疏浚物中镉释放的影响条件

本文模拟研究了疏浚沉积物中Ｃd的释放行为和影响条件。结果表明介质的盐度、pＨ、氧化还原状态等环境条件和疏浚沉积物的污染程度、粒度大小、有机质含量等理化特征对Ｃd的 释放有明显的影响。Ｃd从疏浚物中释放,其释放速率较快,释放率在４０％～９６％之间。疏物的海上倾弃可能引起Ｃd的污染和对部分生态环境的危害。同时还讨论了Ｃd的释放所遵循的动力学规律。     

磁敏感加权成像临床应用和在血管瘤评估中的研究进展

磁敏感加权成像是一种近年发展的MRI新技术,在中枢神经系统疾病中的诊断及鉴别诊断中的重要作用已经得到了广大临床大夫的认可,具有很高的应用价值和拓展前景。SWI作为常规MRI检查的重要补充序列,采用3D梯度回波扫描,完全速度补偿,射频脉冲扰相等技术,具有三维、高分辨率、高信噪比的特点,可以更好地分析软组织血管瘤的结构成分,鉴别活动性出血、机化血栓、钙化及铁沉积等。而且SWI相位图能够清楚显示瘤体内部新生血管、瘤体周围静脉血管位置和形态改变,更有利于准确评估病变范围及程度,为血管瘤定位及定性诊断可以提供更多的影像信息,对于临床诊断及治疗方案的制定、预后评估都具有重要的应用价值。     

Condensed hyperelements method of non-vertical consistent boundaries for wave propagation analysis in irregular media

The study of wave propagation in finite/infinite media has many applications in geotechnical and structural earthquake engineering and has been a focus of research for the past few decades. This paper presents an analysis of 2D anti- plane problems （Love waves） and 2D in-plane problems （Rayleigh waves） in the frequency domain in media consisting of a near-field irregular and a far-field regular part. The near field part may contain structures and its boundaries with the far-field can be of any shape. In this study, the irregular boundaries of the near-field are treated as consistent boundaries, extending the concept of Lysmer＇s vertical consistent boundaries. The presented technique is called the Condensed Hyperelements Method （CHM）. In this method, the irregular boundary is limited to a vertical boundary at each end that is a consistent boundary at the far-field side. Between the two ends, the medium is discretized with hyperelements. Using static condensation, the stiffness matrix of the far-field is derived for the nodes on the irregular boundary. Examples of the application of the CHM illustrate its excellent accuracy and efficiency.     

Sr原子电磁感应透明效应相关理论研究

从理论上研究了Sr原子系统中电磁感应透明（EIT）效应及其伴随的Kerr非线性效应。计算表明,将一级冷却得到的Sr冷原子粘团作为光场与原子相互作用的EIT介质,用较弱的耦合光可以得到一个非常窄的EIT窗口和较强的Kerr非线性效应。该研究结果为实现689nm激光器的线宽压窄及应用EIT效应进行。Sr玻色子冷原子光钟研究提供了理论参考。     

带有小数补偿的低频数控振荡器及其基于FPGA的实现

在分析数控振荡器（NCO）工作原理的基础上,以低频信号为例,研究了影响NCO性能的几个因素。结合杂散特性,着重讨论了频率控制字误差对输出频率带来的影响,提出在相位累加器中加入小数部分补偿,以使降低信号频率门限值和提高输出的准确性。最后采用FPGA（现场可编程门阵列）实现了带有小数补偿的NCO,在兼顾硬件资源的同时优化了系统性能,另外通过仿真验证了这种方法的可行性。     

Distribution of As, Cr and V species in the Po-Adriatic mixing area, (Italy)

The distribution of dissolved and participate concentrations of As, Cr and V was investigated in the mixing area of the Po river in five surveys over the period March 1992-March 1995. The data obtained indicate noticeable contamination of coastal waters of the northern Adriatic with Cr but not As or V. Total dissolved concentrations for As and V were comparable with oceanic levels but were higher by a factor of 4 for Cr. These results suggest either low anthropogenic inputs of As and V, from terrigenous and atmospheric sources, or efficient removal mechanisms. The investigated metals had low reactivity during freshwater-seawater mixing and the distribution of concentrations in the dissolved and solid phases suggests that the dilution process is the main factor controlling the transport of these metals to the sea in low-to-medium solid transport conditions. Further investigations are required to elucidate the behavior of these metals during high solid transport conditions. Significant changes in the speciation of As occurred during the transition between the two end-member matrices. In the coastal waters of the northern Adriatic, the arsenite fraction in winter, and the arsenite and dimethylarsinate fractions in summer increased with respect to riverine waters. Changes in the speciation of chromium were minor, but also showed a small increase in reduced species in marine waters.     

Heavy Metal Load of Sediments of the River Gurk (Carinthia/Austria) — Merits and Limitations of Sequential Leaching Schwermetallbelastung des Sediments der Gurk in Kärnten — Vorzüge und Einschränkungen sequentieller Löseverfahren

By means of the analysis of sediments cored in the small river Gurk (Carinthia/Austria), the input of Ag, Cd, Ce, Cr, Hg, La, Mo, Ni, V, and W from a chemical industrial plant could be detected. To estimate the actual load, and to obtain data for comparison with other sites, both unsieved fine sediments and sediments sieved to 20 μm were investigated from the same cores. Environmental mobilities of toxic heavy metals (Co, Cr, Cu, Ni, Zn) have been shown by sequential leaching following Tessier/Förstner. In the last step, HNO₃ leaches a purely geogenic fraction, which is fairly constant along the investigated river. Whereas the additional Cr from the input of the chemical plant is mainly found in the oxalate-leachable fraction, short-time-load to unpolluted sediments in the laboratory is found mainly in hydroxylamine/acetic acid. Both is due to the high affinity of Cr to Fe- and Mn-oxides. Adsorption/desorption experiments reveal that the low carbonate content of the Gurk sediments increases the importance of Fe/Mn-oxides for the sorption of Cr compared to other samples containing carbonate. The Ni-load was primarily found in weak-acid-leachable and oxalate-leachable fractions. Similarly, the oxalate-leachable fraction is dominant for adsorption of other metals and phosphorus. Other interelement relationships among the amounts leached, which are attributable partly to carbonate-, silicate-, organic or coating phases, have been found by means of factor analyses together with marker fractions for each type.     

热带大气季节内振荡和ENSO的相互关系

通过观测资料的分析和数值模拟,研究了热带大气季节内振荡与ＥＮＳＯ的相互关系．一方面,在Ｅ１Ｎｉｎｏ事件发生之前,热带大气季节内振荡（尤其是在赤道中西太平洋地区）异常偏强,通过海一气相互作用它可能是Ｅ１Ｎｉｎｏ的一种重要激发机制．同时,赤道中西太平洋地区大气季节内振荡的异常加强同东亚中高纬度地区３０—６０天振荡的加强和强东亚冬季风有关．另一方面,ＥＮＳＯ对热带大气季节内振荡也有重要影响,在Ｅ１Ｎｉｎｏ期间,热带大气季节内振荡明显减弱;其结构明显趋于正压性．     

Potential ecological risk of cadmium, lead and arsenic in agricultural black soil in Jilin Province, China

Potential ecological risk of cadmium (Cd), lead (Pb) and arsenic (As) in agricultural black soil in Jilin Province, China was analyzed by the methods of risk assessment based on dose–effect relationships and ecological risk index. Heavy Cd-contamination occurred mainly around the coal mine region. The accumulation area for Pb appeared mostly in the suburbs and roadsides, whereas the higher As content was mainly found in the farmland of suburb and coal mine vicinity. In acute toxicity test, Cd, Pb and As in the soil had adverse effects on both roots and shoots growth in soybean with the greatest toxicity of arsenic and the least toxicity of lead at the same concentration levels. Exposed to Cd, Pb and As, the EC₅₀ (50% effective concentration) values for the growth of soybean root (shoot) were 212.59 (376.70), 528.53 (828.69) and 194.60 (299.03) mg/kg, respectively. Results of potential ecological risk index showed that soil contamination from Cd in some samples had very high potential ecological risk; Pb contamination for almost all sampling sites had moderate ecological risk; while soil contamination from As had low ecological risk. With the present accumulation rate, concentrations of Cd, Pb and As in agricultural black soil near coal mine would reach the threshold values in 68, 175 and 120 years, respectively.     

基于地基GPS遥感的大连地区大气水汽总量变化特征

基于大连地区地基GPS综合观测网遥感反演了大气水汽总量（PWV）,分析了大连地区PWV空间变化、逐月变化和日变化特征以及PWV变化与降水的关系,并利用大连本站2005-2011年的探空资料拟合了大连地区地面温度和大气加权平均温度的关系。结果表明：大连本站的PWV与探空积分的水汽含量相关系数达到0.988,均方根误差为2.5 mm。大连地区PWV南北分布比较均匀;PWV最大的月份为7-8月,最大月平均值约40 mm,PWV最小的月份为1月,最小月平均值小于4 mm;大连地区PWV春季和冬季日变化幅度约0.5 mm,夏季和秋季日变化幅度约1.3 mm。夏季和秋季的PWV日变化呈单峰型,春季和冬季的PWV日变化呈多峰型; 在降水发生前8 h 大气水汽总量有明显增加过程,对降水的发生有指示作用。