滇池农村固体废物和化肥流失治理试验研究

怎样合理处置农村固体废物和减少农田化肥流失一直是农村面源污染控制的难题之一。该研究将农村固体废物的处理与减少化肥施用措施有机结合，利用微生物复合发酵剂和农村固体废物生产活性肥料，开展了一系列农业种植试验和数据监测，在此基础上，提出了一套实用性强、效果好的控制农业固体废物和化肥流失污染的对策措施。     

用废聚苯乙烯泡沫制备胶粘剂

本文研究了回收废旧聚苯乙烯(PS)泡沫塑料制备PS胶粘剂的方法。以废旧聚苯乙烯泡沫塑料为主要原料,选择低毒性、相溶性好的有机溶剂,使其溶解,再与聚乙烯醇(PVA)水溶液共混,制得水包油乳液。加入不同改性材料,制得改性胶粘剂。     

高速公路下伏某煤矿采空区地质特征及注浆充填法治理研究

煤矿采空区是工程建设中不良地质条件之一，其地质特征评价和如何治理是两个关键问题。笔者结合高速公路建设中某采空区的治理实践，对这两方面进行了探索，对工程建筑中所遇各类采空区的地质特征评价及其治理方法有一定借鉴意义。     

光催化氧化法处理难降解废水的研究进展

综述了光催化氧化处理难降解废水的研究现状及发展趋势。介绍了影响光催化氧化反应速率的因素及光催化氧化法在处理难降解废水中的应用。     

地下非均匀非饱和带中地下洞室的渗流问题数值模拟--介质参数的灵敏度分析

影响任何一个地下废物处置场所长期行为的一个重要因素是进入地下废物贮置洞室内的渗流量的大小，预测地下洞室中的渗流量是困难的，特别是当地下废物贮置洞室位于非均质非饱和带中，三维数值模型用于研究地下非均质中非饱和流动及流入地下洞室中的渗流量，讨论了非均质模型与均质模型的比较以及数值剖分尺度对计算结果的影响，进入洞室中的渗漏率随着引入系统中入渗量的增加而增大，选用4个参数来衡量渗流场的非均质程度：(1)介质的平均渗透率K0；(2)Van Genuchten参数α；(3)渗透率空间分布相关尺度；(4)渗透率空间分布变化的标准差σ，根据一个随机实现的渗透率分布，通过改变平均渗透率来研究其对流入洞室中渗透量的影响，对一个固定的入渗率而言，流入洞室中的渗漏率将随着Van Genuchten参数α的减小而减小，模拟结果表明流入洞室的渗漏率与介质的平均渗透率相关，即随平均渗透率的增大，流入洞室的渗漏率亦增大，流入洞室的渗漏率还高度依赖于非均质渗透率场的空间分布相关长度与标准差，一个大的相关长度或高的标准差均能导致流入洞室的渗漏率增大。     

Implications of Analcime Hydrothermally Formed from Na-alumino-borosilicate Glasses Containing Cs and Sr for the Stability of High-level Radioactive Waste Form

Abstract. In order to know the behaviors of radioactive elements such as cesium and strontium during a hydrothermal alteration of borosilicate glass of radioactive waste, some alumino-borosilicate glasses belonging to the systems Na₂O-Al₂O₃-B₂O₃-SiO₂-SrO, Na₂O-Al₂O₃-B₂O₃-SiO₂-Cs₂O and Na₂O-Al₂-O₃-B₂O₃-SiO₂-SrO-Cs₂O have been treated hydrothermally at 200C under a vapor pressure of 1.54 MPa. The result shows that all glasses are changed into crystalline phases with running time up to 60 days, and that analcime-type zeolite is formed as a major product. The formed zeolite is shown to contain cesium and/or strontium. Considering the fact that natural zeolite occurs in wide physicochemical conditions including hydrothermal one, the analcime-type zeolite is expected to fix stably the radioactive elements in the disposal site. Since aluminum is necessary for the formation of the analcime-type zeolite, the waste glass should have aluminum as one of major components.     

Coal mining along the Warfield Fault, Mingo County, West Virginia: a tale of ups and downs

Mine development along a 15-mile (24 km) section of the Warfield Fault in Mingo County, West Virginia has broadened the geological understanding of the fault and its related structures. The fault has been exposed in two new road cuts, one in the northeast-trending segment at Neely Branch and one in the eastern east-trending segment at the head of Marrowbone Creek. Both exposures show a well-defined normal fault with a 45° to 55° N dip, juxtaposing sandstone/shale packages from the roof and the floor of the Coalburg seam. The fault is associated with a thin gouge zone, some drag folding, and parallel jointing. Its trace tends to run parallel to the crest of the adjacent Warfield Anticline. Based on underground mine development and detailed core drilling, the vertical offset along the fault plane ranges from a maximum of 240 ft (73 m) in the central part of the area near the structural bend to less than 100 ft (30 m) in western and eastern directions. The fault is located along the relatively steeply dipping (locally in excess of 25%) southern limb of the Warfield Anticline, and appears related to a late phase of extension involving folded Pennsylvanian strata. On a regional scale, the lithological variations across the fault do not suggest any appreciable strike-slip component.Underground room and pillar mines in the Coalburg seam north and south of the fault have been greatly impacted by the Warfield structures. Due to the combined (and opposite) effects of the folding and faulting, the northern mines are located up to 400 ft (125 m) higher in elevation than the southern ones. Overland conveyor belts connect mining blocks separated by the fault. The practical mining limit along the steep slopes toward the fault is around 15%. Subsidiary normal faults with offsets in the 5- to 15-ft (1.5–4.5 m) range are fairly common and form major roof control and production hurdles. Overall, the Warfield structures pose an extra challenge to mine development in this part of the Appalachian Coalfields.     

Surface analysis of pyrite in the No. 9 coal seam, Wuda Coalfield, Inner Mongolia, China, using high-resolution time-of-flight secondary ion mass-spectrometry

The chemical composition of pyrite in coal can be used to investigate its geological and mineralogical origin. In this paper, high-resolution time-of-flight secondary ion mass spectrometry (TOF-SIMS) was used to study the chemical composition of various pyrite forms in the No. 9 coal seam (S_t,d=3.46%) from the Wuda Coalfield, Inner Mongolia, northern China. These include bacteriogenic, framboidal, massive, cell-filling, fracture-filling, and nodular pyrites. In addition to Fe⁺ (⁵⁴Fe⁺, ⁵⁶Fe⁺, ⁵⁷Fe⁺), other fragment ions were detected in bacteriogenic pyrites, such as ²⁷Al⁺, Si⁺ (²⁸Si⁺, ²⁹Si⁺, ³⁰Si⁺), ⁴⁰Ca⁺, Cu⁺ (⁶³Cu⁺, ⁶⁵Cu⁺), Zn⁺ (⁶⁴Zn⁺, ⁶⁶Zn⁺, ⁶⁷Zn⁺, ⁶⁸Zn⁺), Ni⁺ (⁵⁸Ni⁺, ⁶⁰Ni⁺, ⁶²Ni⁺), and C₃H₇⁺. TOF-SIMS images show bacteriogenic pyrites are relatively rich in Cu, Zn, and Ni, suggesting that bacteria probably play an important role in the enrichment of Cu, Zn, and Ni during their formation. Intense positive secondary ion fragments from framboidal aggregates, such as ²⁷Al⁺, ²⁸Si⁺, ²⁹Si⁺, AlO⁺, CH₂⁺, C₃H₃⁺, C₃H₅⁺, and C₄H₇⁺, indicate that formation of the framboidal aggregates may have occurred together with clay mineral and organic matter, which probably serve as the binding substance. The intense ions of ²⁸Si⁺ and ²⁷Al⁺ from massive pyrites also suggest that their pores incorporated clay minerals during crystallization. Together with the lowest ²⁸Si⁺/²³Na⁺ value, the intense organic positive secondary ion peaks from cell-filling pyrites, such as C₃H₃⁺, C₃H₅⁺, C₃H₇⁺, and C₄H₇⁺, indicate that pyrite formation may have accompanied dissolution or disintegration of the cell. The intense P⁺ peak was observed only in the fracture-filling pyrite and the highest ²⁸Si⁺/²³Na⁺ value of fracture-filling pyrite reflects its epigenetic origin. Together with XRD and REEs data, the stronger ⁴⁰Ca⁺ in nodular pyrite than other pyrite forms shows seawater influence during its formation.     

用卫星高光谱数据提取江西德兴铜矿矿山废水的pH值污染指标

在对德兴铜矿矿山废水的光谱特征深入分析研究的基础上,总结了不同类型水体(酸性水、碱性水以及河流水)的特征光谱,并利用地物谱特征开展矿山废水pH值污染指标提取研究。针对水体光谱反射率低、特征光谱不明显的特点,采用矿区卫星Hyperion高光谱数据,应用ISA算法和掩膜技术识别出水体分布并进一步与MNF变换有效结合,根据波段散点图进行不同pH值水体的有效分割。为矿山废水污染的诊断和监测提供了新技术和理论支撑。     

Evidence of early generation of liquid hydrocarbon from suberinite as visible under the microscope

The early generation of liquid hydrocarbons from suberinite can be clearly observed under the microscope. The generation of this oil-like material, mainly in the form of exsudatinite, from the maceral suberinite occurs at a maturity level of about 0.4% vitrinite reflectance. Hydrocarbons appear to be naturally expelled from coal initially through sweating and agglomeration of suberinite which subsequently forms exsudatinite. It is suggested that extensive expulsion of exsudatinite causes cracks to develop in vitrinite whereas limited expulsion of exsudatinite will only impregnate the vitrinite matrix. If cracks are formed, it is possible they could progressively develop to form an exsudatinite-crack network. The formation of such a network is believed to represent an effective way of hydrocarbon expulsion from coal source rocks.