The Varre-Sai chondrite,a Brazilian fall: petrology and geochemistry

The Varre-Sai meteorite fell along the border of the states of Espirito Santo and Rio de Janeiro, Brazil; on 19 June 2010 at 5:40 pm. Petrography and X-ray powder diffraction (XRD) indicate that the rock is an L5 S4 chondrite, with blastoporphyritic texture that has not been previously described. Geochemical data based on major and rare-earth elements (REEs) show that Varre-Sai is highly similar to the other L chondrites. In Harker diagrams, Varre-Sai, L, and LL chondrites form a single group, suggesting no significant chemical differences between them and contributing to the long-standing debate of whether LL chondrites form a distinct group or whether they are a subset of the L group. Harker diagrams also define a trend from E to H and L/LL chondrites, similar to the cosmochemical trends suggested by other authors. The behaviour of Fe₂O_3t and NiO indicates a relationship with Fe-Ni alloys, and their trend in the diagram suggests some chemical differentiation in the ordinary chondrite parental bodies. The REE content in Varre-Sai, normalized to C chondrites, falls in the field of L chondrites and others, but with slight REE enrichment. The chemical differences in chondrites, mainly in REEs, Fe₂O_3t and NiO could be alternatively interpreted as variations in the inherited agglutinated materials as chondrules, Ca–Al-rich inclusions and Fe–Ni nodules.     

布雅煤矿一井田煤中硫的特征及脱硫方法

从宏观、微观和煤化学几个方面 ,研究了新疆和田县布雅煤矿一号井田主采煤层中硫的赋存形态、含量、变化规律及成因。并提出几种脱硫方法 ,对煤矿生产出质量好的洁净煤 ,有一定的参考价值     

Types of Enclaves and Their Features and Origins in Intermediate-Acid Intrusive Rocks from the Tongling District, Anhui Province, China

Enclaves in intermediate-acid plutons from Tongling can be divided into three types: xenoliths, relics and magmatogenic enclaves. The magmatogenic enclaves consist of cumulates, micrograined dioritite mixtite and dioritic chilled border enclaves. Petrologically, relics with eyed and meta-poikilitic texture are characterized by high content of biotite (>80%) and low content of cordierite and grossular. The cumulates with accumulate texture consist of a great amount of pyroxene, hornblende and minor spinel and phlogopite. The micrograined dioritic mixtite is composed of more hornblendes and feldspar and less needle apatites and an ellipsoid basic core included in plagio-clase. The chilled border enclaves have the same mineral association, but more dark minerals than the host rocks consisting of plagioclase, quartz, alkaline feldspar, hornblende and biotite. Geochemically, the relics exhibit high REE content (455.8×10-6) and high ratio of LREE/HREE, more obvious Eu negative anomaly and are rich in Cr and     

Estimating the crush zone size under a cutting tool in coal

Summary As part of an effort to understand the mechanics of fine fragment formation in coal, which is important in studies of respirable dust due to mining, fracture toughness measurements and the strain energy density (SED) theory were applied to calculate the crush zone size under a cutting tool in coal. This zone is the major source of fine fragments in the 1 to 10 µm size range. The model used in these calculations is a boundary element program containing a failure criterion based on the SED theory. The boundary element program calculates linear elastic stresses at numerous points in the coal material ahead of a cutting bit. These stresses are then input to a subroutine called critical flaw length and orientation (CFLO) which uses the SED theory to determine the CFLO for a small crack at the boundary element stress computation point. The extent of crushing is based on earlier postulates about the role of inherent flaws in a fragmentation process. To form 1 to 10 µm fragments requires firstly a local stress strong enough to activate flaws with a characteristic length less than 1 to 10 µm and secondly, a flaw density sufficient to provide an average spacing between flaws also on the order of 1 to 10 µm. The locus of active 10 µm flaws represents the maximum possible extent of fine fragmentation in the 10 µm or less size range assuming that a sufficient inherent flaw density exists. The approach offers a first order approximation to the extent of crushing under a tool tip. The size and shape of the crush zone volume is affected by the attack angle and geometry of the tool.     

白云鄂博矿物岩石研究的新进展

本文论述了近年来白云鄂博矿区在旷物学、岩石学、地球化学和矿床成因研究方面的进展。在矿物学研究方面,除以往研究过的一百多种矿物外,八十年代中期以后,又相继发现并研究了含铌锐钛矿、含铌钙钛矿、锶铁钛石、水磷钙钍石、白云鄂博矿、未命名氟碳酸盐新种矿物、珀硅钛铈铁矿、硅钡镁石、带云母等矿物;发现了矿物间的共生和交代关系。在岩石学研究方面,找到了霓长岩,发现了霓长岩化作用,确定了火成碳酸岩岩石的存在。在地球化学和矿床成因方面,提出了稀土稀有金属矿化与火成碳酸岩岩浆活动有成因联系的见解。     

Correlation of T-log with E-log in coal-bearing formations

The profile of temperature gradient versus depth (T-log) has been found to be very useful for correlation with electrical resistivity log (E-log) in coal-bearing formations. A positive correlation between electrical resistivity and thermal resistivity is observed in coal sections whereas a negative correlation is found in sandstone/shale beds, thus helping in coal prospect evaluation. T logs have been used to correct the location of coal bed which had apparently been misinterpreted by the E-log. Hole to hole correlation of T-log and E-log is found to be excellent and it is observed that thermal resistivity characteristics of given formations remain fairly uniform. A rough estimation of coal grade is possible from the detailed study of the T-logs. Abrupt changes of temperature gradient as also its reversals have been observed in burnt coal sections.     

Source attribution of urban smog episodes caused by coal combustion

Stable weather conditions together with extensive use of coal combustion often lead to severe smog episodes in certain urban environments, especially in Eastern Europe. In order to identify the specific sources that cause the smog episodes in such environments, and to better understand the mixing state and atmospheric processing of aerosols, both single particle and bulk chemical characterization analysis of aerosols were performed in Krakow, Poland, during winter 2005.Real-time measurements of the bulk PM10 aerosol during a severe smog episode (PM10 mass > 400 µg m^− 3) showed a stable concentration of black carbon in the aerosol, and an increase in the sulphate and chlorine mass contributions towards the end of the episode. Chemical characterization of single particles further helped to identify residential coal burning as the main source that caused this severe smog episode, consisting of single particles with major signals for carbon with simultaneous absence of sulphate, chlorine and calcium. Particles from industrial coal combustion gained importance towards the end of that episode, after residential coal combustion was switched off, indicated by an increase of the percentage of sulphate and chlorine containing particles. Traffic was not a significant source during the severe smog episode. During a lighter smog episode, residential and industrial coal combustion was still predominant, with an increased contribution of traffic and processed/aged aerosols. On a clean day, particle classes containing nitrate were the most abundant. In addition, the aerosol was more internally mixed showing that there were more sources contributing to the total aerosol population.     

基于地震属性的煤层厚度预测模型及其应用

地震属性技术在岩性和构造解释等方面得到了越来越广泛的应用,特别是在煤、油气资源勘探中具有重要的作用.基于淮南矿区谢桥1区13-1煤层地震勘探资料,提取了28种地震属性数据;通过地震属性的分析,优选出平均峰值振幅、振幅的峰态、最大绝对振幅、瞬时频率斜率等4种地震属性作为煤层厚度预测模型基本参数,结合已知钻孔资料,利用多元多项式回归以及BP人工神经网络方法,求出了各属性与煤厚之间的多元多项式回归模型及人工神经网络模型,并对模型进行了误差分析和应用结果对比分析,反映出人工神经网络模型在煤厚预测中具有好的应用效果.     

Predisposition to Induced Seismicity in Some Czech Coal Mines

—Mining-induced seismicity associated with longwall face operations in the Ostrava- Karviná coal mines, Czech Republic, has been investigated in order to establish the conditions leading to a focal zone generation. The study, based on macroseismic and instrumental observations, proved that seismicity is influenced by natural as well as mining conditions. The first group includes the influence of faults, washouts and red beds, while the second one is represented by shaft and/or crosscut safety pillars and various types of remnant pillars. All the cases discussed show that many focal zones are generated in overstressed strata as a consequence of interaction of natural conditions and/or old workings with the active coal face. Received June 18, 1996, accepted March 10, 1997     

Characteristics of phosphate adsorption onto granulated coal ash in seawater

The deterioration of sediments is a serious environmental problem. Controlling nutrient release fluxes from sediments is important to alleviating eutrophication and to reducing terrigenous nutrient loads. The purpose of this study was to evaluate the phosphate removal performance of granulated coal ash (GCA) from seawater, which is produced from coal thermal electric power generation. Batch experiments were carried out to investigate the removal kinetics of phosphate from seawater under both oxic and anoxic conditions. Phosphate was removed well from seawater under both oxic and anoxic conditions. The adsorption isotherm for phosphate revealed that GCA could remove phosphate effectively from seawater above a concentration of 1.7 μmol L⁻¹. GCA can reduce the concentration of phosphate in seawater effectively under anoxic conditions where iron type adsorbents cannot be applied. Therefore, GCA could potentially be used to adsorb phosphate in the organically-enriched sediment, which generally occurs under highly reductive conditions.