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31.
32.
海北化工厂已停产15年之久,但Cr6+污染依旧十分严重.调查得知,海北化工厂原生产废液排放及堆存废渣经降水淋滤作用下渗,是造成该区包气带和地下水Cr6+污染的主要原因.采用地下水质量法和污染指数法评价分析该区地下水Cr6+污染范围和污染影响程度.评价结果显示:Cr6+重度污染区面积0.75 km2,厂区包气带Cr6+平均含量67.67×10-6,平均超标指数1691.75,地下水中Cr6+浓度超过Ⅴ类水标准.在分析厂区周边水文地质条件的基础上,提出清除场地废渣废料并置换被污染的包气带、采用抽水法治理被污染的地下水的综合方案. 相似文献
33.
氢化物发生-原子荧光光谱法测定地球化学样品中痕量碲 总被引:4,自引:4,他引:4
采用焙烧富集分离地球化学样品中痕量Te,并用氢化物发生原子荧光光谱法测定。通过实验确定出方法的最佳实验条件,在此条件下获得的检出限为0.005μg/g,线性范围0.025~10μg/g,精密度(RSD,n=8)为5.03%~9.24%。方法已用于国家一级地球化学标准物质中痕量Te的测定,结果与标准值基本相符。 相似文献
34.
进口DMH90型爆破孔钻机配套钻塔整体性强,起落塔快捷方便,钻塔高度满足不换杆一次成孔,即钻塔有效高度略大于钻孔深度,承受振动冲击力大,施工工作环境恶劣。基于这些特点和难点,爆破塔长期依赖进口,导致成本增高、周期加长,为此进行了进口DMH90型爆破孔钻机配套钻塔的替代进口研究工作。本文介绍了DMH90型爆破孔钻机配套ZT27-45型爆破孔钻塔的研制过程,主要对ZT27-45型爆破孔钻塔的设计要点、结构型式、塔体选材、焊接工艺、防止变形、消除应力、质量检验等方面进行了探索、试验和总结。生产施工实践表明,ZT27-45型钻塔制造质量达到了设计要求,满足爆破孔施工的需要,实现了替代进口,达到了降低成本、缩短工期和提高机械性能的目的。 相似文献
35.
We have investigated a well-ordered sample of natural Cr-bearing dickite from Nowa Ruda (Lower Silesia, Poland) using electron
paramagnetic resonance (EPR) at X- and Q-band frequencies (9.42 and 33.97 GHz, respectively) and optical diffuse reflectance
spectroscopy. The observation of the spin-forbidden transitions at 15500 and 14690 cm−1 allows us to unambiguously identify the major contribution of octahedrally coordinated Cr3+ ions in the optical spectrum. The X- and Q-band EPR spectra show two superposed Cr3+ signals. The corresponding fine-structure parameters were determined at room temperature and 145 K. These results suggest
the substitution of Cr3+ for Al3+ in equal proportions in the two unequivalent octahedral sites of the dickite structure. In kaolin group minerals, the distortion
around Cr3+ ions (λ≈ 0.2–0.4) in Al sites is significantly less rhombic than that observed around Fe3+ ions (λ≈ 0.6–0.8).
Received: 29 June 2001 / Accepted: 22 October 2001 相似文献
36.
37.
本义采用氢化物法分离技术,使样品溶液中的锗转变为气态氢化锗(GeH_4),达到与基体分离的目的,有效地消除了各种离子的干扰。研究并证明了在15%以上的磷酸介质中,各种酸(HCl,H_2SO_4,HNO_3,HCIO_4)度在1%-10%的范围内变化均不影响锗的测定,大大简化了操作手续,方法灵敏度高、使用范围广、准确、简便、快速。Ge的检出限为0.1μg/g,相对标准偏差<7%。可应用于地质,冶金,生物,环保,卫生,食品中微量锗的测定。 相似文献
38.
The distribution of dissolved and participate concentrations of As, Cr and V was investigated in the mixing area of the Po river in five surveys over the period March 1992-March 1995. The data obtained indicate noticeable contamination of coastal waters of the northern Adriatic with Cr but not As or V. Total dissolved concentrations for As and V were comparable with oceanic levels but were higher by a factor of 4 for Cr. These results suggest either low anthropogenic inputs of As and V, from terrigenous and atmospheric sources, or efficient removal mechanisms. The investigated metals had low reactivity during freshwater-seawater mixing and the distribution of concentrations in the dissolved and solid phases suggests that the dilution process is the main factor controlling the transport of these metals to the sea in low-to-medium solid transport conditions. Further investigations are required to elucidate the behavior of these metals during high solid transport conditions. Significant changes in the speciation of As occurred during the transition between the two end-member matrices. In the coastal waters of the northern Adriatic, the arsenite fraction in winter, and the arsenite and dimethylarsinate fractions in summer increased with respect to riverine waters. Changes in the speciation of chromium were minor, but also showed a small increase in reduced species in marine waters. 相似文献
39.
Li Guowu Shi Nicheng Xiong Ming Ma Zhesheng Bai Wenji Fang Qingsong 《Frontiers of Earth Science》2007,1(1):21-25
The origin of native Si-Fe alloy mineral is thought to be related with mantle and aerolite. The native Si-Fe alloy minerals
from podiform chromites of the Luobusha ophiolite in the Yarlong Zangbo suture zone were examined by a new method for powder-like
diffractograms of small single crystals, using an SMART APEX-CCD area-detector X-ray diffractometer. The powder diffraction
pattern shows that the minerals are composed of FeSi, FeSi2, β-FeSi2 and native silicon. The association of these minerals suggests that the crystallization order of the mineral may be from
early to late FeSi→FeSi2→native silicon, accompanied by gradually increasing deoxidization.
Translated from Acta Petrologica et Mineralogica, 2005, 24(5): 453–456 [译自: 岩石矿物学杂志] 相似文献
40.
讨论了预合台体粉末的优点,研究了预合金胎的粉末的制备技术,列举了预合金胎体金刚石钻头的应用效果。 相似文献