姬塬地区长8油层组层序地层格架内成岩相展布特征

通过岩心观察并充分利用普通薄片、铸体薄片、阴极发光、X-衍射和扫描电镜等资料,对姬塬地区长8油层组储层的成岩作用、成岩矿物、成岩阶段和成岩演化序列特征等进行了研究。根据成岩作用类型及强度、成岩矿物等将储层划分为绿泥石衬边弱溶蚀、不稳定组分溶蚀、压实致密、高岭石充填和碳酸盐胶结5种成岩相。并通过岩心薄片资料刻度测井归纳出不同成岩相在GR、AC等测井曲线及其组合上的响应特征,由此实现各单井储层成岩相的连续划分。对长8油层组层序界面和基准面旋回与成岩相展布的关系进行了研究,结果表明层序界面附近不稳定组分溶蚀相及高岭石充填相较为发育,且各井之间对比性良好,同时层序界面也控制了碳酸盐胶结;中期基准面旋回的最大湖泛面处均发育井间可对比的压实致密相,长82中期基准面下降半旋回砂体一方面易于遭受溶蚀产生次生孔,另一方面由于受沉积驻留和碎屑组分影响导致压实强度较弱,因此物性总体比长81砂体好。     

Correlation analysis and partial least square modeling to quantify typical minerals with Chang＇E-3 visible and near-infrared imaging spectrometer＇s ground validation data

In 2013, Chang＇E-3 program will develop lunar mineral resources in-situ detection. A Visible and Near-infrared Imaging Spectrometer （VNIS） has been selected as one payload of CE-3 lunar rover to achieve this goal. It is critical and urgent to evaluate VNIS＇ spectrum data quality and validate quantification methods for mineral composition before its launch. Ground validation experiment of VNIS was carried out to complete the two goals, by simulating CE-3 lunar rover＇s detection environment on lunar surface in the laboratory. Based on the hyperspectral reflectance data derived, Correlation Analysis and Partial Least Square （CA-PLS） algorithm is applied to predict abundance of four lunar typical minerals （pyroxene, plagioclase, ilmenite and olivine） in their mixture. We firstly selected a set of VNIS＇ spectral parameters which highly correlated with minerals＇ abundance by correlation analysis （CA）, and then stepwise regression method was used to find out spectral parameters which make the largest contri- butions to the mineral contents. At last, functions were derived to link minerals＇ abundance and spectral parameters by partial least square （PLS） algorithm. Not considering the effect of maturity, agglutinate and Fe~, we found that there are wonderful correlations between these four minerals and VNIS＇ spectral parameters, e.g. the abundance of pyroxene correlates positively with the mixture＇s absorption depth, the value of absorption depth added as the in- creasing of pyroxene＇s abundance. But the abundance of plagioclase correlates negatively with the spectral parame- ters of band ratio, the value of band ratio would decrease when the abundance of plagioclase increased. Similar to plagioclase, the abundance of ilmenite and olivine has a negative correlation with the mixture＇s reflectance data, if the abundance of ilmenite or olivine increase, the reflectance values of the mixture will decrease. Through model validation, better estimates of pyroxene, plagioclase and ilmenite＇s abundances are given. It is concluded that VNIS has the capability to be applied on lunar minerals＇ identification, and CA-PLS algorithm has the potential to be used on lunar surface＇s in-situ detection for minerals＇ abundance prediction.     

Rapid screening of Zr-containing particles from Chang’e-5 lunar soil samples for isotope geochronology: Technical roadmap for future study

New samples returned by China Chang’e-5 (CE-5) mission offer an opportunity for studying the lunar geologic longevity, space weathering, and regolith evolution. The age determination of the CE-5 samples was among the first scientific questions to be answered. However, the precious samples, most in the micrometer size range, challenge many traditional analyses on large single crystals of zircon developed for massive bulk samples. Here, we developed a non-destructive rapid screening of individual zirconium-containing particle for isotope geochronology based on a Micro X-ray fluorescence analysis (µXRF). The selected particles were verified via scanning electron microscopy (SEM), 3D X-ray microscopy (XRM), and focused ion beam scanning electron microscopy (FIB-SEM) techniques, which showed that zirconium-bearing minerals with several microns were precisely positioned and readily suitable for site-specific isotopic dating by second ion mass spectrometry (SIMS). Such protocol could be also applicable in non-destructively screening other types of particles for different scientific purposes. We therefore proposed a correlative workflow for comprehensively studying the CE-5 lunar samples from single particles on nanometer to atomic scales. Linking various microscopic and spectromicroscopic instruments together, this workflow consists of six steps: (1) single-particle selection with non-destructive µXRF technique, (2) 2D/3D morphological and structural characterization with a correlative submicron 3D XRM and nanoscale resolution FIB-SEM imaging methods, (3) SEM analysis of the surface morphology and chemistry of the selected particle, (4) a series of microscopic and microbeam analyses (e.g., SEM, electron probe microanalysis, and SIMS) on the cross-section of the selected particle to obtain structural, mineralogical, chemical, and isotopic features from the micron to nanometer scale, (5) advanced 2D/3D characterization and site-specific sample preparation of thin foil/tip specimens on a microregion of interest in the selected particle with FIB-SEM technique, and (6) comprehensive analyses on the FIB-milled specimens at nanometer to atomic scale with synchrotron-based scanning transmission X-ray microscopy, analytic transmission electron microscopy, and atom probe tomography. Following this technical roadmap, one can integrate multiple modalities into a uniform frame of multimodal and multiscale correlated datasets to acquire high-throughput information on the limited or precious terrestrial and extraterrestrial samples.     

鄂尔多斯盆地南部延长组长7油组页岩层系天然裂缝发育特征及主控因素

利用地表露头、岩心、薄片和测井资料,对鄂尔多斯盆地南部长7油层组陆相页岩层系天然裂缝的成因类型、发育特征和主控因素进行研究。按地质成因,鄂尔多斯盆地南部长7油层组页岩层系的天然裂缝可以分为构造裂缝和成岩裂缝两大类,其中构造裂缝主要包括剪切裂缝和张性裂缝;成岩裂缝主要包括层理缝、页理缝和收缩裂缝。不同岩性中的天然裂缝发育情况明显不同,致密砂岩中以构造裂缝为主,层理缝仅在粉砂岩和局部细砂岩中发育;页岩和凝灰岩中页理缝、层理缝和构造裂缝均比较发育。不同类型的天然裂缝主控因素明显不同,构造裂缝的发育主要受岩性和岩石力学层层厚控制;砂岩中层理缝的发育主要受碳质纹层、粘土矿物转化程度等因素控制;凝灰岩中层理缝的发育主要受刚性玻屑脱玻化作用的控制;页岩中页理缝的发育主要受纹层、TOC含量和黄铁矿含量的控制。     

构造活动影响下地质事件沉积序列：以鄂尔多斯盆地延长组长7油层组为例

中晚三叠世,印支运动I幕导致秦岭隆升,同期地震、火山活动频发,在鄂尔多斯湖盆中保存了大量地质事件沉积层。为了认识构造活动影响下地质事件沉积序列,探讨地质历史时期内各类地质事件的耦合关系,从全新的角度认识大型坳陷湖盆的形成和演化过程,笔者等以鄂尔多斯盆地内部及周缘的长7油层组野外露头及钻井岩心中发育的关键事件沉积层为研究对象,对地震事件、浊流事件、火山事件、缺氧事件沉积特征和叠置关系进行研究。研究结果表明：在长7期,湖盆中多种事件沉积类型主要受控于中—晚三叠世秦岭造山运动,构造活动引起湖盆沉降,为事件沉积层的保存提供了条件;火山事件喷发的火山灰降落在湖盆中形成凝灰岩层,同时,也为湖盆缺氧事件创造了条件;沉积层因地震活动形成震积岩,而地震活动又是诱发浊流事件发生的关键因素;这些构造活动影响下的地质事件交替发生,共同构成长7油层组内各类事件沉积层的相互叠置关系。     

华庆地区长63储层内部建筑结构模式分析

储层内部建筑结构是评价油气藏、改善水驱开发效果、提高油气采收率的基础和关键。因此,文章以华庆地区长6₃层水下分流河道为例,利用野外露头照片和连井剖面等资料,应用petrel软件,系统建立了华庆地区长6₃储层构造模型和储层参数(孔隙度、渗透率和泥质含量)模型。研究结果表明,三角洲前缘水下分流河道构型界面可划分为5级:其中5级为同期水下分流河道复合砂体的界面,4级为水下分流河道单一砂体的沉积界面,3级为水下分流河道单一砂体内部增生体的界面,2级为增生体内部简单的层系组界面,1级为增生体内部单个交错层系的界面。研究区砂体内部存在侧积夹层、前积夹层和垂积夹层3种类型的夹层。建立的研究区长6₃构造模型总体趋势为西低东高。从孔隙度、渗透率和砂泥岩分布模型图可以看出研究区属于低孔特低渗储层。结构解析结果客观的反映了长6₃储层内部基本单元的展布形态,真实再现了研究区内部砂体的空间形态分布模型图。     

哀牢山南段长安金矿地质特征及找矿方法研究

长安金矿位于哀牢山成矿带南段,是该成矿带上新近发现的又一大型金矿床。该区为哀牢山地体边缘地壳增生带,主要由深变质岩系组成,区内构造断裂发育,对岩浆活动和成矿作用有显著影响。本文总结了长安金矿的地质特征,并以该区的控矿断裂F6为主要研究目标,以地层岩性电性特征作为约束条件,分别展开了磁法、激电、瞬变电磁和大地电磁等综合物探手段的试验研究。研究结果表明,磁法对于该矿找矿效果不明显,瞬变电磁和大地电磁测深反演的电阻率低阻体,准确界定了控矿断裂F6的位置、倾向、断距以及深部延伸情况,通过激电异常可大致判断矿体的位置。所以在长安金矿区下一步的深部隐伏矿勘查中,结合瞬变电磁、激电、大地电磁等地球物理方法,辅以土壤化探异常进行约束,可以达到快速有效找矿之目的。     

长江下游越冬期冷暖长期变化与大型环流低频振动

本文运用上海112年月平均温度资料和1月、10月的月平均海平面气压场110年资料,分析了以上海资料为代表的长江下游地区越冬季节温度由偏冷转向偏暖的长期变化及其有关联的大型环流系统的低频振动。发现近百年中前冬11月、12月和后冬2月这三个月的冷暖长期变化相似,特点是前50年左右偏冷占优势;后50年左右偏暖占优势,相应地10月大型环流中亚洲大陆冷高压的优势是前50年偏强偏东;后50年偏弱偏西,北太平洋高压的变化趋势则是前50年偏弱;后50年偏强。1月气温的长期变化与上述11月、12月和2月的冷暖变化不同,对应的大型环流低频振动也不同。     

High‐precision Dating and Geological Significance of Chang 7 Tuff Zircon of the Triassic Yanchang Formation,Ordos Basin in Central China

The Ordos Basin, as the second largest petroliferous basin of China, contains abundant oil and gas resources, oil shale, and sandstone-type uranium mineral resources. Chang 7 shale is not only the major source rock of the Mesozoic petroliferous system of the Basin, but is also crucial in determining the space-time distribution relationship of the shale section for the effective exploration and development of the Basin's oil and gas resources. To obtain a highly precise age of the shale development section, we collected tuff samples from the top and bottom profile of the Chang 7 Member, Yishi Village, Yaoqu Town, Tongchuan District, on the southern margin of the Ordos Basin and performed high-precision chemical abrasion(CA)–isotope dilution(ID)–thermal ionization mass spectrometry(TIMS) zircon U-Pb dating on the basis of extensive laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS) zircon U-Pb dating data. Our results show the precise ages of the top and bottom zircon in the Chang 7 shale to be 241.06±0.12 Ma and 241.558±0.093 Ma, respectively. We first obtained Chang 7 age data with Grade 0.1-Ma precision and then determined the age of the shale development in the Chang 7 Member to be the early-Middle Triassic Ladinian. This result is supported by paleontological evidence. The deposition duration of the Chang 7 shale is 0.5 Ma with an average deposition rate of the shale section being 5.3 cm/ka. Our research results provide time scale and basic data for further investigation of the basin–mountain coupling relation of the shale section, the sedimentary environment and volcanic ash and organic-matter-rich shale development relation, and the organism break-out and organic-matter enrichment mechanism.     

鄂尔多斯盆地渭北地区上三叠统延长组长7油层组碳酸盐结核中自生碳酸盐矿物的特征

早期形成的碳酸盐结核在埋藏期间会经历多种碳酸盐矿物相沉淀的复杂胶结作用,岩石学研究是探究结核成因的关键。通过野外剖面观察、岩石学观察和阴极发光技术,分析了鄂尔多斯盆地渭北地区上三叠统延长组长7油层组泥页岩中各种形状的方解石和白云石结核中自生碳酸盐矿物的特征。这些结核为成岩早期的产物,构成结核的自生碳酸盐矿物特征显著:(1)球粒方解石结核中,方解石呈纤维状或刃片状,球粒间充填晶粒方解石或因压实呈贴面结合,纤维状方解石发桔红色和暗红色2种光,刃片状方解石发暗红色光;(2)粉晶方解石结核中,方解石呈他形粒状,含有机质包裹体或纤维状晶形残余,晶间含沥青和纤维状方解石残余,主要发暗红色光;(3)白云石结核有泥晶和粉晶2种晶体类型,粉晶白云石结核含较多泥质,泥质条带或有机质条带处常见纤柱状白云石;(4)沿裂缝充填的方解石和白云石常呈纤维状或纤柱状结构,发暗红色光或不发光。研究区长7油层组碳酸盐结核中的方解石和白云石具有不同的成因类型和复杂的胶结作用:球粒方解石和泥晶白云石代表了结核开始形成时的胶结作用,可以准确地反映结核的成因;粉晶方解石、粉晶白云石反映了交代成因;裂缝中纤维状、纤柱状方解石和白云石集合体则为结核经历了较强压实作用之后充填裂缝而成。