High‐Precision Fe and Mg Isotope Ratios of Silicate Reference Glasses Determined In Situ by Femtosecond LA‐MC‐ICP‐MS and by Solution Nebulisation MC‐ICP‐MS

In this study, a technique for high precision in situ Fe and Mg isotope determinations by femtosecond‐laser ablation‐multi collector‐ICP‐MS (fs‐LA‐MC‐ICP‐MS) was developed. This technique was employed to determine reference values for a series of common reference glasses that may be used for external standardisation of in situ Fe and Mg isotope determinations in silicates. The analysed glasses are part of the MPI‐DING and United States Geological Survey (USGS) reference glass series, consisting of basaltic (BIR‐1G, BCR‐2G, BHVO‐2G, KL2‐G, ML3B‐G) and komatiitic (GOR128‐G and GOR132‐G) compositions. Their Fe and Mg isotope compositions were determined by in situ fs‐LA‐MC‐ICP‐MS and by conventional solution nebulisation multi‐collector ICP‐MS. We determined δ⁵⁶Fe values for these glasses ranging between ‐0.04‰ and 0.10‰ (relative to IRMM‐014) and δ²⁶Mg values ranging between ‐0.40‰ and ‐0.15‰ (relative to DSM‐3). Our fs‐LA‐MC‐ICP‐MS results for both Fe and Mg isotope compositions agreed with solution nebulisation analyses within analytical uncertainties. Furthermore, the results of three USGS reference glasses (BIR‐1G, BHVO‐2G and BCR‐2G) agreed with previous results for powdered and dissolved aliquots of the same reference materials. Measurement reproducibilities of the in situ determinations of δ⁵⁶Fe and δ²⁶Mg values were usually better than 0.12‰ and 0.13‰ (2s), respectively. We further demonstrate that our technique is a suitable tool to resolve isotopic zoning in chemically‐zoned olivine crystals. It may be used for a variety of different applications on isotopically‐zoned minerals, e.g., in magmatic or metamorphic rocks or meteorites, to unravel their formation or cooling rates.     

Effets de la vitesse d'écoulement sur le transport et la cinétique de dépôt de particules en suspension en milieu poreux saturé

We study in this paper the transport and deposition of suspended particles in saturated porous media. Some chromatographic short-pulse tests were performed in a laboratory column with a tracer and two types of suspended particles. A mathematical model was used to determine the hydrodispersive parameters and deposition rates from the breakthrough curves. The results show that the fitted parameters obtained vary with the flow rate and the characteristics of the suspended particles. We also observe, at high flow rates, that particles have a migration velocity higher than that of the conservative tracer. To cite this article: A. Benamar et al., C. R. Geoscience 337 (2005).     

The Calcium Isotope Composition (δ44/40Ca) of NIST SRM 915b and NIST SRM 1486

The calcium isotopic composition of NIST SRM 915b and 1486 provided by the National Institute of Standards and Technology was analysed. The δ^44/40Ca values of the two reference materials relative to NIST SRM 915a were: NIST SRM 915b =+0.72 ± 0.04‰ and NIST SRM 1486 =?1.01 ± 0.02‰. NIST SRM 1486 did not require any chemical separation prior to measurement.     

Ubinas: the evolution of the historically most active volcano in southern Peru

Ubinas volcano has had 23 degassing and ashfall episodes since A.D. 1550, making it the historically most active volcano in southern Peru. Based on fieldwork, on interpretation of aerial photographs and satellite images, and on radiometric ages, the eruptive history of Ubinas is divided into two major periods. Ubinas I (Middle Pleistocene >376 ka) is characterized by lava flow activity that formed the lower part of the edifice. This edifice collapsed and resulted in a debris-avalanche deposit distributed as far as 12 km downstream the Rio Ubinas. Non-welded ignimbrites were erupted subsequently and ponded to a thickness of 150 m as far as 7 km south of the summit. These eruptions probably left a small collapse caldera on the summit of Ubinas I. A 100-m-thick sequence of ash-and-pumice flow deposits followed, filling paleo-valleys 6 km from the summit. Ubinas II, 376 ky to present comprises several stages. The summit cone was built by andesite and dacite flows between 376 and 142 ky. A series of domes grew on the southern flank and the largest one was dated at 250 ky; block-and-ash flow deposits from these domes filled the upper Rio Ubinas valley 10 km to the south. The summit caldera was formed between 25 and 9.7 ky. Ash-flow deposits and two Plinian deposits reflect explosive eruptions of more differentiated magmas. A debris-avalanche deposit (about 1.2 km³) formed hummocks at the base of the 1,000-m-high, fractured and unstable south flank before 3.6 ka. Countless explosive events took place inside the summit caldera during the last 9.7 ky. The last Plinian eruption, dated A.D.1000–1160, produced an andesitic pumice-fall deposit, which achieved a thickness of 25 cm 40 km SE of the summit. Minor eruptions since then show phreatomagmatic characteristics and a wide range in composition (mafic to rhyolitic): the events reported since A.D. 1550 include many degassing episodes, four moderate (VEI 2–3) eruptions, and one VEI 3 eruption in A.D. 1667. Ubinas erupted high-K, calc-alkaline magmas (SiO₂=56 to 71%). Magmatic processes include fractional crystallization and mixing of deeply derived mafic andesites in a shallow magma chamber. Parent magmas have been relatively homogeneous through time but reflect variable conditions of deep-crustal assimilation, as shown in the large variations in Sr/Y and LREE/HREE. Depleted HREE and Y values in some lavas, mostly late mafic rocks, suggest contamination of magmas near the base of the >60-km-thick continental crust. The most recently erupted products (mostly scoria) show a wide range in composition and a trend towards more mafic magmas.Recent eruptions indicate that Ubinas poses a severe threat to at least 5,000 people living in the valley of the Rio Ubinas, and within a 15-km radius of the summit. The threat includes thick tephra falls, phreatomagmatic ejecta, failure of the unstable south flank with subsequent debris avalanches, rain-triggered lahars, and pyroclastic flows. Should Plinian eruptions of the size of the Holocene events recur at Ubinas, tephra fall would affect about one million people living in the Arequipa area 60 km west of the summit.Editorial responsibility: D Dingwell     

L'évolution séculaire des températures de surface de la mer Méditerranée (1856–2000)

The mean sea surface temperature anomalies (SSTA) of the Mediterranean Sea during the past 150 years (1856–2000) are analysed. The first empirical orthogonal function (EOF) of the covariance matrix of the SSTA explains more than 45% of the variance, suggesting that the temporal variation of the Mediterranean Sea is largely in phase over the whole basin. The mean variability of Mediterranean SSTA from 1856 to 2000 superposes a main irregular oscillation (period of 60–70 years and mean amplitude of 0.4–0.5 °C) and a weak long-term positive trend (equivalent to an increase of +0.1 °C per century). The last warm phase, which is strongest in the western basin, is not warmer than the decade 1935–1945 or the ending part of the 1960s. The mean temporal evolution of the North Hemisphere is close to the variation of the Mediterranean Sea, except that the long-term increase is more intense in the North Hemisphere. To cite this article: V. Moron, C. R. Geoscience 335 (2003).     

Lawsonite growth in the epidote blueschists from the Ile de Groix (Armorican Massif, France): a potential geobarometer

Abstract The garnet blueschists from the Ile de Groix (Armorican Massif, France) contain millimetre‐ to centimetre‐sized pseudomorphs consisting of an aggregate of chlorite, epidote and paragonite. The pseudomorphed phase developed at a late stage of the deformation history, because it overgrows a glaucophane–epidote–titanite foliation. Garnet growth occurred earlier than the beginning of the ductile deformation, and thus garnet is also included in the pseudomorphs. Microprobe analyses show that garnet is strongly zoned, with decreasing spessartine and increasing almandine and pyrope contents from core to rim. Grossular content is higher in garnet cores (about 35 mole%) compared to garnet rims (about 30 mole%). Blue amphibole has glaucophane compositions with a low Fe³⁺ content and become more magnesian when inclusions in garnet (X_Mg = 0.62–0.65) are compared with matrix grains (X_Mg = 0.67–0.70). Matrix epidote has a pistacite content of about 50 mole%. On the basis of their shape and the nature of the breakdown products, the pseudomorphs are attributed to lawsonite. A numerical model (using Thermocalc ) has been developed in order to understand the reactions controlling both the growth and the breakdown of lawsonite. Lawsonite growth could have taken place through the continuous hydration reaction Chl + Ep + Pg + Qtz + Vap = Gln + Lws, followed by the fluid‐absent reaction Chl + Ep + Pg = Grt + Gln + Lws. Peak P–T conditions are estimated at about 18–20 kbar, 450 °C. This indicates that lawsonite growth took place at increasing P and T, hence can be used as a geobarometer in the buffering assemblage garnet–glaucophane–epidote. The final part of the history is recorded by lawsonite breakdown, after cessation of the ductile deformation, and recording the earliest stages of the exhumation.     

Exercice de scénarisation hydrologique en Afrique de l’Ouest—Bassin du Bani

Résumé

Les pays sub-sahariens basent principalement leur économie sur l’agriculture pluviale. Les projections démographiques à moyen ou long terme montrent que la pression démographique va s’accroître très fortement. A l’avenir, il faudra soutenir encore plus fortement le développement de stratégies agricoles de ces pays : cela nécessite une meilleure connaissance de leurs ressources en eau futures. Cette connaissance de la ressource en eau dans le futur passe par l’élaboration de scenarios climatiques et hydrologiques qui font intervenir différents acteurs, compétents dans des activités très variées, qu’ils soient scientifiques de divers domaines (climatologues, hydrologues, sociologues, …) mais aussi financiers, politiques, acteurs sociaux et décideurs. Ce processus d’élaboration de scenarios s’accompagne de nombreuses incertitudes, plus ou moins bien maitrisées, avec lesquelles doivent s’accommoder les gestionnaires d’ouvrages et planificateurs d’aménagements régionaux. Illustré par l’exemple du bassin du Bani, affluent du fleuve Niger, ce travail propose une réflexion sur la « scénarisation hydrologique » et la prédétermination des paramètres d’un modèle hydrologique dans un contexte global non stationnaire. Le choix de jeux de paramètres a de nombreux impacts sur les résultats de la scénarisation comme l’estimation de la ressource et la variabilité de cette ressource. Ces deux éléments sont fondamentaux pour qui doit conduire un processus de décision en réponse à une demande de stratégie d’aménagement ou à une demande de stratégie de développement. Nous proposons une méthodologie de détermination des jeux de paramètres se basant sur la construction de plusieurs jeux de paramètres issus de calages glissants, qui permet d’aller dans le sens de ce que de plus en plus de gestionnaires préconisent : ne pas essayer de prévoir le futur mais plutôt des futurs envisageables qui forceront des modèles d’impact, ce qui leur permettra de fournir des éléments de décision afin de s’adapter ou d’adapter des solutions d’aménagement aux conditions de ces futurs.

Editeur Z.W. Kundzewicz; Editeur associé C. Perrin

Citation Paturel, J.-E., 2014. Exercice de scénarisation hydrologique en Afrique de l’Ouest—Bassin du Bani. Hydrological Sciences Journal, 59 (6), 1135–1153. http://dx.doi.org/10.1080/02626667.2013.834340     

2007年城市极端天气事件及其危害分析

通过对2007年国内一些主要城市发生的极端天气事件分析,以及与城市建设历史发展过程中的比较,表明城市气象灾害对城市安全运行的威胁日趋严重.由于极端降水天气事件的日益增多以及城市本身扩大发展、人口密度不断增加、城市的热岛效应更加明显等原因,客观上存在易产生剧烈的天气现象和城市承灾能力越来越脆弱等问题.在深入分析致灾因素、致灾结果中,提出需要解决的城市建设规划、应急管理体制等科学问题,同时给出了城市防灾减灾的决策建议.     

High‐Precision Mass‐Dependent Molybdenum Isotope Variations in Magmatic Rocks Determined by Double‐Spike MC‐ICP‐MS

Small mass‐dependent variations of molybdenum isotope ratios in oceanic and island arc rocks are expected as a result of recycling altered oceanic crust and sediments into the mantle at convergent plate margins over geological timescales. However, the determination of molybdenum isotope data precise and accurate enough to identify these subtle isotopic differences remains challenging. Large sample sizes – in excess of 200 mg – need to be chemically processed to isolate enough molybdenum in order to allow sufficiently high‐precision isotope analyses using double‐spike MC‐ICP‐MS techniques. Established methods are either unable to process such large amounts of silicate material or require several distinct chemical processing steps, making the analyses very time‐consuming. Here, we present a new and efficient single‐pass chromatographic exchange technique for the chemical isolation of molybdenum from silicate and metal matrices. To test our new method, we analysed USGS reference materials BHVO‐2 and BIR‐1. Our new data are consistent with those derived from more involved and time‐consuming methods for these two reference materials previously published. We also provide the first molybdenum isotope data for USGS reference materials AGV‐2, the GSJ reference material JB‐2 as well as metal NIST SRM 361.     

Grain size distribution of soils within the Cordillera Blanca,Peru: An indicator of basic mechanical properties for slope stability evaluation

This paper presents results of a study on the mechanical properties of sandy and gravely soils within the Cordillera Blanca, Peru. The soils were divided into groups according to their origin （glacial, fluvial, or debris flow）. The grain size distribution of forty three soil samples was used to classify the soils according to the scheme of the Unified Soil Classification System （USCS）. These distributions have then been used to estimate shear strength and hydraulic properties of the soils. There are clear differences between the soils which reflect their divergent origins. The glacial soils normally fit within one of two distinctive groups according to the proportion of fines （Group A, 7%-21.5%; Group B, 21%-65%）. The estimation of shear strength at constant volume friction angle and peak shear strength of the glacial sediments with low content of fines was made using published data relating to the measured shear strength characteristics of soils with similar origins and grain size distributions. The estimated values were supported by measurements of the angle of repose taken from fourteen samples from two moraines and by shear tests on samples from one locality. The results of the grain size distribution werealso used to estimate the average hydraulic conductivity using the empirical Hazen formula which results were verified by field infiltration tests at two localities.