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41.
V.V. Ryabov O.N. Simonov S.G. Snisar A.A. Borovikov 《Russian Geology and Geophysics》2018,59(8):945-961
The source of sulfur in giant Norilsk-type sulfide deposits is discussed. A review of the state of the problem and a critical analysis of existing hypotheses are made. The distribution of δ34S in sulfides of ore occurrences and small and large deposits and in normal sedimentary, metamorphogenic, and hypogene sulfates is considered. A large number of new δ34S data for sulfides and sulfates in various deposits, volcanic and terrigenous rocks, coals, graphites, and metasomatites are presented. The main attention is focused on the objects of the Norilsk and Kureika ore districts. The δ34S value varies from -14 to + 22.5‰ in sulfides of rocks and ores and from 15.3 to 33‰ in anhydrites. In sulfide-sulfate intergrowths and assemblages, δ34S is within 4.2-14.6‰ in sulfides and within 15.3-21.3‰ in anhydrites. The most isotopically heavy sulfur was found in pyrrhotite veins in basalts (δ34S = 21.6‰), in sulfate veins cutting dolomites (δ34S = 33‰), and in subsidence caldera sulfates in basalts (δ34S = 23.2-25.2‰). Sulfide ores of the Tsentral’naya Shilki intrusion have a heavy sulfur isotope composition (δ34S = + 17.7‰ (n = 15)). Thermobarogeochemical studies of anhydrites have revealed inclusions of different types with homogenization temperatures ranging from 685 °C to 80 °C. Metamorphogenic and hypogene anhydrites are associated with a carbonaceous substance, and hypogene anhydrites have inclusions of chloride-containing salt melts. We assume that sulfur in the trap sulfide deposits was introduced with sulfates of sedimentary rocks (δ34S = 22-24‰). No assimilation of sulfates by basaltic melt took place. The sedimentary anhydrites were “steamed” by hydrocarbons, which led to sulfate reduction and δ34S fractionation. As a result, isotopically light sulfur accumulated in sulfides and hydrogen sulfide, isotopically heavy sulfur was removed by aqueous calcium sulfate solution, and “residual” metamorphogenic anhydrite acquired a lighter sulfur isotope composition as compared with the sedimentary one. The wide variations in δ34S in sulfides and sulfates are due to changes in the physicochemical parameters of the ore-forming system (first of all, temperature and Pch4) during the sulfate reduction. The regional hydrocarbon resources were sufficient for large-scale ore formation. 相似文献
42.
Hydrothermal dolomite commonly closely associates with oil-gas reservoirs and sediment-hosted Pb-Zn deposits, the Mississippi Valley-type (MVT) Pb-Zn deposits in particular. Host rocks of MVT deposits usually experienced extensive dolomitization, and indeed, hydrothermal dolomite is considered as a useful prospective indicator for MVT mineralization. However, genetic link between the hydrothermal dolomitization and MVT Pb-Zn mineralization is a matter of debate. This paper briefly reviewed the nomenclature and research history of hydrothermal dolomite, introduced the major geological, geochemical characteristics, and distribution of hydrothermal dolomite, spatial and possibly genetic relationship between hdyrothermal dolomite and hdyrothermal ore deposits and oil-gas reservoirs based on case studies including the occurrence of hydrothermal dolomites in MVT deposits in Southwest China. The temporal and genetic relationships between dolomitizaiton and thermal sulfate reduction, sulfide precipitation and thus the location of ore mineralization well worthy more attention, and comprehensive geological and isotope geochemical and state of art in situ techniques will contribute to understanding of the genesis of hydrotherml dolomite and the spatially related ore deposits and oil-gas reservoirs. © 2018, Science Press. All right reserved. 相似文献
43.
Dissolved inorganic carbon (DIC) and its carbon isotopic composition in sediment pore waters from the Shenhu area,northern South China Sea 总被引:2,自引:0,他引:2
Tao Yang Shao-Yong Jiang Jing-Hong Yang Ge Lu Neng-You Wu Jian Liu Dao-Hua Chen 《Journal of Oceanography》2008,64(2):303-310
The Shenhu area is one of the most favorable places for the occurrence of gas hydrates in the northern continental slope of
the South China Sea. Pore water samples were collected in two piston cores (SH-A and SH-B) from this area, and the concentrations
of sulfate and dissolved inorganic carbon (DIC) and its carbon isotopic composition were measured. The data revealed large
DIC variations and very negative δ
13C-DIC values. Two reaction zones, 0–3 mbsf and below 3 mbsf, are identified in the sediment system. At site SH-A, the upper
zone (0–3 mbsf) shows relatively constant sulfate and DIC concentrations and δ
13C-DIC values, possibly due to bioturbation and fluid advection. The lower zone (below 3 mbsf) displays good linear gradients
for sulfate and DIC concentrations, and δ
13C-DIC values. At site SH-B, both zones show linear gradients, but the decreasing gradients for δ
13C-DIC and SO4
2− in the lower zone below 3 mbsf are greater than those from the upper zone, 0–3 mbsf. The calculated sulfate-methane interface
(SMI) depths of the two cores are 10.0 m and 11.1 m, respectively. The depth profiles of both DIC and δ
13C-DIC showed similar characteristics as those in other gas hydrate locations in the world oceans, such as the Blake Ridge.
Overall, our results indicate an anaerobic methane oxidation (AMO) process in the sediments with large methane flux from depth
in the studied area, which might be linked to the formation of gas hydrates in this area. 相似文献
44.
M. Gonzlez-Dvila J.M. Santana-Casiano A.G. Gonzlez N. Prez F.J. Millero 《Marine Chemistry》2009,115(1-2):118-124
The oxidation and reduction of nanomolar levels of copper in air-saturated seawater and NaCl solutions has been measured as a function of pH (7.17–8.49), temperature (5–35 °C) and ionic strength (0.1–0.7 M). The oxidation rates were fitted to an equation valid at different pH and ionic strength conditions in sodium chloride and seawater solutions:The reduction of Cu(II) was studied in both media for different initial concentrations of copper(II). When the initial Cu(II) concentration was 200 nM, the copper(I) productions were 20% and 9% for NaCl and seawater, respectively. The effect of speciation of copper(I) reduced from Cu(II) on the rates was studied. The Cu(I) speciation is dominated by the CuCl2− species. On the other hand, the neutral chloride CuCl species dominates the Cu(I) oxidation in the range of 0.1 M to 0.7 M chloride concentrations. 相似文献
45.
Yoann Louis Cdric Garnier Vronique Lenoble Stphane Mounier Neven Cukrov Dario Omanovi Ivanka Pieta 《Marine Chemistry》2009,114(3-4):110-119
An interaction of dissolved natural organic matter (DNOM) with copper ions in the water column of the stratified Krka River estuary (Croatia) was studied. The experimental methodology was based on the differential pulse anodic stripping voltammetric (DPASV) determination of labile copper species by titrating the sample using increments of copper additions uniformly distributed on the logarithmic scale. A classical at-equilibrium approach (determination of copper complexing capacity, CuCC) and a kinetic approach (tracing of equilibrium reconstitution) of copper complexation were considered and compared. A model of discrete distribution of organic ligands forming inert copper complexes was applied. For both approaches, a home-written fitting program was used for the determination of apparent stability constants (Kiequ), total ligands concentration (LiT) and association/dissociation rate constants (ki1,ki- 1).A non-conservative behaviour of dissolved organic matter (DOC) and total copper concentration in a water column was registered. An enhanced biological activity at the freshwater–seawater interface (FSI) triggered an increase of total copper concentration and total ligand concentration in this water layer. The copper complexation in fresh water of Krka River was characterised by one type of binding ligands, while in most of the estuarine and marine samples two classes of ligands were identified. The distribution of apparent stability constants (log K1equ: 11.2–13.0, log K2equ:8.8–10.0) showed increasing trend towards higher salinities, indicating stronger copper complexation by autochthonous seawater organic matter.Copper complexation parameters (ligand concentrations and apparent stability constants) obtained by at-equilibrium model are in very good accordance with those of kinetic model. Calculated association rate constants (k11:6.1–20 × 103 (M s)− 1, k21: 1.3–6.3 × 103 (M s)− 1) indicate that copper complexation by DNOM takes place relatively slowly. The time needed to achieve a new pseudo-equilibrium induced by an increase of copper concentration (which is common for Krka River estuary during summer period due to the nautical traffic), is estimated to be from 2 to 4 h.It is found that in such oligotrophic environment (dissolved organic carbon content under 83 µMC, i.e. 1 mgCL− 1) an increase of the total copper concentration above 12 nM could enhance a free copper concentration exceeding the level considered as potentially toxic for microorganisms (10 pM). 相似文献
46.
Marianne Holmer Ole Pedersen Dorte Krause-Jensen Birgit Olesen Malene Hedegrd Petersen Stephanie Schopmeyer Marguerite Koch Bente Aa. Lomstein Henning S. Jensen 《Estuarine, Coastal and Shelf Science》2009,85(2):319-326
Sulfur and oxygen dynamics in the seagrasses Thalassia testudinum and Syringodium filiforme and their sediments were studied in the US Virgin Islands (USVI) in order to explore sulfide intrusion into tropical seagrasses. Four study sites were selected based on the iron concentration in sediments and on proximity to anthropogenic nutrient sources. Meadow characteristics (shoot density, above- and below-ground biomass, nutrient content) were sampled along with sediment biogeochemistry. Sulfide intrusion was high in T. testudinum, as up to 96% of total sulfur in the plant was derived from sediment-derived sulfides. The sulfide intrusion was negatively correlated to the turnover of sulfides in the sediments regulated by both plant parameters and sediment sulfur pools. Sediment iron content played an indirect role by affecting sulfide turnover rates. Leaf production was negatively correlated with sulfide intrusion suggesting that active growth reduced sulfide intrusion. Sulfide intrusion was lower in S. filiforme (up to 44%) compared to T. testudinum consistent with a higher internal nighttime oxygen concentrations found for S. filiforme. When S. filiforme can take advantage of its ability to maintain high internal oxygen concentrations, as was the case on the USVI, it could increase its success in colonizing unvegetated disturbed sediments with potentially high sulfide concentrations. 相似文献
47.
新型珊瑚海水混凝土力学性能试验研究 总被引:1,自引:1,他引:1
为了解决全珊瑚海水混凝土(coral aggregate seawater concrete,简称CASC)的脆性问题,采用碱式硫酸镁水泥(basic magnesium sulfate cement,简称BMSC)为胶凝材料和剑麻纤维为增韧材料制备了一种新型全珊瑚海水混凝土(NCASC),系统测定了基本力学性能,并与普通硅酸盐水泥制备的CASC、碱式硫酸镁水泥砂石混凝土(basic magnesium sulfate cement concrete,简称BMSCC)、普通砂石混凝土(ordinary portland cement concrete,简称OPC)以及普通轻骨料混凝土(lightweight aggregate concrete,简称LAC)的力学性能进行对比。结果表明:立方体抗压强度(f_(cu),m)在15~35 MPa范围内的NCASC的轴心抗压强度(f_c,m)、劈裂抗拉强度(f_(sp),m)与f_(cu),m之间具有较显著的线性关系;对于f_(cu),m为15~35 MPa的混凝土,相同强度NCASC的f_c,m高于OPC、LAC及BMSCC,其f_c,m与f_(cu),m比值最大,大致在0.85~0.96之间,NCASC的f_(sp),m比OPC和LAC高,但比BMSCC低,且随着强度的提高,OPC与NCASC的f_(sp),m间的差距在增大,而LAC和BMSCC与NCASC的f_(sp),m间的差距在缩小;在强度等级C15~C55的范围中,NCASC和CASC的f_(sp),m、f_c,m与f_(cu),m之间的关系基本可以采用相同的线性回归方程来描述,利用这两个回归线性方程得到对应于标准强度等级的CASC和NCASC的f_(sp),m和f_c,m数据,为CASC力学性能研究与结构设计提供参考依据。 相似文献
48.
49.
Annual wet deposition of excess sulfate at Macquarie Island has been estimated from 5 months of rainwater composition data covering the Austral summer of 1985/86. The resulting figure of 2.1±0.6 mmol/m2/yr is at the low end of previous estimates of maritime excess sulfate deposition by precipitation. Within estimated uncertainty limits this figure is consistent with the DMS emission flux which would be predicted for latitude 50°–60° S, based solely on available Northern Hemispheric DMS measurements.Temporarily at the International Meteorological Institute, Stockholm University, S-106 91, Stockholm, Sweden. 相似文献
50.
Nitrogen and sulfur species in Antarctic aerosols at Mawson,Palmer Station,and Marsh (King George Island) 总被引:4,自引:0,他引:4
D. L. Savoie J. M. Prospero R. J. Larsen F. Huang M. A. Izaguirre T. Huang T. H. Snowdon L. Custals C. G. Sanderson 《Journal of Atmospheric Chemistry》1993,17(2):95-122
High volume bulk aerosol samples were collected continuously at three Antarctic sites: Mawson (67.60° S, 62.50° E) from 20 February 1987 to 6 January 1992; Palmer Station (64.77° S, 64.06° W) from 3 April 1990 to 15 June 1991; and Marsh (62.18° S, 58.30° W) from 28 March 1990, to 1 May 1991. All samples were analyzed for Na+, SO
4
2–
, NO
3
–
, methanesulfonate (MSA), NH
4
+
,210Pb, and7Be. At Mawson for which we have a multiple year data set, the annual mean concentration of each species sometimes vary significantly from one year to the next: Na+, 68–151 ng m–3; NO
3
–
, 25–30 ng m–3; nss SO
4
2–
, 81–97 ng m–3; MSA, 19–28 ng m–3; NH
4
+
, 16–21 ng m–3;210Pb, 0.75–0.86 fCi m–3. Results from multiple variable regression of non-sea-salt (nss) SO
4
2–
with MSA and NO
3
–
as the independent variables indicates that, at Mawson, the nss SO
4
2–
/MSA ratio resulting from the oxidation of dimethylsulfide (DMS) is 2.80±0.13, about 13% lower than our earlier estimate (3.22) that was based on 2.5 years of data. A similar analysis indicates that the ratio at Palmer is about 40% lower, 1.71±0.10, and more comparable to previous results over the southern oceans. These results when combined with previously published data suggest that the differences in the ratio may reflect a more rapid loss of MSA relative to nss SO
4
2–
during transport over Antarctica from the oceanic source region. The mean210Pb concentrations at Palmer and Marsh and the mean NO
3
–
concentration at Palmer are about a factor of two lower than those at Mawson. The210Pb distributions are consistent with a210Pb minimum in the marine boundary layer in the region of 40°–60° S. These features and the similar seasonalities of NO
3
–
and210Pb at Mawson support the conclusion that the primary source regions for NO
3
–
are continental. In contrast, the mean concentrations of MSA, nss SO
4
2–
, and NH
4
+
at Palmer are all higher than those at Mawson: MSA by a factor of 2; nss SO
4
2–
by 10%; and NH
4
+
by more than 50%. However, the factor differences exhibit substantial seasonal variability; the largest differences generally occur during the austral summer when the concentrations of most of the species are highest. NH
4
+
/(nss SO
4
2–
+MSA) equivalent ratios indicate that NH3 neutralizes about 60% of the sulfur acids during December at both Mawson and Palmer, but only about 30% at Mawson during February and March. 相似文献