用线性自由能关系预测金属络合物的热力学性质

Sverjensky与Molling提出的线性自由能关系是根据金属阳离子的热力学性质来预测等结构系列中固体相的标准生成自由能。本文研究结果证实,水溶液中金属络合物与简单金属阳离子之间也存在类似的相关关系,预测值与实验值的差异通常小于1．5kcal／mol或小于一个log单位,这一线性自由能关系对于预测自然环境中重金属的水溶物种的配分、迁移和毒性具有非常重要的应用价值。     

CPL7及其在中国地球系统模式中的应用前景

中国地球系统模式中普遍存在的耦合器CPL6(美国国家大气研究中心的第六代通量耦合器)在很大程度上限制了模式在高分辨率上的发展,新一代耦合器CPL7并行度的可扩展性更高,能够适应更高分辨率的构型。以CPL7与中国科学院大气物理研究所的第二代格点大气环流模式(the Version 2 Grid-point Atmospheric Model of Institute of Atmospheric Physics,Chinese Academy of Sciences)的耦合为例,概述了其耦合原理,为CPL7与中国其他模式的耦合提供相关的经验。结合国内外模式的发展方向,CPL7耦合器在中国未来几年的地球系统模式的耦合改进中将占有很大的优势地位。     

红原泥炭6000a以来元素异常及其可能反映甘青地区人类活动信息的初步研究

通过对红原泥炭沉积剖面Pb,Zn,Fe,Mn,Cu,Co,Ni,Ti,V,Al等10种元素和灰分的测试,发现多数元素在该剖面的变化与灰分变化较为一致,但Cu,Pb和Zn元素的变化在剖面300cm以上出现较大异常:这3种元素的变化与其他元素变化呈相反的规律,而且Pb和Zn两种元素的含量较之剖面下部出现数量级的增大。通过对比,发现元素含量的异常与位于剖面上风区的甘青地区新石器时代晚期-青铜时代文化在发生时间上较为吻合,认为这可能是人类活动环境效应的记录。用600~300cm段的元素变化作为背景值,用与Pb,Zn元素相关较好的4种元素分别计算出二者变化的自然背景值,从而分离出了人类活动强度信息与自然环境背景值,分离结果与著名的青海柳湾墓地出土人口规模对比较好。     

地下水补给与开采量对降水变化响应特征:以京津以南河北平原为例

通过对京津以南河北平原年降水量、地下水补给量和农业开采量三者动态规律及其互动关系研究表明, 年降水量减增, 同期地下水补给量与开采量呈互逆变化规律, 即降水量减小, 补给量变少, 开采量增大; 年降水量增大, 补给量较多, 开采量减小.在连续枯(丰) 水年份, 当年降水量减少(增加) 10mm时, 则地下水系统水量减少7.08 (增加7.06) mm, 水位下降(上升) 5.2~8.7cm; 在10~320mm变幅内, 当年降水量减少(增加) 10%时, 则地下水系统水量减少7.98 (增加7.67) %.气候旱化过程中降水变化对引起补给量减少和开采量增加的幅度, 大于气候增雨过程中降水变化对补给量增大和开采量减少的影响程度.因此, 需要重视连续枯水年份降水变化对地下水系统影响的应对举措, 这对于提高我国北方区域地下水资源供给安全保障具有重大意义.      

Dynamic Relationship Between Entrainment Rate and Summer Monsoon in the Transition Area of Monsoon in the East of Northwest China

Entrainment rate refers to the ratio of surrounding air quality to air quality involved in rising unit distance, including turbulent entrainment and dynamic entrainment, which are applied to the boundary layer parametrization of convective clouds, the improvement of numerical model, the observation of cloud droplet spectral dispersion and the study of tropical cyclones.Based on the daily data at 07:00 and 19:00 every 10 m of five stations such as Minqin, Yuchong, Pingliang, Yinchuan and Yan'an from May to September during 2006-2016, combined with the daily observation data on the ground, the Entrainment Rates(ER) of different heights were calculated, and the relationships between ER and height in different regions, precipitation as well as monsoon during the monsoon period were further obtained. The main results were as follows:\mathrm{①} The ER was proportional to air temperature and saturated water vapor pressure, but inversely proportional to relative humidity. The relative humidity threshold of cloud was 65%. The higher the relative humidity threshold was, the lower the cloud height of different orders of precipitation was, and the cloud height was higher with the increase of rainfall. \mathrm{②}ER had obvious diurnal changes and regional differences: It was obviously smaller at 07:00 than at 19:00 from ground to 3 km, which weakened with the increase of height in the near surface , but strengthened with the increase of height above 500 m; From small to large, the monsoon affected area, the monsoon swing area and the non-monsoon area were in turn, and there was no regional difference above 3 km. \mathrm{③} ER was closely related to the intensity and property of precipitation in monsoon period. The ER weakened with the enhancement of rain intensity from near ground to below 600 m, but strengthened with the enhancement of rain intensity from 500 m to 2~3 km.From near ground to below 700 m, the ER of stable precipitation was strong, but that of convective precipitation was strong above 700 m. The convective precipitation had big saturated water vapor pressure and strong ER , while the stable precipitation had big saturated water vapor density, rich water vapor but weak ER. \mathrm{④}The relationship between ER and monsoon as well as its duration: From no monsoon to monsoon ER was weakened, the strongest maximum height was also decreasing. There was no significant difference in the duration of ER between the non-monsoon area and the monsoon affected area, but the longer the monsoon swing area lasted in the near ground layer, the smaller the ER was, while the opposite was at 1~2 km in the high altitude. \mathrm{⑤}The relationship between ER and the APO monsoon intensity index showed that: At 07:00, the ER strengthened with height from near ground to below 800 m, but weakened with height above 800 m,and the monsoon intensity was not related to the ER. At 19:00, the ER strengthened with the height near ground but weakened with the height above 300 m, and the stronger the monsoon was, the smaller the ER was. The ER weakened with the decrease of boundary layer height.     

颗粒大小对颗粒材料力学行为影响初探

利用一种特殊颗粒材料-玻璃珠进行了一系列室内直剪试验,研究颗粒大小对颗粒材料力学行为的影响。试验一共考虑了3条近乎平行的级配曲线和4种颗粒摩擦情况：干燥状态、水浸润状态、水淹没状态和油浸润状态。试验结果表明,颗粒大小对颗粒材料的力学行为有显著影响,剪胀性随着粒径的增大而增强。为考虑颗粒大小对剪胀性的影响,提出了一种新的剪胀关系式。在该剪胀关系式中,剪胀系数为依赖于颗粒大小和颗粒摩擦等颗粒基本性质的变量。试验研究同时表明临界状态摩擦角随着颗粒大小的增加而增加。此外,从颗粒细观运动的角度提出了颗粒滑动的功能模型,推导出了功能方程,并以此揭示了颗粒大小对临界状态摩擦角影响的细观机制。     

地幔平衡部分熔融和岩浆分离结晶成因岩浆岩的判别

本文在讨论Ⅰ型（地幔平衡部分熔融成因）和Ⅱ型（岩浆分离结晶成因）岩浆岩元素丰度关系公式的基础上，建立了Ⅰ型和Ⅱ型岩浆岩系成因判别公式及判别法则。     

盆山结构与油气分布——以四川盆地为例

根据四川盆地与周缘造山带地貌学、深浅部结构构造及动力学机制等, 其盆山结构可分为板缘(龙门山、米仓山和大巴山)突变型和板内(齐岳山、大娄山和大凉山)渐变型两类。板缘突变型盆山结构具有显著深部结构差异性,浅部构造具典型冲断带(山)和前陆盆地(盆)二元结构,其盆山耦合关系主要受控于深部结构的差异性和造山带的形成演化过程,现今山盆地貌反差大,地形坡度陡,盆山边界明晰。板内渐变型盆山结构, 则深部结构特征相似,浅部构造具挤压-坳陷结构、不发育大规模冲断推覆,现今山盆地貌反差小、盆山边界不清, 盆山为渐变过渡关系,其盆山耦合关系主要受控于邻区(盆外)的构造变形和盆内沉积盖层中多层次滑脱作用。不同盆山结构主要通过对现今四川盆地保存条件的影响而控制现今油气分布。四川盆地现今(残存)大中型油气藏和天然气探明储量的大部分主要分布于突变型盆山结构区,尤其是秦岭构造变形控制域。     

基于耦合关系的干旱绿洲区农村居民点整理分区研究——以张掖市甘州区为例

以张掖市甘州区为例,利用系统科学理论与方法,研究农村居民点整理与农村社会经济之间的动态耦合规律,并以甘州区18个乡镇为研究单元,构建了农村居民点用地整理分区评价指标体系,利用熵值法确定权重,计算农村居民点整理的综合评价值,运用层次筛选法将研究区划分为5个整理区。研究结果：①甘州区农村居民点与农村社会经济的耦合度演化分为3个阶段：1995—1997年,二者不甚协调;1998—2003年,二者都处于持续、稳定、最佳协调发展状态;2004—2007年,二者处于相对稳定协调状态;目前二者处于不甚协调发展阶段。②农村居民点整理分区包括优先整理区、强化整理区、适度整理区、一般整理区和完善整理区。     

考虑含砂量影响的砂-黏混合土应力-应变关系特性研究

将砂与黏土按不同比例干重量均匀混合制成砂-黏混合土,进行不排水三轴剪切试验,研究了含砂量和试验围压对混合土初始切线模量和应力-应变关系的影响,并对其作用机理进行了分析。研究结果表明:含砂量小于50%时,可以认为混合土初始切线模量与含砂量无关。含砂量大于50%小于80%时,初始切线模量随含砂量增加呈线性趋势增长。通过把含砂量参数引入到初始切线模量中对Duncan-Chang模型进行修正,使修正后的模型能够描述含砂量小于80%时混合土的应力-应变关系。当含砂量超过80%,混合土呈应变软化型,随含砂量的增加,初始切线模量逐渐保持稳定,应力-应变曲线峰值应变左移,可应用软化模型对其应力-应变关系进行描述。围压对混合土应力-应变关系有很大影响,在双对数坐标中,随试验围压的增大,初始切线模量呈线性趋势增长。