Provenance of middle to late Palaeozoic sediments in the northeastern Colombian Andes: implications for Pangea reconstruction

ABSTRACT

Global-scale Palaeozoic plate tectonic reconstructions have suggested that Laurentia was obliquely approaching against the northwestern margin of Gondwana until the final agglutination of Pangea. In this contribution integrated petrographic analysis, heavy mineral analysis, and tourmaline geochemistry were done, and U–Pb detrital zircon geochronology was obtained, in late Palaeozoic sedimentary and meta-sedimentary units from the Floresta and Santander Massifs in the Eastern Colombian Andes in order to constrain their provenance and related it with the magmatic, sedimentary, and deformational record of the Gondwana–Laurentia convergence until the late Carboniferous to Permian formation of Pangea. Late Devonian to early Carboniferous sandstones from the Floresta Massif changed from sublithoarenites to lithoarenites, tracking the progressive uplift and unroofing of sedimentary and metamorphic rocks, with associated volcanic activity. The U–Pb detrital zircon geochronology from the sedimentary and metasedimentary of Floresta and Santander documents Mesoproterozoic and Palaeoproterozoic sources, and younger Ordovician to Silurian age populations, that can be related to the early to middle Palaeozoic plutonic rocks and the Amazon Craton. The limited Silurian to Early Devonian detrital ages that contrast with the more significant Middle to Late Devonian zircons that document the erosion of contemporaneous magmatic sources formed after a late Silurian to Early Devonian reduction on the magmatic activity along the proto-Andean margin. These rocks were apparently deformed and metamorphosed between the late Carboniferous and the early Permian. It is suggested that the filling and deformation record of these rocks documented the changes in plate convergence obliquity at the western margin of Gondwana associated with the migration of Laurentia until its final position in Pangea. Between the late Carboniferous and the early Permian, peri-Gondwanan continental terranes also collided with the continental margin. Over-imposed Mesozoic tectonics have contributed to the final redistribution of these terranes to their current position.

Abbreviations:LA: laser ablation inductively couple mass spectrometer; CL: cathodoluminiscence     

Boron and Oxygen Isotope Composition of Certified Reference Materials NIST SRM 610/612 and Reference Materials JB-2 and JR-2

We present data on the concentration, the isotope composition and the homogeneity of boron in NIST silicate glass reference materials SRM 610 and SRM 612, and in powders and glasses of geological reference materials JB-2 (basalt) and JR-2 (rhyolite). Our data are intended to serve as references for both microanalytical and wet-chemical techniques. The δ¹¹ B compositions determined by N-TIMS and P-TIMS agree within 0.5% and compare with SIMS data within 2.5%. SIMS profiles demonstrate boron isotope homogeneity to better than δ¹¹ B = 2% for both NIST glasses, however a slight boron depletion was detected towards the outermost 200 μm of the rim of each sample wafer. The boron isotope compositions of SRM 610 and SRM 612 were indistinguishable. Glasses produced in this study by fusing JB-2 and JR-2 powder also showed good boron isotope homogeneity, both within and between different glass fragments. Their major element abundance as well as boron isotope compositions and concentrations were identical to those of the starting composition. Hence, reference materials (glasses) for the in situ measurement of boron isotopes can be produced from already well-studied volcanic samples without significant isotope fractionation. Oxygen isotope ratios, both within and between wafers, of NIST reference glasses SRM 610 and SRM 612 are uniform. In contrast to boron, significant differences in oxygen isotope compositions were found between the two glasses, which may be due to the different amounts of trace element oxides added at ten-fold different concentration levels to the silicate matrix.     

Yields of suspended sediment and dissolved solids from the Andean basins of Ecuador

Abstract

Water discharge and suspended and dissolved sediment data from three rivers (Napo, Pastaza and Santiago) in the Ecuadorian Amazon basin and a river in the Pacific basin (Esmeraldas) over a 9-year period, are presented. This data set allows us to present: (a) the chemical weathering rates; (b) the erosion rates, calculated from the suspended sediment from the Andean basin; (c) the spatio-temporal variability of the two regions; and (d) the relationship between this variability and the precipitation, topography, lithology and seismic activity of the area. The dissolved solids load from the Esmeraldas basin was 2 × 10⁶ t year^-1, whereas for the Napo, Pastaza and Santiago basins, it was 4, 2 and 3 × 10⁶ t year^-1, respectively. For stations in the Andean piedmont of Ecuador, the relationship between surface sediment and the total sediment concentration was found to be close to one. This is due to minimal stratification of the suspended sediment in the vertical profile, which is attributed to turbulence and high vertical water speeds. However, during the dry season, when the water speed decreases, sediment stratification appears, but this effect can be neglected in the sediment flux calculations due to low concentration rates. The suspended sediment load in the Pacific basin was 6 × 10⁶ t year^-1, and the total for the three Amazon basins was 47 × 10⁶ t year^-1. The difference between these contributions of the suspended sediment load is likely due to the tectonic uplift and the seismic and volcanic dynamics that occur on the Amazon side.

Editor Z.W. Kundzewicz

Citation Armijos, E., Laraque, A., Barba, S., Bourrel, L., Ceron, C., Lagane, C., Magat, P., Moquet, J.-S., Pombosa, R., Sondag, F., Vauchel, P., Vera, A., and Guyot, J.L., 2013. Yields of suspended sediment and dissolved solids from the Andean basins of Ecuador. Hydrological Sciences Journal, 58 (7), 1478–1494.     

20 years of mass balances on the Piloto glacier, Las Cuevas river basin, Mendoza, Argentina

Climatic changes of the 20th century have altered the water cycle in the Andean basins of central Argentina. The most visible change is seen in the mountain glaciers, with loss of part of their mass due to decreasing thickness and a substantial recession in the last 100 years. This paper briefly describes the results of glacier mass balance research since 1979 in the Piloto Glacier at the Cajón del Rubio, in the headwaters of Las Cuevas River, presenting new results for the period 1997–2003. Very large interannual variability of net annual specific balance is evident, due largely to variations in winter snow accumulation, with a maximum net annual value of + 151 cm w.e. and a minimum value of - 230 cm w.e. Wet El Niño years are normally associated with positive net annual balances, while dry La Niña years generally result in negative balances. Within the 24-year period, 67% of the years show negative net annual specific balances, with a cumulative mass balance loss of - 10.50 m water equivalent (w.e.). Except for exceptions normally related to El Niño events, a general decreasing trend of winter snow accumulation is evident in the record, particularly after 1992, which has a strong effect in the overall negative mass balance values. The glacier contribution to Las Cuevas River runoff is analysed based on the Punta de Vacas River gauge station for a hypothetical year without snow precipitation (YWSP), when the snowmelt component is zero. Extremely dry years similar to a YWSP have occurred in 1968–1969, 1969–1970 and 1996–1997. The Punta de Vacas gauge station is located 62 km downstream from Piloto Glacier, and the basin contains 3.0% of uncovered glacier ice and 3.7% of debris-covered ice. The total glacier contribution to Las Cuevas River discharge is calculated as 82 ± 8% during extremely dry years. If glacier wastage continues at the present trend as observed during the last 2 decades, it will severely affect the water resources in the arid central Andes of Argentina.     

基于小波变换的脉冲星弱信号的去噪方法研究

利用小波变换去除噪声的基本原理和方法及消色散方法对毫秒脉冲星极弱信号进行了提取,并对噪声进行了最佳阈值选取实验研究,实现了脉冲星弱信号消色散积累后的检测和抑噪.并研究了软硬阈值估计子等不同阈值消噪技术,进而对PSR 0437-4715信号采用不同方法去噪后的结果进行了分析比较,认为在最大分解层数J=5时对脉冲星信号处理有普适意义.研究结果认为基于小波变换的消噪方法是一种提高信噪比、展示噪声和突变信号的优越方法.     

Origine de la salinité et des principaux éléments majeurs des eaux de la nappe phréatique de la plaine de Ghriss,Nord-Ouest algérien

Résumé

L'origine de la salinité dans les eaux de la nappe Plio-Quaternaire de la plaine de Ghriss (Nord-Ouest de l'Algérie) et la compréhension de ses comportements hydrodynamiques et géochimiques, en réponse à certains forçages naturels et anthropiques, ont été approchées par l’étude combinée des rapports ioniques et d'analyses statistiques des données hydrochimiques. Cette étude a identifié l'alimentation latérale de l'aquifère Plio-Quaternaire par les deux principaux aquifères de la région. La salinisation des eaux de la nappe Plio-Quaternaire résulte essentiellement de la dissolution des évaporites (halite et gypse), de l'infiltration des eaux de ruissellement, et du retour à la nappe des eaux d'irrigation qui sont chargées en sels initialement reconcentrés dans le sol ou dans la zone non saturée. Les concentrations élevées en nitrates et en chlorures sont l'indice d'une pollution anthropique d'origine urbaine ou agricole qui affecte toute la plaine de Ghriss en proportions variables.

Citation Bekkoussa, B., Jourde, H., Batiot-Guilhe, C., Meddi, M., Khaldi, A., et Azzaz, H., 2013. Origine de la salinité et des principaux éléments majeurs des eaux de la nappe phréatique de la plaine de Ghriss, Nord-Ouest Algérien. Hydrological Sciences Journal, 58 (5), 1111–1127.

Editeur Z.W. Kundzewicz; Editeur associé S. Faye     

Determination of Fluorine and Chlorine by Pyrohydrolysis and Ion Chromatography: Comparison with Alkaline Fusion Digestion and Ion Chromatography

A method to determine F and Cl in silicate materials by employing pyrohydrolysis and ion chromatography (IC) is described. Pyrohydrolysis involved mixing a pulverised sample (∼ 40 mg) with V₂O₅ (∼ 160 mg) and heating to 1100 °C under a wet oxygen flow in a quartz tube. Recovery yields of F and Cl were ∼ 97% using a NaF + NaCl standard solution. Detection limits of the pyrohydrolysis-IC method for silicate samples were 0.36 and 0.69 μg g^-1 for F and Cl, respectively. Fluorine and Cl concentrations were determined in the reference materials JB-2, JB-3 and JA-1 from the GSJ; BCR-2, BHVO-1, BHVO-2, AGV-1 and AGV-2 from the USGS; and NIST SRM 610, 612 and 614 glasses. Precisions (RSD) for determinations of F were 1–13% (except NIST SRM 614) and 2–19% for Cl, and were dependent on the concentration and blank correction. Most results obtained in this study were in good agreement with those of previous studies. In comparison, the Na₂CO₃ + ZnO fusion method at 900 °C showed that the yields of F and Cl by alkaline fusion systematically decreased with fusion duration time. The yields were 84% and 83% for JB-3, inferring that F and Cl were lost in this alkaline fusion.     

Temporal Evolution of Magmatism in the Northern Volcanic Zone of the Andes: The Geology and Petrology of Cayambe Volcanic Complex (Ecuador)

In the Northern Volcanic Zone of the Andes, the Cayambe VolcanicComplex consists of: (1) a basal, mostly effusive volcano, theViejo Cayambe, whose lavas (andesites and subordinate dacitesand rhyolites) are typically calc-alkaline; and (2) a younger,essentially dacitic, composite edifice, the Nevado Cayambe,characterized by lavas with adakitic signatures and explosiveeruptive styles. The construction of Viejo Cayambe began >1·1Myr ago and ended at 1·0 Ma. The young and still activeNevado Cayambe grew after a period of quiescence of about 0·6Myr, from 0·4 Ma to Holocene. Its complex history isdivided into at least three large construction phases (Angurealcone, Main Summit cone and Secondary Summit cone) and compriseslarge pyroclastic events, debris avalanches, as well as periodsof dome activity. Geochemical data indicate that fractionalcrystallization and crustal assimilation processes have a limitedrole in the genesis of each suite. On the contrary, field observations,and mineralogical and geochemical data show the increasing importanceof magma mixing during the evolution of the volcanic complex.The adakitic signature of Nevado Cayambe magmas is related topartial melting of a basaltic source, which could be the lowercrust or the subducted slab. However, reliable geophysical andgeochemical evidence indicates that the source of adakitic componentis the subducted slab. Thus, the Viejo Cayambe magmas are inferredto come from a mantle wedge source metasomatized by slab-derivedmelts (adakites), whereas the Nevado Cayambe magmas indicatea greater involvement of adakitic melts in their petrogenesis.This temporal evolution can be related to the presence of thesubducted Carnegie Ridge, modifying the geothermal gradientalong the Wadati–Benioff zone and favouring slab partialmelting. KEY WORDS: adakites; ⁴⁰Ar/³⁹Ar dating; Cayambe volcano; Ecuador; mantle metasomatism; Andes     

Determination of Reference Values for NIST SRM 610–617 Glasses Following ISO Guidelines

We present new reference values for the NIST SRM 610–617 glasses following ISO guidelines and the International Association of Geoanalysts’ protocol. Uncertainties at the 95% confidence level (CL) have been determined for bulk‐ and micro‐analytical purposes. In contrast to former compilation procedures, this approach delivers data that consider present‐day requirements of data quality. New analytical data and the nearly complete data set of the GeoReM database were used for this study. Data quality was checked by the application of the Horwitz function and by a careful investigation of analytical procedures. We have determined quantitatively possible element inhomogeneities using different test portion masses of 1, 0.1 and 0.02 μg. Although avoiding the rim region of the glass wafers, we found moderate inhomogeneities of several chalcophile/siderophile elements and gross inhomogeneities of Ni, Se, Pd and Pt at small test portion masses. The extent of inhomogeneity was included in the determination of uncertainties. While the new reference values agree with the NIST certified values with the one exception of Mn in SRM 610, they typically differ by as much as 10% from the Pearce et al. (1997) values in current use. In a few cases (P, S, Cl, Ta, Re) the discrepancies are even higher.     

Determination of Carbon,Hydrogen, Nitrogen and Sulfur in Geological Materials Using Elemental Analysers

This article describes a series of methods developed for the determination of total carbon (C_Total), organic carbon (C_org), hydrogen, nitrogen and sulfur. The following elemental analysers were used: LECO model RC‐412 for the determination of organic carbon, total carbon and hydrogen; LECO model CS‐200 for the determination of total carbon and sulfur; LECO model TN‐400 for the determination of nitrogen; and LECO model TruSpec CHNS for the determination of organic carbon, total carbon, hydrogen, nitrogen and sulfur. Uncertainty and limits of detection and quantification were calculated for each method, as well as the running costs to define the most effective instrument for each material and each analyte. Accuracy was checked by the application of the Sutarno–Steger test. Finally, a compilation of the results obtained in the determination of C_Total, C_org, H, N and S in forty‐nine reference materials is presented.