四川木里混杂带海山玄武岩辉石斑晶中的熔体包裹体：甘孜-理塘古特提斯洋内热点与洋中脊相互作用的记录

川西木里混杂带位于扬子板块西缘,向西与甘孜-理塘弧前混杂带相接,位于一个大地构造上十分重要的部位。我们详细野外地质调查揭示,木里混杂带由不同类型的大洋板片地层组成,其中海山岩石组合保存相对完整,枕状熔岩与上覆碳酸盐岩帽接触关系以及海山斜坡滑塌堆积组合完整清晰。海山枕状玄武岩具斑状结构,主要斑晶矿物相为单斜辉石,少量基性斜长石,基质为微晶斜长石和辉石。原生熔体包裹体主要寄存于单斜辉石斑晶中,形状不规则,大小20～50μm。熔体包裹体内部组成和结构简单清晰,主要为不透明玻璃质,有的熔体包裹体含圆形-椭圆形收缩气泡,个别熔体包裹体壁可见子矿物结晶析出。对单斜辉石斑晶及其中熔体包裹体的地球化学分析结果揭示,木里混杂带中保留了OIB和E-MORB两类海山玄武岩,其原始岩浆源区为石榴子石二辉橄榄岩低程度熔融。其中,OIB型海山玄武岩(样品HS5)是地幔柱轴部岩浆活动的产物,而E-MORB型海山玄武岩(样品HS2)是某种程度的热点(地幔柱)与洋中脊相互作用的产物。磷灰石U-Pb测年结果和古生物化石证据表明,木里混杂带中的海山形成于石炭纪末-二叠纪初(302±11Ma)。这表明甘孜-理塘(松潘-甘孜)古特提斯分支洋在石炭纪末或更早时期就已经发育。在该分支洋盆内发育地幔柱以及地幔柱(热点)与洋中脊的相互作用。     

承德黑山斜长岩杂岩体辉石特征及其形成温度条件

本文对黑山斜长岩杂岩体中斜方辉石和单斜辉石的光学特征、化学成分及其演化规律作了系统研究的同时,也研究了两种辉石中Fe-Mg的分配,其分配系数K_D值多大于1.37。并用13对共生的二辉石矿物对的化学成分,计算了形成温度为800～980℃。该杂岩体是在平衡条件下缓慢结晶而成。     

镁铁质-超镁铁质岩浆岩中单斜辉石的智能分析研究

区分不同构造环境中岩浆作用是认识地幔中岩浆形成过程的基本手段。目前较为成熟的是利用全岩去区分判别,而利用造岩矿物去判别构造环境、演绎岩浆演化的研究还不够深入。本文运用机器学习的方法,以全球新生代大洋中脊、洋岛以及岛弧构造背景中的镁铁质-超镁铁质岩浆岩中单斜辉石的地球化学数据为研究对象,试图区分这3 种不同构造环境的单斜辉石。通过机器学习方法中K-邻近（K-Nearest Neighbor,KNN）和随机森林（Random Forest,RF）的计算和比较,认为RF 是一种有效的地球化学区分方法,它的结果不仅可用来判别构造环境,同时还能够提取特征元素。同时我们发现,在镁铁质-超镁铁质岩浆岩单斜辉石构造环境判别图解中,Rb、La、Ba、Cr、Sr、Yb、V、Ti、Nd、Eu、Gd等微量元素具有较高的贡献率,而主量元素贡献率较低。在此基础上,我们结合前人的对单斜辉石的构造环境判别图的研究成果,提出几个判别效果较好的判别图解。但是整个研究由于缺少进一步可视化的成果,限制了机器学习方法的推广,这也是今后需要进一步研究的课题。     

A complex magmatic system beneath the Devès volcanic field,Massif Central,France: evidence from clinopyroxene megacrysts

Clinopyroxene megacrysts and mineral aggregates with clinopyroxene occur in the volcanic deposits at Mont Briançon and Marais de Limagne, which are located in the northern part of the Devès volcanic field (Massif Central, France). The clinopyroxenes can be subdivided into five groups based upon their major and trace element chemistry. Types 1a, 1b and 1c have mg# ～0.80 and are relatively Al-rich and low in Na and Fe³⁺. Subdivision into three groups is based on differing trace element signatures. Type 2 clinopyroxenes have mg# = 0.63–0.65 and higher Na and Fe³⁺ (Fe³⁺/ΣFe > 0.4) contents and may contain apatite inclusions. A type 3 megacryst is Fe-rich (mg# = ～0.52) and has the highest Na and Fe³⁺ contents, as well as containing titanite and apatite inclusions. High Fe³⁺ contents in all clinopyroxenes investigated emphasises the need to consider Fe³⁺/Fe²⁺ when assessing the petrologic origin of such megacrysts. The large range in mg# means that the clinopyroxenes could not all have crystallised from the same melt; in fact comparison with the basanitic host lavas from the two localities reveal that nearly all of the megacrysts are xenocrystic in the strict sense. The clinopyroxenes are mostly genetically related, having crystallised from related melts within the magmatic system that had undergone various degrees of differentiation. Similarities in clinopyroxene chemistry indicate that both volcanic centres are linked to the same magmatic system at depth. Assessing the depth of crystallisation reveals that types 1a and 1b formed in the lithospheric mantle, near the asthenosphere–lithosphere boundary, whereas types 1c, 2 and 3 formed in crustal magma chambers or conduits. Eruption was induced by a pulse of Mg-rich magma from the asthenosphere that entered the existing magmatic system, entraining clinopyroxene as megacrysts at several stages of ascent, before erupting at the surface. The style of eruption at Mont Briançon (cinder cone) and Marais de Limagne (maar) is different and most likely reflects local differences in near-surface hydrology. The essentially identical variety in megacrysts at the two localities suggests that eruption must have been nearly contemporaneous.     

Mineral geochemistry of the Sangan skarn deposit,NE Iran: Implication for the evolution of hydrothermal fluid

The Sangan iron skarn deposit is located in the Sabzevar-Dorouneh Magmatic Belt of northeastern Iran. The skarn contains zoned garnet, clinopyroxene and magnetite. Cores and rims of zoned garnets are generally homogeneous, having a relatively high ΣREE, low ΣLREE/ΣHREE ratios, and positive Eu anomalies. The cores of the zoned clinopyroxenes are exceptionally HREE-rich, with relatively high ΣREE and HREE/LREE ratios, as well as positive Eu anomalies. Clinopyroxene rims are LREE-rich, with relatively low ΣREE contents and HREE/LREE ratios, and do not have Eu anomalies. Magnetite grains are enriched in LREEs in comparison with the HREEs and lack Eu anomalies. Variations of fluid composition and physicochemical conditions rather than YAG-type substitution mechanism are considered to have major control on incorporating trace elements, including REE, into the skarn mineral assemblage. Based on baro-acoustic decrepitation analysis, the calc-silicate and magnetite dominant stages were formed at similar temperatures, around 350–400 °C. In the Sangan skarns, hydrothermal fluids shifted from near-neutral pH, reduced conditions with relatively high ΣREE, low LREE/HREE ratios, and U-rich characteristics towards acidic, oxidized conditions with relatively low ΣREE, high LREE/HREE ratios, and U-poor characteristics.     

北大巴山志留系滔河口组碱质斑状玄武岩的岩浆源区及形成环境——来自全岩和辉石斑晶地球化学的约束

北大巴山志留系滔河口组火山-沉积地层发育有粗粒玄武岩、细粒玄武岩、杏仁构造玄武岩和枕状玄武岩四种斑状玄武岩相。它们都属于碱性玄武岩,并具有相似的地球化学特征,富Ti、贫Si,富集大离子亲石元素(LILE,如Th、Rb、Ba)和LREE,轻重稀土分异明显。稀土和微量元素标准化配分型式具有与洋岛玄武岩(OIB)类似的特征。斑晶主要属于单斜辉石族中的次透辉石-透辉石,具有与全岩相似的微量和稀土元素配分形态,表明四种玄武岩相由同一岩浆源区形成。由单斜辉石-熔体平衡温压计计算获得的初始岩浆深度大于67.65km,表明岩浆源区来自地幔。岩浆在上升过程中在39.93～67.65km、14.52～20.46km、4.62～9.24km三个深度范围发生了储积结晶,最后喷出到地表分别形成粗粒玄武岩、细粒和枕状玄武岩、杏仁构造玄武岩。粗粒玄武岩中富含金云母表明岩浆源区遭受了富不相容元素流体的交代作用。玄武岩全岩、单斜辉石地球化学特征以及火山-沉积序列共同表明,滔河口组碱性玄武岩形成于大洋板内环境。     

冀西北姚家庄超镁铁岩-正长岩杂岩体中辉石的环带特征及意义

冀西北姚家庄存在一套晚三叠世的超镁铁岩-正长岩杂岩体,岩体内发育具有环带特征的单斜辉石。辉石的环带有两种:简单环带和复杂环带。简单环带一般为正环带,辉石核部的MgO和Cr2O3含量高,Si O2、Fe O和Na2O含量低;边部的主要氧化物含量与核部刚好相反。简单正环带可以分为两类,其中核边接触带平滑、由核到边化学成分具有渐变特征的正环带辉石可能是岩浆在分离结晶或地壳混染过程中形成。而核边接触带有熔蚀结构、由核到边化学成分突变的正环带辉石可能是早期结晶的辉石颗粒受到晚期低镁岩浆的溶蚀改造而成的。复杂环带具有核-幔-边结构,其中,核部低镁高铁、幔部高镁低铁、边部与核部相似,但其Mg#更低,这些特征暗示了岩浆混合作用的存在,形成辉石核部的母岩浆可能来自富集的岩石圈地幔,幔部高Mg#的特征指示了软流圈地幔物质的贡献,其边部低Mg#的特征则指示了地壳物质的加入。具有韵律环带的复杂辉石是在岩浆多期侵入的过程中形成的。辉石环带的组成特征表明,姚家庄杂岩体是由岩浆多期侵位形成的,后期侵入的岩浆与前期就位的岩浆不断反应,形成了具有多种不同环带特征的辉石,并最终形成了空间上由外到内依次为辉石岩、辉石正长岩和正长岩的环状杂岩体。结合前人的研究成果,推测形成姚家庄岩体的岩浆主要来源于富集的岩石圈地幔,并由少量地壳组分和软流圈物质的贡献。     

Computer modelling of hydrogen defects in the clinopyroxenes diopside and jadeite

Atomistic computer simulation techniques have been employed to model mechanisms of hydrogen incorporation in the clinopyroxenes diopside and jadeite. Calculation of solution reaction energies for the pure phases indicates that hydrogen is most easily incorporated via the formation of [V_Si(OH)₄] ^x hydrogarnet type defects. When components of the two phases are mixed, then solution energies can become exothermic. The substitution of Al for Si in diopside and of Mg or Ca for Al in jadeite, provides favourable routes for hydrogen incorporation, with exothermic values of solution energy. Thus the amount of water present in these minerals in the Earth’s upper mantle will vary with composition. Simulation of IR frequencies associated with O–H stretching at specific defect clusters has also been carried out. An analysis of hydrogen–oxygen bond lengths gives good agreement, although comparison of experimental and calculated IR frequencies are problematic. This is partly due to the complexity of experimental spectra, but may also be due in part to deficiencies in the ability of the model to accurately describe the O–H stretching frequency.     

山东昌乐新生代碱性玄武岩中的巨晶单斜辉石成因研究

山东昌乐新生代碱性玄武岩中除斑晶单斜辉石和基质单斜辉石外,还发育大量巨晶单斜辉石和同源斜方辉石捕掳晶。巨晶单斜辉石与玄武岩间发育复杂和简单两种类型的反应边。复杂反应边往往发育在颗粒较大的巨晶单斜辉石外围。复杂反应边可分为4个带：内部带、过渡带、外部带和边缘带,其中,内部带、过渡带和外部带均由具不同结构特征的单斜辉石＋熔体＋金属氧化物构成,边缘带为不含熔体和金属氧化物的干净的单斜辉石;内部带的单斜辉石具梳状构造,过渡带的单斜辉石具细密筛孔构造,外部带为具似砂钟构造的筛孔状单斜辉石。反应边中单斜辉石、熔体及金属氧化物的成分显示,只有内部带受到单斜辉石巨晶的影响,其余带均受玄武岩浆的制约。简单反应边往往发育在颗粒较小的巨晶单斜辉石外围。简单反应边仅发育不含熔体和金属氧化物的干净的单斜辉石。巨晶单斜辉石的反应边是巨晶与玄武岩浆间温度差造成的。在与玄武岩浆反应的过程中,大颗粒的单斜辉石巨晶需要较长的时间与玄武岩浆达到温度平衡,从而有足够的时间发育包含4个带的复杂反应边;反之,由于缺乏足够的反应时间,小颗粒单斜辉石巨晶的外围只发育不含熔体和金属氧化物的简单反应边。同源斜方辉石捕掳晶的成分与地幔二辉橄榄岩包体中的斜方辉石类似,其边部发育类似于Bowen反应（1956）形成的单斜辉石环边。在单斜辉石Al^IV-Al^VI图解上,巨晶单斜辉石、二辉橄榄岩包体中的单斜辉石以及部分单斜辉石斑晶的核部,均位于较高压力的“麻粒岩和玄武岩中包体”区域,反应边中单斜辉石、基质单斜辉石以及绝大部分斑晶单斜辉石位于“火成岩”区域,说明部分斑晶单斜辉石核部来源于地幔二辉橄榄岩,属于捕掳晶。结合单斜辉石结晶压力的估算,笔者认为巨晶单斜辉石的成因模式为：来自软流圈的碱质基性熔体上侵到地幔岩石圈下部,结晶形成单斜辉石巨晶,后来该熔体携带巨晶单斜辉石与来自上地幔岩石圈、夹带大量二辉橄榄岩包体以及斜方辉石（和单斜辉石）捕掳晶的玄武岩浆混合,巨晶单斜辉石随混合后的碱性玄武岩浆上升、喷出地表。     

雷州英峰岭玄武岩中单斜辉石巨晶的地球化学和地幔交代作用

雷州半岛英峰岭火山岩中单斜辉石巨晶以低Mg^#值(0．62—0．47)、贫重稀土(HREE)和富Al2O3、TiO2、Na2O和中稀土(MREE)为特征，并具有明显的成分变化。随着Mg^#降低，单斜辉石的Al：O，(11．58～6．97％，)、TiO，(2．28～1．06％)和HREE逐渐降低。这种变化特征不同于世界上大多数辉石巨晶的变化规律。随着演化辉石巨晶的大多数不相容元素，如Nb、Sr、Zr、Hf和LREE—MREE逐渐增加。低的Mg^#值和Ni、Co、Cr含量指示巨晶母岩浆是一种强烈演化的残余岩浆(Mg^#=0．27～0．35)。分离结晶模拟表明本研究最富镁的巨晶(Lz-54)的母岩浆很可能是由拉斑玄武质岩浆经70～80％，以单斜辉石为主的结晶分异后形成。而本研究的其它辉石巨晶是该母岩浆在不同演化阶段(25～80％)分离结晶的产物。分离矿物中除了单斜辉石还包含了大量的石榴子石、斜长石和钛铁矿。温压计算表明英峰岭巨晶是高温岩浆在56～60km深的上地幔的结晶产物(r=1290℃～1130℃，P=1.73～1．83GPa)，这一深度有利于石榴子石结晶。对比不同地区辉石巨晶的成分特征和形成条件，作者指出不同地区单斜辉石巨晶各种元素的不同变化规律主要受母岩浆成分和结晶条件控制。巨晶母岩浆在地幔结晶时对围岩橄榄岩进行了不同程度的交代作用。早期贫流体的岩浆对橄榄岩的交代作用较弱，只有Sr，La等强活动性元素被明显改变；晚期富流体(F，P，H2O)岩浆对橄榄岩的交代作用强烈，大多数元素被明显改变。因此，可以推断交代熔体中流体的含量是影响地幔橄榄岩交代作用的关键。