西藏冈底斯中段桑桑花岗质岩体锆石U-Pb年龄与Hf同位素组成及其对岩石成因和构造演化的制约

以西藏冈底斯中段西侧桑桑花岗质岩体为对象,进行了系统的年代学、元素地球化学和锆石Hf同位素组成研究,据此阐明了岩体成因,并探讨了其构造意义。锆石LA-ICP-MS U-Pb定年表明,桑桑花岗质岩体的成岩年龄为49~54 Ma。化学组成上,岩体具有亚碱、准铝、贫磷的特征(A/NKC1.10,P_2O_50.20%),属钙碱性I型花岗岩类。岩体富Cs、Rb、Ba、Th、U、K、Pb和轻稀土,贫Nb、Ta、P与Ti,表现出弧岩浆岩的地球化学特征。岩体的锆石εHf(t)值变化较大,散布于正值与负值之间(=-4.24~+5.49),指示其形成存在不同来源物质的贡献。综合分析表明,桑桑花岗质岩体起源于初生地壳的部分熔融,但在成岩过程中有古老地壳组分的参与。结合区域地质背景,笔者认为这一古老地壳组分最可能来自印亚碰撞过程中俯冲下插的印度地壳,由此说明印度-欧亚大陆碰撞的起始时间应早于54 Ma。     

香草坪花岗岩体年代学和地球化学特征

香草坪岩体主要岩性为中粗粒斑状黑云母花岗岩,SHRIMP锆石U-Pb法年龄为211±2Ma,属于印支期岩浆作用产物。岩石地球化学特征研究表明,其ACNK,微量元素模式图曲线形态总体向右倾,以及轻稀土富集、Eu明显亏损的稀土配分模式曲线特征,与华南S型花岗岩的地球化学特征相似。该岩体高(87Sr/86Sr)i和低εNd(t)的特点,表明其可能是前寒武系中等成熟度的基底岩石经部分熔融形成的。该区基底岩石较高的铀含量,可为香草坪岩体提供充足的铀元素,形成铀元素的初始富集。     

内蒙古四子王旗黑脑包岩体年代学与地球化学特征及其构造演化

内蒙古四子王旗黑脑包岩体位于华北板块北缘早古生代增生造山带,主要由花岗闪长岩和花岗斑岩组成。对花岗闪长岩进行La-ICP-MS锆石U-Pb定年,获得四子王旗黑脑包侵入岩体的2个侵位年龄为407.4±4.7 Ma和268.0±2.7 Ma,分别代表洋陆俯冲事件以及陆陆碰撞事件年龄。岩石地球化学数据显示,四子王旗黑脑包岩体属钙碱性系列,逐步向低钾拉斑系列靠近,并且亏损高场强元素。同位素地质年龄及地球化学数据表明,样品具有同碰撞花岗岩特征。结合区域大地构造背景认为,四子王旗黑脑包地区主要构造背景为西伯利亚板块与华北板块之间俯冲、碰撞和对接过程,属古亚洲洋构造域,而后期的构造演化还有待进一步研究。     

诸广山南部白云岩体岩石地球化学特征及成因

白云岩体位于诸广山南部岩体中东部,是一个重要的产铀岩体,其岩性为粗粒斑状黑云母花岗岩。在主量元素方面,该岩体的岩石富硅（SiO2平均为73.47%）、富铝（A/CNK值平均为1.09）和高的K2O/Na2O值（平均为1.99）;在微量元素方面,富集大离子元素Rb、Th,而Ba、Sr、Ti、Nb、Ta、P亏损明显,具有高的Rb/Sr（平均为6.22）和Rb/Nb值（平均为29.07）,富含铀（平均为9.04×10-6）,可为岩体内铀矿床的形成提供铀源;轻稀土元素富集和轻、重稀土元素分馏相对明显,稀土元素配分曲线呈右倾型,Eu亏损明显;在同位素方面,εNd（t）值低（平均为-10.6）,（87Sr/86Sr）i值高（平均为0.71688）,Nd模式年龄古老（1865～1874 Ma）。这些特征表明,白云岩体属于典型的壳源型花岗岩,是在华南地块和印支地块碰撞结束后不久形成的伸展构造环境中,位于地壳中-下部的古-中元古代地壳组分在伸展、减薄作用产生的减压、导水和地幔上涌等因素的综合影响下,由泥质岩源区发生部分熔融而形成。     

湘南中山地区中棚岩体地球化学特征与铀成矿

通过对中棚岩体地球化学特征的研究,探讨其与铀矿化的关系。中棚岩体属于过铝质花岗岩,高钾钙碱性岩石系列。分析认为,岩体具有S型花岗岩特征,为陆壳物质部分熔融的产物,原岩可能为寒武系浅变质砂岩。构造环境判别认为,岩体属于后碰撞花岗岩范畴,在岩石圈伸展作用构造环境下由寒武系部分熔融所形成。岩体的原岩铀含量较高,为富铀的中棚岩体形成奠定了基础,也为后期成矿提供了充足的铀源。     

Constraining the timing of porphyry mineralization in northwest Iran in relation to Lesser Caucasus and Central Iran; Re–Os age data for Sungun porphyry Cu–Mo deposit

The Neo-Tethyan subduction in Iran is characterized by the Urumieh–Dokhtar magmatic arc (UDMA), formed by northeast-ward subduction of the oceanic crust beneath the central Iran. This belt coincides with the porphyry copper metallogenic belt that comprises several metallogenic zones, including Ahar–Jolfa in northwest Iran. The Ahar–Jolfa metallogenic zone encompasses two main batholiths of Qaradagh and Sheyvardagh and numerous intrusive bodies of Cenozoic, which have produced many base and precious metal deposits and prospects. The former is considered as continuation of the Meghri–Ordubad pluton in South Armenian Block (SAB), which also hosts porphyry copper deposits (PCDs). The Sungun PCD is the largest occurrence in northwest Iran. Rhenium-Osmium ages of Sungun molybdenites are early Miocene and range between 22.9 ± 0.2 and 21.7 ± 0.2 Ma. Comparison of the ages obtained here with published ages for mineralization across the region suggests the following sequence. The earliest porphyry Cu–Mo mineralization event in northwest Iran is represented by Saheb Divan PCD of late Eocene age, which is followed by the second epoch of middle Oligocene, including the Cu–Mo–Au mineralization at Qarachilar and the Haftcheshmeh PCD. Mineralization in Sungun, Masjed Daghi, Kighal and Niaz deposits corresponds to the third mineralization event in northwest Iran. The first epoch in northwest Iran postdates all Eocene mineralizations in SAB, while the second epoch is coeval with Paragachay and the first-stage of Kadjaran PCDs. Its third epoch is younger than all mineralizations in SAB, except the second stage in Kadjaran PCD. Finally, the Cu mineralization epochs in northwest Iran are older than nearly all PCDs and prospects in Central Iran (except the Bondar Hanza PCD), altogether revealing an old to young trend along the UDMA and the porphyry Cu belt towards southeast, resulted from diachronous, later closure of the Neo-Tethyan oceanic basin in central and SE Iran.     

皖南泾县榔桥岩体锆石U-Pb定年、Hf同位素和地球化学特征及其找矿指示意义

安徽泾县榔桥花岗闪长岩体为分布于皖南台褶带北缘壳幔同熔型复式岩体。该岩体主侵入期两个花岗闪长岩样品和侵入后期脉岩一个花岗斑岩样品的锆石U-Pb年龄分别为135.6±1.8Ma,137.6±2.0Ma,136.4±1.9Ma,显示岩体形成于早白垩世。锆石Hf同位素分析表明榔桥岩体可能由中元古代地壳物质部分熔融形成,同时混染有少量古元古代地壳物质。根据全岩Zr含量计算出榔桥岩体花岗闪长岩"锆石饱和温度"为749~781℃,脉岩花岗斑岩"锆石饱和温度"为722~745℃,指示岩浆在成岩过程中快速冷却;元素地球化学研究显示,本区岩石在成岩过程中发生斜长石、钾长石以及副矿物磷灰石、钛铁矿的分离结晶作用。锆石Ce(Ⅳ)/Ce(Ⅲ)比值计算表明榔桥岩体成岩过程中的高氧逸度有利于该区域发生Cu-Au矿化,而斜长石的分离结晶使得EuN/EuN*比值降低,为0.2~0.4。榔桥岩体具有富集大离子亲石元素以及Pb,亏损高场强元素(Nb、Ta、Zr,Ti),以及轻重稀土发生明显的分异,轻稀土相对重稀土明显富集的特征,与岛弧岩浆岩类似;大地构造背景判别表明该岩体的形成与古太平洋板块对欧亚大陆的俯冲碰撞作用密切相关。     

湘东北栗山铜铅锌多金属矿床热液萤石稀土元素地球化学特征及其指示意义

江南造山带中段幕阜山地区栗山大型铜铅锌多金属矿床中伴生规模可观的萤石资源, 储量达41.5万t。该区萤石形成过程与机制尚缺乏有效约束, 制约了对其矿床成因机制的认识和找矿实践。本文通过栗山绿色、紫色及蓝色萤石组构分析、荧光测试和ICP-MS微量元素含量分析, 探讨栗山矿床成矿过程与物理化学环境。岩相学与矿相学证据指示栗山热液活动可划分为四个阶段: 乳白色石英+少量绿色萤石(Ⅰ), 蓝色、紫色萤石+石英+绿泥石+金属硫化物阶段(Ⅱ), 石英+绿色萤石+绿泥石+金属硫化物阶段(Ⅲ)以及石英+方解石阶段(Ⅳ)。各颜色萤石Diamond View荧光测试结果显示深紫色萤石荧光最弱, 蓝色萤石次之, 绿色萤石荧光最强。绿色萤石的∑REE高于蓝色、紫色萤石, 且绿色萤石LREE相对富集而蓝色、紫色萤石HREE相对富集, 表明成矿Ⅱ阶段至Ⅲ阶段成矿温度整体降低且pH值升高。Tb/Ca-Tb/La以及Y/Ho-La/Ho图解指示不同颜色萤石属同源岩浆流体和大气降水产物, 栗山萤石的沉淀机制主要为水岩反应并伴随流体混合。

     

赣杭构造带灵山花岗岩体黑云母的矿物化学特征及其对岩石成因的指示意义

灵山花岗岩体在平面上为一环状分布的侵入体,中心为角闪石黑云母花岗岩,外围为黑云母花岗岩。在角闪石黑云母花岗岩中分布有大量的暗色镁铁质微粒包体。黑云母是大多数中酸性火成岩中比较重要的一种镁铁质矿物,它能很好地反映寄主岩浆的属性和成岩时的物理、化学条件,因此,本文对这两种花岗岩及镁铁质微粒包体中的黑云母开展了系统的岩相学观察和电子探针化学组成研究,探讨灵山岩体的物质来源、成岩条件和岩浆的混合作用过程。研究结果表明两种花岗岩体的黑云母具有不同化学成分,而暗色镁铁质微粒包体中黑云母的化学成分则变化较大。三种黑云母均在低氧逸度条件下晶出。两种花岗岩中的黑云母均富Fe贫Mg,属于铁质黑云母,含铁系数[(Fe~(3+)+Fe~(2+))/(Fe~(3+)+Fe~(2+)+Mg~(2+))]分别为0.65~0.70,0.72~0.78,FeOT/MgO均接近7.04。MF值[2×Mg/(Fe~(2+)+Mg+Mn)]分别为0.64~0.76和0.48~0.60,指示两种花岗岩的物质来源都是以壳源为主。镁铁质微粒包体中黑云母的MF值变化范围比较大,为0.63~1.06,为铁质黑云母到镁质黑云母,暗示包体岩浆经历过不同程度的岩浆混合作用。镁铁质微粒包体中部分黑云母与角闪石黑云母花岗岩中黑云母的结晶条件相似,而部分则有明显差异,推测是由于基性的镁铁质包体岩浆注入到酸性的花岗岩浆是一个连续多阶段的过程。     

Mesoproterozoic Continental Arc Type Granite in the Central Tianshan Mountains: Zircon SHRIMP U-Pb Dating and Geochemical Analyses

The Central Tianshan belt in northwestern China is a small Precambrian block located in the southern part of the Central Asia Orogenic Belt （CAOB）, which is considered as ＂the most voluminous block of young continental crust in the world＂ that comprises numerous small continental blocks separated by Paleozoic magmatic arcs. The Precambrian basement of the central Tianshan Mountains is composed of volcanic rocks and associated volcano-sedimentary rocks that were intruded by granitic plutons. Geochemical analyses demonstrate that the granitic plutons and volcanic rocks were generated in the Andean-type active continental arc environment like today＇s Chile, and the zircon U-Pb SHRIMP dating indicates that they were developed at about 956 Ma, possibly corresponding to the subduction of the inferred Mozambique Ocean under the Baltic-African super-continent.