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81.
N. T. Kaltcheva 《Monthly notices of the Royal Astronomical Society》2000,318(4):1023-1035
The distribution of bright B-type stars in a field with a radius of 5° centred at the Galactic open cluster Cr 121 is studied utilizing Strömgren and H β photometry. All PPM stars earlier than spectral type A0 are used, revealing a loose nearby structure at a distance of 660–730 pc, and a compact more distant group, which appears to be a genuine cluster: Cr 121. Based on similar coordinates, distances and positions on the colour–magnitude (CM) and Hertzsprung–Russell (HR) diagrams, 11 photometric cluster members are selected at a mean distance of 1085(±41 standard error) pc. The results are discussed in the light of both classical and Hipparcos points of view. 相似文献
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83.
使用可见光谱数字化自动分析系统对铁基合金中铬元素可见光谱进行了分析测定。研究了铁基合金中铬元素的Cr 520.60 nm和Cr 534.58 nm分析谱线组的特征,并制作了数字化彩色图谱。探索了铁基合金中铬元素的数字化分析技术,结果可用于铁基合金中铬元素的定性、定量分析和牌号鉴别。 相似文献
84.
采用岛津MXF-2400型多道X荧光光谱仪测定锌铝硅合金中硅及铁的含量,对样品分析面进行了选择,考察了分析面光洁度、样品放置时间对测定的影响条件。方法样品前期处理简便,分析速度快,灵敏度高,硅和铁的相对标准偏差(RSD,n=11)分别为1.15%和0.44%。与其他方法对照,结果相符。 相似文献
85.
This study examined the interaction between Cr(VI) and a Fe-rich soil in the presence of low-molecular-weight organic acids
as a function of pH. Oxalic and tartaric acids were chosen since they existed in soils commonly. Batch experiments showed
that adsorption of Cr(VI) by the soil within the pH range examined was inhibited in the presence of oxalic acid, which was
more pronounced when the initial ratio of [oxalic acid]/[Cr(VI)] was raised from 1:1 to 2:1. With the addition of tartaric
acid, concentration of Cr(VI) in equilibrium solutions was far less than that of single adsorbate system across the pH wide
(2.5–5.5), which was noticeable especially at low pH. The results were attributed to Cr(VI) adsorption and, particularly,
the soil surface catalyzed reduction of Cr(VI) to Cr(III) by tartaric acid. The data reported in this paper suggested that
the mobility, the bioavailability, and the toxicity of Cr(VI) in soil environments might be greatly affected by pH, the presence
and nature of low-weight-molecular organic acids (oxalic and tartaric acids). 相似文献
86.
氢化物发生—原子荧光法直接测定锑及其化合物中的铅 总被引:1,自引:0,他引:1
通过在样品处理阶段用HBr除去大量锑基体,实现了不需再通过其他化学分离直接运用氢化物发生-原子荧光法测定锑及其相关产品中的微量铅,并用于实际样品的分析.该方法对样品检测下限小于10-6,在实际样品分析中,分析结果与原子吸收法测定结果之间无显著性差异,RSD<2.0%(n=4),对样品分析的加标回收率在95%~105%. 相似文献
87.
Chromium (Cr) is a heavy metal that exists in soils in two stable oxidation states, +III and +VI. The trivalent species is an essential nutrient, whereas the hexavalent species is highly toxic. This study investigated the environmental impact of CrIII potentially released into soil from wastes and various materials by determining the risk of oxidation of initially soluble inorganic CrIII into hazardous CrVI. The principal aim was to describe the pH-dependent mechanisms that regulate 1) the formation of CrVI from the easily soluble CrIII and 2) the potential bioavailability of CrIII and that of CrVI species produced in the oxidation of CrIII in agricultural soil (fine sand, organic carbon 3.2%). The amount of CrVI formed in oxic soil conditions was regulated by two counteracting reactions: 1) oxidation of CrIII into CrVI by manganese oxide (MnIVO2) and 2) the subsequent reduction of CrVI by organic matter back to CrIII. The effect of pH on this net-oxidation of CrIII and on the chemical availability of both CrIII and CrVI species was investigated in soil samples incubated with or without excessive amounts of synthetic MnO2, over the chemically adjusted pH range of 3.9–6.3 (+22 °C, 47 d). In soil subsamples without added MnO2, the net-oxidation of CrIII into CrVI (1 mM CrCl3 in soil suspensions, 1:10 w/V) was negligible. As for the MnO2-treated soils, at maximum only 4.7% of added CrIII was oxidized – regardless of the high oxidation potential of these subsamples. The lowest production of CrVI was observed under acidic soil conditions at pH ∼4. At low pH, the net-oxidation diminished as result of enhanced reduction of CrVI back to CrIII. At higher pHs, the oxidation was limited by enhanced precipitation (or adsorption) of CrIII, which lowered the overall amount of CrIII susceptible for oxidation. Moreover, the oxidation reactions by MnO2 were inhibited by formation of Cr(OH)3 coverage on its surface. The pH-dependent chemical bioavailability of added CrIII differed from that of the CrVI formed. At elevated pHs the chemical availability of CrIII decreased, whereas that of CrVI produced increased. However, the risk of CrVI formation through oxidation of the easily soluble inorganic CrIII was considered to be low in agricultural soils high in organic matter and low in innate MnO2. 相似文献
88.
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90.
实验研究了胶印含铬废水化学处理的方法及工艺条件。经化学法处理 ,Cr( )和总 Cr的浓度均能达到国家工业污水排放标准 ;研究结果表明 ,废水中 Cr( )还原成 Cr( )的反应 ,还原剂 Na HSO3 投加量应是 Cr( )重量的 7倍以上 ;Cr(OH) 3 的沉淀反应的适宜 p H范围在 7.5~ 8.5 ,以 p H 8.0时为最佳 ;Cr(OH) 3 的沉淀反应的搅拌时间应在 2 0 min以上为宜 ;沉淀反应的烘干沉渣量为废水总 Cr量的 11倍。该实验研究结果可为含铬废水化学处理法的工艺设计提供理论依据 相似文献