Adsorption of Pentachlorophenol onto Oxide and Clay Minerals： Surface Reaction Model and Environmental Implications

The adsorption of pentachlorophenol （PCP） onto quartz, kaolinite, illite, montmorillonite and iron oxides has been investigated by batch equilibrium techniques. The pH-dependent isotherms are curves with peak values, the position of which is at about pH = 5-6 depending on the mineral species. Based on distribution of both speciation of surface hydroxyls on minerals and PCP in solution a surface reaction model involving surface complexation and surface electrostatic attraction is presented to fit the pH-dependent isotherms, and both reaction constants are calculated. The results show that on quartz and phyllosilicate minerals the predominant adsorption reaction is surface complexation, meanwhile both of surface electrostatic attraction and surface complexation are involved on the iron oxide minerals. The reaction constants of surface electrostatic adsorption are usually one to three orders in magnitude, larger than that of surface complexation. The concentration-dependent isotherms can be well fitted by Langmnir equation with the correlation coefficient R〉0.93 for kaolinite and iron oxides. The maximum adsorption is found in the order： hematite 〉 lepidocrocite 〉 goethite 〉 kaolinite 〉 quartz 〉 montmorillonite ≈ illite, which can be interpreted by consideration of both reaction mechanism and surface hydroxyl density. The significant adsorption of PCP onto mineral surfaces suggests that clay and iron oxide minerals will play an important role as HIOCs are adsorbed in laterite or latertoid soil, which is widespread in South China.     

Mesozoic Bimodal Volcanic Suite in Zhalantun of the Da Hinggan Range and Its Geological Significance： Zircon U-Pb Age and Hf Isotopic Constraints

1 Introduction Mesozoic volcano-intrusive rocks are widely distributed in the Da Hinggan Range of northeastern China, and are considered as one of the most spectacular geological sights in eastern Asia. Recently, studies on granites with high εNd(t) values and Phanerozoic crustal growth in the Centra Asian Orogenic Belt have greatly promoted fundamental research into the geology of this area (Jahn et al., 2000, 2001, 2004; Wu et al., 2000, 2002, 2003). However, work on the eruption time,…     

2017年春季季风间期南海中北部浮游植物生长与微型浮游动物摄食

Phytoplankton growth rates and mortality rates were experimentally examined at 21 stations during the 2017 spring intermonsoon(April to early May) in the northern and central South China Sea(SCS) using the dilution technique, with emphasis on a comparison between the northern and central SCS areas which had different environmental factors. There had been higher temperature but lower nutrients and chlorophyll a concentrations in the central SCS than those in the northern SCS. The mean rates of phytoplankton growth(μ_0) and microzooplankton grazing(m) were(0.88±0.33) d~(–1) and(0.55±0.22) d~(–1) in the central SCS, and both higher than those in the northern SCS with the values of μ_0((0.81±0.16) d~(–1)) and m((0.30±0.09) d~(–1)), respectively.Phytoplankton growth and microzooplankton grazing rates were significantly coupled in both areas. The microzooplankton grazing impact(m/μ_0) on phytoplankton was also higher in the central SCS(0.63±0.12) than that in the northern SCS(0.37±0.06). The microzooplankton abundance was significantly correlated with temperature in the surface. Temperature might more effectively promote the microzooplankton grazing rate than phytoplankton growth rate, which might contribute to higher m and m/μ_0 in the central SCS. Compared with temperature, nutrients mainly affected the growth rate of phytoplankton. In the nutrient enrichment treatment,the phytoplankton growth rate(μn) was higher than μ_0 in the central SCS, suggesting phytoplankton growth in the central SCS was nutrient limited. The ratio of μ_0/μn was significantly correlated with nutrients concentrations in the both areas, indicating the limitation of nutrients was related to the concentrations of background nutrients in the study stations.     

适宜浓度的维生素E促进半滑舌鳎生长激素基因的表达

本实验旨在探究维生素E对半滑舌鳎垂体组织中生长激素基因表达的影响。作者在每千克等氮等能的基础饲料中分别添加0、400和1 600mg的DL-α-生育酚乙酸酯(维生素E)投喂半滑舌鳎(Cynoglossus semilaevis)成鱼(464±2.6) g,进行为期8周的养殖实验;另外,在L-15培养基中添加0、18和54μmol/L的维生素E,对半滑舌鳎成鱼(464±2.6) g的垂体细胞进行为期3 d的体外原代培养实验。分别取垂体组织和原代细胞,通过荧光实时定量PCR分析其gh mRNA的相对表达量。实验结果表明:垂体组织中gh mRNA的相对表达量随着饲料中维生素E含量的增加而呈现先升高后下降的变化趋势,在400 mg/kg组时显著高于其他各组(P0.05);随着细胞培养液中维生素E浓度的升高, gh mRNA的相对表达量显著增加(P0.05)。由此可见,适宜浓度的维生素E能够促进半滑舌鳎垂体组织中生长激素基因的表达。     

短蛸对不同生物饵料利用的比较

为比较短蛸（Octopus ocellatus）对不同生物饵料的利用效果,以南美白对虾、肉球近方蟹、菲律宾蛤仔和玉筋鱼四种饵料进行了饲喂实验。结果表明：1）肉球近方蟹组短蛸增重率显著高于其他各组（P<0.05）,南美白对虾组脏体比显著高于玉筋鱼组（P<0.05）,各饵料组肝体比无显著差异;2）南美白对虾组和肉球近方蟹组短蛸肌肉的蛋白质含量显著高于菲律宾蛤仔组和玉筋鱼组（P<0.05）,肉球近方蟹组脂肪含量显著高于其余各组（P<0.05）,玉筋鱼组灰分含量显著低于其他各组（P<0.05）;3）南美白对虾组短蛸肝胰腺谷丙转氨酶活性显著高于其余各组（P<0.05）,肉球近方蟹组谷草转氨酶活性显著高于其余各组（P<0.05）,玉筋鱼组谷氨酸脱氢酶活性显著低于其余各组（P<0.05）,菲律宾蛤仔组酸性磷酸酶活性显著高于其余各组（P<0.05）,玉筋鱼组胃蛋白酶活性显著高于其他各组（P<0.05）。综上,投喂肉球近方蟹可以显著提高短蛸的增重率;不同饵料对短蛸肌肉的蛋白质、脂肪和灰分含量有影响,对其肝胰腺功能和胃蛋白酶活性也有显著影响。     

海南典型热带海草床4种代表性鱼类的生长特征及其对海草资源量变化的响应

文章以海南岛新村湾、黎安港和潭门港海草床为研究区域, 选取褐篮子鱼(Siganus fuscessens)、点斑篮子鱼(Siganus guttatus)、四带牙鯻(Pelates quadrilineatus)和细鳞鯻(Terapon jarbua) 4种代表性鱼类为研究对象, 分析其体长与体质量的关系, 并探讨4种鱼类对海草资源量变化的响应。结果表明, 除栖息于潭门港海草床的4种鱼为负异速生长, 其他区域海草床的鱼类均为正异速或等速生长; 4种鱼的体质量生长速率(即异速生长因子b)和肥满度呈现黎安港>新村湾>潭门港的趋势, 并与3个海草床的海草覆盖率、密度和生物量的变化趋势一致; 推测海草资源量下降可能增加鱼类的被捕食压力和减少食物来源, 从而导致生活于海草床的代表性鱼类生长速率下降。     

NaHSO3对两种微藻生长及胞外多糖和藻胆蛋白含量的影响

本文研究了0.25~3 mmol/L浓度的NaHSO3对紫球藻(Porphyridium violaceum)和0.06~0.96 mmol/L浓度的NaHSO3对蓝隐藻(Chroomonas placoidea)的叶绿素荧光参数(PSII最大光能转化效率Fv/Fm、相对电子传递速率rETR、光化学淬灭qP、非光化学淬灭NPQ)、细胞密度、干重、胞外多糖和藻胆蛋白含量的影响。研究表明,较低浓度的NaHSO3对紫球藻和蓝隐藻的生长及活性物质积累有促进作用,2种微藻进行生长和活性物质积累的最适NaHSO3浓度分别为0.5和0.12 mmol/L,此条件下,实验结束时,2种微藻的Fv/Fm、rETR、qP、细胞密度、干重、胞外多糖和藻胆蛋白含量均达到最大值,显著高于对照组。其中,紫球藻的最终细胞密度、干重、胞外多糖和藻胆蛋白含量分别比对照组增加了36.0%、19.1%、71.8%和69.0%。蓝隐藻的上述参数在NaHSO3浓度为0.12 mmol/L时则比对照组增加了60.8%、45.4%、60.0%和53.1%。另一方面,NaHSO3浓度为2~3 mmol/L时显著抑制紫球藻生长及活性物质积累,NaHSO3浓度为0.48~0.96 mmol/L则不利于蓝隐藻生长及活性物质积累。研究结果表明,适合紫球藻和蓝隐藻生长及胞外多糖和藻胆蛋白积累的最佳NaHSO3浓度分别为0.5和0.12 mmol/L,该研究为2种微藻的开发利用提供了理论依据。     

发展地理学研究进展与展望

本文回顾和总结了20世纪以来发展地理学的研究进展,涉及发展地理学内涵和理论、领域和方法及其发展趋势。系统梳理了发展地理学在欠发达国家或地区发展收敛、发达地区或国家生活品质提升过程中的收敛及其路径等研究内容。通过分析国外研究进展,指出了发展地理学在中国的发展条件与学科优势,并着眼于国际学术前沿最新动向与国家宏观战略需求,提出了今后中国发展地理学研究需重点关注的领域。未来发展地理学研究应以可持续发展理论为指引,以提升欠发达地区可持续生计能力与区域绿色发展水平为核心,以构建发展地理学理论和跨学科综合集成研究体系为目标,聚焦区域发展的空间格局、扩散特征与收敛研究,探索出服务于区域经济建设与产业发展的调控政策与科学路径。     

基于珠海实证的城市旅游增长极限分析框架

城市旅游是城市的一个开放、高流动的子系统,在一定时期内是相对稳定,有增长极限的。城市旅游增长极限受到供需极限影响,当旅游需求超过供给时,出现过度旅游;而当供给超过需求,就会导致过度旅游化。城市旅游需求增长极限呈现阶梯式,只有当影响城市旅游需求增长的长期因素发生持续重大变化时,城市旅游需求增长才可能突破原有的极限,进入一个新的阶段。城市旅游需求极限规定了城市旅游供给极限,决定了城市在一定时期内适合开发的景区、酒店、餐饮、购物等旅游设施规模。本文基于珠海的实证分析表明,过去十几年,由于旅游供需两方面影响因素缺乏持续重大的变化,城市功能和地位、城市主题和特色等因素相对稳定,加之受到区域其他城市的激烈竞争,珠海中高端旅游需求相对稳定,星级酒店等中高端旅游产品面临增长极限。此时,新增旅游景区和星级酒店并不会带来过夜旅游需求的实质增长,反而可能加剧现阶段旅游供需的失衡,造成过度旅游化。本文也讨论了超越旅游极限的条件以及旅游增长与旅游发展的关系,并进一步建议了旅游统计的改革举措。     

中国城市标度律及标度因子时空特征

城市标度律刻画了城市系统中城市要素与人口数量之间的规模缩放关系,但标度律在中国城市系统中的适用性和意义尚不明确。本文采用中国275个地级及以上城市数据,探究不同城市要素与人口规模的标度关系,并从时空维度探究标度因子的时空演化规律。结果表明：作为典型的快速城市化发展中国家,中国城市发展符合标度律,且呈现出与发达国家不同的特征：中国城市人口集聚带来的经济产出集聚效应显著,而土地利用、基础设施与公共服务的规模经济效应还有待增强。部分基础设施、生活设施要素与人口规模呈超线性或线性关系,与预期的次线性相悖,基础教育、医疗等要素的标度因子则远低于发达国家的次线性阈值,反映了公共资源向大城市聚集、不同规模城市发展不平衡等快速城镇化进程中城市系统的独特性。标度因子的区域分异反映城市发展协调程度差异,其中东北地区不同规模城市差异最为显著。主要城市要素标度因子随时间的变化表明,中国大城市的经济产出集聚效应在2009年最为显著,而后略有下降;中国大城市土地扩张总体上自2000年以来持续加速,2008年以后仍维持在较高水平,管控城市特别是大城市的外延式扩张、提高土地利用效率具有紧迫性。中国城市标度律研究有助于认知快速城市化地区城市系统特征和演化规律,为实现区域协调发展与落实新型城镇化发展战略提供支持。