Determination of Molybdenum, Antimony and Tungsten at sub μg g−1 Levels in Geological Materials by ID-FI-ICP-MS

We have developed a rapid and accurate method for the determination of Mo, Sb and W in geological samples using isotope dilution inductively coupled plasma-mass spectrometry with a flow injection system (ID-FI-ICP-MS). The chemical procedure requires HF digestion of the sample with a Mo-Sb-W mixed spike, subsequent evaporation and dissolution of Mo, Sb and W from Mg and Ca fluorides with HF. Recovery yields of Mo, Sb and W in the extraction were > 94% for samples of peridotite, basalt and andesite composition, with the exception of W in samples of peridotite composition for which recovery was 81%. No matrix effects were observed in the determination of the isotope ratios of Mo, Sb and W in solutions prepared from peridotite, basalt and andesite samples down to a dilution factor of 100. Detection limits of Mo, Sb and W in silicate materials were at the several ng g⁻¹ level. Analysis of the silicate reference materials PCC-1, DTS-1, BCR-1, BHVO-1, AGV-1 from the US Geological Survey and JP-1, JB-1, -2, -3, JA-1, -2, and -3 from the Geological Survey of Japan as well as the Smithsonian reference Allende powder yielded reliable Mo, Sb and W concentrations. The repeatability in the analysis of basalts and andesites was < 9%. This technique requires only 0.2 ml sample solution, and is therefore suitable for analyzing small and/or precious samples such as meteorites, mantle peridotites and their mineral separates.     

An Interpretation of ISO Guidelines for the Certification of Geological Reference Materials

Recommendations for the certification of reference materials, as published by the International Organisation for Standardisation (ISO), are reviewed and proposals made as to how they can be adapted for the certification of new geological reference materials. Whilst acknowledging the important contribution made by the large number of existing matrix-matched geological reference materials, it is recommended that future characterisation programmes should follow the ISO guidelines for certification, not the least so that laboratories can readily use the resultant samples to establish the traceability of geoanalytical results.     

Geochemistry,mineralogy and petrogenesis of the northeast Niğde volcanics,central Anatolia,Turkey

The volcanics exposed in the northeast Niğde area are characterized by pumiceous pyroclastic rocks present as ash flows and fall deposits and by compositions ranging from dacite to rhyolite. Xenoliths found in the volcanics are basaltic andesite, andesite and dacite in composition. These rocks exhibit linear chemical variations between end‐member compositions and a continuity of trace element behaviour exists through the basaltic andesite–andesite–dacite–rhyolite compositional range. This is consistent with the fractionation of ferromagnesian minerals and plagioclase from a basaltic andesite or andesite parent. These rocks are peraluminous and show typical high‐K calc‐alkaline differentiation trends with total iron content decreasing progressively with increasing silica content. Bulk rock and mineral compositional trends and petrographic data suggest that crustal material was added to the magmas by subducted oceanic crust and is a likely contaminant of the source zone of the Niğde magmas. The chemical variations in these volcanics indicate that crystal liquid fractionation has been a dominant process in controlling the chemistry of the northeast Niğde volcanics. It is also clear, from the petrographic and chemical features, that magma mixing with disequilibrium played a significant role in the evolution of the Niğde volcanic rocks. This is shown by normal and reverse zoning in plagioclase and resorption of most of the observed minerals. The xenoliths found in the Niğde volcanics represent the deeper part of the magma reservoir which equilibrated at the higher pressures. Copyright © 2002 John Wiley & Sons, Ltd.     

AVOA techniques for fracture characterization

Different aspects of computational techniques for AVOA analysis (Amplitude Versus Offset and Azimuth) for fracture characterization are considered, in particular: using amplitudes instead of reflection coefficients, smoothing seismic data, and numerical methods for estimation of fracture directions. A new computational method and a new filter for smoothing are suggested. The different computational methods are compared in synthetic reflection surface data with noise, and without noise. Properties of the numerical methods in dependence on different sets of azimuths and offsets are obtained. It is shown a superiority of the new method.     

Sensitivity of the surface temperature to changes in total solar irradiance calculated with the WRF model

The temperature sensitivity of the WRF model to changes in Total Solar Irradiance (TSI). The simulations were performed for a region centered over the North Atlantic Ocean, including portions of Eastern North America, Western Europe and Northwest Africa. Four simulations were run with different TSI values. Also, a fifth simulation was performed in which we varied the initial atmospheric conditions, in order to compare the effect on the temperature of both, changes in the TSI and initial atmospheric conditions. Comparing temperature monthly averages we found that changes in TSI and in the initial conditions have a measurable impact on temperature in the region of study. The sensitivity of the model using non-dimensional parameters was also estimated. The numerical experiments show some features that might allow to distinguish between the effects on the temperature due to changes in TSI from those caused by initial conditions. However, TSI changes are of the same order of magnitude than those of disturbances in the initial conditions. We also found that the mean monthly values of temperature over the full grid, did not present significant variations due to changes of either initial conditions or TSI.     

稻城冰帽库照日冰碛垄的宇生核素10Be年代测定

沙鲁里山南端的稻城冰帽在第四纪曾发生过大规模的冰川作用,然而,关于冰川作用的年代数据相对较少。选择稻城冰帽南缘库照日附近的3套冰碛垄进行宇生核素10Be的暴露年代测定,研究结果表明:(1)库照日最老冰碛垄(E)的暴露年代为(714±8.0)～(529±8.0)kaBP,D垄的暴露年代为(121±2.9)～(114±2.9)kaBP,DC垄的暴露年代为(47±1.3)～(43±1.3)kaBP。由于宇生核素暴露年代所反映的是冰川消退时的年代,因此,我们结合深海氧同位素的气候特征以及其他测年数据推断,E垄、D垄、DC垄可能是MIS16、MIS6以及MIS3b阶段冰川作用的产物;(2)冰川退却是一种逐步退却的模式。样品E的两次测验结果比较吻合,表明宇生核素10 Be暴露测年方法对冰碛垄形成年代的测定是可靠的,该方法在地貌学和第四纪年代学研究中有着巨大的潜力。     

Polymetallic (Pb-Zn-Cu-Ag ± Au) vein-type deposits in brittle-ductile transtensional shear zones,Eastern Sierras Pampeanas (Argentina): Age constraints and significance for the Late Paleozoic tectonic evolution and metallogenesis

This paper discusses new structural, kinematic and geochronological data from polymetallic (Pb-Zn-Cu-Ag ± Au) vein-type deposits hosted in the metamorphic basement of the southern Sierras de Córdoba. A Carboniferous age was established for the hydrothermal event between ∼329 and 315 Ma (Late Mississippian-Early Pennsylvanian) by the K/Ar fine-fraction dating method of sericitic alteration related to metallic ore deposition in the Las Guindas and Oro districts. The obtained ages postdate the spatially associated Devonian magmatism and overlap the A-type Early Carboniferous magmatism defined for the Eastern Sierras Pampeanas. The presence of non-exhumed granitic bodies at shallow depths, possibly related to mineralization, is supported by available geophysical and field evidence.The strain fabric and 3-D kinematic analyses constitute first kinematic data for the Carboniferous basement of the Southern Sierras Pampeanas demonstrating that mineralization was controlled by NNW- and ENE-trending brittle-ductile transtensional shear zones that overprint the earlier high-strain deformation fabrics of the basement. Transtensional deformation has accommodated large amounts of strike-slip movements and subordinated extensional components. The calculated kinematic axes indicate a coherent kinematic pattern of the mineralized systems in the two studied districts, with a maximum extension direction oriented NNE- to NE and maximum shortening direction oriented WNW- to NW. This deformation regime, active during mineralization, point to a non-compressive setting at the Late Mississippian-Early Pennsylvanian boundary. In line with other regional evidence, we propose a distinctive Carboniferous deformational phase in the Eastern Sierras Pampeanas, dominated by transtension. This period would have occurred after the transition with the Devonian compressional/transpressional orogenic regime.     

Flows,system boundaries and the politics of urban metabolism: Waste management in Mexico City and Santiago de Chile

In this paper we examine two central concepts of urban metabolism (‘system boundaries’ and ‘flows’), and explore how to approach them as a means to politicise urban metabolism research. We present empirical findings from two case studies of waste management, in Mexico City and Santiago de Chile, looking at: the materiality of waste flows, the actors involved in them, and how waste flows relate to issues of environmental justice. We argue that urban metabolism, as a methodology to understand urban sustainability, has the potential to produce knowledge to trigger urban transformations, and to analyse the social, political and environmental aspects of waste management in urban areas.     

Diagenesis and anthropogenesis of metals in the recent Holocene sedimentary record of the Ría de Vigo (NW Spain)

To contribute to establishing a historical baseline for future evaluations of the environmental quality of the Ría de Vigo (NW Spain), we report metal contents determined in eight gravity cores obtained at representative locations in 1990 - before the installation of any wastewater treatment plants - and in fractions thereof that were obtained by the BCR sequential extraction method. The results suggest that early diagenesis had been influenced by both hydrodynamic conditions and organic matter input (the latter especially in areas devoted to mariculture), and that anthropogenic inputs had also affected the concentrations and between-fraction distribution of Cu, Pb, Zn and other metals in surficial sediments.