贵州西北部基性侵入岩锆石U-Pb年代学、岩石地球化学特征 及其与铅锌成矿关系初探

贵州西北部发育多处基性侵入岩,总体规模较小(约0.25 Km2),多沿深大断裂侵位,出露于铅锌矿点外围,本文对猫猫厂、凉山两处矿点附近的儿马冲和白岩庆两地小型基性侵入岩进行了重点研究。侵入岩主要岩性为细粒辉长岩,造岩矿物主要为拉长石、普通辉石。SiO2范围为49.60-51.09 wt%,MgO从3.88-4.27 wt %,TiO2为3.69-3.85 wt %。LA-ICP-MS锆石U-Pb定年结果为268.3±7.4 Ma,显示岩浆侵位于二叠纪。基性侵入岩的微量元素蛛网图呈OIB型特征,富集大离子亲石元素（LILE）、轻稀土元素（LREE）,亏损重稀土元素（HFEE）,相对亏损高场强元素（Nb,Ta）,有Sr、Y亏损,Pb富集。(87Sr/86Sr)i范围0.706749～0.707069,(143Nd/144Nd)i范围0.512313～0.512363,εNd(t)范围0.2～1.2;源区熔融深度处于石榴石橄榄岩相深度,可能经历了1-3 %的部分熔融,处于亏损石榴石二辉橄榄岩相向原始石榴石二辉橄榄岩相的过渡区。成岩过程中发生了单斜辉石、斜长石等矿物分离结晶,受到了有限的地壳混染作用,未经历明显的AFC过程。地壳物质在地幔源区中的加入可能是造成地幔富集的主要原因。侵入岩与成矿作用之间的关系,主要通过两方面所表现。一方面是二者间构造活动上的耦合性。另一方面是基性岩在成矿过程中可能发挥了重要的化学屏障层作用。     

我国砂岩型铀矿分带特征研究现状及存在问题

作为一种重要的国家战略资源,砂岩型铀矿床是当今世界上最重要的铀矿床类型之一。本文详细地介绍了砂岩型铀矿在国内外的分布特征及占比情况,并对外生地质作用矿床类型中表生流体作用形成的层间渗透砂岩型和潜水渗透砂岩型铀矿床进行了讨论,发现层间渗透砂岩型铀矿床在外表颜色、矿物组合以及地球化学等方面均具有明显的氧化-还原分带现象,此外,矿床内部还具有细菌分带现象。颜色分带在氧化带、氧化-还原过渡带以及还原带之间具有明显不同的特征;矿物组合在不同分带之间各不相同;地球化学分带表现为U、TOC含量以及Fe~(2+)/Fe~(3+)、Th/U比值在各分带之间差异较大。此外,硫酸盐还原菌、硫杆菌、铁细菌及硝化菌等细菌在不同分带之间的数量相差悬殊,而且硫酸盐还原菌数量与TOC呈明显正相关性。通过矿化带内的碳、硫同位素分析,发现硫酸盐还原菌参与了成矿过程,推测其可能是导致碳、硫同位素分馏的主要因素。总体来看,颜色分带、矿物分带、地球化学分带以及细菌分带均与氧化-还原分带呈耦合关系。本文通过总结层间渗透砂岩型和潜水渗透砂岩型铀矿床的成矿模式和当前分带研究中存在的问题,提出了由细菌、地球化学反应参与的砂岩型铀矿床成矿机理,以及未来亟需解决的若干关键科学问题。典型砂岩型铀矿床的分带现象在物、化、探、遥等领域的异常响应对寻找砂岩型铀矿床具有重要的指导意义。     

内蒙古东升庙和炭窑口多金属硫化物矿床铁同位素地球化学特征及其成矿指示意义

本文报道了内蒙古狼山成矿带内两个最大的铅锌多金属硫化物矿床——东升庙矿床和炭窑口矿床中黄铁矿、黄铜矿单矿物的铁同位素研究结果。东升庙矿床绢云石墨片岩中不规则状黄铁矿的铁同位素组成δ~(56)Fe_(-IRMM)值在+0.04‰~+1.11‰之间,呈现铁的重同位素富集,指示了海水中的铁以氧化态沉淀并在成岩期转化成黄铁矿的矿化过程。东升庙和炭窑口矿床富硫化物矿石中黄铁矿和黄铜矿的铁同位素组成δ~(56)Fe_(-IRMM)值的变化范围为-1.33‰~+0.08‰,具有热液成矿特征,指示金属成矿物质来源于热液流体。另外,绢云石墨片岩中脉状黄铁矿的铁同位素组成δ~(56)Fe_(-IRMM)值的变化范围为-0.39‰~-0.04‰,处于矿石黄铁矿和围岩不规则状黄铁矿之间,指示脉状黄铁矿是热液矿化的产物,并在成矿过程中混入了围岩中早先形成的富集铁的重同位素的黄铁矿。绢云石墨片岩中广泛发育的不规则状黄铁矿与赋存在绢云石墨片岩中的富硫化物矿体具有完全不同的铁同位素组成,指示热液活动对不规则状黄铁矿没有明显成矿物质贡献,因此同沉积热液活动成矿的可能性不大。结合赋存在白云石大理岩中硫化物矿体的顶、底部常见硅化的白云石大理岩角砾,本文提出后生矿化是东升庙多金属硫化物矿体的主要成矿方式。另外,东升庙矿床和炭窑口矿床的矿石硫化物具有相似的铁同位素组成特征,指示两者的成矿物质来源具有相似性。     

鄂尔多斯盆地纳岭沟铀矿床绿泥石特征及地质意义

纳岭沟铀矿床位于鄂尔多斯盆地北部,具有明显的后期热液作用的特征,矿体空间展布主要受控于绿色-灰色砂岩的过渡界面,与绿泥石化的蚀变砂岩关系密切。通过对纳岭沟铀矿床不同颜色砂岩中的绿泥石进行详细的岩相学研究和电子探针化学成分分析,依据绿泥石的成因与共生矿物的关系,识别出绿泥石主要的3种类型:填隙物型绿泥石,片状与黄铁矿共生型绿泥石以及黑云母蚀变型绿泥石;同时通过绿泥石的Fe-Si图解确定了纳岭沟铀矿床不同颜色砂岩中的绿泥石主要为铁镁绿泥石和密绿泥石。根据Al/(Fe+Mg+Al)-Mg/(Fe+Mg)的关系图解确定出不同颜色砂岩中的绿泥石具有铁镁质流体和泥质两种来源,通过绿泥石中主要阳离子与镁的关系图解和计算得出的绿泥石形成温度共同确定出绿泥石是多期次的中低温热液流体作用的产物。综合研究表明,纳岭沟铀矿床的绿泥石形成至少经历了温度稍高的还原性流体和温度稍低的氧化性流体等两个期次的流体作用,稍高温的还原性流体与成矿关系更为重要。与绿泥石形成有关的热液流体作用不仅带入了部分铀,还促进了铀的活化和运移。     

Data analysis of a revisited exploration geochemical dataset of quartz porphyrites from SW Jordan using GIS techniques

The spatial distribution of Cu and its pathfinder elements in quartz porphyrites along Wadi Araba was studied in order to gain an insight about the geologic framework of Cu mineralization in the area. A geochemical exploration data set of 242 samples was revisited. Multivariate statistical and geostatistical analysis were performed on the data set. The objectives of the study were to define Cu relationships with its possible pathfinder elements and to figure out whether geostatistical treatment of exploration data would help telescoping already existing Cu mineralization in Wadi Araba, SW Jordan. Factor analysis and hierarchical cluster analysis were performed on the data set. The results of which indicate that seven elements, namely, Ba, Cr, Mn, Ni, Sc, Sr and V can be considered as pathfinder elements for Cu. Significant correlations do exist between Cu and these elements. The encountered experimental semivariograms of the defined pathfinders were fit to exponential models with varying nugget effects with the exception of Mn which was fit to the spherical model. Ordinary kriging was found to be most appropriate to generate geochemical exploration maps. The applied methods succeeded in deriving valuable information and visualizing the already existing Cu mineralization in Wadi Abu Khusheiba area.     

成岩作用与油气侵位对砂岩铀成矿的约束--以准南硫磺沟地区头屯河组砂岩铀成矿为例

为了解准噶尔盆地南缘硫磺沟地区中侏罗统头屯河组砂岩成岩-流体演化与铀成矿响应,进而客观评价其成矿潜力。通过光薄片鉴定、X衍射、扫描电镜分析得出:目的层主要为岩屑细砂岩,依次经历了浅埋藏、深埋藏和表生-热液成岩阶段,遭受较强的机械压实、胶结及溶蚀作用。其黏土矿物以高岭石为主,碳酸盐矿物有细亮晶和泥晶两类,硅质胶结微弱,局部见细晶黄铁矿及其褐铁矿氧化产物。成岩环境可能经历了由酸性到弱碱性再到酸性,由同生期氧化-浅埋期还原-短暂抬升期氧化还原过渡-缓慢沉降期还原增强-快速抬升期氧化的演化过程。砂岩中存在较多油气包裹体;酸解总烃为5.72~449.14 μL/kg,以CH₄为主;方解石脉δ13C_V-PDB为-25‰~-6.7‰,δ18O_V-SMOW为11.1‰~18.9‰;结合野外调查认为目的层存在一期中等偏弱的后生油气侵位,从而影响了砂体的Eh及pH值。以上成岩过程及烃类流体活动使得目的层早期形成了小型层间氧化带型铀矿并得以局部保存,晚期形成了一定规模的地表潜水氧化带型铀矿体。     

Use of mineral/solution equilibrium calculations to assess the potential for carnotite precipitation from groundwater in the Texas Panhandle,USA

This study investigated the potential for the uranium mineral carnotite (K₂(UO₂)₂(VO₄)₂·3H₂O) to precipitate from evaporating groundwater in the Texas Panhandle region of the United States. The evolution of groundwater chemistry during evaporation was modeled with the USGS geochemical code PHREEQC using water-quality data from 100 groundwater wells downloaded from the USGS National Water Information System (NWIS) database. While most modeled groundwater compositions precipitated calcite upon evaporation, not all groundwater became saturated with respect to carnotite with the system open to CO₂. Thus, the formation of calcite is not a necessary condition for carnotite to form. Rather, the determining factor in achieving carnotite saturation was the evolution of groundwater chemistry during evaporation following calcite precipitation. Modeling in this study showed that if the initial major-ion groundwater composition was dominated by calcium-magnesium-sulfate (>70 precent Ca + Mg and >50 percent SO₄ + Cl) or calcium-magnesium-bicarbonate (>70 percent Ca + Mg and <70 percent HCO₃ + CO₃) and following the precipitation of calcite, the concentration of calcium was greater than the carbonate alkalinity (2mCa⁺² > mHCO₃⁻ + 2mCO₃⁻²) carnotite saturation was achieved. If, however, the initial major-ion groundwater composition is sodium-bicarbonate (varying amounts of Na, 40–100 percent Na), calcium-sodium-sulfate, or calcium-magnesium-bicarbonate composition (>70 percent HCO₃ + CO₃) and following the precipitation of calcite, the concentration of calcium was less than the carbonate alkalinity (2mCa⁺² < mHCO₃^- + 2mCO₃⁻²) carnotite saturation was not achieved. In systems open to CO_2, carnotite saturation occurred in most samples in evaporation amounts ranging from 95 percent to 99 percent with the partial pressure of CO₂ ranging from 10^−3.5 to 10^−2.5 atm. Carnotite saturation occurred in a few samples in evaporation amounts ranging from 98 percent to 99 percent with the partial pressure of CO₂ equal to 10^−2.0 atm. Carnotite saturation did not occur in any groundwater with the system closed to CO₂.     

The Relationship between Jurassic Coal Measures and Sandstone-type Uranium Deposits in the Northeastern Ordos Basin, China

Outcrop and drill hole data show that the Jurassic coal measures in the northeastern Ordos Basin are composed mainly of the Yan'an Formation and the lowstand system tract of the Zhiluo Formation,and there is a regional unconformity between them. The Dongsheng uranium deposit is associated with the Jurassic coal measures. Research data indicate that the Jurassic coal measures in the study area have a certain hydrocarbon-generating capacity,although the metamorphic grade is low(Ro=0.40%–0.58%). In the Dongsheng region alone,the accumulative amount of generated coalbed methane(CBM) is about 2028.29 × 108 –2218.72 × 108 m~3; the residual amount is about 50.92 × 108 m~3,and the lost amount is about 1977 × 108 m~3. Analysis of the burial history of the host rocks and the evolutionary history of the Dongsheng uranium deposit suggests that the Jurassic coal measures generated hydrocarbon mainly from Middle Jurassic to Early Crataceous,which is the main mineralization phase of the Dongsheng uranium deposit. By the Late Cretaceous,a mass of CBM dissipated due to the strong tectonic uplift,and the Dongsheng uranium deposit stepped into the preservation phase. Therefore,the low-mature hydrocarbon-containing fluid in the Jurassic coal measures not only served as a reducing agent for the formation of sandstone-type uranium deposits,but also rendered the second reduction of paleo-interlayer oxidation zone and become the primary reducing agent for ore conservation. Regional strata correlation reveals that the sandstone-type uranium reservoir at the bottom of the Zhiluo Formation is in contact with the underlying industrial coal seams in the Yan'an Formation through incision or in the form of an unconformity surface. In the Dongsheng region with poorly developed fault systems,the unconformity surface and scour surface served as the main migration pathways for low-mature hydrocarbon-containing fluid migrating to the uranium reservoir.     

沉积盆地铀-油(气)共生机理

产于含油(气)盆地中的地浸砂岩型铀矿床与油(气)关系密切,在空间上常与油(气)藏呈共生关系。文章认为其成矿条件和控矿因素相似,并且具有成因联系是二者共生的主要原因。砂岩型铀矿和油(气)藏具有相似的成矿大地构造背景、岩相古地理条件、容矿地层、岩性圈闭、构造控矿条件和有机质基础;在成因上油(气)中的不同组分及其次生矿物对铀有重要的吸附和还原作用,是铀沉淀富集的重要因素之一,铀等放射性元素的存在也有利于油气的生成。由于成矿机理的差异性,砂岩型铀矿与油(气)藏属于异体共生矿床,二者的产出位置并不完全重叠,砂岩型铀矿的产出位置往往更靠近盆缘,且在油(气)储层上方,或以单一矿种产出。     

东昆仑祁漫塔格矿带典型矿田构造背景与岩浆-热力构造特征

以矿田构造–岩相填图为主要方法,研究确定矿田构造和岩浆-热力构造类型及矿床类型,进行成矿富集中心的圈定及找矿预测,是矿田构造背景复杂地区的有效调研方法之一。东昆仑西段祁漫塔格矿带多期构造–岩浆活动强烈,断裂发育,以印支晚期岩浆侵入成矿与找矿进展较大。本次选择景忍–虎头崖、卡尔却卡B区、乌兰乌珠尔三个矿田区,进行1∶10000构造–岩相填图,填制了三个矿田区岩浆–热力构造类型分布图,认为晚三叠世岩浆侵入作用是该区多金属大规模成矿的主要内因,叠加其上的不同方向断裂控矿作用不同,近东西向和北西西向断裂控矿显著,明确了各矿田构造背景和印支期岩浆侵入形成的花岗斑岩+矽卡岩+断裂带热液成矿的模式,厘定了岩浆–热力构造的识别标志,即主要是印支晚期中酸性侵入岩、花岗斑岩、矽卡岩带、大理岩带、接触交代蚀变带、断裂破碎带叠加热液蚀变带等,圈定了成矿和找矿富集中心。