Juan de Fuca洋脊Endeavour段热液硫化物稀土元素地球化学特征

用 ICP-MS对取自 Juan de Fuca洋脊 Endeavour段 5块热液硫化物样品的 13个分析样进行了稀土元素(REE)测试.结果显示该区硫化物样品的 REE含量较低(0.35～ 14.8 μ g/g),所有样品的 REE球粒陨石标准化分布模式均表现出 Eu正异常和 LREE富集的特征,表明硫化物中的 REE来自热液.不同喷口硫化物的 REE含量变化较大,同一块状硫化物不同部位的含量也有较大差异,主要是由于硫化物形成过程中,热液和海水的混合不均一性以及不同矿物沉淀和 (或 )溶解的结果.硫化物 REE的分布特征主要受热液的影响,烟囱内外层 Eu正异常的变化主要受矿物组成和物理化学条件的控制.     

20 years of mass balances on the Piloto glacier, Las Cuevas river basin, Mendoza, Argentina

Climatic changes of the 20th century have altered the water cycle in the Andean basins of central Argentina. The most visible change is seen in the mountain glaciers, with loss of part of their mass due to decreasing thickness and a substantial recession in the last 100 years. This paper briefly describes the results of glacier mass balance research since 1979 in the Piloto Glacier at the Cajón del Rubio, in the headwaters of Las Cuevas River, presenting new results for the period 1997–2003. Very large interannual variability of net annual specific balance is evident, due largely to variations in winter snow accumulation, with a maximum net annual value of + 151 cm w.e. and a minimum value of - 230 cm w.e. Wet El Niño years are normally associated with positive net annual balances, while dry La Niña years generally result in negative balances. Within the 24-year period, 67% of the years show negative net annual specific balances, with a cumulative mass balance loss of - 10.50 m water equivalent (w.e.). Except for exceptions normally related to El Niño events, a general decreasing trend of winter snow accumulation is evident in the record, particularly after 1992, which has a strong effect in the overall negative mass balance values. The glacier contribution to Las Cuevas River runoff is analysed based on the Punta de Vacas River gauge station for a hypothetical year without snow precipitation (YWSP), when the snowmelt component is zero. Extremely dry years similar to a YWSP have occurred in 1968–1969, 1969–1970 and 1996–1997. The Punta de Vacas gauge station is located 62 km downstream from Piloto Glacier, and the basin contains 3.0% of uncovered glacier ice and 3.7% of debris-covered ice. The total glacier contribution to Las Cuevas River discharge is calculated as 82 ± 8% during extremely dry years. If glacier wastage continues at the present trend as observed during the last 2 decades, it will severely affect the water resources in the arid central Andes of Argentina.     

Landslides in the Tandayapa Valley, northern Andes, Ecuador: implications for landform development in humid and tectonically active mountain ranges

Landslides are common throughout the Ecuadorian Andes, but their causal and controlling factors and their roles in landform development have not yet been systematically investigated. This paper reports observations and hypotheses arising from a reconnaissance study of the Tandayapa Valley in the Cordillera Occidental, approximately 30 km west of Quito. This study area is characterised by high local relief (ca. 800 m) associated with dissected mountainous terrain, high annual rainfall (>2,000 mm), and secondary-succession wet montane ‘cloud forest’. Regolith cover is extremely thin on the very steep (45 to >60°) upper main valley slopes, but there are thick accumulations of tephra on the slope crests and ridgetops. These deposits show periods of soil development separated by deposition events. Natural landslides in this environment comprise rare large deep-seated bedrock failures and occasional shallow failures on the steep upper slopes where potentially unstable thicknesses of tephra have accumulated. Landslides associated with construction of roads and forest trails are more common. Back-analysis of one road-cut landslide, using field and laboratory data to characterise the in situ weathered material where possible, indicated that natural shallow failures are unlikely in the absence of a surficial cover of tephra. By analogy with another mountainous tropical landscape, it is suggested that long-term landform development can be explained in terms of channel incision, driven by uplift, producing steep lower valley slopes that eventually exceed bedrock failure thresholds. Therefore, large deep-seated landslides appear to control valley slope form development, whilst the shallow landslides contribute to general denudation.     

An epigenetic origin for the Passagem de Mariana gold deposit, Quadrilátero Ferrífero, Minas Gerais, Brazil

The gold–tourmaline quartz–vein deposit of Passagem de Mariana, in the southeastern part of the Quadrilátero Ferrífero, produced more than 60 tonne of gold, from the end of the 17th Century until 1954. The mine has not operated since 1985. Orebodies are veins composed of white quartz (> 60 vol.%), carbonate (ankerite), tourmaline, sericite and sulfides. Tourmaline (dravite), up to 10 vol.% of the vein, occurs as subhedral, coarse, commonly zoned crystals, and is concentrated along vein boundaries and on the edges of host rock inclusions in the veins. Tourmaline is present in all rock types in the mine, but the chemical composition of the host rocks determinates the intensity of tourmalinization, with the alteration being greater in sericitic phyllites, graphite–sericite phyllites, and calcareous rocks. The most abundant sulfide is arsenopyrite, which is normally associated with pyrite and pyrrhotite. Minor amounts of chalcopyrite, galena, löllingite, berthierite, and maldonite are present throughout the deposit. Sulfides are concentrated at veins boundary or are dispersed in the veins. Arsenopyrite is associated, most commonly, with calcareous rocks, and graphite–sericite phyllite. Pyrrhotite is usually found at the base of itabirites. Gold abundance is directly proportional to sulfide concentration. Hydrothermal alteration associated with the veins includes silicification, tourmalinization, and sulfidation. The mineralized zone is a shear zone associated with a bedding-parallel thrust fault that juxtaposes the itabirite (Lower Proterozoic Minas Supergroup) over other units. This shear zone/thrust fault extends for tens of km beyond the Passagem mine and hosts numerous gold deposits. The richest orebodies are along the itabirite footwall contact and within the graphite–sericite phyllite (Main orebody). Although many lithologic units were mineralized the graphite–sericite phyllite appears to have been most favorable for gold deposition.The area underwent three phases of deformation, D₁, D₂ and D₃. Mineral assemblages indicate upper-greenschist to lower-amphibolite conditions of regional metamorphism. Retrograde metamorphism, characterized by chloritization of biotite and chloritization and biotitization of garnet, developed locally. The gold-bearing veins crosscut the main foliation and lithologic contacts at low angle and occur within, or are in contact with, all lithotypes. Field and laboratory data indicate that gold mineralization at Passagem de Mariana is epigenetic. Gold deposition occurred after the peak of metamorphism, within the late- to post-D₂ period of deformation, which is correlated with second set of structures of Trasamazonian age of Alkmim and Marshak [Alkmim, F.F., Marshak, S., 1998. Transamazonian Orogeny in the Southern São Francisco Craton Region, Minas Gerais, Brazil: evidence for Paleoproterozoic collision and collapse in the Quadrilátero Ferrífero. Precambrian Research 90, 29-58.], indicating that the gold mineralization occurred between 2.124 and 2.04 Ga. We choose to regard Passagem de Marina as an orogenic gold deposit as defined by Groves et al. [Groves, D. I., Goldfarb, R.J., Gebre-Mariam, M., Hagemann, S.G., Robert, F., 1998. Orogenic gold deposits: A proposed classification in the context of their crustal distribution and relationship to other gold deposit types. Ore Geology Reviews 13, 7-27.], i.e., an epigenetic, structurally-hosted lode–gold vein system in a deformed metamorphic terrane.     

A cross section of the eastern Betic Cordillera (SE Spain) according field data and a seismic reflection profile

The BT3 multichannel seismic profile was acquired by the C.G.G. (Compagnie General de Géophysique) in 1977 for hydrocarbon exploration in the eastern Betic Cordillera. REXIMseis Ltd scanned and vectorized a paper copy and then performed post-stack processing, including coherence filtering and deconvolution. The receiver functions of a broad-band seismic station located near the village of Vélez Rubio, at the SE end of the profile, were analysed by Julia et al. [Julia, J., Mancilla, F., Morales, J., 2005. Seismic signature of intracrustal magmatic intrusions in the Eastern Betics (Internal Zone), SE Iberia, Geophysical Research Letters 32, L16304, doi:10.1029/2005GL023274.] to determine the structure of the underlying crust. We have used these Vp data to convert the profile to depth. The profile has a mean SE–NW trend, with a SE-Section 44 km in length followed by a NW-Section 20 km in length. The record includes the first 4 s (twtt), which corresponds to 11 km.Two main areas can be seen in the profile. At the SE-end, a band of high-amplitude discontinuous reflectors dips towards the north. The band is 100 to 200 ms thick, increasing even more northwards. This band reaches the surface at the top of the Maláguide Complex (the upper complex of the Internal Zones). Above these reflectors, an area with chaotic seismic facies and no reflectors corresponds to the outcrops of the olistostromes and turbidites of the Solana Formation, and it is in turn overlain by discontinuous reflectors of the Subbetic rocks.At the NW-end of the profile, a set of high-amplitude continuous reflectors with SE dips point to the location of the Prebetic. Below this section, oblique reflectors of intermediate amplitude indicate the Variscan basement. Over the Prebetic, we have marked the basal thrusts of the Intermediate Units and the Subbetic. Using this seismic data, as well as field observations, we propose a geological cross-section of the upper crust of the eastern Betic Cordillera and a model of the most recent evolution of the orogen. In this model, the Internal Zones and the Subbetic have been welded together from the Middle Burdigalian to the present day and acted as an orogenic wedge that deformed the Intermediate Units and the Prebetic.     

Magma evolution of Quaternary minor volcanic centres in southern Peru,Central Andes

Minor centres in the Central Volcanic Zone (CVZ) of the Andes occur in different places and are essential indicators of magmatic processes leading to formation of composite volcano. The Andahua–Orcopampa and Huambo monogenetic fields are located in a unique tectonic setting, in and along the margins of a deep valley. This valley, oblique to the NW–SE-trend of the CVZ, is located between two composite volcanoes (Nevado Coropuna to the east and Nevado Sabancaya to the west). Structural analysis of these volcanic fields, based on SPOT satellite images, indicates four main groups of faults. These faults may have controlled magma ascent and the distribution of most centres in this deep valley shaped by en-echelon faulting. Morphometric criteria and ¹⁴C age dating attest to four main periods of activity: Late Pleistocene, Early to Middle Holocene, Late Holocene and Historic. The two most interesting features of the cones are the wide compositional range of their lavas (52.1 to 68.1 wt.% SiO₂) and the unusual occurrence of mafic lavas (olivine-rich basaltic andesites and basaltic andesites). Occurrence of such minor volcanic centres and mafic magmas in the CVZ may provide clues about the magma source in southern Peru. Such information is otherwise difficult to obtain because lavas produced by composite volcanoes are affected by shallow processes that strongly mask source signatures. Major, trace, and rare earth elements, as well as Sr-, Nd-, Pb- and O-isotope data obtained on high-K calc-alkaline lavas of the Andahua–Orcopampa and Huambo volcanic province characterise their source and their evolution. These lavas display a range comparable to those of the CVZ composite volcanoes for radiogenic and stable isotopes (⁸⁷Sr/⁸⁶Sr: 0.70591–0.70694, ¹⁴³Nd/¹⁴⁴Nd: 0.512317–0.512509, ²⁰⁶Pb/²⁰⁴Pb: 18.30–18.63, ²⁰⁷Pb/²⁰⁴Pb: 15.57–15.60, ²⁰⁸Pb/²⁰⁴Pb: 38.49–38.64, and δ ¹⁸O: 7.1–10.0‰ SMOW), attesting to involvement of a crustal component. Sediment is absent from the Peru–Chile trench, and hence cannot be the source of such enrichment. Partial melts of the lowermost part of the thick Andean continental crust with a granulitic garnet-bearing residue added to mantle-derived arc magmas in a high-pressure MASH [melting, assimilation, storage and homogenisation] zone may play a major role in magma genesis. This may also explain the chemical characteristics of the Andahua–Orcopampa and Huambo magmas. Fractional crystallisation processes are the main governors of magma evolution for the Andahua–Orcopampa and Huambo volcanic province. An open-system evolution is, however, required to explain some O-isotopes and some major and trace elements values. Modelling of AFC processes suggests the Charcani gneisses and the local Andahua–Orcopampa and Huambo basement may be plausible contaminants.     

Erosional processes, topographic length-scales and geomorphic evolution in arid climatic environments: the ‘Lluta collapse’, northern Chile

The Lluta collapse of northern Chile is one of the oldest recognizable landslides (>2.5 Ma) in a hyperarid continental setting. This paper develops a conceptual landscape evolution model of the Lluta collapse and analyzes the controls of mass wasting and erosion/sediment transport in channels on the topographic development. The data presented here imply that high relief along a topographic scarp, surface fracturing, elevated groundwater table during a more humid climate and an aquitard underlying permeable ignimbrites are preparatory causal factors for landsliding >2.5 Ma ago. A strong seismic event then possibly resulted in the displacement of ca. 26 km³ of mass. Subsequent modification of the landslide scar occurred by backward erosion, resulting in the establishment of a dendritic drainage network and the removal of an additional ca. 24 km³ of material. It appears that this mass was produced by mass wasting in the headwaters, and exported by high-concentrated debris flows in channels. In addition, morphometric information suggest that whereas the geometrical development of the Lluta collapse has been controlled by gravitational mass wasting, the rates of the development of this geomorphic unit have been limited by the export rates of mass and hence by the transport capacity of the flows.     

Influence of glacial retreat on natural hazards of the Palcacocha Lake area, Peru

In this article we describe natural hazards associated with outburst floods of Palcacocha Lake and landslide events on the slopes of its moraine dam, in Cojup Valley, Cordillera Blanca (Peru). These events occurred in the last 70 years and some of them resulted in disasters, which strongly affected the city of Huarás. Field investigations and reference expression hydrodynamic tests as well as archive satellite images and aerial pictures were used to describe the evolution of hazards connected with Palcacocha Lake. Expression hydrodynamic tests proved a high permeability of sandy gravels glacial sediments, which form the present-day lake dam. Seepage through the natural dam forming small ponds below the overflow spillways occurs. A retreat of the glacial tongue causing an increase of the lake volume and unloading of the slope toe areas are the most important recent processes that influence the potential hazards affecting the Cojup valley. The research has proved that the climate warming and ongoing deglaciation play a very significant role in the change of natural hazards conditions in high mountains.     

Contribution of stable isotopes to the understanding of the unsaturated zone of a carbonate aquifer (Nerja Cave, southern Spain)

We analysed the stable isotopes (¹⁸O and ²H) of rainwater and drip water within a cave (Nerja Cave) located in the unsaturated zone of a carbonate aquifer. Rainfall is more abundant and presents lower isotopic content in winter, while the volume of drip water is greater and its isotopic content is lower in summer. The flow analysis of ¹⁸O through the unsaturated zone confirms the seasonal lag between rainfall and the appearance of drip water in the cave and reveals that the unsaturated zone of the aquifer, in the sector of the cave, behaves like an inertial system with a strong capability to modulate the input signal. To cite this article: F. Carrasco et al., C. R. Geoscience 338 (2006).     

Further details on the applicability of Thellier paleointensity method: The effect of magnitude of laboratory field

Twenty years after Tanaka and Kono's pioneering contribution (Tanaka and Kono, 1984), we give some new details on the effect of applied field strength during Thellier paleointensity experiments. Special attention is paid to the relation of magnitude of laboratory field and Coe's quality factors (Coe et al., 1978). Full thermoremanent magnetizations were imparted on natural samples containing low-Ti titanomagnetites of pseudo-single domain structure in a 40-μT magnetic field from 600?°C to room temperature. The samples were subjected to the routine Thellier procedure using a wide range of applied laboratory fields. Results indicate that values of laboratory fields may be accurately reproduced within 2% of standard error. The quality factors, however, decrease when the magnitude of ‘ancient’ field does not match to applied laboratory fields. To cite this article: J. Morales et al., C. R. Geoscience 338 (2006).