was the main factor affecting nitrification process in the soil. Compared to the aerobic soil environment, the transformation of NH₄⁺-N was significantly inhibited under anaerobic incubation condition, and the NO₃^?-N contents decreased by 37.2%, 61.9% and 91.9% under low, medium and high pollution loads, respectively. Nitrification was stronger in the silt soil since its copy number of amoA and nxrA genes was two times larger than that of fine sand. Moreover, the copy numbers of amoA and nxrA genes in the silt soil under the aerobic environment were 2.7 times and 2.2 times larger than those in the anaerobic environment. The abundance changes of the amoA and nxrA functional genes have a positive correlation with the nitrification intensity in the tannery sludge-contaminated soil.