植物在不同形态和不同状态下的荧光光谱特征研究

本文从光合作用的角度出发,讨论了植物叶片在不同形态、不同状态下的荧光光谱特征以及它们对荧光光谱的影响。文章涉及了以下几方面的内容:(1)植物在离体形态和活体形态下的荧光光谱特征;(2)叶片正面与反面的荧光光谱特征;(3)植物不同器官对荧光光谱的影响;(4)叶片放置时间对荧光光谱的影响;(5)叶片经不同处理时对荧光光谱的影响等。其目的是为激光荧光技术用于植被遥感的实施提供基础数据。     

拉尔玛矿床的自然金研究

本文在总结拉尔玛矿床中自然金及共生矿物一般特点的基础上,对自然金的矿物学和化学组成进行了较系统地研究。提出了决定自然金形成及在矿石、矿物中配分的主要地质因素。     

743离子交换快速分离—等离子体光谱法同时测定十五个稀土元素

本文研制了适用于地质样品中15个稀土元素分析的快速方法。样品经碱熔沉淀分离和743阳离子交换树脂分离富集将稀土元素制备成溶液用等离子体光谱法(ICP-AES)进行测量。方法检出限为0.002-0.3μg/g,当稀土元素含量为0.5-80,μg/g时,方法相对标准偏差为15％-2％。本方法经过多年的样品分析考验以及不断的改进和完善,证明方法简便快速,分析数据稳定可靠,能很好地满足地质样品中15个稀土分量测定的要求。     

高美古与凤凰山水汽含量的统计分析

介绍了利用北京师范大学研制的ＩＲＡ－９３５型红外水汽测量仪对云南丽江高美古天文候选点及昆明凤凰山对比点上空垂直大气水汽积分含量Ｗ０的观测结果,给出了两地Ｗ０的日变化曲线及分布图,并对全年测量数据的统计结果作了分析和讨论     

Tar ball frequency data and analytical results from a long-term beach monitoring program

Following the spill of fuel oils from the New Carissa in February 1999, approximately 300 km of beaches on the Pacific coast of North America were surveyed. A long-term observation program focused on the documentation of stranded tar balls in the vicinity of the spill site. Systematic beach surveys which were conducted over the period March 1999 to April 2001 and semi-logarithmic scale, time-series plots proved the most useful format for identifying trends. Beach monitoring continued through to August 2001. by which time 212 tar balls had been analyzed by GC/MS for their chemical characteristics. The samples of tar balls collected between February 1999 and August 2001 were qualitatively compared with New Carissa source oils (NCSO) and 101 (48%) were not consistent with NSCO. The presence of tar balls that are not related to an incident can confound attempts to define cleanup or endpoint criteria and to assess possible injury to natural resources.     

东海超高压榴辉岩中绿帘石、褐帘石、磷灰石和钍石集合体的电子探针成分和化学定年研究

中国大陆超深钻(CCSD)主孔从100米到3000米切穿含柯石英榴辉岩,为系统研究大陆深俯冲过程中含稀土元素副矿物提供了机会。本文报道了该钻孔榴辉岩存在发现的绿帘石、褐帘石、磷灰石和钍石复合颗粒。它们以同心环带结构为特征,从边部向中心依次为绿帘石、褐帘石和磷灰石;钍石既可包裹再磷灰石中,也可见于褐帘石中。电子探针分析显示,褐帘石不仅含有较高的轻稀土元素(LREE2O3=23．36wt％),而且可含有2．6wt％ThO2。根据绿帘石和褐帘石的电子探针高分辨U、Th、Pb成分计算得到绿帘石边部的形成年龄为738±88Ma,该年龄与大别-苏鲁地体榴辉岩的元古代源岩的年龄相当,因此,绿帘石可能为残留相。相反,褐帘石的年龄为220±41Ma,与大别-苏鲁超高压变质年龄相近。因此,褐帘石与磷灰石和钍石一起应该为超高压变质事件的产物。根据绿帘石、褐帘石及其共生的磷灰石和钍石的结构、成分特征和化学定年结果,我们推测绿帘石与可能已完全消耗的独居石很可能为变质副矿物组合的先驱矿物。独居石-绿帘石复合颗粒在榴辉岩相高压／超高压变质过程中反应形成磷灰石+钍石+褐帘石组合。     

Correlation of atmospheric visibility with chemical composition of Kaohsiung aerosols

The objective of this study was to investigate the correlation of visibility with chemical composition of Kaohsiung aerosols. Daytime visibility was observed around noon at two observation sites in metropolitan Kaohsiung, Taiwan in the years of 1999 and 2000. Both seasonal and diurnal variation patterns of visibility were observed in the region. Ambient aerosols were sampled and analyzed for 11 constituents, including water-soluble ionic species (Cl⁻, NO₃⁻, SO₄⁻², NH₄⁺, K⁺, Na⁺, Ca⁺², and Mg⁺²) and carbonaceous contents (OC, EC, and TC), to characterize the chemical composition of Kaohsiung aerosols. Furthermore, a stepwise multiple linear regression model was developed to elucidate the influence of aerosol species on visibility impairments. The results showed that sulfate was the dominant species that affected both light scattering coefficient and visibility. On average, the percentage contributions of visibility degrading species to light scattering coefficient were 29% for sulfate, 28% for nitrate, 22% for total carbon, and 21% for PM_2.5-remainder. An empirical regression model of visibility based on sulfate, nitrate, and relative humidity was also developed. The model showed that sulfate in PM_2.5 was the most sensitive species to visibility variation, suggesting that the reduction of sulfate in PM_2.5 could effectively improve the visibility of metropolitan Kaohsiung. During the investigation period, an event of Asian dusts intruded metropolitan Kaohsiung and dramatically increased the aerosol loadings, especially in the coarse particles. However, local visual air quality did not degrade accordingly during the Asian dust event because both visibility and light scattering coefficient are affected mainly by the fine particles. The results are discussed in detail in the paper.     

Statistical empirical index of chemical weathering in igneous rocks: A new tool for evaluating the degree of weathering

Chemical weathering indices are useful tools in characterizing weathering profiles and determining the extent of weathering. However, the predictive performance of the conventional indices is critically dependent on the composition of the unweathered parent rock. To overcome this limitation, the present paper introduces an alternative statistical empirical index of chemical weathering that is extracted by the principal component analysis (PCA) of a large dataset derived from unweathered igneous rocks and their weathering profiles. The PCA analysis yields two principal components (PC1 and PC2), which capture 39.23% and 35.17% of total variability, respectively. The extent of weathering is reflected by variation along PC1, primarily due to the loss of Na₂O and CaO during weathering. In contrast, PC2 is the direction along which the projections of unweathered felsic, intermediate and mafic igneous rocks appear to be best discriminated; therefore, PC1 and PC2 represent independent latent variables that correspond to the extent of weathering and the chemistry of the unweathered parent rock. Subsequently, PC1 and PC2 were then mapped onto a ternary diagram (MFW diagram). The M and F vertices characterize mafic and felsic rock source, respectively, while the W vertex identifies the degree of weathering of these sources, independent of the chemistry of the unweathered parent rock.

The W index has a number of significant properties that are not found in conventional weathering indices. First, the W index is sensitive to chemical changes that occur during weathering because it is based on eight major oxides, whereas most conventional indices are defined by between two and four oxides. Second, the W index provides robust results even for highly weathered sesquioxide-rich samples. Third, the W index is applicable to a wide range of felsic, intermediate and mafic igneous rock types. Finally, the MFW diagram is expected to facilitate provenance analysis of sedimentary rocks by identifying their weathering trends and thereby enabling a backward estimate of the composition of the unweathered source rock.     

Control of wind strength and frequency in the Aral Sea basin during the late Holocene

Changing content of detrital input in laminated sediments traced by XRF scanning and microfacies analyses reflect prominent variations in sedimentation processes in the Aral Sea. A high-resolution record of titanium from a core retrieved in the northwestern Large Aral Sea allows a continuous reconstruction of wind strength and frequency in western Central Asia for the past 1500 yr. During AD 450–700, AD 1210–1265, AD 1350–1750 and AD 1800–1975, detrital inputs (bearing titanium) are high, documenting an enhanced early spring atmospheric circulation associated with an increase in intensity of the Siberian High pressure system over Central Asia. In contrast, lower titanium content during AD 1750–1800 and AD 1980–1985 reflects a diminished influence of the Siberian High during early spring with a reduced atmospheric circulation. A moderate circulation characterizes the time period AD 700–1150. Unprecedented weakened atmospheric circulation over western Central Asia are inferred during ca. AD 1180–1210 and AD 1265–1310 with a considerable decrease in dust storm frequency, sedimentation rates, lamination thickness and detrital inputs (screened at 40-μm resolution). Our results are concurrent with changes in the intensity of the Siberian High during the past 1400 yr as reported in the GISP2 Ice Core from Greenland.     

南京太平门地段雪松树年轮及其根土中化学元素含量的相关性研究

１９９４年在南京市太平门街道采集了五株雪松的年轮样及其根部土壤（黄棕壤ｐＨ＝６．６８）,分别测定了Ｌｉ、Ａｌ、Ｐ、Ｋ、Ｍｎ、Ｃｏ、Ｃｕ、Ｚｎ、Ｃｄ、Ｂａ和Ｐｂ等１１种化学元素含量,实测结果验证了雪松年轮与其根部当年土壤中化学元素含量满足对数线性相关模式;ｌｇＣ′（Ｚ,ｔ）＝ａ（Ｚ）＋ｂ（Ｚ）ｌｇＣ（Ｚ,ｔ）。根据年轮元素含量Ｃ（Ｚ,ｔ）可以重建过去根土中元素含量Ｃ′（Ｚ,ｔ）,即反映环境（土壤）中元素含量的逐年演变的年份序列。利用Ｃ（Ｚ,ｔ）中最低含量可估算该地段黄棕壤的土壤元素背景值。