不同压实度荆门弱膨胀土的一维膨胀-压缩特性

为探讨压实膨胀土的体变行为,以荆门弱膨胀土为研究对象,借助高压固结仪对6种制样压实度下的膨胀土试样进行了一维无荷载膨胀和含一次卸载-再加载循环的压缩试验。基于膨胀试验结果,构建了膨胀时程方程,通过参数分析,明确了方程参数的物理意义,并建议了膨胀时程曲线3阶段的划分方法。基于压缩试验结果,探讨了固结屈服应力、压缩指数Cc、回弹指数Cs、膨胀力与制样压实度、土体结构性、膨胀势、孔隙比的相关关系。试验结果及其分析表明,膨胀土体积变化是膨胀势与外部荷载、湿度变化的耦合作用结果,且具有强烈的水-力路径依赖性。     

Competition behaviour of metal uptake in cementitious systems: An XRD and EXAFS investigation of Nd- and Zn-loaded 11 Å tobermorite

Cement-based materials play an important role in multi-barrier concepts developed worldwide for the safe disposal of hazardous and radioactive wastes. Cement is used to condition and stabilize the waste materials and to construct the engineered barrier systems (container, backfill and liner materials) of repositories for radioactive waste. In this study, bulk-X-ray absorption spectroscopy (XAS) was used to investigate the uptake mechanism of Nd on the crystalline C–S–H phase 11 Å tobermorite in the presence of Zn (co-absorbing metal), and vice versa, as potential competitor under strongly alkaline conditions (pH = 12.5–13.3). The Zn and Nd concentration in all samples was 50,000 ppm, whereas the reaction times varied from 1 to 6 months.Extended X-ray absorption fine structure (EXAFS) data of the Nd L_III-edge indicate that the local structural environment of Nd consists of ∼7–8 O atoms at 2.42 Å, ∼7–8 Si at ∼3.67 Å and ∼5–6 Ca at ∼3.8 Å, and that this environment remains unchanged in the presence and absence of Zn. In contrary, Zn K-edge EXAFS data exhibit distinct differences in the presence and absence of Nd as co-absorbing element. Data analysis indicates that Zn is tetrahedrally coordinated (∼4 O at ∼1.96 Å) and the obtained structural data in the simultaneous presence of Nd and Zn are consistent with the formation of mixed Zn surface complexes and Zn bound in the interlayer remaining in these positions also with prolonged reaction times (up to 6 months). However, without the co-absorbing element Nd, strong structural changes in the uptake mechanisms of Zn are observable, e.g., after 3 month reaction time Zn–Zn backscattering pairs can be observed. These findings suggest that Nd has an influence on the incorporation of Zn in the tobermorite structure. In addition, the results of this study indicate that competitive uptake of metal cations with similar sorption behaviour by C–S–H phases can take place, deserving further attention in future assessments of the safe disposal of radioactive wastes in cement-based repositories.     

原料配比对氯氧镁水泥固化砾石土干密度的影响

干密度是评价软土固化质量的重要指标,一般通过室内击实试验获得。以氯氧镁水泥(MOC)为结合料,砾石土为固化对象,研究了原料配比对MOC固化砾石土击实性能的影响。通过室内击实试验,考察了轻烧镁粉掺量、卤水浓度、卤水掺量和活性MgO/MgCl_2物质的量比(Mg/Cl比)影响混合料干密度的规律。结果表明:MOC固化砾石土击实料的干密度随卤水掺量增加先增加后降低,随轻烧镁粉掺量及Mg/Cl比的增加而先增加后降低,随卤水浓度及轻烧镁粉掺量的增加而增加,随卤水浓度增加及Mg/Cl比降低而增加。     

煤电阻率与其瓦斯含量关系的实验研究

煤体中的瓦斯含量能显著影响煤的电阻率,本文利用高精度电阻测试实验装置,在连续吸附/解吸与等体积吸附/解吸条件下,对煤样的电阻率随瓦斯含量的变化规律进行测定。研究结果表明:煤样在连续吸附/解吸与等体积吸附/解吸条件下,电阻率随着瓦斯吸附量增大先逐渐减小,后趋于平稳;等体积吸附(静态吸附)时电阻率改变较连续吸附(动态吸附)明显,且等体积解吸结束时,煤体电阻率距离原始值较远;在瓦斯解吸过程中,煤体电阻率随煤中瓦斯含量增大呈线性减小。研究结果为利用煤体电阻率与瓦斯含量的线性关系预测矿井瓦斯含量提供了理论依据,对指导现场的瓦斯含量测量具有重要意义。     

A natural cement analogue study to understand the long-term behaviour of cements in nuclear waste repositories: Maqarin (Jordan)

The geological storage of nuclear waste includes multibarrier engineered systems where a large amount of cement-based material is used. Predicting the long term behaviour of cement is approached by reactive transport modelling, where some of the boundary conditions can be defined through studying natural cement analogues (e.g. at the Maqarin natural analogue site). At Maqarin, pyrometamorphism of clay biomicrites and siliceous chalks, caused by the in-situ combustion of organic matter, produced various clinker minerals. The interaction of infiltrating groundwater with these clinker phases resulted in a portlandite-buffered hyperalkaline leachate plume, which migrated into the adjacent biomicrite host rock, resulting in the precipitation of hydrated cement minerals.In this study, rock samples with different degrees of interaction with the hyperalkaline plume were investigated by various methods (mostly SEM-EDS). The observations have identified a paragenetic sequence of hydrous cement minerals, and reveal how the fractures and porosity in the biomicrite have become sequentially filled. In the alkaline disturbed zone, C-A-S-H (an unstoichiometric gel of Ca, Al, Si and OH) is observed to fill the pores of the biomicrite wallrock, as a consequence of reaction with a high pH Ca-rich fluid circulating in fractures. Porosity profiles indicate that in some cases the pores of the rock adjacent to the fractures became tightly sealed, whereas in the veins some porosity is preserved. Later pulses of sulphate-rich groundwater precipitated ettringite and occasionally thaumasite in the veins, whereas downstream in the lower pH distal regions of the hyperalkaline plume, zeolite was precipitated.Comparing our observations with the reactive transport modelling results reveals two major discrepancies: firstly, the models predict that ettringite is precipitated before C-A-S-H, whereas the C-A-S-H is observed as the earlier phase in Maqarin; and, secondly, the models predict that ettringite acts as the principal pore-filling phase in contrast to the C-A-S-H observed in the natural system. These discrepancies are related to the fact that our data were not available at the time the modelling studies were performed. However, all models succeeded in reproducing the porosity reduction observed at the fracture–rock interface in the natural analogue system.     

Long-term coupled behaviour of cemented paste backfill in load cell experiments

A pressure cell apparatus has been developed in this research work to study the long-term hydro-mechanical behaviour of cemented paste backfill (CPB) cured under applied stress. The samples are cured for 7, 28, 90 and 150 days and the evolution of their mechanical, hydraulic, physical and microstructural properties is studied. Also, the suction, temperature and electrical conductivity are monitored for a period of 150 days of curing. The testing and monitoring programmes are conducted in undrained conditions, with and without pressure application. The obtained results show that the curing stress affects the hydro-mechanical behaviour of CPB for up to 28 days. Within this curing period, the CPB exhibits enhanced hydro-mechanical performance. However, application of sustained excessive curing stress onto the CPB samples induces the propagation of microcracks in the backfill structure, thus causing lower mechanical strength and higher fluid permeability at the more advanced ages. Furthermore, the mineralogical and chemical compositions of the tailings (e.g., sulfidic tailings) can significantly alter the mechanical strength properties (uniaxial compressive strength and elastic modulus) and the permeability of the CPB. The evolution of coupled factors and characteristics of the CPB at an early age control and influence its long-term behaviour and performance.     

新型膨大管柱堵漏工具的研究与试制

为了提高钻遇断层、大裂缝、溶洞及流水溶洞情况发生的失返性漏失堵漏的成功率,研制了一种新型膨大管柱堵漏工具。该工具直接送达漏层,使堵漏材料在受限空间内凝固,并在井眼轨迹穿过的通道上建立所需体积和强度的堵塞,从而解决失返性漏失问题。介绍了该堵漏工具的结构组成、选材、制造工艺和使用方法。     

Swelling model study of expansive soil at K-0 and triaxial stress stateEI北大核心CSCD

A series of swelling tests is performed on a typical Nanyang expansive soil with medium swelling capacity compacted at various initial densities and water contents. The swelling tests are separately conducted using the conventional oedometer to confine the lateral swelling of the soil specimens, and using the GDS triaxial apparatus to allow the free volumetric swelling. The multiple nonlinear mathematical method is adopted to obtain the lateral swelling model (i.e. K-0 model), which fully considers the coupled effect of initial degree of compaction, moisture content and overburden pressure on the swelling strain. Also, an empirical model for the relationship between spherical stress and volumetric strain is proposed by triaxial swelling test. Based on the K-0 swelling model, a formula is proposed to quantitatively evaluate the swell potential, and also a theoretical calculation method is derived to determine the processing layer thickness of expansive soil slope. Based on the assumption that volumetric swelling strain only changes with spherical stress and is not affected by the deviatoric stress, the correlations between the K-0 model and triaxial model are analyzed, and a method to calculate the volumetric swelling strain by only employing the K-0 model is given. Experimental results show that the proposed K-0 model with multifactor coupling is reasonable to predict the swelling potential of compacted expansive soil. It is found that the key factor to link the K-0 model and triaxial swelling model is assuming an average static lateral pressure coefficient. The average static lateral pressure coefficient tends to decreases with increasing overburden pressure by inversion method. This tendency of average static lateral pressure coefficient is believed to rely on the fact that lateral swelling pressure decreases with the increase of overburden pressure.     

Sulphate Attack in Lime-Treated Marine Clay

The use of lime to improve the properties of soft clays is not new. Recently the deep lime mixing technique has been extended to coastal regions for improving the behavior of weak marine clays. But lime treatment technique should be approached carefully for clay containing a high percentage of sodium sulphate. The presence of sulphate in lime-treated clays may result in high swelling due to the formation of the expansive mineral, ettringite. A limited study of lime-treated marine clays has shown a need to further explore the formation of ettringite and its stability with time. In this article, a laboratory investigation was carried out to examine the influence of sodium and calcium sulphates on the behavior of lime column treated marine clay. Scanning electron microscopy (SEM) was used to identify the formation of various reaction products, including ettringite. Test results indicate that the formation of ettringite in the lime-sodium sulphate-clay system adversely affects the engineering behavior of the marine clay, whereas the addition of calcium sulphate significantly improves the engineering characteristics of the soil.     

Modelling chemo‐hydro‐mechanical behaviour of unsaturated clays: a feasibility study

Effective capabilities of combined chemo‐elasto‐plastic and unsaturated soil models to simulate chemo‐hydro‐mechanical (CHM) behaviour of clays are examined in numerical simulations through selected boundary value problems. The objective is to investigate the feasibility of approaching such complex material behaviour numerically by combining two existing models. The chemo‐mechanical effects are described using the concept of chemical softening consisting of reduction of the pre‐consolidation pressure proposed originally by Hueckel (Can. Geotech. J. 1992; 29 :1071–1086; Int. J. Numer. Anal. Methods Geomech. 1997; 21 :43–72). An additional chemical softening mechanism is considered, consisting in a decrease of cohesion with an increase in contaminant concentration. The influence of partial saturation on the constitutive behaviour is modelled following Barcelona basic model (BBM) formulation (Géotech. 1990; 40 (3):405–430; Can. Geotech. J. 1992; 29 :1013–1032). The equilibrium equations combined with the CHM constitutive relations, and the governing equations for flow of fluids and contaminant transport, are solved numerically using finite element. The emphasis is laid on understanding the role that the individual chemical effects such as chemo‐elastic swelling, or chemo‐plastic consolidation, or finally, chemical loss of cohesion have in the overall response of the soil mass. The numerical problems analysed concern the chemical effects in response to wetting of a clay specimen with an organic liquid in rigid wall consolidometer, during biaxial loading up to failure, and in response to fresh water influx during tunnel excavation in swelling clay. Copyright © 2005 John Wiley & Sons, Ltd.