Sediment budget of the Napo River,Amazon basin,Ecuador and Peru

The upstream‐downstream sediment budget along the Napo River (100 520 km², 6300 m³ s^?1) was studied in the Andean foothills of Ecuador, at the west of the Amazon basin. A comparative study was made during four hydrological cycles (2001–2005) for three hydrological stations located upstream, and during one hydrological cycle (2004–2005) for the fourth one located near the mouth of the Napo River (region of Iquitos in Peru). This analysis showed an unusual increase in the concentration of suspended sediment recorded for the western part of the Amazon plain. Like the runoff (81 l s^?1 km²), which is a world's maximum, the erosion rate (1160 t km^?2 year^?1, i.e. 47% of total suspended solid (TSS) export at the exit of Ecuador), one of the highest for a floodplain basin is the result of a stepper slope than in the rest of the Andean foothills, where typically sedimentation phenomena are predominant, and can be explained in part by a greater tectonic activity. Similar phenomenes were evidenced in small mountainous rivers in New Guinea (Milliman and Syvitski, 1992; Milliman, 1995). On the headwaters of the Napo River drainage basin, the tectonic uplift causes the Pastaza Megafan's existence. This progressively diverts the course of Napo River towards north and also provokes the remobilization of fine fluvial deposits. Moreover, this geodynamic trend is completed by the impact of volcanic eruption, earthquakes and landslides. The combination of these phenomena, so common in the region, has provided a large sediment transfer, not only at present but also in the past, as can be confirmed by the presence of incised terraces, mainly formed by volcanic materials. Then, these results were compared with a similar study carried out further south in the Madeira basin at the Bolivian foothills. These studies show the spatio‐temporal variability of the relation between sediment transfer and geodynamic processes at the Andean Piedmont. Copyright © 2009 John Wiley & Sons, Ltd.     

The status of artisanal fishing in El Salvador

El Salvador is one of the most environmentally degraded nations in Latin America, but the declining fishing industry is under-studied compared with deforestation and landuse. This paper examines the reactions to fish stock decline of two generations of fishers in La Union, El Salvador on the Golfo de Fonseca, one of the most important fishing areas in Latin America, using face to face interviews and questionaires. Both older (>35 years) and younger (<36 years) fishers supplemented their income with trading, farming and loans from their relatives in the United States. All older fishers reported larger fish catches five and ten years previously than at present. Previously, fishers caught more fish, but significantly more younger fishers than older fishers reported their fathers caught more fish than they did, indicating an increasing gap in fish catches in recent decades. More younger fishers than older fishers had fathers or male kin who were also fishers, indicating young men were less likely to join fishing without a parent or kin already involved. Minorities of both older and younger fishers engaged in supplementary activities. Environmental degradation disuaded fishers from switching to farming or hunting. The findings are similar to findings elsewhere on the decline of fish resources and generational gaps in environmental knowledge, but differ in that some other studies report fewer opportunities for fishers to access alternative or complementary activities. These findings are relevant to Latin American studies, considering the great value of the Golfo de Fonseca to the livelihoods of Central America.     

Yardangs in terrestrial ignimbrites: Synergistic remote and field observations on Earth with applications to Mars

The conditions of formation and the form of yardangs in ignimbrites in the Central Andes of Chile, Bolivia, and Argentina may be the most convincing terrestrial analog to the processes and lithology that produce the extensive yardangs of the Medusae Fossae Formation (MFF) of Mars. Through remote and field study of yardang morphologies in the Central Andes we highlight the role that variable material properties of the host lithology plays in their final form. Here, ignimbrites typically show two main facies: an indurated and jointed facies, and a weakly to poorly indurated, ash- and pumice-rich facies. Both facies are vertically arranged in large (erupted volume >100's of km³) ignimbrites resulting in a resistant capping layer, while smaller (10's of km³) ignimbrites are made predominantly of the weakly indurated facies. The two facies have quite different mechanical properties; the indurated facies behaves as strong rock, fails by block collapse and supports steep/vertical cliffs, while the non-indurated facies is more easily eroded and forms gentle slopes and manifests as more subdued erosional forms. In response to aeolian action, the presence of an upper indurated facies results in large, elongate, high aspect ratio (1:20-1:40) megayardangs that form tall (100 m), thin ridges with steep to vertical walls. These are built on a broad apron of the weakly indurated facies with abundant fallen blocks from the upper indurated facies. These terrestrial megayardangs appear to be analogous to megayardangs with associated block fields seen on Mars. Smaller-volume, weakly indurated ignimbrites are sculpted into smaller, stubbier forms with aspect ratios of 1:5-1:10 and heights rarely exceeding 10 m. Excavation of a windward basal moat suggests an erosional progression like that seen in incipient yardangs on Mars. Excavation rates of 0.007-0.003 cm/year are calculated for the weakly indurated ignimbrites. While a persistent strong unidirectional wind is the dominant parameter controlling yardang formation and orientation, a role for flow separation and vorticity is also suggested by our observations at both yardang types. While the indurated facies is commonly pervasively jointed, jointing is of secondary importance in controlling yardang orientation. Serrated margins, a common feature on Mars, result from oblique intersections of jointing with yardang flanks or scarps of ignimbrite. The processes of yardang formation we describe from ignimbrites from the Central Andes are not necessarily specific to ignimbrites, but do connote that degree and distribution of induration is a major control in yardang formation and this has implications for the lithology of the MFF on Mars.     

Définition et datation de la Formation de Venaco (Corse) : dépôt d’origine gravitaire d’âge Priabonien

Priabonian age is highlighted for the first time in Corsica in the Venaco Formation using the presence of specific microfauna (in particular some representatives of Turborotalia cerroazulensis lineage). This silicoclastic formation is mainly represented by coarse facies. It is composed of three members from south to north and from oldest towards youngest: member of Uboli, Cardo and Orsu. The sedimentologic analysis reveals a gravity depositional environment, involving different type of currents. Sedimentologic and chronologic characteristics make the Venaco Formation and the Annot Formation (p.p.) equivalent. Dating the Venaco Fm. brings confirmation that the green schist metamorphism of the Variscan batholith and the related deformation are from the pre-Priabonian period.     

Evaluation of a Quality Control Monitor Material for the Routine Electron Probe Microanalysis of Kimberlite Exploration Garnets

Election probe microanalysis of indicator minerals is extensively used in the exploration for kimberlite deposits, the evaluation of specific kimberlite occurrences for their diamond bearing potential and to classify grains into different chemical and lithological mantle associations. Kimberlite exploration programmes can involve several tens of thousands of indicator mineral analyses. Procedures for monitoring data quality and consistency of analyses across large data sets are commonly absent. Suitable monitor minerals should be used to verify the data quality of kimberlite exploration and evaluation data sets. This material should have a suitable composition, be homogenous, be available in sufficient quantities and have a similar appearance to the unknown samples. Garnet P1, a megacryst garnet from the Premier kimberlite, was found to have a suitable composition as a monitor for kimberlite garnet analyses. Data were collected on the monitor material at regular intervals during routine analyses, over an extended period, both as a fixed grain mounted on the sample holder and as separate grains set within batches of routine samples. The data were evaluated to assess the quality and consistency in the analyses of large data sets over time. The monitor material was also analysed at independent laboratories using their routine analytical set-up and calibration procedures for comparative purposes. Values are given for the mean ± 2s range, which can serve as guide values for acceptable analyses for all elements.     

Accurate and Precise Elemental Abundance of Zinc in Reference Materials by an Isotope Dilution Mass Spectrometry TIMS Technique

A thermal ionisation mass spectrometric technique enabled the abundance of Zn in geological and biological reference materials and water samples to be measured by double spiking isotope dilution mass spectrometry enriched in the ⁶⁷Zn and ⁷⁰Zn isotopes. In the past, thermal ionisation mass spectrometry proved to be difficult for low-level zinc isotopic measurements. The size of Zn samples used for isotopic determination, in particular the biological RMs, represents an important breakthrough. These results represent the most accurate and precise concentrations measured for Zn in these samples. The maximum fractional uncertainty was that for TILL-3 (2%), while the minimum fractional uncertainty was 0.7% for both BCR-1 and W-2. The inhomogeneity of Zn in HISS-1 was revealed while other reference materials appeared homogeneous at the 95% confidence uncertainty. The certified concentration of Zn in HISS-1 and IMEP-19 by their producers are 28% and 3.8% higher than the values measured in this work. These are the first Zn concentration measurements in these materials by the isotope dilution-TIMS technique, except for BCR-1, NIES N^o 9 and IMEP-19. Reducing the blank enabled accurate measurement in water at the ng g^-1 level demonstrating the applicability of the technique for low-level Zn samples.     

Spatiotemporal Dynamics of a Páramo Ecosystem in the Northern Ecuadorian Andes 1988-2007

Páramo is a term used to describe tropical alpine vegetation between the continuous timberline and the snow line in the Northern Andes. Páramo environments provide important species habitat and ecosystem services. Changes in spatial extent of the páramo ecosystem at Pambamarca in the Central Cordillera of the northern Ecuadorian Andes were analysed using multi-temporal Landsat TM/ETM+ satellite data. The region suffered a loss of 1826.6 ha or 20% of the total area at a rate of 100 ha/annum during 1988-2007 period. It is found that permanent páramo cover decreased from 8350 ha in 1988 to 5864 ha in 2007 at a fairly constant rate(R2=0.94). This loss is attributed to expansion of commercial agriculture and floriculture in the valleys coupled with increased population pressure. Land at higher elevations has been cleared for small scale agriculture. Loss of the páramo ecosystem will exert a number of negative impacts on ecosystem services and livelihoods of the local population at Pambamarca.     

Calcium,Na, K and Mg Concentrations in Seawater by Inductively Coupled Plasma‐Atomic Emission Spectrometry: Applications to IAPSO Seawater Reference Material,Hydrothermal Fluids and Synthetic Seawater Solutions

We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q^® water. We obtained an average reference value r_K (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg^?1)/(g kg^?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to r_Na, r_Ca and r_Mg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids.     

Sulfur Concentration in Geochemical Reference Materials by Solution Inductively Coupled Plasma‐Mass Spectrometry

With implications for the origin of ore deposits, redox state of the atmosphere, and effects of volcanic outgassing, understanding the sulfur cycle is vital to our investigation of Earth processes. However, the paucity of sulfur concentration measurements in silicate rocks and the lack of well‐calibrated reference materials with concentrations relevant to the rocks of interest have hindered such investigations. To aid in this endeavour, this study details a new method to determine sulfur concentration via high mass resolution solution inductively coupled plasma‐mass spectrometry (ICP‐MS). The method is based on an aqua regia leach, involving relatively rapid sample preparation and analysis, and uses small test portion masses (< 50 mg). We utilised two independently prepared standard solutions to calibrate the analyses, resulting in 4% accuracy, and applied the method to eight geochemical reference materials. Measurements were reproducible to within ~ 10%. Sulfur concentrations and isotopes of six reference materials were measured additionally by elemental analyser‐combustion‐isotope ratio mass spectrometry to independently evaluate the accuracy of the ICP‐MS method. Reference materials that yielded reproducible measurements identical to published values from other laboratories (JGb‐1, JGb‐2 and MAG‐1) are considered useful materials for the measurement of sulfur. Reference materials that varied between studies but were reproducible for a given test portion perhaps suffer from sample heterogeneity and are not recommended as sulfur reference materials.     

Precise and Accurate In Situ Determination of Lead Isotope Ratios in NIST,USGS, MPI‐DING and CGSG Glass Reference Materials using Femtosecond Laser Ablation MC‐ICP‐MS

Lead isotope ratio data were obtained with good precision and accuracy using a 266 nm femtosecond laser ablation (fLA) system connected to a multi‐collector ICP‐MS (MC‐ICP‐MS) and through careful control of analytical procedures. The mass fractionation coefficient induced by 266 nm femtosecond laser ablation was approximately 28% lower than that by 193 nm excimer laser ablation (eLA) with helium carrier gas. The exponential law correction method for Tl normalisation with optimum adjusted Tl ratio was utilised to obtain Pb isotopic data with good precision and accuracy. The Pb isotopic ratios of the glass reference materials NIST SRM 610, 612, 614; USGS BHVO‐2G, BCR‐2G, GSD‐1G, BIR‐1G; and MPI‐DING GOR132‐G, KL2‐G, T1‐G, StHs60/80‐G, ATHO‐G and ML3B‐G were determined using fLA‐MC‐ICP‐MS. The measured Pb isotopic ratios were in good agreement with the reference or published values within 2s measurement uncertainties. We also present the first high‐precision Pb isotopic data for GSE‐1G, GSC‐1G, GSA‐1G and CGSG‐1, CGSG‐2, CGSG‐4 and CGSG‐5 glass reference materials obtained using the femtosecond laser ablation MC‐ICP‐MS analysis technique.