东昆仑得尔龙地区华力西期花岗岩地质地球化学特征及构造环境分析

东昆仑得尔龙地区花岗岩体侵位于二叠纪—三叠纪早期,岩石类型为黑云母花岗闪长岩、黑云母二长花岗岩、二云母二长花岗岩。早期次的黑云母花岗闪长岩中含有暗色的镁铁质矿物包体。SiO2含量为65.04%~73.47%,全碱含量为5.29%~8.52%,K2O/Na2O平均值为0.70,Al2O3平均为14.79%;亏损高场强元素Ta,Nb;∑REE平均为142.9×10-6,轻稀土元素相对富集,(La/Yb)N平均为17.15,δEu平均为0.71,表现为弱亏损。研究表明得尔龙地区花岗岩属次铝-过铝(高钾)钙碱性S型花岗岩,形成于后造山环境;岩浆源区的物质是多源的,主要为地壳物质的重熔,其次为幔源岩浆的底侵。     

秦岭山阳-柞水地区燕山期中酸性侵入岩地球化学特征、锆石U-Pb年龄及Lu-Hf同位素组成

秦岭山阳-柞水地区广泛出露燕山期中酸性花岗(斑)岩体,并有大量与其相关的斑岩-矽卡岩型Cu-Mo-Fe、Cu-AuFe矿化。LA-ICP-MS锆石U-Pb测年结果表明,与矿化密切相关的斑岩体形成于144.6~141.5Ma。岩石地球化学分析结果表明,这些花岗(斑)岩体SiO2含量为55.73%~67.80%,K2O含量为2.52%~6.40%,Na2O含量为1.94%~5.19%,Al2O3含量为14.61%~16.10%,FeOT含量为2.1%~9.0%,MgO含量为1.32%~5.52%,主体显高钾钙碱性准铝质特征。A/CNK1.1,P2O5与SiO2负相关,Mg#平均为49,含有角闪石、黑云母、榍石、磁铁矿等矿物,属I型花岗岩类;稀土元素分异明显,无明显Eu异常;富集K、Rb、Sr、Ba等大离子亲石元素,Nb、Ta、Ti、P和Hf等高场强元素亏损,属后碰撞型花岗岩。岩体的锆石εHf(t)为-4.5~+1.78,平均为-0.87,表明其岩浆源区为地壳物质的熔融岩浆与幔源岩浆的混合,且以地壳熔融成份为主;Hf同位素二阶段模式年龄(t DM2)为1479~1084Ma,表明其壳源源区物质可能形成于中晚元古代(1.4~1.0Ga)。     

北冈底斯带日土县-拉梅拉山口花岗岩体的岩石地球化学特征、锆石U-Pb测年及Hf同位素组成

对西藏西部日土县城以南-拉梅拉山口一带的花岗岩体开展了详细的岩相学、岩石地球化学和锆石U-Pb年代学及Hf同位素研究。所有样品铝饱和指数A/CNK集中在0.76~1.0之间,为准铝质类型。CIPW标准矿物组合为Q+Or+Ab+An+Di（或C）+Hy。在稀土元素配分图中呈现出右倾缓倾斜型的特征,轻稀土元素富集并出现较强的分馏作用,重稀土元素无分馏-轻微分馏。δEu在0.56~0.99范围之间,属于铕亏损型。大离子亲石元素出现分化,富集Rb、Pb、Th而亏损K、Ba,高场强元素Nb、Ta、Ti等明显亏损。获得钾长花岗岩、二长花岗岩及花岗闪长岩中岩浆结晶锆石的LA-ICP-MS U-Pb年龄分别为：79.4±0.4Ma、 81.0±0.5Ma和81.3±0.5Ma,结合锆石稀土元素和岩浆振荡环带特征及Th/U比值,上述年龄结果可代表岩石的结晶年龄,表明该套岩体为晚白垩世侵位的大型岩基。两件样品的锆石均具有正的Hf同位素初始比值ε_Hf（t）,两阶段Hf模式年龄（t_DM2）分别介于547.5~658.0Ma、523.4~710.2Ma之间。分析认为该套岩体的物质来源应该为富角闪石的下地壳,可能为幔源岩浆首先侵入到地壳基底岩石中形成新生地壳,然后在温度约为700~800℃之间、压力<8kbar且富含流体的影响下,这种既有新生地壳又有古老基底地壳构成的混合地壳发生部分熔融而形成。这一结论与野外宏观露头上岩体中大量发育暗色微粒包体等直接岩石学证据相佐证。结合区域构造演化及岩体所处的大地构造位置,该套花岗岩体应该形成于洋壳闭合时的碰撞造山过程,其形成与侵位与北侧班公湖-怒江结合带的构造演化有成因上的联系,是班公湖-怒江特提斯洋向南的俯冲碰撞的产物。     

柴达木盆地西部昆北断阶带基底花岗岩锆石U-Pb年龄、地球化学特征及其地质意义

柴达木盆地西部基底分布有大量的有花岗岩类岩石。通过对柴达木盆地西部昆北断阶带钻遇的基底花岗岩样品开展详细的岩石学、锆石激光探针等离子体质谱U-Pb同位素年代学及岩石地球化学研究表明,锆石U-Pb同位素年龄为467~450Ma,显示基底花岗岩的结晶年龄为中-晚奥陶世,属于加里东期岩浆侵入旋回。详细的岩石地球化学分析表明,昆北断阶带基底花岗岩属过铝高钾钙碱性系列,其稀土元素配分模式为具有Eu负异常的轻稀土元素富集型,昆北断阶带中南部基底花岗岩属上地壳物质熔融,同碰撞环境下形成的花岗岩。综合区域上的研究成果,昆北断阶带及其以西地区存在中奥陶世-早志留世的加里东期构造-岩浆事件,这对探讨柴达木盆地西部基底花岗岩成因类型及岩浆演化具有重要的意义。     

祁连东部西格拉高Sr/Y型花岗岩LA-ICP-MS锆石U-Pb定年及其地球化学特征

西格拉花岗岩体位于祁连东部的米屈花岗岩带上,空间上呈NW-NWW向展布,岩体由花岗闪长岩-花岗岩-正长岩组成,主要岩性为花岗闪长岩。LA-ICP-MS锆石U-Pb定年结果表明,西格拉花岗闪长岩存在两期岩浆作用,年龄分别为465.6±6.5Ma、443.2±4.8Ma,其中,前者与祁连洋俯冲极性发生转变的时限(~463Ma)相近,而后者与祁连洋闭合的时间(~445Ma)相似。早期淡色花岗闪长岩具正铕异常(δEu=2.44),晚期暗色花岗闪长岩则为弱负/正铕异常(δEu=0.94~1.32),两者均显示出高Si、Al,富Na贫K,富集Ba、Sr、LREE,高Sr/Y值,低Y、HREE含量,亏损HFSE(Nb、Ta、Ti、P)的特征,与Martin et al.(2005)划分的高硅埃达克岩(HSA)相似。其源区可能均残留石榴子石、普通角闪石及少量金红石,而斜长石则大量参与部分熔融过程,推测早期花岗闪长岩的源区深度可能超过50km;整体上,由早期→晚期反映出加厚地壳减薄、地幔组分贡献增强的趋势;两者可能均为加厚下地壳物质部分熔融的产物。     

内蒙古东南部早三叠世花岗岩带岩石地球化学特征及其构造环境

锆石U-Pb定年结果表明位于林西县北西的转山子岩体的形成时代为245.6±0.9Ma,该岩体与内蒙古东南部的龙头山和建设屯岩体共同构成一条大致平行于西拉木伦河蛇绿岩带的早三叠世花岗岩带。岩石学和地球化学分析表明,上述早三叠世岩体属于钙碱性和高钾钙碱性系列,铝饱和指数(ACNK)均小于1.1,属于偏铝质或弱过铝质的I型花岗岩。其中,转山子岩体轻重稀土分馏较弱,含有较低的Sr含量(400×10-6),显示经典岛弧岩石的特征;建设屯岩体具有强烈的轻重稀土分馏以及较高的Sr含量(400×10-6),显示埃达克岩的地球化学特征;龙头山岩体的轻重稀土分馏特征和Sr的含量总体介于前两者之间。锆石Hf同位素分析表明,上述三个岩体都具有正的εHf(t)值。岩石地球化学特征反映它们起源于不同深度的新生下地壳不同程度的部分熔融作用。综合考虑区域地层和岩浆岩资料,本文认为该花岗岩带与区域上同时代的镁铁质火山岩共同形成于西伯利亚和中朝古板块碰撞造山过程中与伸展有关的地球动力学环境,可能与向南俯冲的古亚洲洋板块在早三叠世的断离引起的软流圈上涌有关。     

Distribution of 238U, 232Th and 40K in plutonic rocks of Greece

One hundred and twenty one samples from every major plutonic body (mainly granitic) of Greece have been analyzed by γ-ray spectrometry to determine the specific activities of ²³⁸U, ²³²Th and ⁴⁰K (Bq/kg). The range of the activity concentrations of these radionuclides was 2.3–266.4, 1.8–375.5 and 55.0–1632.0 Bq/kg and their average values were 79.2, 85.3 and 881.4 Bq/kg respectively. Any possible connection between the specific activities of ²³⁸U, ²³²Th and ⁴⁰K and some characteristics of the studied samples (age, rock-type, colour, grain-size, occurrence and chemical composition) is investigated. Samples of particular colour, rock-type, occurrence and chemical composition have been identified for their distinctive levels of natural radioactivity, while age and grain-size do not affect the concentrations of ²³⁸U, ²³²Th and ⁴⁰K. The range of the Th/U ratio was 0.7–12.69. This great variation in the Th/U ratios, especially when it is found among the samples of the same pluton, is also discussed and explained by alteration and tectonic–metamorphic processes.     

大兴安岭北段喀喇其花岗斑岩体地球化学特征、锆石U-Pb年龄及构造背景

本文对大兴安岭北部喀喇其花岗斑岩体进行了岩石学、地球化学及锆石U-Pb年代学的研究,探讨了其形成的构造背景。结果表明:喀喇其花岗斑岩体锆石U-Pb年龄为132 Ma±1 Ma,表明其形成时代应为早白垩世晚期;岩石具有高钾钙碱性系列,过铝质特征;稀土元素属于轻稀土富集型,分布模式为右倾、左陡右平型式,具有较明显的Eu负异常特征。认为该花岗岩为铝质A型花岗岩,属于地壳岩石部分熔融的产物;该期岩浆侵位活动受蒙古—鄂霍茨克构造体系影响,形成于后造山大陆弧或后碰撞弧环境。     

Magmatic control on the contrasting Sn feritility of different granite plutons in the giant Gejiu orefield.SCIEI北大核心CSCD

云南个旧锡矿是全球最大的锡多金属矿床之一,但矿区内同时代花岗岩成锡矿潜力差异显著,其控制因素仍不清楚。本文选取贫矿的龙岔河似斑状花岗岩和成锡矿的老厂-卡房(后文简称老-卡)花岗岩为研究对象,通过全岩地球化学成分和黑云母成分分析,系统研究个旧矿区不同花岗岩成锡矿潜力差异的控制因素。测试结果表明,龙岔河花岗岩和老-卡花岗岩具有相似的、以表壳物质为主的岩浆源区以及较高的初始熔融温度,表明岩浆源区和熔融条件不是控制二者成矿潜力差异的主要原因。黑云母成分显示老-卡花岗岩和龙岔河花岗岩均具有较低的氧逸度,岩浆演化过程中锡为不相容元素,有利于锡在残余熔体中富集,表明氧逸度条件也不是导致成矿潜力差异的关键因素。龙岔河花岗岩发育角闪石、榍石、黑云母,而老-卡花岗岩发育岩浆白云母,指示后者分异程度更高。此外,与龙岔河花岗岩相比,老-卡花岗岩具有富硅,贫钛、铁、镁、钙和稀土元素特征,稀土元素呈现“海鸥式”配分模式,并且具有较低的Nb/Ta、Zr/Hf、K/Rb和较高的Rb/Sr比值,同样指示老-卡花岗岩具有更高的结晶分异程度。并且相比于龙岔河花岗岩为准铝质的特征,老-卡花岗岩的过铝质特征有利于锡分配进入岩浆出溶的流体相中富集成矿。因此,岩浆性质和演化程度是导致个旧地区不同花岗岩成矿潜力差异的主要原因,龙岔河花岗岩形成锡矿化的潜力较小。     

Does continental crust transform during eclogite facies metamorphism?

Eclogites within exhumed continental collision zones indicate regional burial to depths of at least 60 km, and often more than 100 km in the coesite‐stable, ultra‐high pressure (UHP) eclogite facies. Garnet, omphacitic pyroxene, high‐Si mica, kyanite ± coesite should grow at the expense of low‐P minerals in most felsic compositions, if equilibrium obtained at these conditions. The quartzofeldspathic rocks that comprise the bulk of eclogite facies terranes, however, contain mainly amphibolite facies, plagioclase‐bearing assemblages. To what extent these lower‐P minerals persisted metastably during (U)HP metamorphism, or whether they grew afterwards, reflects closely upon crustal parameters such as density, strength and seismic character. The Nordfjord area in western Norway offers a detailed view into a large crustal section that was subducted into the eclogite facies. The degree of transformation in typical pelite, paragneiss, granitic and granodioritic gneiss was assessed by modelling the equilibrium assemblage, comparing it with existing parageneses in these rocks and using U/Th–Pb zircon geochronology from laser ablation ICPMS to establish the history of mineral growth. U–Pb dates define a period of zircon recrystallization and new growth accompanying burial and metamorphism lasting from 430 to 400 Ma. Eclogite facies mafic rock (~2 vol.% of crust) is the most transformed composition and records the ambient peak conditions. Rare garnet‐bearing pelitic rocks (<10 vol.% of crust) preserve a mostly prograde mineral evolution to near‐peak conditions; REE concentrations in zircon indicate that garnet was present after 425 Ma and feldspar broke down after 410 Ma. Felsic gneiss – by far the most abundant rock type – is dominated by quartz + biotite + feldspar, but minor zoisite/epidote, phengitic white mica, garnet and rutile point to a prograde HP overprint. Relict textures indicate that much of the microstructural framework of plagioclase, K‐feldspar, and perhaps biotite, persisted through at least 25 Ma of burial, and ultimately UHP metamorphism. The signature reaction of the eclogite facies in felsic rocks – jadeite/omphacite growth from plagioclase – cannot be deduced from the presence of pyroxene or its breakdown products. We conclude that prograde dehydration in orthogneiss leads to fluid absent conditions, impeding equilibration beyond ~high‐P amphibolite facies.