Sodic Pyroxene and Sodic Amphibole as Potential Reference Materials for In Situ Lithium Isotope Determinations by SIMS

Two large pegmatitic crystals of sodic pyroxene (aegirine) and sodic amphibole (arfvedsonite) from the agpaitic igneous Ilímaussaq Complex, south Greenland were found to be suitable as reference materials for in situ Li isotope determinations. Lithium concentrations determined by SIMS and micro‐drilled material analysed by MC‐ICP‐MS generally agreed within analytical uncertainty. The arfvedsonite crystal was homogeneous with [Li] = 639 ± 51 μg g^?1 (2s, n = 69, MC‐ICP‐MS and SIMS results). The aegirine crystal shows strongly developed sector zoning, which is a common feature of aegirines. Using qualitative element mapping techniques (EPMA), the homogeneous core of the crystal was easily distinguished from the outermost sectors of the crystals. The core had a mean [Li] of 47.6 ± 3.6 μg g^?1 (2s, n = 33) as determined by SIMS. The seven micro‐drilled regions measured by solution MC‐ICP‐MS returned slightly lower concentrations (41–46 μg g^?1), but still overlap with the SIMS data within uncertainty. Based on MC‐ICP‐MS and SIMS analyses, the variation in δ⁷Li was about 1‰ in each of the two crystals, which is smaller than that in widely used glass reference materials, making these two samples suitable to serve as reference materials. There was, however, a significant offset between the results of MC‐ICP‐MS and SIMS. The latter deviated from the MC‐ICP‐MS results by ?6.0 ± 1.9‰ (2s) for the amphibole and by ?3.9 ± 1.9‰ (2s) for the aegirine. This indicates the presence of a significant matrix effect in SIMS determinations of Li isotopes for amphibole and pyroxene relative to the basalt glasses used for calibration. Based on the MC‐ICP‐MS results, mean δ⁷Li values of +0.7 ± 1.2‰ (2s, n = 10) for the arfvedsonite crystal and of ?3.7 ± 1.2‰ (2s, n = 7) for the core of the aegirine crystal were calculated. Adopting these values, SIMS users can correct for the specific IMF (instrumental mass fractionation) of the ion probe used. We propose that these two crystals serve as reference materials for in situ Li isotope determinations by SIMS and pieces of these two crystals are available from the first author upon request.     

Generalized de Sitter solution in multi-dimensional cosmology with static internal spaces

A multi-dimensional cosmological model with space-time consisting of n(n ≥ 2) Einstein spaces M_i is investigated in the presence of a cosmological constant λ and a homogeneous minimally coupled free scalar field. A generalized de Sitter solution was found for λ > 0 and a Ricci-flat external space for the case of static internal spaces with fine tuning of parameters.     

Does hillslope trenching enhance groundwater recharge and baseflow in the Peruvian Andes?

As Andean glaciers rapidly retreat due to climate change, the balance of groundwater and glacial meltwater contributions to stream discharge in tropical, proglacial watersheds will change, potentially increasing vulnerability of water resources. The Shullcas River Watershed, near Huancayo, Peru, is fed only partly by the rapidly receding Huaytapallana glaciers (<20% of dry season flow). To potentially increase recharge and therefore increase groundwater derived baseflow, the government and not‐for‐profit organizations have installed trenches along large swaths of hillslope in the Shullcas Watershed. Our study focuses on a nonglacierized subcatchment of the Shullcas River Watershed and has 2 objectives: (a) create a model of the Shullcas groundwater system and assess the controls on stream discharge and (b) investigate the impact of the infiltration trenches on recharge and baseflow. We first collected hydrologic data from the field including a year‐long hydrograph (2015–2016), meteorological data (2011–2016), and infiltration measurements. We use a recharge model to evaluate the impact of trenched hillslopes on infiltration and runoff processes. Finally, we use a 3‐dimensional groundwater model, calibrated to the measured dry season baseflow, to determine the impact of trenching on the catchment. Simulations show that trenched hillslopes receive approximately 3.5% more recharge, relative to precipitation, compared with unaltered hillslopes. The groundwater model indicates that because the groundwater flow system is fast and shallow, incorporating trenched hillslopes (~2% of study subcatchment area) only slightly increases baseflow in the dry season. Furthermore, the location of trenching is an important consideration: Trenching higher in the catchment (further from the river) and in flatter terrain provides more baseflow during the dry season. The results of this study may have important implications for Andean landscape management and water resources.     

Etude de l’évaporation de la nappe phréatique des zones arides: cas de Ouargla (Algérie)

La majorité des surfaces mises en valeur dans les zones arides et semi-arides de l’Algérie reposent sur des nappes phréatiques très minéralisées dont le niveau est proche de la surface du sol (0–1,5 m). En présence de conditions climatiques très sévères, le processus d’évaporation de ces nappes contribue en grande partie à la salinisation des terres et la dégradation du milieu. Les résultats de l’étude de l’évaporation de la nappe phréatique de la région de Ouargla montre que l’évaporation diminue au fur et à mesure que le niveau de la nappe s’éloigne de la surface du sol. L’évaporation de la nappe est maximale et égale à l’évaporation du plan d’eau lorsque le niveau de cette nappe est situé dans la couche 0–0,6 m et devient minimale au dessous de 1,7 m. Pour une meilleure mise en valeur des terres et une production agricole élevée, il est nécessaire de connaître la profondeur critique de la nappe phréatique, profondeur pour laquelle l’évaporation est faible et par conséquent le dépôt de sels est faible dans les sols à texture sableuse de la région aride de Ouargla.     

Variabilité et tendances observées sur les débits moyens mensuels,saisonniers et annuels dans le bassin de la Falémé (Sénégal)

Le changement climatique, lié au réchauffement de la Terre, agit directement sur notre milieu naturel en le transformant et s’accompagne de modifications dans le cycle hydrologique. Il s’en suit une baisse drastique des ressources en eau disponibles du fait de la forte diminution des totaux pluviométriques reçus. Dans cette étude, nous utilisons le test de Mann-Kendall pour caractériser la variabilité et les tendances des débits dans le bassin de la Falémé sur la période 1954–2014. Les résultats de l’analyse révèlent une tendance à la baisse statistiquement significative sur pratiquement tous les mois et sur les périodes de hautes et de basses eaux. Une tendance a été observée aussi sur les années de faible hydraulicité durant lesquelles l’écoulement des périodes de hautes et basses eaux est moins important. Le test de Mann-Kendall s’est donc avéré efficace pour indiquer les tendances négatives de l’écoulement dans le bassin de la Falémé.     

Modélisation glacio-hydrologique et gestion des ressources en eau dans les Andes équatoriennes : l’exemple de Quito

La forte croissance socio-économique de Quito a conduit à d’importants projets de transferts interbassins, intensifiant la mobilisation des ressources d’altitude situées dans des zones écologiques sensibles et connaissant une fonte accélérée des glaciers. Afin d’étudier divers scénarios d’évolutions, nous proposons une modélisation du continuum climat/glacier/hydrologie/gestion des ressources en eau. Utilisant l’outil Water Evaluation and Planning (WEAP), nous avons développé : (1) une modélisation hydro-climatologique semi-distribuée avec des données mensuelles homogénéisées par vectorisation régionale ; (2) une modélisation de la production en eau des glaciers et de leur évolution interannuelle ; (3) une modélisation en unités hydrologiques distinguant différentes couvertures de sols ; et (4) une modélisation de la gestion distinguant droits, allocation et usages de l’eau. Nous présentons les résultats du calage hydrologique mensuel (1963–2006), en étudiant particulièrement l’équifinalité de diverses paramétrisations. Nous montrons la souplesse, la robustesse et les limites de la modélisation proposée, contribuant à cerner différentes incertitudes dans l’évaluation de scénarios prospectifs.     

Modélisation de propagation d’écoulement entre lits mineur et majeur sur les fleuves Sénégal et Niger

In the Senegal River valley and Niger Inner Delta, the annual floods inundate a wide floodplain consisting of a complex network of lakes and channels, where topographic information needed by standard hydraulic models is difficult to obtain. To represent the flood propagation between mainstream and floodplain, we use a model designed for flood propagation in river mainstreams with flat bed and large overflow and without topographic data. Depending on the water level in the riverbed, the model calibrated on the levels observed at two stations gives the level in the floodplains and propagation time between stations. Several cases are tested for various types of hydraulic connections between mainstream and floodplain. The model could correctly reproduce the flood rise and fall in the floodplain, even for a lake connected by a single channel to the riverbed or in the case of a strong attenuation of the flood between very distant stations.     

A regional water balance indicator inferred from satellite images of an Andean endorheic basin in central-western Argentina

In the Central Andes of Argentina (30–37°S), snowmelt is the main source of freshwater, an essential natural resource for ~2.2 million people in the adjacent arid lowlands. In this region, Laguna Llancanelo collects the water inputs from the Malargüe endorheic basin. Previous studies concerning the annual and intra-annual variations of this lagoon and its relationship with regional climate are rare. We obtained a monthly record for the Laguna Llancanelo area (LLA, 1984–2013) using the modified normalized difference water index derived from Landsat images. Monthly LLA ranges between 35 km² and 411 km² and is significantly related to variations of the Río Malargüe, the main snow-fed tributary to the lagoon. There is no long-term relationship between LLA and local rainfall, but rapid increases in LLA result from heavy rainfall around the lagoon. Conversely, rapid reductions in LLA encompass periods with both reduced discharge from the Río Malargüe and low local rainfall. The LLA integrates moisture of both Pacific (snowfall in the upper Andes) and Atlantic (lowland rainfall) origins; therefore, we propose using LLA as an indicator of regional water balance.     

Distribution of whitemouth croaker (Micropogonias furnieri, Desmarest 1823) larvae in the Río de la Plata estuarine front

Whitemouth croaker (Micropogonias furnieri) larvae obtained and hydrographic data collected in the Rio de la Plata estuary (35°S–56°W) between 1987 and 2000 were used to explore the early life stages spatial and temporal distribution patterns and their relation to oceanographic features. The spatial distribution, restricted to a band in the inner part of the estuary, coincided with the bottom salinity front and the maximum turbidity zone (MTZ, turbidity front). Larvae were present during the warmest months (October through May) within a range of 14–24.5 °C temperature and 0.9–33 salinity. A vertically stratified sampling performed in the region where the largest abundance was found (December 2005 and March 2006) was used to test the hypothesis that larvae retention occurs in the bottom salinity front.The vertically stratified sampling showed larvae throughout the water column with high predominance in the river–estuary transition zone. A positive correlation between abundance and the bottom salinity horizontal gradient was found. The size analysis showed that the largest individuals (>10 mm SL), probably undergoing the settlement process, inhabited near the bottom and that the smallest (<10 mm SL) were present in the whole water column. Length distribution along the front showed no trend.Results support the estuarine retention hypothesis of previous studies on whitemouth croaker gravid females, eggs distribution and outcomes from a numerical simulation model. Retention in the salinity front/MTZ would allow larvae to benefit from food accumulation in the region, the high turbidity level provide shelter against predators and retention in the estuary secure closeness to the main nursery ground.