Isotopic analysis of early solar system objects by an ion microprobe: Parametric studies and initial results

Magnesium, potassium and calcium isotope compositions in terrestrial samples and refractory phases from primitive meteorites are determined using an ion microprobe. A thorough investigation of the different instrument parameters is carried out to ensure that conditions necessary for high mass resolution and high precision isotopic studies are adequately satisfied. The instrument can be tuned to achieve mass resolution (M/ΔM) of up to 10,000 (M≤60); it has a very good dynamic stability (ΔB/B≤10 ppm over durations of ≤40 minutes) and the counting system has an effective dead-time of ≤25 nsec and a dynamic background of ≤0·01 c/s. Reproducibility and precision of isotopic measurements are checked by analyzing magnesium and titanium isotopic compositions in terrestrial standards and isotopically doped silicate glasses. A precision of 2‰ (2σ _m ) was achieved during magnesium isotopic analysis in samples with low Mg content (200 ppm). Results from studies of magnesium and potassium isotopic compositions in several Ca−Al-rich refractory inclusions (CAIs) from the primitive meteorites Efremovka and Grosnaja, representing some of the early solar system objects, are presented. The well-behaved Mg−Al isotopic systematics confirm the pristine nature of the Efremovka CAIs inferred earlier from petrographic and trace element studies. The Grosnaja CAIs that have experienced secondary alterations show disturbed magnesium isotopic systematics. Observation of excess²⁶Mg in several of the analyzed CAIs confirms the presence of the now extinct²⁶Al (t _1/2=7×10⁵ years) in the solar nebula at the time of CAI formation. Our data also suggest a relatively uniform distribution of²⁶Al in the solar nebula. Several Efremovka CAIs with excess²⁶Mg also have excess⁴¹K resulting from the decay of⁴¹Ca (t _1/2≃10⁵ years). This observation constrains the time interval between cessation of nucleosynthetic input to the solar nebula and the formation of some of the first solar system solids (CAIs) to less than a million years.     

Last glacial maximum climate inferences from cosmogenic dating and glacier modeling of the western Uinta ice field, Uinta Mountains, Utah

During the last glacial maximum (LGM), the western Uinta Mountains of northeastern Utah were occupied by the Western Uinta Ice Field. Cosmogenic ¹⁰Be surface-exposure ages from the terminal moraine in the North Fork Provo Valley and paired ²⁶Al and ¹⁰Be ages from striated bedrock at Bald Mountain Pass set limits on the timing of the local LGM. Moraine boulder ages suggest that ice reached its maximum extent by 17.4 ± 0.5 ka (± 2σ). ¹⁰Be and ²⁶Al measurements on striated bedrock from Bald Mountain Pass, situated near the former center of the ice field, yield a mean ²⁶Al/¹⁰Be ratio of 5.7 ± 0.8 and a mean exposure age of 14.0 ± 0.5 ka, which places a minimum-limiting age on when the ice field melted completely. We also applied a mass/energy-balance and ice-flow model to investigate the LGM climate of the western Uinta Mountains. Results suggest that temperatures were likely 5 to 7°C cooler than present and precipitation was 2 to 3.5 times greater than modern, and the western-most glaciers in the range generally received more precipitation when expanding to their maximum extent than glaciers farther east. This scenario is consistent with the hypothesis that precipitation in the western Uintas was enhanced by pluvial Lake Bonneville during the last glaciation.     

Short-lived nuclides in the early solar system

Isotopic records in meteorites provide evidence for the presence of several short-lived nuclides in the early solar system with half-lives varying from 10⁵ to ∼8x10⁷ years. Most of the nuclides with longer half-life (> 10⁷ years) are considered to be products of stellar nucleosynthesis taking place over long time scales in our galaxy. However, for the relatively shorter-lived nuclides, two possibilities exist; they could be products of energetic particle interactions taking place in a presolar or early solar environment, or, they could have been produced in a stellar source and injected into the protosolar molecular cloud just prior to its collapse. The presently available data appear to support the latter case and put a stringent constraint of less than a million years for the time scale for the collapse of the protosolar molecular cloud to form the Sun and some of the first solar system solids. This short time scale also suggests the possibility of a triggered origin for the solar system with the very process of injection of the short-lived nuclides acting as the trigger for the collapse of the protosolar molecular cloud. Fossil records of the short-lived nuclides in meteorites also provide very useful chronological information on the early solar system processes like the time scale for nebular processing, the time scales for differentiation and for metal/silicate fractionation within planetesimals. The currently available data suggest a time scale of a few million years for nebular processing and a relatively short time scale of about ten million years within which differentiation, melting and recrystallization in some of the planetesimals took place.     

宇生核素深度剖面暴露测年的原理与应用

宇生核素暴露测年技术是目前第四纪地貌年代测定最常用的方法之一,由于难以定量化继承性核素以及侵蚀对样品暴露年代的影响（通常假设继承性和侵蚀的影响为0）,其测年结果难以反映地貌的真实暴露年代。通过测定地貌剖面不同深度样品的宇生核素浓度,建立"宇生核素浓度-深度"剖面曲线,可同时定量化研究地貌体的暴露年龄、继承性宇生核素浓度以及侵蚀速率,有效地弥补了宇生核素暴露测年中继承性核素以及侵蚀速率不确定性的缺陷。基于蒙特卡洛方法的宇生核素深度剖面暴露测年模型（简称蒙特卡洛深度剖面模型）是最常用的计算模式之一,然而,国内关于该方法的原理及其应用研究相对较少,大大限制了该方法的广泛使用。本文详细阐述了蒙特卡洛深度剖面模型的原理及其在冰川地貌、河流阶地、冲洪积扇等地貌测年中的应用。此外,介绍了深度剖面模型的复现、非稳态模型、线性反演模型等其他几种计算模式并进一步探讨了蒙特卡洛深度剖面模型暴露测年技术的野外采样方法,以使其能够广泛应用于第四纪地貌学和年代学研究中。     

青藏高原东南部他念他翁山全新世早中期冰进事件研究

他念他翁山位于横断山脉西部,是海洋性冰川向亚大陆性冰川的过渡区,维持冰川发育的降水补给主要由西南季风带来,该区第四纪冰川进退对西南季风波动有较为直接的反映。正是这一地理位置的特殊性,使得该区第四纪冰川研究具有重要意义。采用野外地貌调查与宇宙成因核素测年技术相结合的方法,试图查明他念他翁山青古隆槽谷全新世期间冰川地貌学特征,并确定其发生的具体时间,探讨其响应机制。结果显示：他念他翁山全新世早中期冰川波动的时限介于（6.13±0.37）~（8.83±0.50） ka,可能是当时西南季风强盛,降水增加的结果。研究可为探究冰川作用与西南季风气候变化及全球气候变化之间的动力学联系提供新依据。     

10Be Exposure Ages Obtained From Quaternary Glacial Landforms on the Tibetan Plateau and in the Surrounding Area

In situ terrestrial cosmogenic nuclide (TCN) exposure dating using ¹⁰Be is one of the most successful techniques used to determine the ages of Quaternary deposits and yields data that enable the reconstruction of the Quaternary glacial history of the Tibetan Plateau and the surrounding mountain ranges. Statistical analysis of TCN ¹⁰Be exposure ages, helps to reconstruct the history of glacial fluctuations and past climate changes on the Tibetan Plateau, differences in the timing of glacier advances among different regions. However, different versions of the Cosmic‐Ray‐prOduced NUclide Systematics on Earth (CRONUS‐Earth) online calculator, which calculates and corrects the TCN ages of Quaternary glacial landforms, yield different results. For convenience in establishing contrasts among regions, in this paper, we recalculate 1848 ¹⁰Be exposure ages from the Tibetan Plateau that were published from 1999 to 2017 using version 2.3 of the CRONUS‐Earth calculator. We also compare the results obtained for 1594 ¹⁰Be exposure ages using different versions (2.2, 2.3 and 3.0) of the CRONUS‐Earth calculator. The results are as follows. (1) Approximately 97% of the exposure ages are less than 200 ka. A probability density curve of the exposure ages suggests that greater numbers of oscillations emerge during the Holocene, and the peaks correspond to the Little Ice Age, the 8.2 ka and 9.3 ka cold events; the main peak covers the period between 12 and 18 ka. (2) In most areas, the newer versions of the calculator produce older ¹⁰Be exposure ages. When different versions of the CRONUS‐Earth calculator are used, approximately 29% of the ¹⁰Be exposure ages display maximum differences greater than 10 ka, and the maximum age difference for a single sample is 181.1 ka.     

Cosmogenic nuclide budgeting of floodplain sediment transfer

Cosmogenic nuclides produced in quartz may either decay or accumulate while sediment is moved through a river basin. A change in nuclide concentration resulting from storage in a floodplain is potentially important in large drainage basins in which sediment is prone to repeated burial and remobilization as a river migrates through its floodplain. We have modeled depth- and time-dependent cosmogenic nuclide concentration changes for ¹⁰Be, ²⁶Al, and ¹⁴C during sediment storage and mixing in various active floodplain settings ranging from confined, shallow rivers with small floodplains to foreland-basin scale floodplains traversed by deep rivers. Floodplain storage time, estimated from channel migration rates, ranges from 0.4 kyr for the Beni River basin (Bolivia) to 7 kyr for the Amazon River basin, while floodplain storage depth, estimated from channel depth, ranges from 1 to 25 m.For all modeled active floodplain settings, the long-lived nuclides ¹⁰Be and ²⁶Al show neither significant increase in nuclide concentration from irradiation nor decrease from decay. We predict a hypothetical response time after which changes in ¹⁰Be or ²⁶Al concentrations become analytically resolvable. This interval ranges from 0.07 to 2 Myr and exceeds in all cases the typical residence time of sediment in a floodplain. Due to the much shorter half life of ¹⁴C, nuclide concentrations modeled for the in situ-produced variety of this nuclide are, however, sensitive to floodplain storage on residence times of < 20 kyr.The cosmogenic nuclide composition of old deposits in currently inactive floodplains that have been isolated for periods of millions of years from the river that once deposited them is predicted to either increase or decrease in ¹⁰Be and ²⁶Al concentration, depending on the depositional depth. These conditions can be evaluated using the ²⁶Al/¹⁰Be ratio that readily discloses the depth and duration of storage.We illustrate these models with examples from the Amazon basin. As predicted, modern bedload collected from an Amazon tributary, the Bolivian Beni River, shows no systematic change in nuclide concentration as sediment is moved through 500 km of floodplain by river meandering. In contrast, in the central Amazon floodplain currently untouched by the modern river system, low ²⁶Al/¹⁰Be ratios account for minimum burial depths of 5 to 10 m for a duration of > 5 Myr.The important result of this analysis is that in all likely cases of active floodplains, cosmogenic ¹⁰Be and ²⁶Al concentrations remain virtually unchanged over the interval sediment usually spends in the basin. Thus, spatially-averaged denudation rates of the sediment-producing area can be inferred throughout the entire basin, provided that nuclide production rates are scaled for the altitudes of the sediment-producing area only, because floodplain storage does not modify nuclide concentrations introduced from the sediment source area.     

Large rockslides in the Southern Central Andes of Chile (32–34.5°S): Tectonic control and significance for Quaternary landscape evolution

The distribution and age of large (> 0.1 km²) Pliocene to recent rockslides in the Chilean Cordillera Principal (32–34.5 S), the Southern Central Andes, has been analyzed to determine the rockslide triggering mechanisms and impact on regional landscape evolution. Most of the rockslides appear in the western Cordillera Principal and cluster along major geological structures. Variographic analyses show spatial correlation between rockslides, geological structures and shallow seismicity. A relative chronosequence was calibrated with existing ¹⁴C and ⁴⁰Ar/³⁹Ar dates and new cosmogenic nuclide exposure ages for selected rockslides. Rockslide-induced sediment yield was estimated with empirical relations for rockslide area distributions. Throughout the Quaternary, rockslides have delivered sediment to streams at rates equivalent to denudation rates of 0.10 ±0.06 mm a^− 1, while estimates using short term (20 a) seismicity records are 0.3_− 0.2^+ 0.6 mm a^− 1. The estimates of sediment transfer and the spatial distribution of rockslides reflect a landscape in which tectonic and geological controls on denudation are more significant than climate.     

Nickel isotope heterogeneity in the early Solar System

We report small but significant variations in the ⁵⁸Ni/⁶¹Ni-normalised ⁶⁰Ni/⁶¹Ni and ⁶²Ni/⁶¹Ni ratios (expressed as ε⁶⁰Ni and ε⁶²Ni) of bulk iron and chondritic meteorites. Carbonaceous chondrites have variable, positive ε⁶²Ni (0.05 to 0.25), whereas ordinary chondrites have negative ε⁶²Ni (− 0.04 to − 0.09). The Ni isotope compositions of iron meteorites overlap with those of chondrites, and define an array with negative slope in the ε⁶⁰Ni versus ε⁶²Ni diagram. The Ni isotope compositions of the volatile-depleted Group IVB irons are similar to those of the refractory CO, CV carbonaceous chondrites, whereas the other common magmatic iron groups have Ni isotope compositions similar to ordinary chondrites. Only enstatite chondrites have identical Ni isotope compositions to Earth and so appear to represent the most appropriate terrestrial building material. Differences in ε⁶²Ni reflect distinct nucleosynthetic components in precursor solids that have been variably mixed, but some of the ε⁶⁰Ni variability could reflect a radiogenic component from the decay of ⁶⁰Fe. Comparison of the ε⁶⁰Ni of iron and chondritic meteorites with the same ε⁶²Ni allows us to place upper limits on the ⁶⁰Fe/⁵⁶Fe of planetesimals during core segregation. We estimate that carbonaceous chondrites had initial ⁶⁰Fe/⁵⁶Fe < 1 × 10^− 7. Our data place less good constraints on initial ⁶⁰Fe/⁵⁶Fe ratios of ordinary chondrites but our results are not incompatible with values as high as 3 × 10^− 7 as determined by in-situ measurements. We suggest that the Ni isotope variations and apparently heterogeneous initial ⁶⁰Fe/⁵⁶Fe results from physical sorting within the protosolar nebula of different phases (silicate, metal and sulphide) that carry different isotopic signatures.     

P–PINI: A cosmogenic nuclide burial dating method for landscapes undergoing non-steady erosion

Existing methods of cosmogenic nuclide burial dating perform well provided that sediment sources undergo steady rates of erosion and the samples experience continuous exposure to cosmic rays. These premises exert important limitations on the applicability of the methods. And yet, high mountain sediment sources are rife with transient processes, such as non-steady erosion by glacial quarrying and/or landsliding, or temporary cosmic-ray shielding beneath glaciers and/or sediment. As well as breaching the premises of existing burial dating methods, such processes yield samples with low nuclide abundances and variable ²⁶Al/¹⁰Be ratios that may foil both isochron and simple burial-age solutions. P–PINI (Particle-Pathway Inversion of Nuclide Inventories) is a new dating tool designed for dating the burial of sediments sourced from landscapes characterized by abrupt, non-steady erosion, discontinuous exposure, and catchments with elevation-dependent ²⁶Al/¹⁰Be production ratios. P–PINI merges a Monte Carlo simulator with established cosmogenic nuclide production equations to simulate millions of samples (¹⁰Be–²⁶Al inventories). The simulated samples are compared statistically with ¹⁰Be–²⁶Al measured in field samples to define the most probable burial age. Here, we target three published ¹⁰Be–²⁶Al datasets to demonstrate the versatility of the P–PINI model for dating fluvial and glacial sediments. (1) The first case serves as a robust validation of P–PINI. For the Pulu fluvial gravels (China), we obtain a burial age of 1.27 ± 0.10 Ma (1σ), which accords with the isochron burial age and two independent chronometers reported in Zhao et al. (2016) Quaternary Geochronology 34, 75–80. The second and third cases, however, reveal marked divergence between P–PINI and isochron-derived ages. (2) For the fluvial Nenana Gravel (USA), we obtain a minimum-limiting burial age of 4.5 ± 0.7 Ma (1σ), which is compatible with unroofing of the Alaska Range starting ∼ 6 Ma, while calling into question the Early Pleistocene isochron burial age presented in Sortor et al. (2021) Geology 49, 1473–1477. (3) For the Bünten Till (Switzerland), we obtain a limiting burial age of <204 ka (95th percentile range), which conforms with the classical notion of the most extensive glaciation in the northern Alpine Foreland assigned to the Riss glaciation (sensu marine isotope stage 6) contrary to the isochron burial age presented in Dieleman et al. (2022) Geosciences, 12, 39. Discrepancies between P–PINI and the isochron ages are rooted in the challenges posed by the diverse pre-burial ²⁶Al/¹⁰Be ratios produced under conditions characteristic of high mountain landscapes; i.e., non-steady erosion, discontinuous cosmic-ray exposure, and elevation-dependent ²⁶Al/¹⁰Be production ratios in the source region, which are incompatible with the isochron method, but easily accommodated by the stochastic design of P–PINI.