微钻取样-TIMS/MC-ICPMS和LA-MC-ICPMS分析矿物岩石87Sr/86Sr比值的技术比较

微区Sr同位素体系相对于传统全岩Sr同位素研究,可以揭示样品自身存在的不均一性,更好地反映样品经历的地质过程,已被广泛应用于各种地质研究领域,如研究壳幔相互作用、岩浆起源和演化,岩浆体系开放性研究,沉积盆地物源示踪及气候环境研究。准确测定Rb-Sr同位素比值是应用该同位素体系的前提。微钻取样-热电离质谱/多接收电感耦合等离子体质谱(TIMS/MC-ICPMS)和激光剥蚀多接收电感耦合等离子体质谱(LA-MC-ICPMS)作为分析地质样品微区Sr同位素组成的有效手段,已经得到了较为广泛的应用。两种技术在样品制备、干扰校正和质谱测试等方面各具优势和不足。微钻取样-TIMS/MC-ICPMS的最大优势是可获得高精度的Sr同位素数据(外精度优于100×10-6,2SD);但由于需要进行化学处理,流程繁琐耗时(约10天),实验周期较长,同时需要严格控制化学流程空白,且取样直径(200~2000μm)和取样深度(100~2000μm)较大,空间分辨率较低,但是该方法可以对高Rb样品(如钾长石)进行有效分析。LA-MC-ICPMS的最大优势是样品制备简单,数小时即可完成,且分析效率高,根据样品Sr含量的大小激光束斑直径多在60~300μm之间变化,其空间分辨率较前一种方法高,可在短时间内对大量样品进行分析。但由于不能进行化学分离,分析过程中存在多种干扰(如Rb、Ca、Kr和REEs等),影响了测试的精度(约200×10-6,2SD)和准确度(约150×10-6)。该方法目前只能对高Sr低Rb的样品(如斜长石、磷灰石等)进行有效分析,而对于干扰元素含量较高的样品目前无法应用。本文认为,对于微钻取样法,应将改进化学流程作为重点研究方向,提高化学处理效率,同时改善微钻取样法的取样技术,减小取样直径和深度以提高空间分辨率;对于激光剥蚀法,重点突破Kr、Rb和二价REEs等干扰校正问题,提高干扰元素含量较高的样品的分析精度和准确度,同时需要提高仪器灵敏度以满足低Sr含量样品的分析要求。     

微波消解-电感耦合等离子体质谱法测定生物样品中微量硒的方法研究

生物样品中微量元素硒的分析检测,经典方法是湿法消解-氢化物发生原子荧光光谱法(HGAFS)。湿法消解处理生物样品需使用大量试剂,并且消解时间长,样品背景值高;HG-AFS的分辨率较低,已经不能满足微量硒的分析需求。解决生物样品的消解过程缓慢、试剂用量大的问题是提高样品中微量元素硒的检出限和分辨率的前提。本文采用湿法消解和微波消解两种消解体系处理样品,对两种方法制备的溶液分别采用HG-AFS和电感耦合等离子体质谱法(ICP-MS)进行测定,通过对比试验确定了微波消解ICP-MS方法可以实现生物样品中微量硒的准确测定。对比试验表明:采用高压密闭微波消解前处理样品技术可以大大缩短消解时间,减少试剂用量,降低了样品背景值;利用ICP-MS直接进行测定,方法检出限为0.01μg/g,精密度(RSD,n=12)小于4%,低于HG-AFS的检出限(0.03μg/g)和精密度(10%)。微波消解ICP-MS方法操作简单快捷,降低了方法检出限,提高了样品分析的准确度和精密度。     

Post-installation pore-pressure changes around spudcan and long-term spudcan behaviour in soft clay

This paper presents a dual-stage Eulerian–Lagrangian analysis for modelling the entire process of spudcan installation in soft clay, followed by consolidation and working load operation. The analysis consists of three components, namely undrained effective stress Eulerian analysis of spudcan installation, mesh-to-mesh variable mapping and coupled-flow Lagrangian analysis for the post-installation spudcan working behaviour. The results show good agreement with centrifuge model data but also highlight the importance of replicating the hysteretic behaviour of the soil. The findings also show that while a wished-in-place approach was able to model the long-term bearing response of the spudcan, rotational stiffness was over-estimated. This is due to the fact that, while the wished-in-place analysis was able to model the hardening of the soil ahead of the spudcan, it was unable to model the softening of back-flowed soil behind spudcan. The latter influences the spudcan fixity significantly, but not bearing response. Although the analyses were conducted using ABAQUS, they can, in principle, be conducted using other codes.     

A coupled hydro-mechanical analysis for prediction of hydraulic fracture propagation in saturated porous media using EFG mesh-less method

The details of the Element Free Galerkin (EFG) method are presented with the method being applied to a study on hydraulic fracturing initiation and propagation process in a saturated porous medium using coupled hydro-mechanical numerical modelling. In this EFG method, interpolation (approximation) is based on nodes without using elements and hence an arbitrary discrete fracture path can be modelled.The numerical approach is based upon solving two governing partial differential equations of equilibrium and continuity of pore water simultaneously. Displacement increment and pore water pressure increment are discretized using the same EFG shape functions. An incremental constrained Galerkin weak form is used to create the discrete system of equations and a fully implicit scheme is used for discretization in the time domain. Implementation of essential boundary conditions is based on the penalty method. In order to model discrete fractures, the so-called diffraction method is used.Examples are presented and the results are compared to some closed-form solutions and FEM approximations in order to demonstrate the validity of the developed model and its capabilities. The model is able to take the anisotropy and inhomogeneity of the material into account. The applicability of the model is examined by simulating hydraulic fracture initiation and propagation process from a borehole by injection of fluid. The maximum tensile strength criterion and Mohr–Coulomb shear criterion are used for modelling tensile and shear fracture, respectively. The model successfully simulates the leak-off of fluid from the fracture into the surrounding material. The results indicate the importance of pore fluid pressure in the initiation and propagation pattern of fracture in saturated soils.     

基于生态重要性评价与最小累积阻力模型的重庆市生态安全格局构建

生态安全格局构建是保障生态系统稳定运行,实现区域生态安全的重要途径。本文以重庆市为例,基于生态服务功能和生态敏感性对重庆市进行生态重要性评价,将生态极重要区域与自然保护地共同作为生态源地。首先从生态本底和生态胁迫两个角度选取高程、坡度、土地利用类型、距道路距离、距水体距离、夜间灯光指数6个阻力因子构建了典型山地动物的生态阻力面,然后利用最小累积阻力模型（MCR）模拟潜在生态廊道,完成市域生态安全格局的构建。研究表明,重庆市生态源地30 751.11 km²,占全市总面积的37.32%,主要分布在渝东北与渝东南的山林地。将识别的73条潜在生态廊道、138个生态节点与生态源地进行叠加,结合重庆的山水格局,构建了"两区、三带、四核、多廊、多点"的多层次生态安全格局,为重庆市生态保护和修复工作提供科学参考。     

银川市景观生态风险评价与生态安全格局优化构建

银川市生态保护与高质量发展已成为黄河流域可持续发展的重要组成部分,亟需优化区域生态安全格局。以银川市为研究区,综合生态风险评价模型和最小累积阻力模型,分析了银川市景观生态风险的时空分异特征,构建了生态安全格局并提出了生态安全保护策略。结果表明：（1） 银川市景观生态风险整体呈中北部高、南部低的空间分布特征,2000、2010年和2020年的景观生态风险指数平均值分别为0.2155、0.2145和0.2130,生态风险整体呈下降趋势,生态风险等级总体由高等级向低等级转移。（2） 共识别优化银川市生态廊道22条,生态节点52个,生态廊道累计长度约511.23 km,大致呈“北西—东南”方向网状分布,北部稀疏、南部密集。6条关键廊道贯穿南北,沿贺兰山国家级自然保护区—黄河—白芨滩国家级自然保护区一带分布,形成了“三纵”的空间格局分布特征。（3） 银川市优化后的生态安全格局由819.56 km²的生态源地、22条生态廊道和52个生态节点构成,并提出了针对生态源地、廊道和节点的生态安全保护策略,以期为银川市景观生态风险评价和生态安全水平的提升提供理论参考和依据。     

Study on Corrosion Resistance of Ni-W-P Coating in Hypersaline Brine

正Brine resource is rich in China,but its exploitation has been a problem.Hypersaline brine will corrode equipment and materials seriously during the brine exploitation and transportation.The corrosion problem can cause great     

贵州省黔西县龙场煤矿南回风立井地面预注浆工程得失探讨

龙场煤矿南回风井采用立井开拓方式,设计直径φ5.5m,掘深268m。根据井检施工报告,揭露断层破碎带一处,含水层3段,预计涌水量37m^3/h。按照立井施工规范,必须进行预注浆处理。为此,设计共分三个层序,每层序各3孔共9孔（其中最后层序3个孔为检验加强孔）。因业主不同意施工第三层序孔,预注浆处理后井筒涌水量将近10m^3/h,但仍未达到全井少于6m^3/h的目的,以致未达到设计目的,增加了施工难度,延缓了工期。本文就注浆施工从设计到施工进行剖析,指出施工中的得失,对类似工程有指导作用。     

长距离顶管工程中注浆减摩作用机理及效果分析

长距离顶管施工中除了克服迎面阻力外,尚需克服巨大的侧面摩擦阻力,故直接顶进非常困难。探讨了利用膨润土泥浆注浆以减小顶进阻力的技术。对注浆材料的结构、注浆工艺和减摩机理进行了较为系统的阐述,并结合工程实例对长距离顶管中顶进力的理论值与实际值做了比较。结果表明,注浆减摩效果十分明显。该技术值得在实际工程中推广应用。