柴达木盆地西部第三系咸水湖相原油地球化学特征

在系统分析柴达木盆地西部各油田40余个原油样品碳同位素和饱和烃、芳烃组成的基础上,全面剖析了该地区第三系湖相原油的地球化学特征.研究结果表明,这些原油具有特殊的碳同位素组成和异常的生物标志物分布.其全油碳同位素偏重(-26‰～-24‰);正构烷烃系列单体烃碳同位素分布曲线呈水平状,表现出类同于海相有机质的碳同位素组成特征.它们的生物标志物中正烷烃系列兼具奇碳和偶碳优势双重碳数分布模式;呈强植烷优势,Pr/Ph值大多<0.6;伽玛蜡烷普遍异常丰富,C35藿烷含量高,表征高盐、厌氧的咸水湖相沉积环境性质.芳烃组份以萘、菲系列为主,而二苯并噻吩等含硫有机化合物相对含量较低,反映该地区咸水湖相原油源岩沉积相的特殊性.柴西各油田原油地球化学参数在区域上呈规律性变化趋势,与其源岩沉积相的时空变迁相一致.     

Spatial variation in shallow sediment methane sources and cycling on the Alaskan Beaufort Sea Shelf/Slope

The MITAS (Methane in the Arctic Shelf/Slope) expedition was conducted during September, 2009 onboard the U.S. Coast Guard Cutter (USCGC) Polar Sea (WAGB-11), on the Alaskan Shelf/Slope of the Beaufort Sea. Expedition goals were to investigate spatial variations in methane source(s), vertical methane flux in shallow sediments (<10 mbsf), and methane contributions to shallow sediment carbon cycling. Three nearshore to offshore transects were conducted across the slope at locations approximately 200 km apart in water column depths from 20 to 2100 m. Shallow sediments were collected by piston cores and vibracores and samples were analyzed for sediment headspace methane (CH₄), porewater sulfate (SO₄²⁻), chloride (Cl⁻), and dissolved inorganic carbon (DIC) concentrations, and CH₄ and DIC stable carbon isotope ratios (δ¹³C). Downward SO₄²⁻ diffusion rates estimated from sediment porewater SO₄²⁻ profiles were between −15.4 and −154.8 mmol m⁻² a⁻¹ and imply a large spatial variation in vertical CH₄ flux between transects in the study region. Lowest inferred CH₄ fluxes were estimated along the easternmost transect. Higher inferred CH₄ flux rates were observed in the western transects. Sediment headspace ${\mathrm{\delta }}^{13}{\text{C}}_{{\text{CH}}_4}$ values ranged from −138 to −48‰, suggesting strong differences in shallow sediment CH₄ cycling within and among sample locations. Measured porewater DIC concentrations ranged from 2.53 mM to 79.39 mM with δ¹³C_DIC values ranging from −36.4‰ to 5.1‰. Higher down-core DIC concentrations were observed to occur with lower δ¹³C where an increase in ${\mathrm{\delta }}^{13}{\text{C}}_{{\text{CH}}_4}$ was measured, indicating locations with active anaerobic oxidation of methane. Shallow core CH₄ production was inferred at the two western most transects (i.e. Thetis Island and Halkett) through observations of low ${\mathrm{\delta }}^{13}{\text{C}}_{{\text{CH}}_4}$ coupled with elevated DIC concentrations. At the easternmost Hammerhead transect and offshore locations, ${\mathrm{\delta }}^{13}{\text{C}}_{{\text{CH}}_4}$ and DIC concentrations were not coupled suggesting less rapid methane cycling. Results from the MITAS expedition represent one of the most comprehensive studies of methane source(s) and vertical methane flux in shallow sediments of the U.S. Alaskan Beaufort Shelf to date and show geospatially variable sediment methane flux that is highly influenced by the local geophysical environment.     

海水中溶解态铵盐氮同位素分析的预处理方法

以蒸馏法为基础, 研究了适合海水中铵盐稳定氮同位素分析的预处理方法。对蒸馏法预处理过程中的最佳蒸馏时间、沸石的选取、铵盐最适浓度范围等分别进行改进和优化, 获得稳定、高效的海水中铵盐氮稳定同位素分析预处理方法。结果表明: 最佳蒸馏时间为50 min, 铵盐的回收率为(97±5.8)%。测定了不同沸石对不同浓度氨氮的吸附率, 筛选出酸性条件下铵氮吸附效率较高且稳定的康华科技沸石; 确定铵盐的最佳适用浓度范围为2～10 μmol/L, 在该浓度范围内氮回收率94%～99%,氮分馏系数为0.1‰～0.8‰。将此方法应用于长江口海域水样分析, 结果表明, 这一方法可以应用于河口中铵盐的氮同位素分析, 能够为河口中溶解态氮的来源及循环机理等研究提供有效信息。     

南海北部陆坡ZSQD196PC柱状样末次间冰期以来的古海洋学记录：氧同位素、有孔虫和硅藻

为了解南海北部陆坡末次间冰期以来的古海洋沉积环境演化特征,对研究区ZSQD196PC柱状样有孔虫、硅藻及有孔虫氧同位素资料开展了分析。依据沉积有孔虫、硅藻主要属种的百分含量、丰度及组合特征,将有孔虫划分为3个组合,分别对应于氧同位素MIS1、2、3~4期;将硅藻划分为4个组合,大致对应于MIS1~4期。MIS1期有孔虫以暖水种占优势,Pulleniatina obliquiloculata百分含量显著升高;硅藻丰度低且以热性种占优势,其中冷期出现大量沿岸种,反映相对温暖的气候条件。MIS2~4期有孔虫以冷水种占优势,温跃层种含量相对较高;硅藻丰度高且以广布种占优势,出现沿岸种含量的升高,反映较冷的气候条件。通过对比浮游有孔虫氧同位素,分析讨论了末次盛冰期、Blling—Allerd暖期和新仙女木事件在ZSQD196PC柱状样的沉积响应,揭示了末次冰期中的气候波动。     

云南兰坪盆地北部东缘铅锌矿床喷流沉积成因的厘定———来自矿物学和硫同位素证据

通过详细的野外地质工作和显微镜下观察,对云南兰坪盆地东北部维西—乔后断裂带上三叠统石钟山组(T₃s)中产出的铅锌矿床成因进行厘定。研究结果表明,测区内存在大量典型的同生沉积矿床标志,如:纹层构造、条纹条带构造、网脉构造、黄铁矿条带软沉积构造、黄铁矿草莓状结构、黄铁矿胶状构造、闪锌矿同心环状构造等。青甸湾矿床金属硫化物硫同位素测试结果显示,黄铁矿的δ34 S介于3.7‰ ~ 8.1‰,均值5.34‰; 闪锌矿的δ34 S介于5.2‰ ~ 10.0‰之间,均值为7.18‰; 方铅矿的δ34 S介于5.2‰ ~ 9.9‰之间,均值为7.275‰,铅锌矿床硫来源于海水硫酸根无机还原。结合矿床形成时代及大地构造背景,认为该区铅锌矿为喷流沉积作用形成。      

Stable Isotope Composition of Rainfall,Surface Water and Groundwater along the Yellow River

The intention of this work is to consider the stable isotopic compositions of oxygen and deuterium in rainfall, surface water and groundwater along the Yellow River in the North China Plain (NCP). This demonstrated that the δ18O values in groundwater varied from –10.17 to –6.85‰, with mean value of –8.76‰, and that the δD ranged from –68.7 to –58.0‰, with mean value of –63.4‰, respectively. The δ18O values in surface water varied from –8.36 to 1.32‰, with mean value of –6.8‰, and δD ranged from –64.4 to –35.1‰, with mean value of –57.6‰, respectively. Further, The range of Cl- values of groundwater varied from 5.9 to 340.5 mg/L and that values ranged from 30.1 to 81.9 mg/L in surface water samples and Na+ value changed from 27.4 to 321 mg/L in groundwater, while that in surface water varied from 24.8 to 50.5 mg/L. Most of the points fall below the GMWL?, but are close to the LMWL.? Therefore the results indicated that the groundwaters along the Yellow River were influenced by rainfall in heavy events and surface water.     

松辽盆地南部浅层天然气地球化学特征及其成因分析

由于松辽盆地南部浅层天然气成因研究比较薄弱,通过采集伏龙泉地区泉头组天然气样品,对天然气组分、碳同位素、轻烃组分进行了分析。结果表明该地区天然气有油型气和生物降解气2种成因。第一类天然气甲烷碳同位素值在-35‰左右,甲烷及其同系物碳同位素呈正碳分布;甲基环己烷指数在20%左右、环己烷指数略高于10%,符合油型气的特征。由甲烷碳同位素计算的R₀值,以及轻烃中的庚烷值和异庚烷值均在高-过成熟的范围,因此是高成熟的油型气。第二类天然气甲烷碳同位素偏轻,丙烷碳同位素偏重;轻烃色谱图中以环烷烃为主峰,轻烃内组成中支链烷烃和环烷烃含量高,各项轻烃参数(甲基环己烷指数、庚烷值、K1值等)都在较大范围内波动,为生物降解气。这一研究对于今后该区天然气勘探与资源评价及其成藏机理研究具有重要意义。     

重庆地区岩溶地下河水溶解无机碳及其稳定同位素特征

稳定碳同位素是指示岩溶动力系统碳来源及转化的重要指标。为揭示重庆地区岩溶地下水中溶解无机碳基本特征和碳来源,本文对该地区63条岩溶地下河水样进行了水化学和碳同位素分析。研究结果表明,重庆地区地下河水溶解无机碳主要表现形式为HCO3-,雨季由于稀释作用其浓度低于旱季。重庆岩溶地下河水δ13C-DIC（V-PDB）旱季变化范围为-15.34 ‰～-5.89 ‰,雨季变化范围为-17.40 ‰～-4.23 ‰。根据δ13C同位素质量平衡方法,计算得到重庆地下河旱季碳酸盐岩溶蚀对DIC贡献为45.1 % ～79.7 %,雨季平均为34.6 %～82.1 % 。计算结果表明,在人类活动不断增强的情况下,岩溶水体DIC通量中碳酸盐岩溶解来源的DIC和其参与岩溶地下水δ13C值的形成并不一定是岩溶作用理论方程中所计算的50 %,而是有一定的变化范围。因此在计算岩溶作用碳汇时,建议通过δ13C值扣除碳酸盐岩溶蚀形成DIC的通量后再来推算岩溶作用形成的碳汇量。      

基于15N同位素技术的岩溶地下河硝酸盐污染变化特征研究——以重庆青木关地下河为例

根据2010年5月至2010年10月每月对青木关地下河河水的监测数据,利用15N同位素技术并结合水化学指标,分析地下河的水化学特征以及硝态氮来源的时空变化特征。结果表明,地下河出口丁家龙洞硝态氮浓度(5.077mg/L)比入口天池硝态氮浓度(0.842mg/L)高6倍多。入口天池处地下河河水硝态氮浓度比较低,δ15N浓度变化范围为-7.0475‰~+7.059‰,变化幅度不大,说明该点的氮污染较低,地下水受外界影响较小,污水和粪便不是主要的δ15N来源。出口丁家龙洞处的δ15N浓度变化范围在-21.453‰~+37.825‰,总体浓度高且变化幅度大,受上游养猪场粪便直接排入及降水影响较大。