Crustal growth during back‐arc closure: Cretaceous exhumation history of Cordillera Darwin,southern Patagonia

The Cordillera Darwin metamorphic complex is unique in the Andes in exposing kyanite–staurolite schist north of the Beagle Channel in southern Patagonia. Garnet in amphibolite facies pelitic schists from Bahía Pia has patchy textures whereby some grains consist of clear, grossular‐rich garnet with fine‐grained S1 inclusion trails truncated by regions of turbid spessartine–pyrope‐rich garnet with biotite, muscovite, plagioclase and quartz inclusions. Micron‐scale aqueous inclusions in turbid garnet are consistent with recrystallization facilitated by fluid ingress; S2 inclusion trails indicate this was broadly contemporary with the growth of kyanite and staurolite in the matrix. Pseudosection modelling in Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–Fe₂O₃ (NCKFMASHTO) is used to infer a P–T path dominated by decompression from 12 to 9 kbar at T ≈ 620 °C, coupled with garnet mode decreasing from ～5% to <1%. U–Th–Pb in situ dating of S2 monazite indicates that staurolite and kyanite growth and thus exhumation was underway before 72.6 ± 1.1 Ma. Contact aureoles developed adjacent to late granite intrusions include sillimanite‐bearing migmatites formed at P ≈ 6 kbar after 72 Ma. Metamorphism of southern Cordillera Darwin induced by continental underthrusting beneath the arc, related to closure of the Rocas Verdes back‐arc basin, was terminated by thrusting‐controlled exhumation, with the rocks at P ≈ 9 kbar by c. 73 Ma and 6 kbar by c. 70 Ma.     

Space–time rainfall variability in the Paute basin,Ecuadorian Andes

Despite the importance of mountain ranges as water providers, knowledge of their climate variability is still limited, mostly due to a combination of data scarcity and heterogeneous orography. The tropical Andes share many of the main features of mountain ranges in general, and are subject to several climatic influences that have an effect on rainfall variability. Although studies have addressed the large-scale variation, the basin scale has received little attention. Thus, the purpose of this study was to obtain a better understanding of rainfall variability in the tropical Andes at the basin scal, utilizing the Paute River basin of southern Ecuador as a case study. Analysis of 23 rainfall stations revealed a high spatial variability in terms of: (i) large variations of mean annual precipitation in the range 660–3400 mm; (ii) the presence of a non-monotonic relation between annual precipitation and elevation; and (iii) the existence of four, sometimes contrasting, rainfall regimes. Data from seven stations for the period 1964–1998 was used to study seasonality and trends in annual, seasonal and monthly precipitation. Seasonality is less pronounced at higher elevations, confirming that in the páramo region, the main water source for Andean basins, rainfall is well distributed year round. Additionally, during the period of record, no station has experienced extreme concentrations of annual rainfall during the wet season, which supports the concept of mountains as reliable water providers. Although no regional or basin-wide trends are found for annual precipitation, positive (negative) trends during the wet (dry) season found at four stations raises the likelihood of both water shortages and the risk of precipitation-triggered disasters. The study demonstrates how variable the precipitation patterns of the Andean mountain range are, and illustrates the need for improved monitoring. Copyright © 2007 John Wiley & Sons, Ltd.     

Evaluating digital elevation models for glaciologic applications: An example from Nevado Coropuna, Peruvian Andes

This paper evaluates the suitability of readily available elevation data derived from recent sensors – the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) and the Shuttle Radar Topography Mission (SRTM) – for glaciological applications. The study area is Nevado Coropuna (6426 m), situated in Cordillera Ampato of Southern Peru. The glaciated area was 82.6 km² in 1962, based on aerial photography. We estimate the glacier area to be ca. 60.8 km² in 2000, based on analysis of the ASTER L1B scene.We used two 1:50,000 topographic maps constructed from 1955 aerial photography to create a digital elevation model with 30 m resolution, which we used as a reference dataset. Of the various interpolation techniques examined, the TOPOGRID algorithm was found to be superior to other techniques, and yielded a DEM with a vertical accuracy of ± 14.7 m. The 1955 DEM was compared to the SRTM DEM (2000) and ASTER DEM (2001) on a cell-by-cell basis. Steps included: validating the DEM's against field GPS survey points on rock areas; visualization techniques such as shaded relief and contour maps; quantifying errors (bias) in each DEM; correlating vertical differences between various DEM's with topographic characteristics (elevation, slope and aspect) and subtracting DEM elevations on a cell-by-cell basis.The RMS error of the SRTM DEM with respect to GPS points on non-glaciated areas was 23 m. The ASTER DEM had a RMS error of 61 m with respect to GPS points and displayed 200–300 m horizontal offsets and elevation ‘spikes’ on the glaciated area when compared to the DEM from topographic data.Cell-by-cell comparison of SRTM and ASTER-derived elevations with topographic data showed ablation at the toes of the glaciers (− 25 m to − 75 m surface lowering) and an apparent thickening at the summits. The mean altitude difference on glaciated area (SRTM minus topographic DEM) was − 5 m, pointing towards a lowering of the glacier surface during the period 1955–2000. Spurious values on the glacier surface in the ASTER DEM affected the analysis and thus prevented us from quantifying the glacier changes based on the ASTER data.     

Unravelling evapotranspiration controls and components in tropical Andean tussock grasslands

The study of the environmental factors that control evapotranspiration and the components of evapotranspiration leads to a better understanding of the actual evapotranspiration (ET) process that links the functioning of the soil, water and atmosphere. It also improves local, regional and global ET modelling. Globally, few studies so far focussed on the controls and components of ET in alpine grasslands, especially in mountainous sites such as the tussock grasslands located in the páramo biome (above 3300 m a.s.l.). The páramo occupies 35 000 km² and provides water resources for many cities in the Andes. In this article, we unveiled the controls on ET and provided the first insights on the contribution of transpiration to ET. We found that the wet páramo is an energy-limited region and net radiation (Rn) is primarily controlling ET. ET was on average 1.7 mm/day. The monthly average evaporative fraction (ET/Rn) was 0.47 and it remained similar for wet and dry periods. The secondary controls on ET were wind speed, aerodynamic resistance and surface resistance that appeared more important for dry periods, where significantly higher ET rates were found (20% increase). During dry events, transpiration was on average 1.5 mm/day (range 0.7–2.7 mm/day), similar to other tussock grasslands in New Zealand (range 0.6–3.3 mm/day). Evidence showed interception contributes more to ET than transpiration. This study sets a precedent towards a better understanding of the evapotranspiration process and will ultimately lead to a better land-atmosphere fluxes modelling in the tropics.     

Quantifying groundwater–surface water interactions in a proglacial valley,Cordillera Blanca,Peru

A myriad of downstream communities and industries rely on streams fed by both groundwater discharge and glacier meltwater draining the Cordillera Blanca, Northern Peruvian Andes, which contains the highest density of glaciers in the tropics. During the dry season, approximately half the discharge in the region's proglacial streams comes from groundwater. However, because of the remote and difficult access to the region, there are few field methods that are effective at the reach scale to identify the spatial distribution of groundwater discharge. An energy balance model, Rhodamine WT dye tracing, and high‐definition kite‐borne imagery were used to determine gross and net groundwater inputs to a 4‐km reach of the Quilcay River in Huascaran National Park, Peru. The HFLUX computer programme ( http://hydrology.syr.edu/hflux.html ) was used to simulate the Quilcay River's energy balance using stream temperature observations, meteorological measurements, and kite‐borne areal photography. Inference from the model indicates 29% of stream discharge at the reach outlet was contributed by groundwater discharge over the study section. Rhodamine WT dye tracing results, coupled with the energy balance, show that approximately 49% of stream water is exchanged (no net gain) with the subsurface as gross gains and losses. The results suggest that gross gains from groundwater are largest in a moraine subreach but because of large gross losses, net gains are larger in the meadow subreaches. These insights into pathways of groundwater–surface water interaction can be applied to improve hydrological modelling in proglacial catchments throughout South America. Copyright © 2016 John Wiley & Sons, Ltd.     

Rhyacian-Orosirian tectonic history of the Juiz de Fora Complex: Evidence for an Archean crustal reservoir within an island-arc system

The southern São Francisco Paleocontinent (SFP) comprises Archean nuclei and Paleoproterozoic complexes encompassing magmatic arcs juxtaposed during a Rhyacian to Orosirian orogenic event. The Juiz de Fora Complex (JFC) represents an imbricated thrust system that comprises orthogranulites with a wide compositional range formed in an intra-oceanic setting during the Siderian to the Orosirian and later accreted to the southeastern margin of the SFP. Here we report new petrological, geochemical, whole-rock Nd and Sr data, as well as zircon U–Pb ages from felsic and mafic orthogranulites from the JFC. The new data is combined with a regional compilation that enables an evaluation of the interaction between magmatism and orogenetic episodes in the context of the consolidation of São Francisco Paleocontinent during the Rhyacian–Orosirian. Pre collisional Island Arc tholeiites (IAT), Tonalites-Trondhjemites-Granodiorites (TTGs) and sanukitoid magmatism occurred from 2200 Ma to 2085 Ma. This was followed by post-collisional magmatism, which is represented by hybrid granitoids coeval with the emplacement of E-MORB basic rocks. Crustal signatures for the Rhyacian to Orosirian evolution are highlighted by the dominance of negative ε_Nd(t) associated with Meso- to Neoarchean Nd T_DM model ages as well as inherited zircon grains from the hybrid granitoids. The JFC is extensively highlighted in the literature as a primitive intra-oceanic arc, but here we propose the reworking or recycling of ancient crustal segments within the mature arc stage of the JFC, suggesting a Mesoarchean crustal source involved in the JFC evolution.     

West versus East Mediterranean Sea: origin and genetic differentiation of the sea cucumber Holothuria polii

We studied the genetic structure of the sea cucumber Holothuria (Roweothuria) polii (Delle Chiaje 1823) by analysing the mitochondrial DNA variation in two fragments of cytochrome oxidase I (COI) and 16S genes. Individuals were collected in seven locations along the Mediterranean Sea, which cover a wide range of the species distribution. We found high haplotype diversity for COI and moderate diversity for 16S, and low nucleotide diversity for both genes. Our results for the COI gene showed many recent and exclusive haplotypes with few mutational changes, suggesting recent or ongoing population expansion. The Western and Eastern Mediterranean populations exhibited slight but significant genetic differentiation (COI gene) with higher genetic diversity in the East. The most ancient haplotype was not present in the westernmost sampling location (SE Spain). The oldest expansion time was observed in Turkey, corresponding to mid‐Pleistocene. Turkey had also the highest genetic diversity (number of total and exclusive haplotypes, polymorphisms, haplotype and nucleotide diversity). This suggests that this region could be the origin of the subsequent colonizations through the Mediterranean Sea, a hypothesis that should be assessed with nuclear markers in future research.     

Gas-charged sediments in the Ría de Arousa: Short- to long-term fluctuations?

Repeated surveys at control sites in the gas accumulation fields from the Ría de Arousa (Galicia, NW Spain) have shown that the top of the acoustic turbidity fluctuates vertically. The vertical movement of gas fronts is more apparent in the gas fields located in the outer ría, where fluctuations of up to 1.5 ms (1.1 m) have been detected. At the inner ría, the depth to the top of the gas horizons varied between 0.5 and 1 ms (40 to 80 cm). Short-term (diurnal) fluctuations associated with the hydrostatic pressure variations of the water column during a tidal cycle have been identified as the most likely factors to explain fluctuations of gas fields in the outer ría. At the inner ría, gas fields are affected by these short-term pressure changes superimposed on long-term temperature and salinity variations of bottom water masses. This combination produces a different pattern of variation in gas fields from the inner and the outer ría. Prominent pockmarks and acoustic plumes have also been monitored throughout the three seismic surveys. Many of these pockmarks exhibit active characteristics, including the observance of plumes of escaping fluids and sediment.     

Determination of Fluorine and Chlorine by Pyrohydrolysis and Ion Chromatography: Comparison with Alkaline Fusion Digestion and Ion Chromatography

A method to determine F and Cl in silicate materials by employing pyrohydrolysis and ion chromatography (IC) is described. Pyrohydrolysis involved mixing a pulverised sample (∼ 40 mg) with V₂O₅ (∼ 160 mg) and heating to 1100 °C under a wet oxygen flow in a quartz tube. Recovery yields of F and Cl were ∼ 97% using a NaF + NaCl standard solution. Detection limits of the pyrohydrolysis-IC method for silicate samples were 0.36 and 0.69 μg g^-1 for F and Cl, respectively. Fluorine and Cl concentrations were determined in the reference materials JB-2, JB-3 and JA-1 from the GSJ; BCR-2, BHVO-1, BHVO-2, AGV-1 and AGV-2 from the USGS; and NIST SRM 610, 612 and 614 glasses. Precisions (RSD) for determinations of F were 1–13% (except NIST SRM 614) and 2–19% for Cl, and were dependent on the concentration and blank correction. Most results obtained in this study were in good agreement with those of previous studies. In comparison, the Na₂CO₃ + ZnO fusion method at 900 °C showed that the yields of F and Cl by alkaline fusion systematically decreased with fusion duration time. The yields were 84% and 83% for JB-3, inferring that F and Cl were lost in this alkaline fusion.