Timing of brittle faulting and thermal events,Sydney region: association with the early stages of extension of East Gondwana

Structural studies in the Sydney region have revealed the presence of vertical to near-vertical, north-northeast-striking faults that are manifest as joint swarms and highly brecciated zones in which gouge of varying thickness is developed. Strike-slip movement accompanied by minor dip-slip, normal movement occurred on these faults. Timing of movement on these faults by K–Ar dating of illite and illite–smectite in fractions extracted from fault gouges, was attempted. These dates were compared with dates obtained from the host-rocks. K–Ar ages determined from the 2–10 μm to <0.1 μm fractions produced from the gouge and host-rocks, range from 159.5 ± 3.2 to 106.6 ± 2.1 Ma (n = 26). In <0.5 μm fractions extracted from the gouges that are less contaminated by detrital phases, K–Ar ages vary from 138 ± 4.4 to 106.5 ± 2.1 Ma (mean 121 Ma; n = 6) which are similar to ages obtained from host-rocks in the Sydney region. The similarity in age between the host rocks and gouge suggests that the K–Ar system has been reset. The resetting is attributed to a thermal event at ca 120 Ma related to the underplating of felsic intrusions associated with early stages of breakup of East Gondwana. Subsequent to this event, dykes of Early Eocene age (K–Ar whole-rock: 51.0 ± 1.1 Ma) exploited north-northeast-striking faults and subsequently developed brecciated margins. These observations and the fact that gouge formed before the thermal event suggests that movement took place on north-northeast-striking faults prior to 120 Ma and after 51 Ma.     

Age and composition of dykes emplaced before and during the opening of the Tasman Sea—source implications

Abstract

Dykes are common in the wave-cut platforms along the coast from Newcastle to Sydney. According to some authors, they may be related to the opening of the Tasman Sea that commenced ca 84?Ma ago. However, there are few detailed radiogenic dating and geochemical studies to evaluate this. We attempt to resolve this by K–Ar dating of plagioclase in and geochemical studies of, basaltic dykes intruding Permo-Triassic sequences on the wave-cut platforms and Carboniferous and Permo-Triassic sequences inland. The plagioclase separated from the dykes give K–Ar ages ranging from 266 to 53?Ma with the majority older than 84?Ma indicating that most dykes were emplaced before the Tasman Seafloor formation. The dykes are generally mildly alkaline, high-Ti basalts; fewer are tholeiitic and calc-alkaline, low-Ti basalts. Strongly light rare earth element (LREE)-enriched patterns typify the former and flat, LREE-depleted or slightly to moderately enriched LREE patterns, the latter. High-Ti basalts have ocean-island-basalt-like and low-Ti basalts, calc-alkaline or mid-ocean ridge basalt (MORB)-like patterns. Most high-Ti and some low-Ti basalts show plume-like characteristics, others N-type MORB and arc-like characteristics. Dykes intruding the Carboniferous sequences show a distinct contamination signature that could be crustal or due to subduction-related metasomatism of the subcontinental lithospheric mantle. The sources of the basaltic magmas vary substantially and in places changes with time. All alkali basalts are derived from enriched asthenospheric sources at varying depths (90–147?km) and most tholeiitic, low-Ti basalts have been extracted from asthenospheric and depleted asthenospheric–lithospheric sources indicating substantial compositional heterogeneity of the mantle. Further, Nd model ages varying from Neoproterozoic (940–580?Ma) to Paleozoic (460–370?Ma) suggest variation in the age of mantle sources for the basalts.     

A major change in magma sources in late Mesozoic active margin of the circum-Sea of Japan domain: Geochemical constraints from late Paleozoic to Paleogene mafic dykes in the Sergeevka belt,southern Primorye,Russia

More than 30 mafic dykes crop out in the Sergeevka belt in the coastal South Primorye, Far East Russia, of which geologic settings have been unclear for years. This study conducted major- and trace elements characterization, Sr–Nd isotope analyses, and Ar–Ar amphibole and U–Pb zircon datings for these rocks in order to identify their origin. The results demonstrated that all dykes are characterized by high Ba/Yb and low Nb/Y, Zr/Y, and Th/Yb ratios, which suggest their origin from arc melts derived from thin wedge mantle and shallow-dipping slab. These dykes are clearly separated into two distinct age/geochemistry suites; that is, the Paleogene and Early Cretaceous one with dolerites/basalts and adakitic rocks, and the Permian–Triassic one with high-Mg and high-Al gabbro-dolerite varieties. Their geochemistry suggests that the older suite was sourced from a primitive depleted MORB mantle (DMM)-type mantle, whereas the younger suite from an enriched mantle II (EM2)-type mantle domain. The transition in source type from DMM to EM2 occurred during the Jurassic-earliest Cretaceous time, probably by a strong influence of a mantle plume onto the long-continuing subduction-related magmatism. The plume influence reached the maximum when the unique meimechite-picrite complex formed in the region.     

Grain to outcrop-scale frozen moments of dynamic magma mixJing in the syenite magma chamber,Yelagiri Alkaline Complex,South India

Magma mixing process is unusual in the petrogenesis of felsic rocks associated with alkaline complex worldwide. Here we present a rare example of magma mixing in syenite from the Yelagiri Alkaline Complex, South India. Yelagiri syenite is a reversely zoned massif with shoshonitic (Na₂O + K₂O=5–10 wt.%, Na₂O/K₂O = 0.5–2, TiO₂ <0.7 wt.%) and metaluminous character. Systematic modal variation of plagioclase (An_11–16 Ab_82–88), K-feldspar (Or_27–95 Ab_5–61), diopside (En_34–40Fs_11–18Wo_46–49), biotite, and Ca-amphibole (edenite) build up three syenite facies within it and imply the role of in-situ fractional crystallization (FC). Evidences such as (1) disequilibrium micro-textures in feldspars, (2) microgranular mafic enclaves (MME) and (3) synplutonic dykes signify mixing of shoshonitic mafic magma (MgO = 4–5 wt.%, SiO₂ = 54–59 wt.%, K₂O/Na₂O = 0.4–0.9) with syenite. Molecular-scale mixing of mafic magma resulted disequilibrium growth of feldspars in syenite. Physical entity of mafic magma preserved as MME due to high thermal-rheological contrast with syenite magma show various hybridization through chemical exchange, mechanical dilution enhanced by chaotic advection and phenocryst migration. In synplutonic dykes, disaggregation and mixing of mafic magma was confined within the conduit of injection. Major-oxides mass balance test quantified that approximately 0.6 portions of mafic magma had interacted with most evolved syenite magma and generated most hybridized MME and dyke samples. It is unique that all the rock types (syenite, MME and synplutonic dykes) share similar shoshonitic and metaluminous character; mineral chemistry, REE content, coherent geochemical variation in Harker diagram suggest that mixing of magma between similar composition. Outcrop-scale features of crystal accumulation and flow fabrics also significant along with MME and synplutonic dykes in syenite suggesting that Yelagiri syenite magma chamber had evolved through multiple physical processes like convection, shear flow, crystal accumulation and magma mixing.     

http://www.sciencedirect.com/science/article/pii/S1674987113001151

Magma mixing process is unusual in the petrogenesis of felsic rocks associated with alkaline complex worldwide. Here we present a rare example of magma mixing in syenite from the Yelagiri Alkaline Comp...     

Structure of a hypovolcanic acid complex inferred from magnetic susceptibility anisotropy measurements: the Western Red Hills granites (Skye,Scotland, Thulean Igneous Province)

 The geochemistry and the injection mechanism of hypovolcanic ring dykes have been extensively studied, but such is not the case for their internal fabric. The Tertiary Western Red Hills epigranites of the Isle of Skye are a classic example of such intrusions. Using anisotropy of magnetic susceptibility measurements, we present the first structural data of their internal magmatic fabric. The magnetic foliations, equated with the magmatic flow planes, have strikes which roughly follow the walls of the different intrusions. They dip steeply toward the convex wall of each intrusion. The lineations, or maximal magnetic susceptibility axes, generally have shallow plunges, except in the latest granite intrusion. These structures appear to be related to the compressional deformation of each intrusion toward the end of its crystallization. This shortening would be a consequence of a radial and compressive stress field acting after each injection of magma. This radial stress field is interpreted as the effect of high magma pressures originating from the acid magma chamber underlying the ring-dyke complex at a shallow depth. Received: 10 October 1995 / Accepted: 4 June 1997     

Mafic and ultramafic magmatism and associated mineralization in the Dharwar craton,southern India

Evidence of mafic and ultramafic magmatism exists in many parts of the Dharwar craton which is divided into two blocks, the West Dharwar Craton (WDC) and the East Dharwar Craton (EDC). The mafic-ultramafic rocks occur in supracrustal/greenstone belts and in numerous enclaves and slivers in the WDC. The oldest recorded maficultramafic rocks, which are mainly komatiitic in nature, are preserved in the Sargur Group which is more than 3.3–3.4 Ga old, the youngest being manifested by 63–76 Ma old mafic dyke magmatism, possibly related to Deccan volcanism. In the Sargur Group, ultramafics rocks greatly dominate over mafic lithological units. Both extrusive and intrusive varieties, the latter in the form of differentiated layered complexes, occur. Mafic volcanics exists in all the greenstone belts of the eastern block and in the Bababudan and Western Ghats belts of the western block. In addition to the Sargur Group where stratigraphic sequences are unclear, mafic magmatism is recorded in three different formations of the Bababudan Group and two sub-divisions of the Shimoga and Chitradurga Groups where basaltic flows are conspicuous. In the well studied greenstone belts of Kolar and Hutti in the EDC, three to four different Formations of mafic volcanic rocks have been mapped. Isotopic dating has indicated that while mafic magmatism in the greenstone belts of the EDC covers only a short time span of between 2.65 to 2.75 Ga, those in the Dharwar Supergroup of the WDC cover a much longer time span from 3.35 to 2.5 Ga. Mafic dyke magmatism has taken place repeatedly from 2.45 Ga to about 1.0 Ga, but, the peak of emplacement was between 1.8 and 1.4 Ga when the densely developed swarms on the western and south western portions of the Cuddapah Basin and in the central part of Karnataka, were intruded. Emplacement of potassic ultramafic magma in the form of kimberlite-lamproite which is confined to the EDC, is a later magmatic event that took place between 1.4 Ga and 0.8 Ga. From a mineralization perspective, mafic magmatism of the supracrustal groups of the WDC and the greenstone belts of the EDC are the most important. V-Ti-magnetite bands constitute the most common deposit type recorded in the mafic-ultramafic complexes of the Sargur Group with commercially exploitable chromite deposits occurring in a number of belts. PGE mineralization of possible commercial value has so far been recorded in a single mafic-ultramafic complex, while copper-nickel mineralization occurs at certain localities in the Sargur and Chitradurga Groups. Gold mineralization hosted by mafic (occasionally ultramafic) rocks has been noted in many of the old workings located in supracrustal groups of rocks in the WDC and in the greenstone belts of EDC. Economically exploitable mineralization, however, occurs mainly in the greenstone belts of the Kolar, Ramagiri-Penkacherla and Hutti-Maski and along the eastern margin of the Chitradurga belt, where it is associated with a major N-S striking thrust zone separating the WDC from the EDC. Gold deposits of the eastern greenstone belts are comparable to those of the younger greenstone belts of Canada, Zimbabwe and Australia where the mineralization is associated with quartz carbonate veins often in iron-rich metabasic rocks. The gold was emplaced as hydrothermal fluids, derived from early komatiitic and tholeiitic magmas, and injected into suitable dilatent structures. The other common type of mineralization associated with the ultramafic rocks of the Sargur Group and supracrustal belts, particularly of the WDC, are asbestos and soapstone, related to autometamorphism/metasomatism. Ruby/sapphire deposits occur in places at the contacts of ultramafic rocks with the Peninsular Gneiss, and are related to contact metamorphism and metasomatism. Mineable magnesite deposits related to low-temperature hydrothermal/lateritic alteration exist in the zone of weathering, particularly in the more olivine-rich rocks. Recent spurt in diamond exploration is offering promise of discovering economically workable diamondiferous kimberlite/lamproite intrusions in the EDC.     

碳酸盐岩干酪根催化降解生烃过程及动力学研究

以甘肃平凉地区奥陶系碳酸盐岩干酪根为对象,利用热模拟实验方法和化工催化原理,从热解生烃组成特征、生烃量及生烃动力学等方面考察了不同介质对干酪根热解生烃过程的影响。结果表明,碳酸盐岩对干酪根生烃过程具有反催化作用,随着温度的增加,反催化作用越明显。膏岩CaSO₄则表现出正催化作用,各种盐类对干酪根生烃过程影响较小。干酪根热解动力学研究表明,生烃动力学参数活化能E与视频率因子A之间不是独立变化的,它们之间存在一定的关系,即:E与lnA呈线形关系,这对于认识碳酸盐岩干酪根的化学结构及热解生烃机理具有一定的参考价值。     

藏南彭措林埃达克质岩脉的岩石成因及对区域成矿作用的启示

彭措林岩脉群位于藏南冈底斯斑岩铜矿带中段的西侧,宽约3~5m,呈近南北向穿截冈底斯岩基。两组样品的锆石U-Pb定年结果为9.7±0.2Ma和9.9±0.3Ma。岩石地球化学研究显示,岩石以高SiO_2(67.05%~69.96%)、K_2O(6.05%~6.88%)和低MgO(0.47%~1.27%)为特征,高度富集轻稀土元素(LREE)和大离子亲石元素(LILE),亏损高场强元素(HFSE),具有高Sr/Y和La/Yb比值,表现出埃达克岩地球化学亲合性。相对冈底斯中新世埃达克质斑岩而言,该岩脉更加富集放射性成因Sr、Pb同位素(~(87)Sr/~(86)Sr_((i))=0.7120~0.7123,~(206)Pb/~(204)Pb=18.812~18.844,~(207)Pb/~(204)Pb=15.705~15.728,~(208)Pb/~(204)Pb=39.424~39.523)、具更低的Nd同位素值(εNd(t)=-10.9~-9.8)和更为古老的Nd模式年龄(tDM=1.36~1.43Ga)。以上地球化学分析表明,彭措林岩脉很可能起源于加厚的古老下地壳,相较于冈底斯斑岩铜矿带内其他的中新世斑岩而言,其岩浆源区含有更少的幔源组分和更多的古老地壳组分。锆石微量元素结果显示,岩脉的氧逸度较低(ΔFMQ=-6.7~+2.1,平均值为-1.4)。故而,彭措林埃达克质岩脉不具备区域成矿潜力的原因可以归结如下:(1)下地壳岩浆源区中新生幔源组分含量较少,指示了古老下地壳中岛弧幔源岩浆注入量较少,因而岛弧期堆晶至下地壳的金属硫化物极为有限;(2)较低的氧逸度导致岩浆萃取金属的能力相对较弱。结合前人研究可知,下地壳中新生幔源组分的贡献率是影响冈底斯斑岩铜矿带后碰撞埃达克岩能否成矿的关键因素。     

Geochemical characteristics of ophiolitic rocks from the southern margin of the Sivas basin and their implications for the Inner Tauride Ocean,Central-Eastern Turkey

Number of dismembered ophiolite bodies crop out between Sivas and Malatya on the top of the Eastern Tauride platform in the central-eastern Turkey. One of which at the southern margin of the Sivas basin in the Tecer Mountain area comprises melange and the lower part of an oceanic lithospheric section on top of the Tauride platform. The mantle tectonites are characterized by variably serpentinized harzburgites and dunites, and are intruded by numerous isolated dykes. The gabbroic cumulates consist of olivine gabbro, gabbro and gabbronorite. The major and trace element geochemistry of the mafic cumulate rocks suggests that the primary magma was compositionally similar to those observed in modern island-arc tholeiitic sequences. The isolated dykes are exclusively basaltic in composition and display geochemically two distinct subgroups: Group I is represented by high TiO₂ (.87–1.47 wt.%) and other incompatible elements, whereas Group II is characterized by low TiO₂ (.36–.66 wt.%) and other incompatible elements. The Group I isolated diabase dykes have flat to slightly LREE-depleted profiles (La/Yb_N = .32–.79), whereas the Group II isolated diabase dykes are more depleted in general and have a LREE-depleted character (La/Yb_N = .19–.49). This suggests that the isolated dykes were derived from an island arc tholeiitic magma (Nb/Y = .02–.05) with different degrees of partial melting (Group II > Group I) and relatively high oxygen fugacity in intra-oceanic subduction zone. The ophiolitic rocks in the study area may well be compared with the Divri?i ophiolite to the southeast. All the evidence suggests that the isolated dykes in the Tecer Mountain area differ from the alkaline isolated dykes cutting the Divri?i ophiolite. Since the late stage dykes (~76 Ma) in the Divri?i area are alkaline, the tholeiitic isolated dykes in the present study should have been emplaced prior to the alkaline dykes during Late Cretaceous SSZ-spreading (~90 Ma) within the Inner Tauride Ocean.