Estimating groundwater recharge in a cold desert environment in northern China using chloride

Understanding sources and rates of recharge to the Badain Jaran Desert in northern China is important for assessing sustainability of the area’s oasis lake ecosystem and its water resources in general. For this purpose, direct recharge was investigated with the chloride mass balance method for 18 unsaturated zone profiles (6–16 m depth). Spatial variability is low across the area (range in mean Cl in profiles: 62–164 mg/L Cl), largely attributable to the uniformity of sandy unsaturated zone conditions. No strong correlations between environmental factors of profile locations and recharge rates were found, though a weak relationship between recharge and vegetation density was suggested. The study area’s complex dune morphology appears to have no measurable impact on recharge variability. Mean estimated diffuse recharge is 1.4 mm/year (1.0–3.6 mm/year for 95% confidence level), approximately 1.7% of mean annual precipitation. Temporal fluctuations in recharge due to climate variability are apparent and there is good correspondence in temporal trends over a time span of 200–300 years. Water balance considerations indicate that direct recharge is insufficient to support the numerous perennial lakes in the study area, suggesting that diffuse recharge presently plays a minor role in the overall water balance of the desert’s shallow Quaternary aquifer.     

艾比湖水体中氯离子测定方法分析

提出用氯离子选择电极测定艾比湖水体中氯离子含量的方法,并研究了测定条件。标准曲线在1.0×10-1～1.0×10-4mol/L范围内呈良好的线性关系,回收率为95.6%～103%,RSD为1.51%～4.34%,结果表明该方法简便、快速、准确。     

乌兰布和沙漠降水入渗补给对气候变化的响应

为探究地下水补给对气候变化的响应,以乌兰布和沙漠为例,基于氯质量平衡法,通过野外打钻和室内离子分析,重建区域地下水补给历史和短时间尺度的气候变化过程。结果表明：降水对沙漠地区的地下水补给非常小,对比周边地区记录发现,地下水补给呈现出由西向东逐渐增大的趋势,且一定程度上反映出贺兰山对季风气流的阻挡作用,在相关季风较弱年份,贺兰山西侧降水补给弱于东侧。过去600年来本地区的气候波动大,1455-1500 AD、1600-1650 AD是气候较为干旱的时期,18世纪末至19世纪初是环境演化一个重要的时间界限,自此以后的漫长时间,干旱化进程进一步加剧,尤其是1920-1930 AD,区域极端干旱。本研究也验证了处于季风边缘沙漠地区降水入渗补给对气候变化所呈现出的响应差异。     

盐纺Ca^2＋和Cl^-离子水化异常映震特征研究

通过对盐纺Ca^2＋、Cl^-离子观测值进行月均值及方差值分析处理,认为盐纺水化点Ca^2＋、Cl^-离子的月均值及其方差值曲线有较好的映震效果,其异常变化与区域内成组中等地震活动关系密切,并就盐纺水化点Ca^2＋、C^l-离子的动态异常与区域地震活动之间的可能关系进行探讨。     

A description of chloride cell and kidney tubule alterations in the flatfish Solea senegalensis exposed to moderately contaminated sediments from the Sado estuary (Portugal)

The effects of sediment-bound contaminants on kidney and gill chloride cells were surveyed in juvenile Solea senegalensis exposed to fresh sediments collected from three distinct sites of the Sado Estuary (Portugal) in a 28-day laboratorial assay. Sediments were analyzed for metallic contaminants, polycyclic aromatic hydrocarbons and organochlorines as well as for total organic matter, redox potential and fine fraction. The potential for causing adverse biological effects of each surveyed sediment was assessed by comparison of contaminant levels to available guidelines for coastal sediments, namely the Threshold Effects Level (TEL) and the Probable Effects Level (PEL). The Sediment Quality Guideline Quotient indices (SQGQ) were calculated to compare the overall contamination levels of the three stations. A qualitative approach was employed to analyze the histo/cytopathological traits in gill chloride cells and body kidney of fish exposed to each tested sediment for 0, 14 and 28 days. The results showed that sediment contamination can be considered low to moderate and that the least contaminated sediment (from a reference site, with the lowest SQGQ) caused lesser changes in the surveyed organs. However, the most contaminated sediment (by both metallic and organic xenobiotics, with highest SQGQ) was neither responsible for the highest mortality nor for the most pronounced lesions. Exposure to the sediment presenting an intermediate SQGQ, essentially contaminated by organic compounds, caused the highest mortality (48%) and the most severe damage to kidneys, up to full renal necrosis. Chloride cell alterations were similar in fish exposed to the two most contaminated sediments and consisted of a pronounced cellular hypertrophy, likely involving fluid retention and loss of mitochondria. It can be concluded that sediment contamination considered to be low or moderate may be responsible for severe injury to cells and parenchyma involved in the maintenance of osmotic balance, contributing for the high mortality levels observed. The results suggest that sediment-bound organic contaminants such as PAHs (polycyclic aromatic hydrocarbons) and PCBs (polychlorinated biphenyls) may be very toxic to the analyzed organs, especially the kidney, even when present in low-risk concentrations.     

盐湖氯化物资源开发与环保

简述了盐湖氯化物资源综合开发势在必行 ;探讨开展氯化学研究的必要 ;并对与氯平衡相关的环保问题和水制约问题做了分析     

巴丹吉林沙漠包气带Cl-示踪与气候记录研究

Cl^-是自然界中最稳定的示踪剂, 包气带水Cl^-浓度与降水中Cl^-浓度的差异可以反映降水的有效入渗补给量和包气带水的年龄。基于CMB的氯累积年龄可以用³⁶Cl/Cl在三个时间尺度上校正。利用CMB研究了巴丹吉林沙漠南缘的两个钻孔剖面的Cl^-与含水量的分布状况, 计算了800a以来的地下水补给量及其所反映的气候波动特征。在该地区, 多年平均降雨量为89mm, 而平均补给量仅为1.3mm。干旱沙漠地区最近800a气候明显经历了4个干期和3个湿期。1500-1530年是干旱区气候突变的时期, 18世纪末至19世纪初是气候环境演化的又一个十分重要的时间界限, 自此以后的漫长时间, 干旱化进程进一步加剧。     

干湿循环对混凝土在高浓度卤水中氯离子扩散行为的影响

在高浓度盐湖卤水中,采用自然扩散法进行了混凝土的III维氯离子扩散实验,研究了普通混凝土(Ordinary Portland cement concrete,OPC)、高强混凝土(High strength concrete,HSC)、高性能混凝土(High performance concrete,HPC)、钢纤维增强高性能混凝土(Steel fiber reinforced high performance concrete,SFRHPC)和高强高模聚乙烯纤维增强高性能混凝土(High elasticity module Polyethylene fiber reinforced high performance concrete,HEMPFRHPC)的氯离子扩散行为,探讨了干湿循环对混凝土氯离子扩散行为的影响。结果表明,干湿循环作用加快了OPC、HSC和HPC的氯离子扩散速度,而且毛细管作用对OPC、HSC、HPC和SFRHPC的氯离子扩散行为有一定程度的影响,从而导致混凝土表面氯离子浓度的富集现象更加明显。进一步研究发现,干湿循环降低了OPC的表观氯离子扩散系数,但是对HSC、MPC和HEMPFRHPC的表观氯离子扩散系数则没有明显的影响。     

On the Problem of Sample Preservation by Freezing

During routine analysis of running water samples differences of the analytical results of water‐soluble anions were observed between analysis carried out immediately after sampling and after storage of the cooled/frozen sample. This phenomenon was investigated for some years with the “model ion” chloride. A high number of samples (ca. 210) were analysed over three years with different analytical methods, and by alteration of the sample containers the discrete physical influence of the wall effect of the sample vessel could be worked out definitely. No significant differences occur with the mean value of the year but the single values have high differences in the positive or negative direction. Assuming a similar behaviour of other water constituents when preserved by freezing the analytical values had to be looked at very critically.     

浅谈粉碎洗涤盐生产中的技术改造

对粉碎洗涤盐的技改过程、技改方向进行了总结并列举大量实验数据 ,说明技改前后粉洗盐质量变化及成功经验。同时对粉洗盐粒度存在的问题进行了分析并提出建议