江苏南部地区煤层气资源

根据江苏南部地区二叠系龙潭组煤系的分布和规模、煤矿瓦斯涌出特征、煤的产气能力、煤层的储集条件等煤层气地质条件综合研究工作，认为该区煤层气资源存在一定的勘探开发前景，对各典型含煤区块煤层气综合评价出有远景区（A类）、较有远景区（B类）和远景差区（C类）。     

中国南方晚二叠世乐平煤的成因及成煤物质

乐平煤是分布于苏浙皖赣地区龙潭组中的特有煤种(俗称树皮煤),也是一种具良好生烃潜力的烃源岩。乐平煤中,壳质组和可溶有机质含量高,母质类型为高等植物和低等生物双重来源,元素组成具富氢、低氧、高含硫的特征,应属海相成因的泥炭坪沉积。成煤物质主要来源于真蕨、种子蕨和科达类等植物的树皮体。树皮体又可分为茎皮体和根皮体两种亚组分。依据煤的显微组分组成和树皮体富集程度的不同,乐平煤可分为原地型、过渡型和微异地型三种成因类型。乐平煤的研究对整个南方二叠纪煤成烃资源的评价具重要的地质意义。     

Mineralogy and Mineral Chemistry of the Cretaceous Duolong Gold‐Rich Porphyry Copper Deposit in the Bangongco Arc,Northern Tibet

The Early Cretaceous Duolong gold‐rich porphyry copper deposit is a newly discovered deposit with proven 5.38 Mt Cu resources of 0.72% Cu and 41 t gold of 0.23 g t^?1 in northern Tibet. Granodiorite porphyry and quartz diorite porphyrite are the main ore‐bearing porphyries. A wide range of hydrothermal alteration associated with these porphyries is divided into potassic, argillic and propylitic zones from the ore‐bearing porphyry center outward and upward. In the hydrothermal alteration zones, secondary albite (91.5–99.7% Ab) occurs along the rim of plagioclase phenocryst and fissures. Secondary K‐feldspar (75.1–96.9% Or) replaces plagioclase phenocryst and matrix or occurs in veinlets. Biotite occurs mainly as matrix and veinlet in addition to phenocryst in the potassic zone. The biotite are Mg‐rich and formed under a highly oxidized condition at temperatures ranging from 400°C to 430°C. All the biotites are absent in F, and have high Cl content (0.19–0.26%), with log (X_Cl/X_OH) values of ?2.74 to ?2.88 and IV (Cl) values of ?3.48 to ?3.35, suggesting a significant role of chloride complexes (CuCl₂^‐ and AuCl₂^‐) in transporting and precipitating copper and gold. Chlorites are present in all alteration zones and correspond mainly to pycnochlorite. They have similar Fe/(Fe+Mg), Mn/(Mn+Mg) ratios, and a formation temperature range of 280–360°C. However, the formation temperature of chlorite in the quartz‐gypsum‐carbonate‐chlorite vein is between 190°C and 220°C, indicating that it may have resulted from a later stage of hydrothermal activity. Fe³⁺/Fe²⁺ ratios of chlorites have negative correlation with Al^IV, suggesting oxygen fugacity of fluids increases with decreasing temperature. Apatite mineral inclusions in the biotite phenocrysts show high SO₃ content (0.44–0.82%) and high Cl content (1–1.37%), indicating the host magma had a high oxidation state and was enriched in S and Cl. The highest Cl content of apatite in the propylitic zone may have resulted from pressure decrease, and the lowest Cl content of apatite in the argillic zone may have been caused by a low Cl content in the fluids. The low concentration of SO₃ content in the hydrothermal apatite compared to the magmatic one may have resulted from the decrease of oxygen fugacity and S content in the hydrothermal fluid, which are caused by the abundant precipitation of magnetite.     

海水中234Th的超低水平液闪谱仪测定

本文提出了利用超低水平液闪谱仪测定海水中234Th的方法.海水经氢氧化铁吸附共沉淀富集后,接着用阴离子交换和TBP/煤油萃取进行Th同位素的分离与纯化.对一系列测定条件进行了详细的研究,提出了测定海水中234Th的适宜程序,即在含有234Th和产额示踪剂230Th的纯化后的5mol/dm3HNO3溶液中加入TBP/煤油进行萃取,然后用0.1mol/dm3HNO3反萃取,后者是先用契伦柯夫计数法测量234Th(通过234mPa),后加入闪烁液Hisafe 3用α/β模式测量α放射体230Th.对于α和β放射体液闪谱仪的计数效率分别为100%和55.7%±2.7%.234Th的化学回收率和总探测效率分别为70%～80%和30%～45%.该法测定海水中的234Th快速、简便和高效.     

铵锌镉还原法测试硝酸盐氮、氧同位素方法研究

本研究利用铵锌镉还原法将海水、湖水和自来水水体中硝酸盐转化为N₂O气体测试氮、氧同位素, 结果表明当反应体系的pH值在6～8之间, NO₃^-还原为NO₂^-的转化率大于95%, NO₂^-还原为N₂O的转化率大于99%。配置5种丰度的硝酸盐氮、氧同位素标样, 将实验结果与理论值绘制校准曲线, 氮同位素校准曲线斜率为0.48, 相关性良好(R²=0.999 8), 5种丰度δ¹⁵N_N2O标准偏差在0.18‰～0.43‰之间(n=5);氧同位素校准曲线斜率为0.70, 相关性良好(R²=0.999 6), 5种丰度δ¹⁸O_N2O标准偏差在0.27‰～0.46‰之间(n=5)。铵锌镉还原法与镉柱还原法测定硝酸盐氮、氧同位素结果的精密度和准确度一致, 同时海水、湖水和自来水3种不同类型水样的硝酸盐氮、氧同位素测试数据满足实验要求, 而且在实验流程的简洁性和高效性方面更具优势。     

用离子色谱法测定金矿区水样中常规无机离子

利用DX－120离子色谱仪进行阴阳离子的精密度和准确度测定，100mg/L时相对标准偏差范围为1．00％－3．80％，回收经95．83％－105．00％；5mg／L时相对标准偏差范围为1．18％－4．57％，回收率92．40％－103．20％，完全达到实际要求。用该离子色谱仪测定甘肃阳山金矿山水样中常规无机离子，数据表明该区域水质较好，所测离子浓度都未超过饮用水标准。     

肥城市采煤塌陷区治理模式探索研究

肥城煤田作为国家重要能源基地,开发历史悠久,为我国高速发展的国民经济做出了巨大贡献。但长期开采导致塌陷范围广、深度大、积水严重,生态环境遭受严重破坏,给矿区群众的生产生活带来严重影响。该文总结了目前普及化程度较高的采煤塌陷区治理模式,以此为基础,对肥城市采煤塌陷区按照因地制宜的原则,通过分析研究、归纳得出适应于肥城市采煤塌陷区四种不同的治理模式,分别为:土地复垦治理模式、“渔业+农业”治理模式、生态修复治理模式、综合治理模式,并对四种治理模式进行了阐述分析,对今后肥城市采煤塌陷区治理起到借鉴和指导作用。     

塔里木盆地塔中低凸起地层水化学特征对不整合的响应

对塔中低凸起地层水化学特征与不整合之间关系的研究结果表明,地层水化学特征对不整合具有很好的响应。在遭受强烈抬升和剥蚀、之间形成不整合的奥陶系和志留系,以及紧靠不整合面附近的石炭系CⅢ油组,其地层水具有矿化度、Cl-含量、K Na 含量和r(Cl-Na)/rMg值相对较小,而HCO3-含量、rNa/rCl值和rSO42-×100/rCl值相对较大的特点,反映出地质历史时期大气降水的影响。在志留系与石炭系之间以及志留系与奥陶系之间的不整合面附近,地层水的矿化度、r(Cl-Na)/rMg值和B3 含量变小,而rNa/rCl值和rSO24-×100/rCl值变大,具有典型的遭受大气淋滤的地层水化学基本特征。     

四川平武板状绿柱石矿物学特征及板状成因

在综合该区绿柱石产出背景的基础上,从围岩蚀变、矿物共生组合、矿物标型形态和绿柱石测温测压等方面确定平武绿柱石矿床是气成高温浅成石英脉型矿床。文中对绿柱石矿物进行了湿法化学分析、X射线粉晶衍射分析、微形貌分析,研究了该区绿柱石的形态、物性、化学成分及类质同象特征,确定该区绿柱石为板状晶形的含铯钠锂绿柱石,碱金属平均质量分数为2.412%(Li2O+Na2O+K2O+ Rb2O+Cs2O)。板状含碱绿柱石一般发育在伟晶岩中,气成高温热液矿床中产出板状含碱绿柱石极为罕见。在以上工作基础上,从绿柱石形成的内因和外因两方面探讨了绿柱石的板状成因。     

Coalbed methane reservoirs’ pore-structure characterization of different macrolithotypes in the southern Junggar Basin of Northwest China

Coalbed methane (CBM) development in the southern Junggar Basin of Northwest China has aroused extensive attention owing to its significant resource potential. The accurate characterization of coal pore structure is important for CBM exploration and production. In order to explore the relationship between coal pore structure and macrolithotype, which has rarely been studied in the southern Junggar Basin, a series of laboratory experiments were performed on eight samples of different macrolithotypes. The results show that the porosity exhibits regularity with macrolithotype in the order bright < semibright < semidull < dull, and also shows an increase with the rise of the inertinite content. The pore-size distribution results show that the dominating pores of bright and semibright coals are usually greater than that of dull and semidull coals in size. The pore-type analysis indicates that the bottleneck pores (Type B) are well developed in dull and semidull coals, while bright and semibright coals mainly host two sides (Type A), namely opened pores and one-side-closed pores (Type C). The pore-type and -size distribution strongly affect pore connectivity refers to the facts that: 1) the proportion of effective porosity increases with an increasing proportion of pores greater than 100 nm in size; and 2) that the mercury withdrawal efficiency is always lower when the pores are mostly of Type B. So the pore connectivity of semibright and bright coals is higher than that of semidull and dull coals. Furthermore, pores are developed mainly in the inertinite, with pore-type being dominated by Type B and C, secondly in the vitrinite, with pore-type being dominated by Type A and C, and less developed in the liptinite with pore-type of B and C. The pore connectivity of each maceral is in the order vitrinite > inertinite > liptinite. Finally, according to the research results, the reservoir fracturing improvement should be more arranged on the dull or semi-dull coals, and the producing layers should be bright or semi-bright coals as much as possible on the premise that the gas contents of coal layers are not much different from each other.