On the Composition of Airborne Particles Influenced by Emissions of the Volcano Popocatépetl in Mexico

A 17-day field campaign was carried out in April–May 1999 to determine thecontribution that gaseous volcanic emissions make to the compositionof solid particles,particularly to the presence and quantity of sulfates. Theexperimental site was located inTonantzintla (in the State of Puebla), only 30 km E from the volcanoPopocatépetl, whichhas been in an active phase since the end of 1993. An analysis ofthe carbon monoxide(CO) and sulfur dioxide (SO₂) in the ambient air identifiedvolcanic influence in 6 out ofthe 17 days sampled. Particles collected in an 8-stage cascadeimpactor were analyzed for inorganic ions (by liquid chromatography).A non-parametric test indicates asignificant difference on the total particle mass and thesulfate fraction between days withand without volcanic influence. This difference was predominantlyobserved in the stages that collect the smaller particles. Windsat 500 mb (roughly corresponding to thesummit of the volcano) indicate a westerly transport from thevolcano to the experimentalsite, even though surface winds do not show a clear signal ofsuch a transport. Back trajectories from the experimental site werecalculated and clearly indicated that air parcels on the daysindependently identified as with volcanic influence had indeed passed over the volcano.     

软钾镁矾溶解动力学Ⅰ:对K~ ,Mg~(2 )/SO_4~(2-)—H_2O三元体系的研究(50-75℃)

前言青藏高原的诸多盐湖中存在大量的钾、钠、镁复盐,如KCI和KSO。这两种钾肥可以由盐湖中所含的钾钱复盐光卤石和软钾镁矾（K。SO。·MgSO。·sH刀）在水中溶解制得,因此,有必要对复盐溶解过程进行系统的研究,夏树屏等人‘’,‘’已对复盐氯碳酸镁和氯柱硼镁石等的溶解转化机理和动力学进行了较为详细的研究,解决了不同类型复盐的研究方法和数据处理方法。德国和独联体两国的学者对钾光卤石固体盐矿的工艺及基础研究曾进行过不少的工作H．H．Emons和HVo…等‘”对钾光卤石的天然单晶和压块光卤石不同条件下的溶解速度常数及…     

藏东玉龙铜矿带含矿斑岩及成岩系列

西藏东部新生代玉龙铜矿带含矿斑岩,包括玉龙、扎拉尕、莽总、多霞松多和马拉松多等,均为同期不同阶段侵入地质体构成的复式岩体。岩石类型有石英二长斑岩、二长花岗斑岩、正长花岗斑岩和碱长花岗斑岩。岩石化学成分均富碱（Ｎａ２Ｏ＋ｋ２Ｏ〉８％）、高钾和Ｋ２Ｏ／Ｎａ２Ｏ比值远大于１等,属于碱性钾质系列,即钾玄岩系列。     

热泉热液金矿化中嗜热微生物——有机质的地球化学作用

本文主要通过对热泉热液金成矿过程中的热泉水化学成分和组分的分析,得出泉水中金与氮磷硫、氟硅碳两组组分有很好的相关性。嗜热硫酸盐还原菌能使［Ａｕ（ＨＳ）２］－和［Ａｕ（Ｓ２Ｏ３）２］３－都氧化还原成硫化物,从而使金由热水溶液中沉淀。热泉沉积软泥的有机质中的含硫氨基酸、含硫芳烃也起到了一定的聚金作用。     

碘酸钡置换碘-四氯化碳萃取光度法测定矿物气液包裹体中微量SO_4~(2-)

本文根据碘酸钡与矿物气液包裹体中ＳＯ２－４交换反应析出的碘酸根与碘化镉反应析出碘,采用碘－四氯化碳萃取光度法间接测定ＳＯ２－４,取得了较为满意的结果。     

Cu and Fe associated with humic acids in sediments of a tropical coastal lagoon

The amount of Cu and Fe associated with humic acids was estimated in five sediment cores from a tropical coastal lagoon (Piratininga Lagoon, Rio de Janeiro, Brazil). Core samples were analysed for humic acid contents, total Fe and Cu content. Fe and Cu associated with humic acids were also measured. Results show amounts of humic acids ranging from 0.7 to 21.7% of the dry weight of sediment (average 4.6%, standard deviation 4.4%). Concentrations of Fe and Cu ranged from 0.3 to 6.0% (average 2.2%, S.D. 1.2%) and from <1.0 to 65.0 μg g⁻¹ (average 28.6 μg g⁻¹, S.D. 16.4 μg g⁻¹), respectively. The results of strongly bound metals show that while humic acids are the main carrier for Cu, Fe does not seems to be significantly associated with this organic matter.     

钛白副产绿矾生产聚合硫酸铁的研究

本文以钛白副产品绿矾为原料,氧化后,加入聚合剂生产聚合硫酸铁。     

草酰胺合铜(Ⅱ)配合物的合成和热分解反应

合成了3种单核配合物,通过元素分析、摩尔电导和红外光谱进行了表征。在动态空气下,采用热重和差热技术研究了N,N′-双氨烷基草酰胺合铜(Ⅱ)配合物热分解动力学。用Achar法和Coats-Redfen法分析了非等温动力学数据,并对比动力学参数提出了最合适的热分解动力学模型。由热重曲线计算出了热分解反应的活化能、热焓和指前因子。对比配合物N,N′-双-2氨乙基草酰胺合铜(Ⅱ)、N,N′-双-2氨丙基草酰胺合铜(Ⅱ)和N,N′-双-3-氨丙基草酰胺合铜(Ⅱ)初始分解温度,配合物的热稳定性排序为:Cu(oxpn)>Cu(oxap)>Cu(oxen)     

Biological and environmental changes in Lake Baikal during the late Quaternary inferred from carbon, nitrogen and sulfur isotopes

An 8-m continuous sediment core, approximately 250-ky-old at the bottom, from Academician Ridge in Lake Baikal, has been analyzed for the stable isotopes of carbon, nitrogen and sulfur, in order to study the paleoclimatic and paleobiological changes that occurred in the Eurasian continental interior. These isotopic changes are closely related to changes in vertical lake-water circulation between glacial and interglacial periods. Sedimentary organic carbon in cool periods is more enriched in ¹³C (−23.8‰ on average) than that in warm periods (−27.0‰ on average). The ¹³C-enrichment of organic carbon suggests a decrease of land-derived organic matter influx to the lake, less precipitation, and loss of terrestrial vegetation around Lake Baikal in cool periods. Pyrite in high total sulfur/total organic carbon (TS/TOC) layers shows strong depletion in ³⁴S (−20.8‰ to −32.4‰) during climate transitions from glacial to interglacial periods at the beginning of oxygen isotope stages (OIS) 1, 5 and 7. The ³⁴S-depleted pyrite indicates augmentation of dissimilatory sulfate reduction by sulfate reducing bacteria (SRB) at the sediment-water interface. Enhancement of aqueous sulfate concentrations and limitation of oxygen circulation to the surface sediments might also occur in the climate transition periods. The δ¹⁵N values of total nitrogen increase abruptly by ∼2‰ just after the δ³⁴S negative peaks, which may result from low nutrient concentrations in the euphotic zone associated with water circulation changes in Lake Baikal.     

The effect of copper-treated net pens on farmed salmon (Salmo salar) and other marine organisms and sediments

Samples of Atlantic salmon (Salmo salar), saithe (Pollacius virens), blue mussel (Mytilus edulis), brown seaweed (Ascophyllum nodosum) and sediment were collected from six different fish farms. Five of the farms used net pens treated with copper-containing coatings, whereas one farm did not use copper-containing coating (this was used as a reference location). Samples of muscle, liver and gills of Atlantic salmon and saithe, blue mussel and brown seaweed were freeze dried, homogenised, wet digested and analysed for copper by flame atomic absorption spectrometry. The results showed no significant differences in copper concentrations among the samples from the different locations. The copper contents of some of the samples appeared to be in the upper part of the normal concentration range. From a nutritional point of view, the use of copper-coatings on net pens did not affect the quality of the seafood products either within, or around the net pen.