四川盆地天然气藏的破坏与保存条件剖析

天然气藏勘探的成功或失利,取决于气藏圈闭的封堵系统和散失系统。介绍了四川盆地气藏圈闭封堵系统和散失系统的类型、分布范围和对气藏圈闭的保存和破坏作用。气藏圈闭封堵系统的优劣取决于圈闭的有效封堵面与区域盖层的有效整体封闭条件和区域水动力停滞带环境条件,封堵系统良好的圈闭,勘探成功率高。气藏圈闭散失系统由缺乏区域盖层有效整体封闭条件的剥蚀区、区域水动力自由交替带环境、通天断层或潜伏通天断层组成。散失系统导致圈闭失效,从而造成勘探失利。通过对四川盆地天然气藏的破坏与保存条件的多个实例剖析,提出在四川盆地及我国南方海相天然气勘探中应当重视对天然气藏破坏与保存条件的研究,以利于天然气藏勘探区块、目标的选择和勘探效率的提高。     

海河流域严重干旱500hPa信号场异常信号分析

基于严重少雨旬的定义,分析海河流域1961～2009年严重少雨旬的分布特征,进而对汛期40个典型严重少雨旬的500hPa信号场进行经验正交分解(EOF分析).结果表明:EOF第一模态的方差贡献率达到35.3％,远高于其他模态;第一模态呈现出2个负异常区和1个正异常区,在对应的环流背景下,海河流域受暖性高压控制,高纬冷空气及低纬暖湿气流难以到达流域上空交绥,持续高温少雨造成流域严重干旱.     

柴达木盆地西部地区咸化湖盆天然气地球化学特征及成因类型判识指标——以古近系—新近系为例

根据天然气地球化学基本理论,对柴达木盆地西部（柴西）地区天然气的地球化学特征进行分析。测试和收集该地区18个油气田及含油气构造的83个天然气样品,分析其组分和C同位素数据,结果显示,该区天然气以烃类气体为主,烃类含量介于79.24%~99.81%之间,天然气比重介于0.72~1.36之间,天然气干燥系数（C1/C2+）介于1.04~617.8之间,甲烷C同位素值介于-51.4‰~-24.2‰之间,乙烷C同位素值介于-34.2‰~-17.4‰之间。在此基础上,对该区不同构造带的天然气成因类型进行研究。研究结果表明,柴达木盆地西部地区天然气类型可划分为腐泥型气、腐殖型气、混合气3类,柴西北部天然气主要为腐泥型气和混合气,少量腐殖型气;柴西南部主要为腐泥型气,少量混合气。同时,建立了天然气成因类型的判识指标,对该区的天然气地球化学特征有了较为深入的认识,对今后的天然气勘探具有指导意义。     

Preservation of diagenetic products of β-carotene in sedimentary rocks from the Lopare Basin (Bosnia and Herzegovina)

Sedimentary rocks from the saline formation of the Lopare Basin were investigated. Sediments contain a moderate amount of immature to marginally mature algal organic matter deposited under slightly reducing to anoxic and slightly saline to hypersaline conditions. Almost all of the samples contain β-carotane in a relatively high quantity, and in some, it represents the most abundant compound in the total distribution of hydrocarbons. The objective of the study was to determine the conditions that are favourable to precursors of β-carotene and/or the preservation of the carotenoid hydrocarbon skeleton. Moreover, the dominant transformation pathways of β-carotene under different redox and salinity conditions, which lead to the formation of aromatic carotenoids were defined.     

姬塬北地区延长组长7-长8油层组泥岩地球化学特征与地质意义

基于对鄂尔多斯盆地姬塬北地区上三叠统延长组长7、长8油层组泥岩样品微量元素和稀土元素的测试分析发现,长7、长8油层组泥岩REE富集,Eu总体上呈明显的负异常;REE分布模式图显示轻、重稀土元素分异明显,曲线在La-Eu段表现为斜率较大的"右倾型",在Gd-Lu段表现为斜率较小的"平缓型"。结合Sr/Cu、Sr/Ba、V/(V+Ni)、Ceanom等特征参数的分析发现,长7、长8油层组泥岩形成于温湿、微咸水、还原水体的沉积环境。泥岩(La/Yb)N地化指标显示悬浮物颗粒总体表现为沉降缓慢,沉积速率低,由下至上泥岩悬浮物沉积速率表现为由高到低的变化趋势。同时,δCe、δEu及La/Lb-∑REE判别图解,指示长7、长8油层组泥岩母岩以花岗岩为主,同时有少量碱性玄武岩的混入,源区构造背景为大陆边缘环境。     

Preliminary evaluation of hydrochemistry of the Kalambaina Formation, Sokoto Basin, Nigeria

Hydrochemical investigations in the Kalambaina Formation have been initiated to determine potability and suitability of the shallow groundwater for domestic and agricultural uses. This limestone formation is an extensive aquifer supplying water to livestock and domestic wells in its outcrop areas. The aquifer is recharged by rainfall and discharges mainly into the Sokoto–Rima River system and lakes at Kware, Gwadabawa and Kalmalo in Nigeria. Because recharge to the aquifer is mainly from rainfall, the quality of the groundwater is controlled essentially by chemical processes in the vadose zone and locally by human activities. Water samples were taken at 11 sites comprising boreholes, dug wells and a spring and were chemically analysed for their major ion components. Hydrochemical results show water of fairly good quality. It is, however, hard and generally of moderate dissolved solids content. Concentration of the total dissolved solids is between 130 and 2,340 mg/l. Concentrations of ions vary widely but a high concentration of K⁺ is found in places. NO₃⁻ is on the higher side of the World Health Organization (WHO) permissible limits, indicating pollution in such areas. Groundwater chemistry is predominantly of two facies, namely the calcium–magnesium–bicarbonate and calcium–magnesium–sulphate–chloride facies. These facies probably evolved primarily as a result of dissolution of calcium and magnesium carbonates as well as some human/land-use activities.     

沁水盆地原始水动力场类型及其对煤层气排采的影响

水动力场研究在煤层气勘探开发中具有重要作用。本文首先讨论了基于煤层气井排采资料的水动力场研究方法,在分析沁水盆地柿庄区块原始水动力场特点的基础上,结合前人在盆地其他区块水动力场的研究成果,分析了沁水盆地原始水动力场的类型,进而探讨了水动力场类型对煤层气排采的控制作用。研究表明:沁水盆地自边缘向腹部依次存在重力驱动型、滞流型和压实驱动型三种类型的区域原始水动力场;重力驱动型和滞流型水动力场具备煤层气保存条件,含气量高,煤层气排采效果相对较好,而压实驱动型水动力场虽具备一定的保存条件,但因地层压力较高,煤层气井排水降压困难,产气效果较差;无论是在重力驱动型还是滞流型的区域水动力场中,局部的低势汇聚区具备煤层气保存和排采的有利条件,煤层气开发效果一般较好。在未来煤层气勘探开发过程中,应将重力流驱型或滞流型水动力场所在区域中的局部低势汇聚区作为煤层气开发的甜点区。     

四川盆地陆相侏罗系白垩系界线问题探讨

侏罗系/白垩系界线是国际地层年表中少有几个未定全球界线层型（GSSP）之一。传统上依据菊石类生物将Berriasian阶底界定义为白垩系的底界。国际上西北太平洋Shatsky Rise的Berriasian阶最底部玄武岩岩床的同位素年代学年龄为145 Ma,从而为侏罗系/白垩系界线提供了最接近的年龄估计值。在国际上,地层对比划分大都根据海相地层,中国广泛发育的陆相侏罗系/白垩系,难以与国际标准地层对比。中国四川盆地以陆相生物为标志的界线划分与国际年代地层对比困难,导致对四川盆地陆相侏罗系/白垩系界线问题的认识长期未有更新。根据陆相生物对比结果的同时,结合考虑同位素测年、磁性地层和旋回地层,有望获得良好的效果。基于同位素测年数据和陆相生物对比分析,在遂宁组中发现了最年轻的~120 Ma的碎屑锆石U-Pb年龄,而且该套地层与国际对比的核心证据介形类的研究也有新的发现,表明遂宁组有可能属于白垩系而非原认为的侏罗系。将沙溪庙组和遂宁组作为侏罗系/白垩系过渡地层系统研究,有可能在该套地层内部发现界线标志。      

抚顺盆地油页岩地质特征及其成矿过程

抚顺盆地位于郯庐断裂带北延东支[CD2]抚顺[CD1]密山断裂带上,盆内赋存有厚达200 m的巨厚油页岩层,按含油率高低,可分为上部富矿层和下部贫矿层。富矿层中水平层理发育,含油率多为5%~8%,最高可达12%;贫矿层中层理很少,多数层段含油率小于3%。地球化学分析结果显示,油页岩中有机碳含量较高,最高可达13.1%。油页岩属Ⅰ[CD*2]Ⅱ型干酪根,成熟度较低。整个含油页岩岩系的形成经历了盆地初始裂陷、加速裂陷、稳定发育、较快速裂陷、较慢速裂陷、终止裂陷6个阶段。综合分析表明,油页岩贫矿层形成于盆地周缘夷平程度较高、物源供给较少、盆地基底沉降相对较快、有机质堆积比例较低的浅湖环境;油页岩富矿层形成于盆地周缘夷平程度较高、物源供给较少、盆地基底沉降速率相对缓慢、有机质堆积比例相对较高的浅湖环境。     

Geochemical fractionation of Ni,Cu and Pb in the deep sea sediments from the Central Indian Ocean Basin: An insight into the mechanism of metal enrichment in sediment

Metal speciation study in combination with major element chemistry of deep sea sediments provided possible metal enrichment pathways in sediments collected from environmentally different locations of Central Indian Ocean Basin (CIB). Metal speciation study suggests that Fe–Mn oxyhydroxide phase was the major binding phase for Ni, Cu and Pb in the sediments. The second highest concentrations of all these metals were present within the structure of the sediments. Easily reducible oxide phase (within the Fe–Mn oxyhydroxide binding phases) was the major host for all the three metals in the studied sediments. Major element chemistry of these sediments revealed that there was an increased tendency of Cu and Ni to get incorporated into the deep sea sediment via the non-terrigenous Mn-oxyhydroxide fraction, whereas, Pb gets incorporated mostly via amorphous Fe-hydroxides into the sediment from the CIB. This is the first attempt to provide an insight into the mechanism of metal enrichment in sediment that host vast manganese nodule.