Fluid Inclusions and Hydrogen,Oxygen, Sulfur Isotopes of Nuri Cu‐W‐Mo Deposit in the Southern Gangdese,Tibet

The Nuri Cu‐W‐Mo deposit is located in the southern subzone of the Cenozoic Gangdese Cu‐Mo metallogenic belt. The intrusive rocks exposed in the Nuri ore district consist of quartz diorite, granodiorite, monzogranite, granite porphyry, quartz diorite porphyrite and granodiorite porphyry, all of which intrude in the Cretaceous strata of the Bima Group. Owing to the intense metasomatism and hydrothermal alteration, carbonate rocks of the Bima Group form stratiform skarn and hornfels. The mineralization at the Nuri deposit is dominated by skarn, quartz vein and porphyry type. Ore minerals are chalcopyrite, pyrite, molybdenite, scheelite, bornite and tetrahedrite, etc. The oxidized orebodies contain malachite and covellite on the surface. The mineralization of the Nuri deposit is divided into skarn stage, retrograde stage, oxide stage, quartz‐polymetallic sulfide stage and quartz‐carbonate stage. Detailed petrographic observation on the fluid inclusions in garnet, scheelite and quartz from the different stages shows that there are four types of primary fluid inclusions: two‐phase aqueous inclusions, daughter mineral‐bearing multiphase inclusions, CO₂‐rich inclusions and single‐phase inclusions. The homogenization temperature of the fluid inclusions are 280°C–386°C (skarn stage), 200°C–340°C (oxide stage), 140°C–375°C (quartz‐polymetallic sulfide stage) and 160°C–280°C (quartz‐carbonate stage), showing a temperature decreasing trend from the skarn stage to the quartz‐carbonate stage. The salinity of the corresponding stages are 2.9%–49.7 wt% (NaCl) equiv., 2.1%–7.2 wt% (NaCl) equiv._, 2.6%–55.8 wt% (NaCl) equiv. and 1.2%–15.3 wt% (NaCl) equiv., respectively. The analyses of CO₂‐rich inclusions suggest that the ore‐forming pressures are 22.1 M Pa–50.4 M Pa, corresponding to the depth of 0.9 km–2.2 km. The Laser Raman spectrum of the inclusions shows the fluid compositions are dominated in H₂O, with some CO₂ and very little CH₄, N₂, etc. δD values of garnet are between ?114.4‰ and ?108.7‰ and δ¹⁸O_H2O between 5.9‰ and 6.7‰; δD of scheelite range from ?103.2‰ to ?101.29‰ and δ¹⁸O_H2O values between 2.17‰ and 4.09‰; δD of quartz between ?110.2‰ and ?92.5‰ and δ¹⁸O_H2O between ?3.5‰ and 4.3‰. The results indicate that the fluid came from a deep magmatic hydrothermal system, and the proportion of meteoric water increased during the migration of original fluid. The δ³⁴S values of sulfides, concentrated in a rage between ?0.32‰ to 2.5‰, show that the sulfur has a homogeneous source with characteristics of magmatic sulfur. The characters of fluid inclusions, combined with hydrogen‐oxygen and sulfur isotopes data, show that the ore‐forming fluids of the Nuri deposit formed by a relatively high temperature, high salinity fluid originated from magma, which mixed with low temperature, low salinity meteoric water during the evolution. The fluid flow through wall carbonate rocks resulted in the formation of layered skarn and generated CO₂ or other gases. During the reaction, the ore‐forming fluid boiled and produced fractures when the pressure exceeded the overburden pressure. Themeteoric water mixed with the ore‐forming fluid along the fractures. The boiling changed the pressure and temperature, oxygen fugacity, physical and chemical conditions of the whole mineralization system. The escape of CO₂ from the fluid by boiling resulted in scheelite precipitation. The fluid mixing and boiling reduced the solubility of metal sulfides and led the precipitation of chalcopyrite, molybdenite, pyrite and other sulfide.     

水口山Pb－Zn－Au矿田含矿流体的性质、来源及其环流历程

在矿床地质研究的基础上，从矿物包裹体的显微岩相学、均一化温度、成分、含盐度和Ｈ、０、Ｃ稳定同位素组成方面，探讨了水口山Ｐｂ─Ｚｎ─Ａｕ矿田含矿流体的性质、来源及其环流历程。含矿流体系由岩浆期后热液和地下水混合而成。对于水口山矿区而言，岩浆热液起着主导作用；对于康家湾矿区而言，岩浆期后热液和地下水热液均起着重要作用。热液成矿期从早到晚，随着温度和含盐度的逐渐降低，地下水中雨水／地层卤水的比值逐渐增大。含矿流体的环流历程经历了５个阶段。     

Ore-bearing fluids of the Eldorado gold deposit (Yenisei Ridge,Russia)

The Eldorado low-sulfide gold-quartz deposit, with gold reserves of more than 60 tons, is located in the damage zone of the Ishimba Fault in the Yenisei Ridge and is hosted by Riphean epidote-amphibolite metamorphic rocks (Sukhoi Pit Group). Orebodies occur in four roughly parallel heavily fractured zones where rocks were subject to metamorphism under stress and heat impacts. They consist of sulfide-bearing schists with veins of gray or milky-white quartz varieties. Gray quartz predominating in gold-bearing orebodies contains graphite and amorphous carbon identified by Raman spectroscopy; the contents of gold and amorphous carbon are in positive correlation. As inferred from thermobarometry, gas chromatography, gas chromatography-mass spectrometry, and Raman spectroscopy of fluid inclusions in sulfides, carbonates, and gray and white quartz, gold mineralization formed under the effect of reduced H₂O-CO₂-HC fluids with temperatures of 180 to 490 °C, salinity of 9 to 22 wt.% NaCl equiv, and pressures of 0.1 to 2.3 kbar. Judging by the presence of 11% mantle helium (³He) in fluid inclusions from quartz and the sulfur isotope composition (7.1-17.4‰ δ³⁴S) of sulfides, ore-bearing fluids ascended from a mantle source along shear zones, where they “boiled”. While the fluids were ascending, the metalliferous S- and N-bearing hydrocarbon (HC) compounds they carried broke down to produce crystalline sulfides, gold, and disseminated graphite and amorphous carbon (the latter imparts the gray color to quartz). Barren veins of milky-white quartz formed from oxidized mainly aqueous fluids with a salinity of < 15 wt.% NaCl equiv at 150-350 °C. Chloride brines (> 30 wt.% NaCl equiv) at 150-260 °C impregnated the gold-bearing quartz veins and produced the lower strata of the hydrothermal-granitoid section. The gold mineralization (795-710 Ma) was roughly coeval to local high-temperature stress metamorphism (836-745 Ma) and intrusion of the Kalama multiphase complex (880-752 Ma).     

西藏墨竹工卡县邦铺钼(铜)矿床辉钼矿稀土—微量元素特征及对成矿流体性质的指示

文章以西藏墨竹工卡县邦铺钼(铜)矿床辉钼矿为研究对象,采用高精度电感耦合等离子质谱( ICPMS)对辉钼矿进行了稀土和微量元素测试.测试结果显示辉钼矿具有轻稀土富集的右倾配分模式,轻重稀土内部分馏明显.辉钼矿稀土元素不同程度地出现铕负异常和铈负异常现象,分析得出其铕负异常可能是继承了成矿流体自身铕亏损的特征,而铈负异常...     

A comprehensive survey of lignin geochemistry in the sedimentary organic matter along the Kapuas River (West Kalimantan, Indonesia)

In this first study of lignin geochemistry in the world’s longest river on an island, surface sediments were collected along the Kapuas River, three lakes in the upper river, a tributary in the lower river and a separate river during June-July 2007 and December 2007-January 2008. The samples were analyzed for lignin-derived phenols and bulk elemental and stable carbon isotope compositions. Λ values (the sum of eight lignin phenols, expressed as mg/100 mg organic carbon (OC)) ranged from 0.13 to 3.70. Ratios of syringyl/vanillyl (S/V) and cinnamyl/vanillyl (C/V) ranged from 0.34 to 1.18 and 0.28 to 1.40, respectively, indicating the presence of non-woody angiosperm tissues. The high vanillic acid to vanillin (Ad/Al)v (0.71-2.01) and syringic acid to syringaldehyde (Ad/Al)s (0.72-2.12) ratios indicate highly degraded lignin materials. In the upper Kapuas River, highly degraded soil materials discharged from lands that were barren as a result of deforestation activities were detected in the locations directly in those vicinities. The middle Kapuas River showed rapid organic matter degradation, probably due to the presence of fresh terrestrial and phytoplankton organic matter fueling the biogeochemical cycling. The Kapuas Kecil River, one of the two branches in the lower reach of the Kapuas River, showed higher levels and diagenesis of sedimentary organic matter due to input from anthropogenic sources and increased marine organic matter near the mouth. This study shows that different stretches along the river exhibit different levels and composition of sedimentary organic matter, as well as different carbon dynamics, which is directly attributable to the varying landscapes and quality of organic matter.     

NaCl-H2O-CO2体系人工合成流体包裹体实验研究

NaCl- H2O-CO2体系流体是热液成矿系统中最常见的流体之一,针对该体系相关特征的研究对理解热液矿床的成矿机制和过程、成矿流体特征等具有重要的理论和实际意义.本文利用愈合人工水晶裂隙的技术,开展100 MPa、800℃条件下NaCl-H2 O-CO2体系流体的人工合成包裹体实验,并对其物理化学性质进行了初步探讨.通过对合成的包裹体进行岩相学观察、显微测温以及喇曼光谱分析,结果表明,在实验温压条件下合成的包裹体捕获了既定组成的流体;人工合成NaCl- H2O-CO2体系流体包裹体与天然流体包裹体具有相似的特征,可以作为天然包裹体的参照物应用于流体包裹体及地质流体的研究,特别是在评价CO2在热液矿床成矿过程中的作用方面,NaCl-H2O-CO2体系人工合成包裹体具有广阔的应用前景.     

陕西凤太晚古生代拉分盆地动力学与金-多金属成矿

采用沉积盆地构造-古地理位置恢复重建和构造-岩相学等新方法研究认为,凤太晚古生代沉积盆地属于受板块斜向俯冲碰撞动力学控制下的拉分盆地。在中泥盆世初期,凤太沉积盆地被周缘垂向基底隆起分隔,其成盆构造动力学主要受四组同生断层,晚古生代沉降中心和沉积中心不断发生迁移。中泥盆世中期在盆地北部形成了北西向沉降中心和沉积中心,晚泥盆世末期沉积盆地萎缩,沉降中心和沉积中心收缩于沉积盆地中心。石炭纪沉降中心和沉积中心从盆地中心迁移到盆地四周边缘的同生断裂带附近,在沉积盆地北侧边缘商丹带南侧,形成了石炭纪-早三叠世与俯冲消减带有关的楔状沉积充填体。在凤太拉分盆地中形成的近东西向、北北东向、近南北向和北西向网状同生断裂带系统共同控制了凤太泥盆纪拉分盆地形成与演化过程。其中,商丹带（西段）、礼县-凤县-凤镇-山阳同生断裂带（中段）和酒奠梁-镇安-板岩镇同生断裂带（西段）三个主控同生断裂带不但在泥盆纪期间对于凤太泥盆纪拉分盆地形成具有显著控制作用,而且石炭纪-早三叠世拉分盆地演化过程也具有十分重要的控制作用,石炭纪-早三叠世同生断裂带发生构造反转并控制了沉降中心和沉积中心。采用沉积盆地动力学和构造-岩相学等新方法研究认为,在凤太晚古生代拉分盆地具有分级特征,西部凤县二级盆地为金-多金属成矿集中区,东部太白二级盆地为金矿成矿集中区。在八方山-银母寺三级拉分盆地中,八方山和银母寺等多金属矿床与八卦庙超大型金矿床具有矿田尺度上成矿分带,主要由于三级盆地、同生断裂、热水沉积岩相和构造热流体叠加岩相控制了矿田和矿床尺度上金与多金属成矿分带。凤太拉分盆地北部和东部金矿矿源层和初步富集成矿形成主要与泥盆纪钠长岩相和钠质热水沉积岩相有关,并受钠长碳酸质角砾岩-铁白云石钠长石角砾岩等石炭纪构造-热流体岩相叠加;凤太拉分盆地南部温江寺三叠系浊积岩系中热水硅质岩相和层状英安质凝灰岩是卡林型金矿重要赋矿层位;凤太拉分盆地中部热水沉积-改造型铅锌矿主要与硅质岩相和菱铁矿铁白云岩相等热水沉积相密切有关。     

水平定向钻进管道敷设地层响应实验分析

在应用水平定向钻进非开挖技术进行近地表管道敷设时,由于上覆地层厚度(C)、钻孔直径(D)和钻井液压力(p)三者无法准确设计,往往会导致地表的变形,进而形成裂缝通道致使地表发生钻井液的溢流.分析了非黏聚力地层的溢流通道形式,同时推导了极限钻井液压力的计算公式.结合室内外实验及应用情况,得出了实测钻井液压力和计算钻井液压力同C/D值的变化规律,即C/D越大,极限钻井液的压力值也就越高.在同一地层中,一般钻井液压力的峰值出现在水平孔段的中间位置.根据C/D值,在保证钻井液不发生溢流的情况下,得出了不同水平孔径范围所对应的上覆地层最小厚度.     

方解石脉对中扬子地区沉湖土地堂复向斜油气保存单元的指示意义

野外观测表明,中扬子地区沉湖土地堂复向斜京山县城附近野外露头中二叠系和三叠系方解石脉主要是沿节理缝发育,脉体宽度较小。方解石脉的镜下微观的结晶特征、阴极发光特征、脉体穿插关系可以判断二叠系脉体大约有两期,三叠系脉体大约有三期。碳氧同位素值表明,三叠系方解石脉和围岩的氧同位素差值不大(Δδ18 O的差异范围为-0.19‰～4.12‰,平均值为1.9‰),二叠系方解石脉和围岩氧同位素差异较大(Δδ18 O的差异范围为4.07‰～12.03‰,平均值为7.3‰),三叠系脉体的流体直接来源于围岩,二叠系裂隙中方解石脉的形成过程中可能主要受到有机质的影响。方解石脉体中的流体包裹体均一温度在研究区建立的代表性虚拟井的埋藏史和热史基础上,推测二叠系方解石脉形成深度为3 000m～3 700m,形成深度约为2 000m～3 000m,两套地层中的方解石脉的形成时期为J3—K1燕山构造运动期。中扬子地区在多旋回的沉降和沉积过程中形成的上组合的区域性盖层(中三叠统—下侏罗统的泥质岩)在江汉平原区具有较好的封盖性。     

盆地动力学研究综述及展望

沉积盆地是地球系统的浅层组成部分,是壳-幔、岩石圈-软流圈两级圈层相互作用的浅部表现形式。沉积盆地分析不仅可以揭示不同类型化石能源、沉积型层控矿产、砂岩型铀矿等资源的分布规律,为矿产勘探提供直接依据,而且可以为大地构造演化过程、重大构造事件、全球环境变迁及气候演变提供丰富资料和详细证据。当代盆地分析不断从单一沉积学分析拓展到综合分析,从静态要素分析拓展到过程和动力机制分析。盆地动力学研究内容包括3部分,即以沉积学分析为主的盆地充填动力学、以构造地质学分析为主的盆地形成演化动力学和多学科交叉的盆地流体动力学研究。近10多年来,盆地动力学研究在深水沉积学、高精度层序地层学、源-汇系统、源区剥蚀过程及其深部响应、大陆边缘盆地动力学及盆地流体动力学等方面取得了长足的进展。