利用铀矿床进行天然类似物研究

天然类似物研究是国际上新兴起的一门边缘科学。本文结合我国实际情况，综述研究的意义以及我国开展这项研究的有利条件、课题优选和具体开发内容。     

瑞典硫化物矿山尾矿淋滤水的控制

在瑞典,硫化物矿尾矿污染水的淋滤造成巨大的环境污染问题。本文概述一项利用天然土覆盖尾矿、最大限度地减少淋滤水的调查报告。研究表明,天然土渗水性是如此之高,以致于起不到明显的隔水效果。天然土盖层只能减少高降雨量期或迅速化雪期的渗水量,而且只对淋滤水峰值有作用。但是,作为一种蓄水体,位于尾矿顶部的密封盖层具有重要意义,它可以增加蒸腾损失。     

包气带黄土环境研究与放射性废物处置

黄土中的粘粒含量较高、比表面积较大、吸附性较强、阳离子交换容量也较高,这些因素对迟滞放射性核素的迁移有利。而且黄土的非饱和渗透系数K(θ)远远低于它的饱水渗透系数K_(?)。使得放射性核素在黄土中的迁移很慢。因此,包气带黄土作为中、低放射性废物处置库的环境屏障是可行的。     

利用尾矿废石制造微晶玻璃花岗岩的投资可行性分析

在论述尾矿废石利用现状的基础上,对利用尾矿废石制造微晶玻璃花岗岩的投资可行性进行了分析,提供了一套可用于此类决策的分析方法。     

城市垃圾填埋场粘土基防渗浆材的实验研究

文章研制了一种低渗透系数并对污染物有一定吸附阻滞作用的浆材,即膨润土-粉煤灰-水泥(BFS)浆材,用于垃圾填埋场以防治渗沥液渗漏污染周围地下水和土壤。通过正交试验优选出了以膨润土为主的配方:膨润土22%~25%、粉煤灰20%~23%、水泥15%~18%、纯碱1.2%~1.4%、稀释剂TMH加量0.3%~0.45%。该浆材结实率大于99.6%,固结体28d渗透系数小于0.8×10-7cm/s,无侧限抗压强度小于2.0MPa,渗透系数比一般水泥粘土浆材降低约2个数量级。通过采自长春某垃圾填埋场的渗沥液进行固结体的渗透试验,该浆材的固结体对CODCr、氨氮和磷的吸附阻滞率均达到了82%以上。文章的创新点在于浆材配方的选材不但考虑了降低固结体渗透系数,使其符合规范要求,而且考虑了材料成分对渗沥液中污染物的吸附阻滞作用,同时降低了固结体的抗压强度和脆性,使其有一定的塑性和韧性,以适应填埋场的地基变形。     

山西晋城矿区成庄井田3号煤储层的物性研究

对研究区内3号煤储层的几何形态、割理和孔隙系统进行了研究,并引入了储层结构综合指数(SI)来评价研究区内煤层透气性特征和甲烷运移能力,并得出了如下结论:①全区煤层厚度稳定,是煤层甲烷的良好储集层;②根据全区割理发育程度推测出,构造主应力来自NE-SW方向;③通过孔隙系统研究,3号煤层基本上属于非渗透性储层;④成庄井田3号煤层结构综合指数(SI)等值线平面图,显示了煤层透气性由东北向西南呈逐渐变差的趋势。     

Properties and depositional environment of the Neogene Elhovo Lignite, Bulgaria

Several Mio-Pliocene aged lignite seams occur as part of a non-marine transgressive sequence in the Elhovo graben in south-eastern Bulgaria. The present study is focused on 45 samples collected from three boreholes in the eastern part of the basin. Petrographic data along with ash and sulphur contents were used in order to determine the lateral and vertical variations of the coal facies and depositional environment of the Elhovo lignite.The lignite seams accumulated in a rheotrophic, low-lying mire with high pH value and are characterized by high ash yields and sulphur contents. Despite of the neutral to weakly alkaline environment the bacterial activity was limited and the tissue preservation and gelification were mainly controlled by the redox conditions.Vegetation rich in decay resistant conifers dominated in the Elhovo basin together with mesophytic angiosperm species. The absence of algal remains and sapropelic coal indicated that open water areas were not present during peat accumulation. The latter processed in an environment, characterized by low subsidence rate, in which prior to the burial the woods were subjected to severe mechanical destruction. According to our interpretation, the enhanced impregnation of the tissues bacteria and fungi played only a secondary role in the process of humification. The lignite from borehole 122 and partly from BH 145 deposited in an environment characterized by relatively low (ground)water table, whereas to the south an area dominated by a flooded forest swamp (BH 104) formed. This is suggested by the better tissue preservation and gelification of the organic matter in BH 104. The vertical variation of the maceral composition in the studied lignite is interpreted as a consequence of vegetational changes, rather than to changes in the depositional environment. The low contents of inertinite macerals indicate that despite of the low water level the environment was relatively wet and the thermal and oxidative destruction of the tissues was limited.Peat accumulation was terminated by a major flooding event and a short term establishment of a lake. In contrast to the West Maritsa basin, no seam formed in the Elhovo basin during the filling stage of the lake.     

Trace elements in the Goze Delchev coal deposit, Bulgaria

The geochemistry of trace elements in the underground and open-pit mine of the Goze Delchev subbituminous coal deposit have been studied. The coals in both mines are highly enriched in W, Ge and Be, and at less extent in As, Mn and Y as compared with the world-wide Clarkes for subbituminous coals. Ni and Ti are also enhanced in the underground coals, and Zr, Cr and Mo in the open-pit mine coals.Characteristic for the trace element contents in the deposit is a regular variation with depth. The following patterns were distinguished for profile I: a — the element content decreases from the bottom to the top of the bed paralleling ash distribution (Fe, Co, As, Sb, V, Y, Mo, Cs, REE, Hf, Ta, Th, P and Au); b — Ge and W are enriched in the near-bottom and near-top coals; c — in the middle part of the bed the content of K and Rb is maximal, while that of U is slightly enriched; d — Ba content decreases from the top to the bottom of the bed. In profile II, W and Be contents decrease from the bottom to the top. The near-bottom, and especially the near-roof samples of profile IV are highly enriched in Ge, while for W the highest is the content of the near-bottom sample.Ge, Be, As, Mn, Cl and Br are mainly organically associated. The organic affiliation is still strong for Co, B, Sr, Ba, Sb, U, Th, Mo, La, Ce, Sm, Tb and Yb in the underground coals, and Fe, Co, Na, W, Sr, Y and Ag in the coals from the open-pit mine. K, Rb, Ti, Zr, Hf and Ta are of dominant inorganic affinity. The chalcophile and siderophile elements correlate positively with Fe and each other and may be bound partly with pyrite or other sulphides and iron containing minerals.Compared statistically by the t-criteria, the elements Na, Li, Cu, Zn, Pb, Cr, Ni, Co, Mo, Fe and Be are of higher content in the open-pit mine. Tungsten is the only element of higher concentration in the underground mine. The contents of Ge, As, Sr, V, Mn, Y, Zr and P are not statistically different in both mines.It was supposed that there were multiple sources of the trace elements in the deposit. The source of the highly enriched elements (W, Ge, Be, and As) most probably were the thermal waters in the source area. The contemporary mineral springs are of high content of these elements. Another source were the hosting Mesta volcanic rocks, which are enriched in Sb, Mo, Hf, U, Th, As, Li and Rb. Some of the volcanics were hydrothermally altered and enriched or depleted of many elements. Thus, the hydrothermal solutions were also suppliers of elements for the coals. It is obvious that the contents, distribution and paragenesis, of the trace elements in both Goze Delchev coals reflect the geochemical specialization of the source area, including rocks, paleo- and contemporary thermal waters.     

Control and prevention of gas outbursts in coal mines, Riosa–Olloniego coalfield, Spain

Underground coal mines have always had to control the presence of different gases in the mining environment. Among these gases, methane is the most important one, since it is inherent to coal. Despite of the technical developments in recent decades, methane hazards have not yet been fully avoided. This is partly due to the increasing depths of modern mines, where methane emissions are higher, and also to other mining-related circumstances, such as the increase in production rates and its consequences: difficulties in controlling the increasing methane levels, increasing mechanization, the use of explosives and not paying close attention to methane control systems.The main purposes of this paper are to establish site measurements using some critical parameters that are not part of the standard mining-control methods for risk assessment and to analyze the gas behavior of subvertical coal seams in deep mines in order to prevent gas incidents from occurring. The ultimate goal is the improvement in mining conditions and therefore in safety conditions.For this purpose, two different mines were instrumented for mine control and monitoring. Both mines belong to the Riosa–Olloniego coalfield, in the Asturias Central Basin, Spain and the areas instrumented are mined via subhorizontal sublevels at an actual depth of around 1000 m under the overburden of Mount Lusorio.During this research, a property favoring gas outbursts was site measured for the first time in an outburst-prone coal (8th Coalbed), gas pressure and its variations, which contributed to complete the data available from previous characterizations and to set some guidelines for assessing the potential outburst-prone areas. A gas-measurement-tube set has been designed for measuring gas pressure as well as its variation over time as a result of nearby workings and to calculate permeability.The paper establishes the effect of overlapping of works, but it also shows the efficacy of two preventive measures to be applied: high pressure water infusion and the exploitation of a protective coal seam (7th Coalbed), that must be mined preferably two complete sublevels before commencing the advance in the outburst-prone coalbed. Both measures constitute an improvement in the mining sequence and therefore in safety, and should be completed with a systematic measurement to control the risk: gas pressure in the 8th Coalbed in the area of influence of other workings, to establish the most suitable moment to renew the advance. Further researches could focus on ascertaining the permeability, not only in mined areas but also in areas of the mine that are still not affected by mining work and on tuning more finely the ranges of influence of overstress time and overlap distance of the workings of the 7th Coalbed in the 8th Coalbed.     

中国城市固体废弃物甲烷排放研究

The greenhouse effect of methane (CH4) is only inferior to that of carbon dioxide (CO2). As an important anthropogenic emission source, the calculation of the emission amount of CH4 from waste treatment in landfills plays an important role in compiling greenhouse gases inventory and in estimating the climate change effects caused by increasing of greenhouse gases. Based on the previous work, and according to the sampling and analysis on municipal solid waste (MSW) in typical cities, the degradable organic carbon (DOC) percentile was identified in typical cities in recent years. According to the IPCC greenhouse gases inventory guideline and default method of CH4 emission from MSW landfills, and in light of MSW managing situation in different regions, the amount of CH4 emission was calculated. The results show that the amount of CH4 emission decreases geographically from east to west and it increases temporally from 1994 to 2004 in China.